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Residual Attention-BiConvLSTM:一种新的全球电离层TEC
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作者 王浩然 刘海军 +5 位作者 袁静 乐会军 李良超 陈羿 单维锋 袁国铭 《地球物理学报》 北大核心 2025年第2期413-430,共18页
电离层总电子含量(TEC)预测对提高全球卫星导航系统(GNSS)的精度具有重要意义.现有的TEC map预测模型主要通过顺序堆叠时空特征提取单元来实现.这种模型搭建方法会因多个卷积层顺序堆叠而损失细粒度的TEC map的空间特征,导致模型精度不... 电离层总电子含量(TEC)预测对提高全球卫星导航系统(GNSS)的精度具有重要意义.现有的TEC map预测模型主要通过顺序堆叠时空特征提取单元来实现.这种模型搭建方法会因多个卷积层顺序堆叠而损失细粒度的TEC map的空间特征,导致模型精度不够;还会由于多层堆叠导致梯度消失或梯度爆炸问题.本文借鉴残差注意力(Residual Attention)的思想,在TEC map预测模型中增加了残差注意力模块,提出了Residual Attention-BiConvLSTM模型.该模型中的残差注意力模块能同时提取粗、细粒度空间特征,并对其进行加权.本文在全球TEC map数据上与ConvLSTM、ConvGRU、ED-ConvLSTM和C1PG进行了对比实验.实验结果表明,本文所提出的Residual Attention-BiConvLSTM模型的RMSE、MAE、MAPE和R^(2)在太阳活动高年和年均优于对比模型.本文还在一次磁暴事件中对比了5种模型的预测效果.实验结果表明,大磁暴发生时,本文模型与C1PG相近,优于其他3种对比模型.本文的研究工作为电离层map预测模型搭建提供一个新思路. 展开更多
关键词 电离层TEC map预测 残差注意力模块 residual Attention-BiConvLSTM 时空预测模型
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Making waste profitable: Efficient recovery of metallic iron from jarosite residues
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作者 Songshan Zhou Yunhui Han +11 位作者 Rong Huang Yin Huang Qingyuan Dong Haiyin Gang Jinchuan Qin Xi Yu Xiangfei Zeng Wenxing Cao Jiqin Wang Shaoqin Chen Rong Wang Mengjun Chen 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第7期66-76,共11页
To address the hazardous by-product of zinc smelting and resource utilization of jarosite residue,this study applies an electric field-assisted hot acid treatment to completely recycle iron(Fe).This innovative approac... To address the hazardous by-product of zinc smelting and resource utilization of jarosite residue,this study applies an electric field-assisted hot acid treatment to completely recycle iron(Fe).This innovative approach aims to enhance the leaching efficiency of Fe from jarosite residue.The introduction of an electric field changes the charge distribution on the surface of the particles to enhance ions and electrons exchange and promotes the collision between particles to strengthen reaction kinetics.Based on the above,the leaching efficiency of Fe in jarosite under sulfuric acid attack has improved observably.The result shows that Fe leaching efficiency reaches 98.83%,which is increased by 28%under the optimal experimental conditions:current density of 30 mA·cm^(-2),H_(2)SO_(4) concentration of 1.5 mol·L^(-1),solid-liquid ratio of 70 g·L^(-1),temperature of 80℃ and time of 12 h.Leaching kinetics calculations show that the apparent activation energy is 16.97 kJ·mol^(-1) and the leaching of jarosite residue is controlled by a mixture of chemical reaction and diffusion,as well as the temperature and concentration of the leaching solution have an influence on leaching.This work provides a feasible idea for the efficient leaching of Fe from jarosite residue. 展开更多
关键词 Jarosite residue Electric filed Leaching kinetics
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Interaction mechanism of cyanide with pyrite during the cyanidation of pyrite and the decyanation of pyrite cyanide residues by chemical oxidation
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作者 Wenwen Han Hongying Yang Linlin Tong 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2024年第9期1996-2005,共10页
The toxic cyanides in cyanide residues produced from cyanidation process for gold extraction are harmful to the environment.Pyrite is one of the main minerals existing in cyanide residues.In this work,the interaction ... The toxic cyanides in cyanide residues produced from cyanidation process for gold extraction are harmful to the environment.Pyrite is one of the main minerals existing in cyanide residues.In this work,the interaction of cyanide with pyrite and the decyanation of pyrite cyanide residue were analyzed.Results revealed that high pH value,high cyanide concentration,and high pyrite dosage promoted the interaction of cyanide with pyrite.The cyanidation of pyrite was pseudo-second-order with respect to cyanide.The decyanation of pyrite cyanide residue by Na_(2)SO_(3)/air oxidation was performed.The cyanide removal efficiency was 83.9% after 1 h of reaction time under the optimal conditions of pH value of 11.2,SO_(3)^(2-) dosage of 22 mg·g^(-1),and air flow rate of 1.46 L·min^(-1).X-ray photoelectron spectroscopy analysis of the pyrite samples showed the formation of Fe(Ⅲ)and FeSO_(4) during the cyanidation process.The cyanide that adsorbed on the pyrite surface after cyanidation mainly existed in the forms of free cyanide(CN^(-))and ferrocyanide(Fe(CN)_(6)^(4-)),which were effectively removed by Na_(2)SO_(3)/air oxidation.During the decyanation process,air intake promoted pyrite oxidation and weakened cyanide adsorption on the pyrite surface.This study has practical significance for gold enterprises aiming to mitigate the environmental impact related to cyanide residues. 展开更多
关键词 PYRITE CYANIDE DECYANATION sodium sulfite/air oxidation cyanide residue
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Furfural residues derived nitrogen-sulfur co-doped sheet-like carbon: An excellent electrode for dual carbon lithium-ion capacitors
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作者 Xiaoying Guo Yan Qiao +4 位作者 Zonglin Yi Christian Marcus Pedersen Yingxiong Wang Xiaodong Tian Peide Han 《Green Energy & Environment》 SCIE EI CAS CSCD 2024年第9期1427-1439,共13页
