Design of metal-organic frameworks(MOFs)-based photocatalyst for solar fuel production and photo-degradation of pollutants

Metal organic frameworks(MOFs)is a research hotspot in the solar fuel production and photo-degradation of pollutants field due to high surface area,rich metal/organic species,large pore volume,and adjustability of structures and compositions.Therefore,in this review,we first summarized the design factors of photocatalytic materials based on MOF from the perspective of"star"MOF.The modification strategies of MOFs-based photocatalysts were discussed to improve its photocatalytic activity and specific applications were summarized as well,including photocatalytic CO_(2)reduction,photocatalytic water splitting and photo-degradation of pollutants.Finally,the advantages and disadvantages of MOFs-based photocatalysts were discussed,the current challenges were highlighted,and suggestions for future research directions were proposed.

Software Frameworks, Architectural and Design Patterns

Software systems can be among the most complex constructions in engineering disciplines and can span into years of development. Most software systems though implement in part what has already been built and tend to follow known or nearly known architectures. Although most software systems are not of the size of say Microsoft Windows 8, complexity of software development can be quick to increase. Thus among these methods that are the most important is the use of architectural and design patterns and software frameworks. Patterns provide known solutions to re-occurring problems that developers are facing. By using well-known patterns reusable components can be built in frameworks.Software frameworks provide developers with powerful tools to develop more flexible and less error-prone applications in a more effective way. Software frameworks often help expedite the development process by providing necessary functionality “out of the box”.?Providing frameworks for reusability and separation of concerns is key to software development today. In this study I take a look at the state of art and the impact of frameworks and patterns in software development.

Research on the Design and Implementation of Detection System of Nutz Framework Meteorological Metrical Device

In people’s daily life, the role of weatherforecast is self-evident. However, the accuracy offorecasting is based on the accuracy and reliability ofmeteorological data which depends on the sensitivityof meteorological device. Therefore, an importantduty of the detection institution of meteorologicalmetrical device is to have the effective detectionof meteorological device, so as to ensure a highsensitivity of the device. However, the meteorologicaldevice used by some meteorological bureaus is nottechnologically advanced and the device detectionmode is too old, which cannot meet the new regulationsissued by the China Meteorological Administration.So it is necessary for the meteorological bureau todevelop a set of devices that can easily meet the newmeteorological measurement requirements, which is ofgreat significance to ensure the accurate measurementof meteorological data.

The Framework Design of Intelligent Checkers

As one of the research direction in the field of artificial intelligence, the computer game has a great practical significance. Checkers become a represent of complete knowledge game that because of it has few chess pieces, and moves easily, So it can reflect the thought of the computer game better. First, the recursive algorithm of artificial intelligence can achieve the independent moves and checkmates in draughts game program. Second, the optimization of evaluation function makes the program choose beneficial move ways. Third, the game tree can improve the level of computer in-depth thinking, simplify the search scope, and save computer thinking time by pruning, which improve the level of chess program. In this paper, overall framework of intelligent checkers is built from board representation, game tree, valuation optimization. Based on the accumulation of experience, algorithm upgrade, depth analysis of existing framework,then we give a more optimized system framework and then strengthen the computer game level.

Metal-organic-framework-derived copper-based catalyst for multicomponent C-S coupling reaction

Copper-based metal-organic frameworks(Cu-MOFs)are a promising multiphase catalyst for catalyzing C-S coupling reactions by virtue of their diverse structures and functions.However,the unpleasant odor and instability of the organosulfur,as well as the mass-transfer resistance that exists in multiphase catalysis,have often limited the catalytic application of Cu-MOFs in C-S coupling reactions.In this paper,a Cu-MOFs catalyst modified by cetyltrimethylammonium bromide(CTAB)was designed to enhance mass transfer by increasing the adsorption of organic substrates using the long alkanes of CTAB.Concurrently,elemental sulfur was used to replace organosulfur to achieve a highly efficient and atom-economical multicomponent C-S coupling reaction.

Logical Framework,Path Selection and Mechanism Design for Cultivation of New Type Professional Farmers

New type professional farmers are farmers who possess certain resources and capitals,have certain extent of spirit of entrepreneurship,and are fully capable of obtaining and allocating resources related to agricultural production and management,and engaged in agricultural production and management for obtaining average profit.Cultivation of new type professional farmers should be promoted in the process and at the background of"coordinated development of industrialization,informationization,urbanization and agricultural modernization".It should establish a proper cultivation subject system consisting of government,enterprises,rural communities and nonprofit organizations.Relying on multiple motive forces,efforts should be concentrated on cultivating those farmers with enterprising,highly innovative and learning ability,to guide traditional farmers to change into learning,enterprising and innovative ones.In addition,cultivation of new type professional farmers must rely on farmer education and training,modern agricultural development,increase in agricultural comparative advantage,innovation of rural management system and mechanism,multiple types of agricultural operation on a fairly large scale,as well as construction and regulation of new rural communities.Finally,it is recommended to provide system guarantee from long-term input mechanism of new type professional farmer education and training,incentive and restrictive mechanism of new type professional farmer cultivation,and construction of favorable environment for agricultural entrepreneurship.

