In order to evaluate the applicability of the organic polymeric flocculants(OPF) in the treatment of oil refinery sludge, experiments were conducted to show that OPF have better performance of flocculation than inorga...In order to evaluate the applicability of the organic polymeric flocculants(OPF) in the treatment of oil refinery sludge, experiments were conducted to show that OPF have better performance of flocculation than inorganic flocculants. Both the anionic and cationic OPF have satisfactory flocculation efficiency in oil sludge treatment, but the latter are more cost efficient. Among the over 20 types of flocculants tested, 2 OPF(CPAM 2 and HPAM 2) were selected as the treatment agents, based on their good treatment performances, oil resistance and economic feasibility. It was demonstrated in the industrial scale centrifugal dewatering experiments that the application of either CPAM 2 or HPAM 2 could achieve high treatment efficiency of the oil sludge dewatering and reduce the COD of centrifugal liquid to less than 1000 mg/L.展开更多
In this study, a novel flocculant was prepared by an inorganic polymetric flocculant (IPF) - polysilicate ferro- aluminum sulfate (PSFA) and rectorite (REC). The structure of the PSFA-REC composite was characterized b...In this study, a novel flocculant was prepared by an inorganic polymetric flocculant (IPF) - polysilicate ferro- aluminum sulfate (PSFA) and rectorite (REC). The structure of the PSFA-REC composite was characterized by Fourier transform infrared (FT-IR) spectroscopy and X-ray diffraction (XRD), in order to determine the optimal temperature. The flocculation test was made at 25℃, 45℃ and 65℃, the results indicated that when the temperature was 65℃, the removal efficiency of the oil and COD was the best, which was 87.2% and 92.6% respectively. Then by comparisons among rectorite (REC), PSFA and the composite PSFA-REC at the temperature of 65℃ and the optimal dosage of 11 mg/L, the composite PSFA-REC showed better flocculation performance than flocculant REC and PSFA alone.展开更多
After conducting a lot of screening experiments the appropriate flocculating formulations for treating high-concentration wastewater discharged from a certain refinery were selected. The oil removal rate and COD remov...After conducting a lot of screening experiments the appropriate flocculating formulations for treating high-concentration wastewater discharged from a certain refinery were selected. The oil removal rate and COD removal achieved by these flocculating formulations were better than that achieved by the conventional compound formulation consisting of polyaluminium chloride(PAC) and polyacrylamide(PAA) . Addition of an oil/water separating agent to the formulation could improve its oil removal performance to facilitate the oil/water separation of the oil-in-water emulsion in the high-concentration wastewater along with improved adaptability of the formulation to the wastewater containing high concentration of pollutants. This flocculating agent has promising prospects for commercial application.展开更多
The use of new food grade polysaccharides (mucilage) obtained from Hibiscus esculentus and Trigonella foenum graceum,commonly called Okra and Fenugreek,respectively,as flocculants was described.These polysaccharides w...The use of new food grade polysaccharides (mucilage) obtained from Hibiscus esculentus and Trigonella foenum graceum,commonly called Okra and Fenugreek,respectively,as flocculants was described.These polysaccharides were used for removal of solids (suspended solids (SS) and total dissolved solids (TDS)) and dyes from real textile effluents and aqueous solutions of different class of synthetic dyes.Influences of varying polysaccharide concentration,contact time and pH on removal of pollutant from the textile...展开更多
In this study,a high-efficiency cationic flocculant,P(DAC-MAPTAC-AM),was successfully prepared using UV-induced polymerization technology.The monomer Acrylamide(AM):Acryloxyethyl Trimethyl ammonium chloride(DAC):metha...In this study,a high-efficiency cationic flocculant,P(DAC-MAPTAC-AM),was successfully prepared using UV-induced polymerization technology.The monomer Acrylamide(AM):Acryloxyethyl Trimethyl ammonium chloride(DAC):methacrylamido propyl trimethyl ammonium chloride(MAPTAC)ratio,monomer concentration,photoinitiator concentration,urea content,and cationic monomer DAC:MAPTAC ratio,light time,and power of highpressure mercury lamp were studied.The characteristic groups,characteristic diffraction peaks,and characteristic proton peaks of P(DAC-MAPTAC-AM)were confirmed by fourier transform infrared spectroscopy(FTIR),X-Ray diffraction(XRD),1H nuclear magnetic resonance spectrometer(1H NMR),and scanning electron microscopy(SEM).The effects of dosage,pH value,and velocity gradient(G)value on the removal efficiencies of turbidity,COD,ammonia nitrogen,and total phenol by poly aluminum ferric chloride(PAFC),P(DACMAPTAC-AM),and PAFC/P(DAC-MAPTAC-AM)in the flocculation treatment