The state-of-the-art lithium-ion capacitors (LICs),consisting of high-capacity battery-type anode and high-rate capacitor-type cathode,can deliver high energy density and large power density when comparing with tradit... The state-of-the-art lithium-ion capacitors (LICs),consisting of high-capacity battery-type anode and high-rate capacitor-type cathode,can deliver high energy density and large power density when comparing with traditional supercapacitors and lithium-ion batteries,respectively.However,the ion kinetics mismatch between cathode and anode leads to unsatisfied cycling lifetime and anode degradation.Tremendous efforts have been devoted to solving the abovementioned issue.One promising strategy is altering high conductive hard carbon anode with excellent structural stability to match with activated carbon cathode,assembling dual-carbon LIC.In this contribution,one-pot in-situ expansion and heteroatom doping strategy was adopted to prepare sheet-like hard carbon,while activated carbon was obtained involving activation.Ammonium persulfate was used as expanding and doping agent simultaneously.While furfural residues (FR) were served as carbon precursor.The resulting hard carbon (FRNS-HC) and activated carbon (FRNS-AC)show excellent electrochemical performance as negative and positive electrodes in a lithium-ion battery (LIB).To be specific,374.2 m Ah g^(-1)and 123.1 m Ah g^(-1)can be achieved at 0.1 A g^(-1)and 5 A g^(-1)when FRNS-HC was tested as anode.When combined with a highly porous carbon cathode (S_(BET)=2961 m^(2)g^(-1)) synthesized from the same precursor,the LIC showed high specific energy of147.67 Wh kg^(-1)at approximately 199.93 W kg^(-1),and outstanding cycling life with negligible capacitance fading over 1000 cycles.This study could lead the way for the development of heteroatom-doped porous carbon nanomaterials applied to Li-based energy storage applications. 展开更多
关键词 Furfural residue Ammonium persulfate Sheet-like carbon Lithium-ion capacitors Hard carbon
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Chemical Composition of Pineapple Press Residues (Ananas comosus) and Effect on Growth Performance of Rabbit (Oryctolagus cuniculus)
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作者 Bertine Marie Noël Noumbissi Emile Miegoue +4 位作者 Nathaniel Arnaud Jordy Nguema Nathalie Ngouopou Mweugang Langston Wilfried Edie Nounamo Cedric Nyah Kwayep Fernand Tendonkeng 《Open Journal of Animal Sciences》 2024年第4期321-335,共15页
With a view to improving rabbit production performance, a trial on the chemical composition of pineapple press residue (Ananas comosus) and the effect of its incorporation in the ration on rabbit growth performance (O... With a view to improving rabbit production performance, a trial on the chemical composition of pineapple press residue (Ananas comosus) and the effect of its incorporation in the ration on rabbit growth performance (Oryctolagus cuniculus) was carried out at the KUATE Cunicole Farm in Bandjoun, in Western Cameroon. To do this, 36 rabbits of the local breed, aged 53 days with an average weight of 1337 ± 119 g were distributed and randomly assigned to 3 experimental rations corresponding respectively to treatments or batches T0, T1 and T2. The animals in treatment T0 received a ration containing no pineapple press residue, while those in treatments T1 and T2 received a ration containing 20% and 40% pineapple press residue, respectively. These residues were dried and ground for chemical composition analysis. The feed served as well as refusals from the previous day were weighed each morning to assess feed intake. The animals were weighed every 7 days to assess weight performance. At the end of the trial which lasted 7 weeks, the animals were fasted for 24 hours, then sacrificed to evaluate carcass characteristics and the relative weights of some digestive organs. The results of this study showed that pineapple press residues had a high crude fiber content (19.2%) and energy (2500 Kcal/kg DM). Their incorporation had no significant effect on feed intake and feed conversion ratio. The average live weight, weight gain and average daily weight gain of the animals receiving the ration with 20% inclusion of pineapple press residue were comparable to those of the control group and significantly higher than those of animals fed with 40% inclusion of pineapple residue. The highest carcass yields were obtained with rabbits fed 20% pineapple press residue in their ration. The cost of feed for the production of a kilogram live weight of rabbit tends to decrease with the ration incorporated with 20% pineapple press residue. Pineapple press residues constitute a by-product that can be recycled and their incorporation at 20% can increase rabbit growth performance and reduce production costs. 展开更多
关键词 Chemical Composition Growth Pineapple Press residue Production Cost RABBIT
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Soybean Response to Weed Residues in the Soil
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作者 Dwayne D. Joseph Michael W. Marshall Matthew Cutulle 《Agricultural Sciences》 2024年第8期801-811,共11页