Framework for a System of Systems Design Oriented to Evolution

A framework was proposed for designing a system of systems(SoS) that takes account of the system' s evolution over time.Given the design space of the SoS analysis,construct a multiepoch scenario design,SoS optimization,and robust designs.A hybrid model based on multi-agent and system dynamic models was used to analyze the evolution of an SoS and find robust designs.The framework can help decision makers generate a robust SoS structure based on the SoS' s capabilities over multiple epochs.

UbD Framework in Teaching Confucian Filial Piety and Its Relevance in Modern Society

This study explores the lasting relevance of Confucian filial piety in Chinese culture that promotes individual self-cultivation, family harmony, and social stability. The Understanding by Design (UbD) framework is proposed as an effective approach for teaching Confucius’ wisdom and the reinforcement of the cognitive, affective and psychomotor learning outcomes. This approach emphasizes “backward design” which prioritizes meaningful understanding over memorization. Integrating filial piety into the UbD framework enhances students’ understanding of its philosophical foundations and modern significance, while also strengthening their intercultural communication skills. The study concludes that UbD approach develops language skills and cultural sensitivity, encouraging insights into the dynamic nature of cultural values. The meaningful outcomes through integrating the approach into filial piety curriculum design can support students’ development of self-awareness, empathy, and ethical maturity, which foster values essential for ethical leadership and community-oriented responsibilities.

Using a Task-based Teaching Framework in Lesson Designing

Task-basedteachingandlearningis becoming more and more popularin China now,andthe aimof taskis to create a real purpose for language use and provide a natural context for language study· This article introduces what a task-based teaching frameworkis and the three phases of pre-task, while-task and post-task,combined withsomethoughts about howwe shouldconvertthosetasksinto actual classroomactivities while using the task-based teaching framework in designing the lessons and howthe teacher and students participate inthe lessons·

A Study on High School Mathematics Teaching Design Based on Teaching for Robust Understanding: Taking the Cosine Theorem as an Example

Teachers’teaching behavior plays a crucial role in students’development,and there are problems in the current teaching behavior of mathematics teachers such as ignoring students’cognitive needs,lack of equal opportunities for students’classroom performance as well as lack of formative evaluation of students.In order to solve the phenomenon,this paper analyzes and explains how to promote teaching based on the Teaching for Robust Understanding(TRU)evaluation framework with the goal of focusing on the development of all students,taking the teaching design of The Cosine Theorem as an example,and provides ideas and methods for first-line high school mathematics teachers.

Development of a distributed and integratable manufacturing execution system framework

Using remote method invocation (RMI) and a distributed object-oriented technique, this paper presents a systematic approach to developing a manufacturing execution system (MES) framework, which is open, modularized, distributed, configurable, interoperable and maintainable. Moreover, the design patterns for the framework .are developed and a variety of functional components are designed by inheriting appropriate patterns. And then an application is constructed by invoking corresponding methods of related components. An MES system implementing the framework and design patterns can be facilely integrated with other manufacturing applications, such as enterprise resource planning (ERP) and floor control system (FCS) .

软件复用与Framework框架技术

讲述了软件复用的基本概念和关键技术因素,分析了框架技术的基本概念以及常见的框架系统,并将框架同构件、设计模式进行了比较,最后给出了基于面向对象框架的软件开发过程模型。

基于.NET Framework 3.5架构的高校网络考勤管理系统的设计与开发

在高校教学管理工作中,学生日常考勤管理是其主要内容,是保证高校教育教学秩序正常运行的重要手段。该文描述一个基于.NET Framework 3.5架构的网络考勤系统的设计原理、总体结构及功能实现,提高考勤管理工作效率,实现学生、教师之间的数据共享,并对校园数字化工作起到有力的促进作用。

基于CATIA平台的Framework装配技术

结合具体的组件装配设计,以CATIA V5为平台,提出了Framework方法,提高了装配设计效率。

CAD Framework中基于知识的设计流管理

设计流管理是CAD Framework(框架结构)中一个新的研究领域。本文在给出与设计流有关的基本概念的基础上,采用结构约束和数据约束的方法实现对设计流的知识表示,并通过设计经验的获取途径、进一步的知识生成以及设计流的执行、一致性的处理和设计流的评估,详细讨论CAD Framework 中基于知识的设计流管理。文中还给出了相应的设计流管理系统的总体设计。