of coal chemical wastewater were investigated.Results showed that the optimal conditions for the flocculation of coal chemical wastewater using P(DAC-MAPTAC-AM)alone are as follows:dosage of 8-12 mg/L,G value of 100-250 s^-1,and pH value of 4-8.The optimal dosage of PAFC is 90-150 mg/L with a pH of 2-12.The optimal dosage for PAFC/P(DAC-MAPTAC-AM)is as follows:PAFC dosage of 90-150 mg/L,P(DAC-MAPTAC-AM)dosage of 8-12 mg/L,and pH range of 2-6.When P(DAC-MAPTAC-AM)was used alone,the optimal removal efficiencies of turbidity,COD,ammonia nitrogen,and total phenol were 81.0%,35.0%,75.0%,and 80.3%,respectively.PAFC has good tolerance to wastewater pH and good pH buffering.Thus,the flocculation treatment of coal chemical wastewater using the PAFC/P(DAC-MAPTAC-AM)compound also exhibits excellent resistance and buffering capacity.展开更多
In our previous studies,several papermaking sludge-based flocculants(PSBFs)were synthesized from wood pulp papermaking sludge.The structure-activity relationships of the PSBFs have been investigated in simulated dye w...In our previous studies,several papermaking sludge-based flocculants(PSBFs)were synthesized from wood pulp papermaking sludge.The structure-activity relationships of the PSBFs have been investigated in simulated dye wastewater treatment,but their efficiencies in practical printing and dyeing wastewater(PPDW)treatment are unknown.Herein,an PSBF was prepared,and its performance is discussed in comparison to polyaluminium chloride(PAC)and polyacrylamide(PAM)in PPDW treatment.The PSBF was used in three ways:as an independent flocculant,as a PAC aid,or used to treat the effluent of the PAC system.The results indicated that adding PSBF alone produced similar color and chemical oxygen demand(COD_(Cr))removals as the PAC system alone,but PSBF performed better than PAC when the pH of PPDW was higher than 7.0.Adding PSBF as a PAC aid improved the color,COD_(Cr)and turbidity removals,but the elimination efficiencies were slightly lower than those of the PAC+PAM system.However,when PSBF was used as a flocculant to treat the effluent of the PAC system(PAC→PSBF),the effluent qualities were enhanced.Compared with the PAC system,the color and COD_(Cr)removals of PAC→PSBF system increased by 16.21%and 13.26%,respectively.The excitation and emission matrix fluorescence results indicated that PSBF removed tryptophan-like pollutants more efficiently than PAC.Considering the pH requirements of the subsequent bioreactor treatment in practice,the PAC→PSBF system were also investigated at the PPDW pH level of 7.0.Its maximum removal efficiencies of color,COD_(Cr)and turbidity were 90.17%,32.60%and 82.50%,respectively.展开更多
Poly(2-hydroxyethylmethacrylate) chains were grafted onto the backbone of agar using a microwave assisted method involving a combination of microwave irradiation and ceric ammonium nitrate to initiate the grafting r...Poly(2-hydroxyethylmethacrylate) chains were grafted onto the backbone of agar using a microwave assisted method involving a combination of microwave irradiation and ceric ammonium nitrate to initiate the grafting reaction. The synthesized graft copolymers were characterized by intrinsic viscosity measurements, Fourier transform infrared spectroscopy, elemental analysis (C, H, N, O and S) and scanning electron microscopy. Ag-g-P (HEMA)-2 showed a much higher flocculation efficacy than agar. The optimized dosage of flocculation for Ag-g-P (HEMA)-2 in the wastewater was found to be 0.75 ppm. Compared to agar, Ag-g-P(HEMA)-2 was found to considerably reduce the pollutant load in the wastewater.展开更多
Although microbial treatments of heavy metal ions in wastewater have been studied, the removal of these metals through incorporation into carbonate minerals has rarely been reported. To investigate the removal of Fe^3...Although microbial treatments of heavy metal ions in wastewater have been studied, the removal of these metals through incorporation into carbonate minerals has rarely been reported. To investigate the removal of Fe^3+ and Pb^2+, two representative metals in wastewater, through the precipitation of carbonate minerals by a microbial flocculant (MBF) produced by Bacillus mucilaginosus. MBF was added to synthetic wastewater containing different Fe^3+ and Pb^2+ concentrations, and the extent of flocculation was analyzed. CO2 was bubbled into the mixture of MBF and Fe^3+/Pb^2+ to initiate the reaction. The solid substrates were analyzed via X-ray diffraction, transmission electron microscopy and energy dispersive spectroscopy. The results showed that the removal efficiency decreased and the MBF adsorption capacity for metals increased with increasing heavy metal concentration. In the system containing MBF, metals (Fe^3+ and Pb^2+), and CO2, the concentrated metals adsorbed onto the MBF combined with the dissolved CO2, resulting in oversaturation of metal carbonate minerals to form iron carbonate and lead carbonates. These results may be used in designing a method in which microbes can be utilized to combine CO2 with wastewater heavy metals to form carbonates, with the aim of mitigating environmental problems.展开更多