Soybean production systems that return plant residues to the soil surface are gaining in popularity. As these practices become more widespread, more crop and weed residues are being introduced into the upper soil prof... Soybean production systems that return plant residues to the soil surface are gaining in popularity. As these practices become more widespread, more crop and weed residues are being introduced into the upper soil profile. Greenhouse studies were conducted to determine the effects of varying concentrations of Palmer amaranth and pitted morningglory plant residues (aboveground portion of the plant) on soybean production. The study was arranged in a completely randomized experimental design with five treatments and five replications. Palmer amaranth and pitted morningglory residues were incorporated into soil at 20,000, 40,000, 80,000 and 160,000 ppm. Inert plastic residue at the same residue levels was included as a check. Soybean dry weight, leaf area and leaf tissue nutrient content were recorded during the study. A decrease in soybean dry weight and leaf area was observed as Palmer amaranth residue in the soil increased. Palmer amaranth residues of 160,000 ppm and 80,000 ppm in the soil significantly reduced soybean dry weight by 69% and 59%, respectively, and soybean leaf area by 60% and 57%, respectively. In contrast, pitted morningglory and inert plastic residues had no observable effect on soybean growth and development. This study demonstrated Palmer amaranth residues in the soil impacted early season soybean growth and development. 展开更多
关键词 Reduced Tillage Plant residues ALLELOPATHY Glycine max L.
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Advanced Thermochemical Conversion Approaches for Green Hydrogen Production from Crop Residues
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作者 Omojola Awogbemi Ayotunde Adigun Ojo Samson Adedayo Adeleye 《Journal of Renewable Materials》 EI CAS 2024年第1期1-28,共28页
The huge volumes of crop residues generated during the production,processing,and consumption of farm products constitute an ecological nuisance when ineffectively managed.The conversion of crop residues to green hydro... The huge volumes of crop residues generated during the production,processing,and consumption of farm products constitute an ecological nuisance when ineffectively managed.The conversion of crop residues to green hydrogen is one of the sustainable management strategies for ubiquitous crop residues.Production of green hydrogen from crop residue sources will contribute to deepening access to clean and affordable energy,mitigating climate change,and ensuring environmental sustainability.However,the deployment of conventional thermochemical technologies for the conversion of crop residues to green hydrogen is costly,requires long residence time,produces low-quality products,and therefore needs to be upgraded.The current review examines the conventional,advanced,and integrated thermochemical conversion technologies for crop residues for green hydrogen production.After a brief overview of the conventional thermochemical techniques,the review delves into the broad narration of advanced thermochemical technologies including catalytic pyrolysis,microwave pyrolysis,co-pyrolysis,hyropyrolysis,and autothermal pyrolysis.The study advocates the deployment of integrated pyrolysis,anaerobic digestion,pyrolysis,and gasification technologies will ensure scalability,decomposition of recalcitrant feedstocks,and generation of high grade green hydrogen.The outlook provides suggestions for future research into cost-saving and sustainable integrated technologies for green hydrogen production towards achieving carbon neutrality and a circular bio-economy. 展开更多
关键词 Crop residues carbon neutrality PYROLYSIS GASIFICATION green hydrogen thermochemical conversion
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Research Progress of QuEChERS Pretreatment Technique in the Detection of Multiple Pesticide Residues
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作者 Bo LIU Dawei WANG +3 位作者 Yuhang GUO Xuehua WANG Lei WANG Yajuan SONG 《Agricultural Biotechnology》 2024年第2期10-11,37,共3页
The QuEChERS extraction technique is a pretreatment technique that has been rapidly applied in recent years and is widely used in the field of pesticide residues with many advantages. This technique is based on solid ... The QuEChERS extraction technique is a pretreatment technique that has been rapidly applied in recent years and is widely used in the field of pesticide residues with many advantages. This technique is based on solid phase extraction (SPE), which uses the interaction between adsorbent and impurities in the matrix to achieve the purpose of purification. The method has easier operation and better purification effect than SPE. In this paper, the research progress of the QuEChERS technique in pesticide residue detection in different fields in recent years and its future development were reviewed, hoping to provide reference for further development and utilization of the QuEChERS technique in pesticide residue detection in the future. 展开更多
关键词 QUECHERS PRETREATMENT Pesticide residues Research progress
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Indoor Toxicity of Emamectin Benzoate and Chlorantraniliprole Against Spodoptera litura and Their Residues on Lotus Plants