MFC中设计模式(Design Pattern)简析

设计模式是对软件开发人员设计经验的提炼。文章从已经构建好的MFC类库中选取典型结构,分析其中体现的设计模式(Design Pattern)思想。通过分析比较,使之认识到软件复用已经从代码复用提高到设计过程和设计经验复用的高度。

Composition Optimization and Microstructure Design in MOFs-Derived Magnetic Carbon-Based Microwave Absorbers:A Review

Magnetic carbon-based composites are the most attractive candidates for electromagnetic(EM)absorption because they can terminate the propagation of surplus EM waves in space by interacting with both electric and magnetic branches.Metal-organic frameworks(MOFs)have demonstrated their great potential as sacrificing precursors of magnetic metals/carbon composites,because they provide a good platform to achieve high dispersion of magnetic nanoparticles in carbon matrix.Nevertheless,the chemical composition and microstructure of these composites are always highly dependent on their precursors and cannot promise an optimal EM state favorable for EM absorption,which more or less discount the superiority of MOFs-derived strategy.It is hence of great importance to develop some accompanied methods that can regulate EM properties of MOFs-derived magnetic carbon-based composites e ectively.This review comprehensively introduces recent advancements on EM absorption enhancement in MOFs-derived magnetic carbon-based composites and some available strategies therein.In addition,some challenges and prospects are also proposed to indicate the pending issues on performance breakthrough and mechanism exploration in the related field.

Computational screening and design of nanoporous membranes for efficient carbon isotope separation

Stable isotopes have been routinely used in chemical sciences,medical treatment and agricultural research.Conventional technologies to produce high-purity isotopes entail lengthy separation processes that often suffer from low selectivity and poor energy efficiency.Recent advances in nanoporous materials open up new opportunities for more efficient isotope enrichment and separation as the pore size and local chemical environment of such materials can be engineered with atomic precision.In this work,we demonstrate the unique capability of nanoporous membranes for the separation of stable carbon isotopes by computational screening a materials database consisting of 12,478 computation-ready,experimental metal-organic frameworks(MOFs).Nanoporous materials with the highest selectivity and membrane performance scores have been identified for separation of^(12)CH_4/^(13)CH_4 at the ambient condition(300 K).Analyzing the structural features and metal sites of the promising MOF candidates offers useful insights into membrane design to further improve the performance.An upper limit of the efficiency has been identified for the separation of^(12)CH_4/^(13)CH_4 with the existing MOFs and those variations by replacement of the metal sites.

Metal organic framework‐ionic liquid hybrid catalysts for the selective electrochemical reduction of CO_(2) to CH4

The electrochemical reduction of CO_(2) towards hydrocarbons is a promising technology that can utilize CO_(2) and prevent its atmospheric accumulation while simultaneously storing renewable en‐ergy.However,current CO_(2) electrolyzers remain impractical on a large scale due to the low current densities and faradaic efficiencies(FE)on various electrocatalysts.In this study,hybrid HKUST‐1 metal‐organic framework‒fluorinated imidazolium‐based room temperature ionic liquid(RTIL)electrocatalysts are designed to selectively reduce CO_(2) to CH_(4).An impressive FE of 65.5%towards CH_(4) at-1.13 V is achieved for the HKUST‐1/[BMIM][PF_(6)]hybrid,with a stable FE greater than 50%maintained for at least 9 h in an H‐cell.The observed improvements are attributed to the increased local CO_(2) concentration and the improved CO_(2)‐to‐CH_(4) thermodynamics in the presence of the RTIL molecules adsorbed on the HKUST‐1‐derived Cu clusters.These findings offer a novel approach of immobilizing RTIL co‐catalysts within porous frameworks for CO_(2) electroreduction applications.

A UML profile for framework modeling

The current standard Unified Modeling Language(UML) could not model framework flexibility and extendibility adequately due to lack of appropriate constructs to distinguish framework hot-spots from kernel elements. A new UML profile that may customize UML for framework modeling was presented using the extension mechanisms of UML, providing a group of UML extensions to meet the needs of framework modeling. In this profile, the extended class diagrams and sequence diagrams were defined to straightforwardly identify the hot-spots and describe their instantiation restrictions. A transformation model based on design patterns was also put forward, such that the profile based framework design diagrams could be automatically mapped to the corresponding implementation diagrams. It was proved that the presented profile makes framework modeling more straightforwardly and therefore easier to understand and instantiate.