文摘In order to evaluate the applicability of the organic polymeric flocculants(OPF) in the treatment of oil refinery sludge, experiments were conducted to show that OPF have better performance of flocculation than inorganic flocculants. Both the anionic and cationic OPF have satisfactory flocculation efficiency in oil sludge treatment, but the latter are more cost efficient. Among the over 20 types of flocculants tested, 2 OPF(CPAM 2 and HPAM 2) were selected as the treatment agents, based on their good treatment performances, oil resistance and economic feasibility. It was demonstrated in the industrial scale centrifugal dewatering experiments that the application of either CPAM 2 or HPAM 2 could achieve high treatment efficiency of the oil sludge dewatering and reduce the COD of centrifugal liquid to less than 1000 mg/L.
文摘In this study, a novel flocculant was prepared by an inorganic polymetric flocculant (IPF) - polysilicate ferro- aluminum sulfate (PSFA) and rectorite (REC). The structure of the PSFA-REC composite was characterized by Fourier transform infrared (FT-IR) spectroscopy and X-ray diffraction (XRD), in order to determine the optimal temperature. The flocculation test was made at 25℃, 45℃ and 65℃, the results indicated that when the temperature was 65℃, the removal efficiency of the oil and COD was the best, which was 87.2% and 92.6% respectively. Then by comparisons among rectorite (REC), PSFA and the composite PSFA-REC at the temperature of 65℃ and the optimal dosage of 11 mg/L, the composite PSFA-REC showed better flocculation performance than flocculant REC and PSFA alone.
文摘After conducting a lot of screening experiments the appropriate flocculating formulations for treating high-concentration wastewater discharged from a certain refinery were selected. The oil removal rate and COD removal achieved by these flocculating formulations were better than that achieved by the conventional compound formulation consisting of polyaluminium chloride(PAC) and polyacrylamide(PAA) . Addition of an oil/water separating agent to the formulation could improve its oil removal performance to facilitate the oil/water separation of the oil-in-water emulsion in the high-concentration wastewater along with improved adaptability of the formulation to the wastewater containing high concentration of pollutants. This flocculating agent has promising prospects for commercial application.
文摘The use of new food grade polysaccharides (mucilage) obtained from Hibiscus esculentus and Trigonella foenum graceum,commonly called Okra and Fenugreek,respectively,as flocculants was described.These polysaccharides were used for removal of solids (suspended solids (SS) and total dissolved solids (TDS)) and dyes from real textile effluents and aqueous solutions of different class of synthetic dyes.Influences of varying polysaccharide concentration,contact time and pH on removal of pollutant from the textile...
基金National Key Research and Development Program of China(No.2017YFB0602500)2018 Six Talent Peaks Project of Jiangsu Province(No.JNHB-038)。
文摘In this study,a high-efficiency cationic flocculant,P(DAC-MAPTAC-AM),was successfully prepared using UV-induced polymerization technology.The monomer Acrylamide(AM):Acryloxyethyl Trimethyl ammonium chloride(DAC):methacrylamido propyl trimethyl ammonium chloride(MAPTAC)ratio,monomer concentration,photoinitiator concentration,urea content,and cationic monomer DAC:MAPTAC ratio,light time,and power of highpressure mercury lamp were studied.The characteristic groups,characteristic diffraction peaks,and characteristic proton peaks of P(DAC-MAPTAC-AM)were confirmed by fourier transform infrared spectroscopy(FTIR),X-Ray diffraction(XRD),1H nuclear magnetic resonance spectrometer(1H NMR),and scanning electron microscopy(SEM).The effects of dosage,pH value,and velocity gradient(G)value on the removal efficiencies of turbidity,COD,ammonia nitrogen,and total phenol by poly aluminum ferric chloride(PAFC),P(DACMAPTAC-AM),and PAFC/P(DAC-MAPTAC-AM)in the flocculation treatment of coal chemical wastewater were investigated.Results showed that the optimal conditions for the flocculation of coal chemical wastewater using P(DAC-MAPTAC-AM)alone are as follows:dosage of 8-12 mg/L,G value of 100-250 s^-1,and pH value of 4-8.The optimal dosage of PAFC is 90-150 mg/L with a pH of 2-12.The optimal dosage for PAFC/P(DAC-MAPTAC-AM)is as follows:PAFC dosage of 90-150 mg/L,P(DAC-MAPTAC-AM)dosage of 8-12 mg/L,and pH range of 2-6.When P(DAC-MAPTAC-AM)was used alone,the optimal removal efficiencies of turbidity,COD,ammonia nitrogen,and total phenol were 81.0%,35.0%,75.0%,and 80.3%,respectively.PAFC has good tolerance to wastewater pH and good pH buffering.Thus,the flocculation treatment of coal chemical wastewater using the PAFC/P(DAC-MAPTAC-AM)compound also exhibits excellent resistance and buffering capacity.