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作者 CUI Kan XU Zhi-de +5 位作者 LI Kai-long CHEN Wu-ying HU Ya-hui XIAO Jian-ping HAO Xiao-bin WEI Lin 《Agricultural Science & Technology》 CAS 2024年第3期44-49,共6页
Spodoptera litura is the most threatening pest in lotus production,seriously affecting the lotus yield and quality.Emamectin benzoate and chlorantraniliprole,the main insecticides for controlling S.litura on vegetable... Spodoptera litura is the most threatening pest in lotus production,seriously affecting the lotus yield and quality.Emamectin benzoate and chlorantraniliprole,the main insecticides for controlling S.litura on vegetables,are widely used by farmers to control S.litura on lotus plants.To determine the application concentrations,control effects,and safety of the two insecticides in lotus fields,indoor experiments were conducted to determine the control effects of 200 g/L chlorantraniliprole(SC)and 5%emamectin benzoate(WDG),and the residues of the two insecticides in the water,lotus leaves,and lotus seeds after field application were determined by HPLC-MS/MS.The indoor experiment results showed that chlorantraniliprole and emamectin benzoate both had good control effects on S.litura,with the median lethal concentrations(LC50)of 17.700 and 1.694 mg/L,respectively.After unmanned aerial vehicle spraying of emamectin benzoate at 20 g/667m^(2),there was no residue of emamectin benzoate in the water or lotus leaves after 5 d.After spraying of chlorantraniliprole at 20 mL/667m^(2),the residual amounts in the water and lotus leaves after 9 d were 0.005 and 0.007 mg/L,respectively.No residue of the two insecticides was detected in lotus seeds(dry and fresh)2 h after spraying.Therefore,it was recommended that chlorantraniliprole and emamectin benzoate can be used to control S.litura in lotus fields during the growth period,while attention should be paid to the application interval for safety.Considering the safe harvesting of lotus seeds and leaves,it was recommended that the preharvest intervals of chlorantraniliprole and 5%emamectin benzoate should be 9 d. 展开更多
关键词 ‘Cunsanlian’ Spodoptera litura Emamectin benzoate CHLORANTRANILIPROLE Insecticide residue
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Research Progress on Detection Techniques of Fungicide Residues in Chinese Chives
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作者 Xiuying CHEN Zhe MENG +5 位作者 Chen DING Huihui LIU Yancheng ZHOU Jinlu LI Yanhua YAN Lei WANG 《Agricultural Biotechnology》 2024年第1期43-48,共6页
Chinese chive is a kind of medicinal and edible plant,with many diseases,and chemical fungicides are usually used for control.In order to find out the risk of pesticide residues in Chinese chives,this paper summarized... Chinese chive is a kind of medicinal and edible plant,with many diseases,and chemical fungicides are usually used for control.In order to find out the risk of pesticide residues in Chinese chives,this paper summarized relevant literatures published in recent years,and sorted out and analyzed the types of pesticides used and detection techniques of common diseases in Chinese chives. 展开更多
关键词 Chinese chive Pesticide residues FUNGICIDE Detection technique
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Retention of harvest residues promotes the accumulation of topsoil organic carbon by increasing particulate organic carbon in a Chinese fir plantation
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作者 Jiamin Yang Ke Huang +5 位作者 Xin Guan Weidong Zhang Renshan Li Longchi Chen Silong Wang Qingpeng Yang 《Forest Ecosystems》 SCIE CSCD 2024年第5期720-727,共8页
Background As commonly used harvest residue management practices in subtropical plantations,stem only harvesting(SOH)and whole tree harvesting(WTH)are expected to affect soil organic carbon(SOC)content.However,knowled... Background As commonly used harvest residue management practices in subtropical plantations,stem only harvesting(SOH)and whole tree harvesting(WTH)are expected to affect soil organic carbon(SOC)content.However,knowledge on how SOC and its fractions(POC:particulate organic carbon;MAOC:mineral-associated organic carbon)respond to different harvest residue managements is limited.Methods In this study,a randomized block experiment containing SOH and WTH was conducted in a Chinese fir(Cunninghamia lanceolata)plantation.The effect of harvest residue management on SOC and its fractions in topsoil(0–10cm)and subsoil(20–40cm)was determined.Plant inputs(harvest residue retaining mass and fine root biomass)and microbial and mineral properties were also measured.Results The responses of SOC and its fractions to different harvest residue managements varied with soil depth.Specifically,SOH enhanced the content of SOC and POC in topsoil with increases of 15.9%and 29.8%,respectively,compared with WTH.However,SOH had no significant effects on MAOC in topsoil and SOC and its fractions in subsoil.These results indicated that the increase in POC induced by the retention of harvest residue was the primary contributor to SOC accumulation,especially in topsoil.The harvest residue managements affected SOC and its fractions through different pathways in topsoil and subsoil.The plant inputs(the increase in fine root biomass induced by SOH)exerted a principal role in the SOC accumulation in topsoil,whereas mineral and microbial properties played a more important role in regulating SOC dynamics than plants inputs in subsoil.Conclusion The retention of harvest residues can promote SOC accumulation by increasing POC,and is thus suggested as an effective technology to enhance the soil carbon sink for mitigating climate change in plantation management. 展开更多
关键词 Chinese fir plantation Soil organic carbon Particulate organic carbon Mineral-associated organic carbon Harvest residue management
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Determination of 14 Organophosphorus Pesticide Residues in Mutton by Gel Permeation Chromatography-Gas Chromatography-Mass Spectrometry(GPC-GC-MS)
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作者 Junpeng ZHAO Richard Avoi +2 位作者 Azman Bin Atil@Azmi Jiao CHEN Ling YUN 《Agricultural Biotechnology》 2024年第3期28-30,33,共4页
[Objectives]This study was conducted to purify mutton samples by gel permeation chromatography(GPC).[Methods]Fourteen organophosphorus pesticide residues in samples were qualitatively and quantitatively analyzed by ga... [Objectives]This study was conducted to purify mutton samples by gel permeation chromatography(GPC).[Methods]Fourteen organophosphorus pesticide residues in samples were qualitatively and quantitatively analyzed by gas chromatography-mass spectrometry(GC-MS)in selective ion scanning mode(SIM).[Results]The organophosphorus pesticide standard solutions showed good linearity in the mass concentration range of 0.1-10.0μg/ml with correlation coefficients(r)not lower than 0.999,and the detection limits(S=3 N)ranged from 0.01 to 0.05 mg/kg.The average recovery values were in the range of 80.2%-99.7%,with relative standard deviations(RSDs,n=3)in the range of 1.8%-6.3%,at the addition levels of 0.5,1.0 and 2.0 mg/kg.[Conclusions]The method is simple,sensitive and accurate,and can be used for the determination of organophosphorus pesticide residues in mutton. 展开更多
关键词 MUTTON Gas chromatography-mass spectrometry Gel permeation chromatography ORGANOPHOSPHORUS Pesticide residue
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Assessment of Contamination Degree of Oil Residues on a Former Agricultural Site
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作者 Marinela Florica Bodog Emil Catalin Schiopu +1 位作者 Ghita Cristian Crainic Andra Nicoleta Lazar 《Journal of Agricultural Science and Technology(A)》 2024年第2期67-82,共16页
In this study,our goal is to identify the land surface that has been polluted/degraded by petroleum products or other identified causes through laboratory analysis,to assess the depth of current contamination and to i... In this study,our goal is to identify the land surface that has been polluted/degraded by petroleum products or other identified causes through laboratory analysis,to assess the depth of current contamination and to identify the specific causes of contamination.The level of contamination will be assessed by analyzing a total of 90 soil samples,both within the first 30 cm depth and within the 30-60 cm interval.The potential impact of the petroleum activities and their effects on the environment and agricultural development in the area will be evaluated by studying the distribution of the chemical elements analyzed,particularly total petroleum hydrocarbons(TPH).In addition,a thematic map was created using MapSys 10.0 software based on their distribution,indicating the polluted areas using color codes and values.This analysis and mapping revealed that 7,473 square meters of the site were severely contaminated at 30 cm,representing approximately 25% of the site. 展开更多
关键词 Degradation oil POLLUTION residues soil surface thematic map
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Valorization of Agricultural Residues for Hydrogen-Based Electricity Generation towards Circular Bioeconomy
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作者 Patience Afi Seglah Komikouma Apelike Wobuibe Neglo 《Open Journal of Energy Efficiency》 2024年第2期57-78,共22页
Global crises, notably climate shocks, degraded ecosystems, and growing energy demand, enforce sustainable production and consumption pathways. A circular bioeconomy offers the opportunities to actualize resource and ... Global crises, notably climate shocks, degraded ecosystems, and growing energy demand, enforce sustainable production and consumption pathways. A circular bioeconomy offers the opportunities to actualize resource and eco-efficiency enhancement, valorization of waste streams, reduction of fossil energy and greenhouse gas (GHG) emissions. Albeit biomass resources are a potential feedstock for bio-hydrogen (bio-H2) production, Ghana’s agricultural residues are not fully utilized. This paper examines the economic and environmental impact of bio-H2 electricity generation using agricultural residues in Ghana. The bio-H2 potential was determined based on biogas steam reforming (BSR). The research highlights that BSR could generate 2617 kt of bio-H2, corresponding to 2.78% of the global hydrogen demand. Yam and maize residues contribute 50.47% of the bio-H2 produced, while millet residues have the most negligible share. A tonne of residues could produce 16.59 kg of bio-H2 and 29.83 kWh of electricity. A total of 4,705.89 GWh of electricity produced could replace the consumption of 21.92% of Ghana’s electricity. The economic viability reveals that electricity cost is $0.174/kWh and has a positive net present value of $2135550609.45 with a benefit-to-cost ratio of 1.26. The fossil diesel displaced is 1421.09 ML, and 3862.55 kt CO2eq of carbon emissions decreased corresponding to an annual reduction potential of 386.26 kt CO2eq. This accounts for reducing 10.26% of Ghana’s GHG emissions. The study demonstrates that hydrogen-based electricity production as an energy transition is a strategic innovation pillar to advance the circular bioeconomy and achieve sustainable development goals. 展开更多