文摘In our previous studies,several papermaking sludge-based flocculants(PSBFs)were synthesized from wood pulp papermaking sludge.The structure-activity relationships of the PSBFs have been investigated in simulated dye wastewater treatment,but their efficiencies in practical printing and dyeing wastewater(PPDW)treatment are unknown.Herein,an PSBF was prepared,and its performance is discussed in comparison to polyaluminium chloride(PAC)and polyacrylamide(PAM)in PPDW treatment.The PSBF was used in three ways:as an independent flocculant,as a PAC aid,or used to treat the effluent of the PAC system.The results indicated that adding PSBF alone produced similar color and chemical oxygen demand(COD_(Cr))removals as the PAC system alone,but PSBF performed better than PAC when the pH of PPDW was higher than 7.0.Adding PSBF as a PAC aid improved the color,COD_(Cr)and turbidity removals,but the elimination efficiencies were slightly lower than those of the PAC+PAM system.However,when PSBF was used as a flocculant to treat the effluent of the PAC system(PAC→PSBF),the effluent qualities were enhanced.Compared with the PAC system,the color and COD_(Cr)removals of PAC→PSBF system increased by 16.21%and 13.26%,respectively.The excitation and emission matrix fluorescence results indicated that PSBF removed tryptophan-like pollutants more efficiently than PAC.Considering the pH requirements of the subsequent bioreactor treatment in practice,the PAC→PSBF system were also investigated at the PPDW pH level of 7.0.Its maximum removal efficiencies of color,COD_(Cr)and turbidity were 90.17%,32.60%and 82.50%,respectively.
文摘Poly(2-hydroxyethylmethacrylate) chains were grafted onto the backbone of agar using a microwave assisted method involving a combination of microwave irradiation and ceric ammonium nitrate to initiate the grafting reaction. The synthesized graft copolymers were characterized by intrinsic viscosity measurements, Fourier transform infrared spectroscopy, elemental analysis (C, H, N, O and S) and scanning electron microscopy. Ag-g-P (HEMA)-2 showed a much higher flocculation efficacy than agar. The optimized dosage of flocculation for Ag-g-P (HEMA)-2 in the wastewater was found to be 0.75 ppm. Compared to agar, Ag-g-P(HEMA)-2 was found to considerably reduce the pollutant load in the wastewater.
基金supported by the National Science Foundation for Creative Research Groups(No.41021062)the National Key Basic Research Program of China(No.2013CB956700)
文摘Although microbial treatments of heavy metal ions in wastewater have been studied, the removal of these metals through incorporation into carbonate minerals has rarely been reported. To investigate the removal of Fe^3+ and Pb^2+, two representative metals in wastewater, through the precipitation of carbonate minerals by a microbial flocculant (MBF) produced by Bacillus mucilaginosus. MBF was added to synthetic wastewater containing different Fe^3+ and Pb^2+ concentrations, and the extent of flocculation was analyzed. CO2 was bubbled into the mixture of MBF and Fe^3+/Pb^2+ to initiate the reaction. The solid substrates were analyzed via X-ray diffraction, transmission electron microscopy and energy dispersive spectroscopy. The results showed that the removal efficiency decreased and the MBF adsorption capacity for metals increased with increasing heavy metal concentration. In the system containing MBF, metals (Fe^3+ and Pb^2+), and CO2, the concentrated metals adsorbed onto the MBF combined with the dissolved CO2, resulting in oversaturation of metal carbonate minerals to form iron carbonate and lead carbonates. These results may be used in designing a method in which microbes can be utilized to combine CO2 with wastewater heavy metals to form carbonates, with the aim of mitigating environmental problems.