关键词 Agricultural residues Biogas Steam Reforming BIO-HYDROGEN ELECTRICITY Circular Bioeconomy
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A timing self-cleaning nanoherbicide:Design of triple-structure nanovectors for weed control and pesticide residues treatment
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作者 Jiao Cheng Mei Li +3 位作者 Ri-xin Zhu Jing-yi Li Jun Yin Wang Xiao 《Advanced Agrochem》 2024年第4期298-307,共10页
Pesticide residues treatment is a crucial issue for both agricultural production and environmental protection.In recent years,designing self-cleaning nanoformulations has emerged as a promising strategy for reducing p... Pesticide residues treatment is a crucial issue for both agricultural production and environmental protection.In recent years,designing self-cleaning nanoformulations has emerged as a promising strategy for reducing pesticide residues in a convenient and cost-effective manner.However,traditional physical blending methods of photodegradation reagents with nanocarriers have limitations in terms of pesticide residue degradation efficiency and active ingredient efficacy.Here,a new type of timing self-cleaning nanoherbicide dicamba@mSiO_(2)/ATA/TiO_(2)with a triple structure was fabricated.Dicamba,a widely used herbicide that was attracting increasing concern over its high efficiency and broad spectrum,was selected as the model herbicide and loaded on the mSiO_(2)shell.In the stage of pesticide release,the TiO_(2)and dicamba were separated by the timing-barrier.Therefore,the efficacy of dicamba was not affected by the photocatalyst.During the release process,the ATA layer continuously absorbed the reactive oxygen species(ROS)produced by TiO_(2)and was gradually degraded.Finally,the barrier was destroyed,and the residual dicamba in the carrier was degraded by TiO_(2).Compared with the traditional physical blending method,this triple structure avoided the degradation of active ingredients by photocatalysts during the pesticide release period.The experimental results suggested that this nanoformulation improved the efficacy of the herbicide,and reduced the pesticide residues,providing a new approach for self-cleaning nanopesticides research. 展开更多
关键词 Nanopesticide SELF-CLEANING Pesticide residues Photocatalytic degradation
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Biochemical, functional and antioxidant potential of higher fungi cultivated on agro-industrial residues. Part Ⅱ: Cultures on mixtures of spent mushroom substrates and mushroom cropping by-products
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作者 Marianna Dedousi Eirini Maria Melanouri +2 位作者 Ilias Diamantis Seraphim Papanikolaou Panagiota Diamantopoulou 《Resources Chemicals and Materials》 2024年第3期175-187,共13页
Novel substrates consisted of different fresh agro-industrial residues,their corresponding and commercial spent mushroom substrates(i.e.SMS deriving from laboratory-scale experiments and SMS deriving from industrial-s... Novel substrates consisted of different fresh agro-industrial residues,their corresponding and commercial spent mushroom substrates(i.e.SMS deriving from laboratory-scale experiments and SMS deriving from industrial-scale experiments by Green Zin S.A.-SMS GZ)and Pleurotus waste(PW;stipes/mishappen mushrooms)were used in blends for a new cultivation cycle of Pleurotus ostreatus and P.eryngii mushrooms in bags.Their impact on the biochemical properties(intra-cellular polysaccharides-IPSs,protein,lipid,total phenolic compounds-TPCs,individual carbohydrates composition of the IPSs)in the first-and second-flush whole mushrooms,pilei and stipes,as well as the fatty acids composition,the antioxidant activity(in the first-flush mushroom parts)and glucan content of stipes were examined.Both species produced satisfactory IPSs quantities in all substrates(28.69-46.38%,w/w)and significant protein amounts(18.37-26.80%,w/w).The further SMS addition(80%,w/w instead of 40%,w/w)in the cultivation substrates affected positively the mushroom IPSs values,whereas the highest protein content was detected in mushroom’s parts cultivated on substrates consisted of fresh agro-industrial residues.Mushroom’s lipid content was affected differently by the various substrate combinations,with SMS presence resulting in mushrooms with a lower fat content than those produced in substrates with PW addition.Fresh substrates with PW and those with coffee residue were the most favorable for TPCs production.Regarding production flushes,the nutritional value of mushrooms was comparable between them,only a slight increase in TPCs of second-flush carposomes was detected.Glucose was the predominant monosaccharide of the produced IPSs,combined with a significant production of total and β-glucans.SMSs and PW addition had a positive impact on antioxidant activity,too.A higher quantity of lipids,TPCs and significant antioxidant activity were detected in all Pleurotus pilei than stipes,whereas the latter were richer in IPSs.Both pilei and stipes had a significant protein amount.Hence,the data obtained by this study support the positive effect of different types of SMS and mushroom waste on P.ostreatus and P.eryngii nutritional value. 展开更多
关键词 PLEUROTUS Agro-industrial residues Spent mushroom substrate Stipes Pilei
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From waste to wealth:Coal tar residue derived carbon materials as low-cost anodes for potassium-ion batteries
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作者 Zhonghua Lu Jun Shen +5 位作者 Xin Zhang Lingcong Chao Liang Chen Ding Zhang Tao Wei Shoudong Xu 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS 2025年第2期464-475,共12页
Carbon materials are widely recognized as highly promising electrode materials for various energy storage system applications.Coal tar residues(CTR),as a type of carbon-rich solid waste with high value-added utilizati... Carbon materials are widely recognized as highly promising electrode materials for various energy storage system applications.Coal tar residues(CTR),as a type of carbon-rich solid waste with high value-added utilization,are crucially important for the development of a more sustainable world.In this study,we employed a straightforward direct carbonization method within the temperature range of 700-1000℃to convert the worthless solid waste CTR into economically valuable carbon materials as anodes for potassium-ion batteries(PIBs).The effect of carbonization temperature on the microstructure and the potassium ions storage properties of CTR-derived carbons(CTRCs)were systematically explored by structural and morphological characterization,alongside electrochemical performances assessment.Based on the co-regulation between the turbine layers,crystal structure,pore structure,functional groups,and electrical conductivity of CTR-derived carbon carbonized at 900℃(CTRC-900H),the electrode material with high reversible capacity of 265.6m Ah·g^(-1)at 50 m A·g^(-1),a desirable cycling stability with 93.8%capacity retention even after 100 cycles,and the remarkable rate performance for PIBs were obtained.Furthermore,cyclic voltammetry(CV)at different scan rates and galvanostatic intermittent titration technique(GITT)have been employed to explore the potassium ions storage mechanism and electrochemical kinetics of CTRCs.Results indicate that the electrode behavior is predominantly governed by surface-induced capacitive processes,particularly under high current densities,with the potassium storage mechanism characterized by an“adsorption-weak intercalation”mechanism.This work highlights the potential of CTR-based carbon as a promising electrode material category suitable for high-performance PIBs electrodes,while also provides valuable insights into the new avenues for the high value-added utilization of CTR. 展开更多
关键词 coal tar residue carbon materials ANODE potassium-ion batteries high value-added
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Social function scores and influencing factors in patients with residual depressive symptoms
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作者 Zong-Ling Liao Xiao-Li Pu +1 位作者 Zhi-Yi Zheng Jie Luo 《World Journal of Psychiatry》 SCIE 2025年第1期117-127,共11页
BACKGROUND At present,the influencing factors of social function in patients with residual depressive symptoms are still unclear.Residual depressive symptoms are highly harmful,leading to low mood in patients,affectin... BACKGROUND At present,the influencing factors of social function in patients with residual depressive symptoms are still unclear.Residual depressive symptoms are highly harmful,leading to low mood in patients,affecting work and interpersonal communication,increasing the risk of recurrence,and adding to the burden on families.Studying the influencing factors of their social function is of great significance.AIM To explore the social function score and its influencing factors in patients with residual depressive symptoms.METHODS This observational study surveyed patients with residual depressive symptoms(case group)and healthy patients undergoing physical examinations(control group).Participants were admitted between January 2022 and December 2023.Social functioning was assessed using the Sheehan Disability Scale(SDS),and scores were compared between groups.Factors influencing SDS scores in patients with residual depressive symptoms were analyzed by applying multiple linear regression while using the receiver operating characteristic curve,and these RESULTS The SDS scores of the 158 patients with depressive symptoms were 11.48±3.26.Compared with the control group,the SDS scores and all items in the case group were higher.SDS scores were higher in patients with relapse,discon-tinuous medication,drug therapy alone,severe somatic symptoms,obvious residual symptoms,and anxiety scores≥8.Disease history,medication compliance,therapy method,and residual symptoms correlated positively with SDS scores(r=0.354,0.414,0.602,and 0.456,respectively).Independent influencing factors included disease history,medication compliance,therapy method,somatic symptoms,residual symptoms,and anxiety scores(P<0.05).The areas under the curve for predicting social functional impairment using these factors were 0.713,0.559,0.684,0.729,0.668,and 0.628,respectively,with sensitivities of 79.2%,61.8%,76.8%,81.7%,63.6%,and 65.5%and specificities of 83.3%,87.5%,82.6%,83.3%,86.7%,and 92.1%,respectively.CONCLUSION The social function scores of patients with residual symptoms of depression are high.They are affected by disease history,medication compliance,therapy method,degree of somatic symptoms,residual symptoms,and anxiety. 展开更多
关键词 DEPRESSIVE residual symptoms Social function Influence factors
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Structural and microwave absorption properties of CoFe_(2)O_(4)/residual carbon composites
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作者 Yuanchun Zhang Shengtao Gao +3 位作者 Xingzhao Zhang Dacheng Ma Chuanlei Zhu Jun He 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS 2025年第1期221-232,共12页
Electromagnetic interference,which necessitates the rapid advancement of substances with exceptional capabilities for bsorbing electromagnetic waves,is of urgent concern in contemporary society.In this work,CoFe_(2)O_... Electromagnetic interference,which necessitates the rapid advancement of substances with exceptional capabilities for bsorbing electromagnetic waves,is of urgent concern in contemporary society.In this work,CoFe_(2)O_(4)/residual carbon from coal gasification fine slag(CFO/RC)composites were created using a novel hydrothermal method.Various mechanisms for microwave absorption,including conductive loss,natural resonance,interfacial dipole polarization,and magnetic flux loss,are involved in these composites.Consequently,compared with pure residual carbon materials,this composite offers superior capabilities in microwave absorption.At 7.76GHz,the CFO/RC-2 composite achieves an impressive minimum reflection loss(RL_(min))of-43.99 dB with a thickness of 2.44 mm.Moreover,CFO/RC-3 demonstrates an effective absorption bandwidth(EAB)of up to 4.16 GHz,accompanied by a thickness of 1.18mm.This study revealed the remarkable capability of the composite to diminish electromagnetic waves,providing a new generation method for microwave absorbing materials of superior quality. 展开更多
关键词 coal gasification slag residual carbon hydrothermal method microwave absorption CoFe_(2)O_(4)
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Optimized reinforcement of granite residual soil using a cement and alkaline solution: A coupling effect
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作者 Bingxiang Yuan Jingkang Liang +5 位作者 Baifa Zhang Weijie Chen Xianlun Huang Qingyu Huang Yun Li Peng Yuan 《Journal of Rock Mechanics and Geotechnical Engineering》 2025年第1期509-523,共15页
Granite residual soil (GRS) is a type of weathering soil that can decompose upon contact with water, potentially causing geological hazards. In this study, cement, an alkaline solution, and glass fiber were used to re... Granite residual soil (GRS) is a type of weathering soil that can decompose upon contact with water, potentially causing geological hazards. In this study, cement, an alkaline solution, and glass fiber were used to reinforce GRS. The effects of cement content and SiO_(2)/Na2O ratio of the alkaline solution on the static and dynamic strengths of GRS were discussed. Microscopically, the reinforcement mechanism and coupling effect were examined using X-ray diffraction (XRD), micro-computed tomography (micro-CT), and scanning electron microscopy (SEM). The results indicated that the addition of 2% cement and an alkaline solution with an SiO_(2)/Na2O ratio of 0.5 led to the densest matrix, lowest porosity, and highest static compressive strength, which was 4994 kPa with a dynamic impact resistance of 75.4 kN after adding glass fiber. The compressive strength and dynamic impact resistance were a result of the coupling effect of cement hydration, a pozzolanic reaction of clay minerals in the GRS, and the alkali activation of clay minerals. Excessive cement addition or an excessively high SiO_(2)/Na2O ratio in the alkaline solution can have negative effects, such as the destruction of C-(A)-S-H gels by the alkaline solution and hindering the production of N-A-S-H gels. This can result in damage to the matrix of reinforced GRS, leading to a decrease in both static and dynamic strengths. This study suggests that further research is required to gain a more precise understanding of the effects of this mixture in terms of reducing our carbon footprint and optimizing its properties. The findings indicate that cement and alkaline solution are appropriate for GRS and that the reinforced GRS can be used for high-strength foundation and embankment construction. The study provides an analysis of strategies for mitigating and managing GRS slope failures, as well as enhancing roadbed performance. 展开更多
关键词 Granite residue soil(GRS) REINFORCEMENT Coupling effect Alkali activation Mechanical properties
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