Comparison of Optimization Schemes for the Flue Gas Purification System of a Garbage Incineration Power Plant

A garbage incineration power plant is proposed to be built somewhere. Due to local environmental capacity and local policy,the demand on the flue gas emission indicators of the project is high,but the conventional purification process of flue gas produced during waste incineration（ SNCR denitrification ＋dry/semi-dry deacidification ＋ adsorption of dioxins and heavy metals by activated carbon ＋ bag dusting） has been unable to meet this requirement,and the newly added wet deacidification and SCR denitrification processes can meet this requirement. The flue gas purification process was optimized,and two feasible schemes were compared to choose the better one.

The Performance Study on Adsorption of SO2 of CuO Modifying 13X Zeolite Molecular Sieve

Research and development of efficient, economical and resource-based flue gas desulfurization technology has always been a hot spot in the field of air pollution control. Molecular sieve materials have been paid attention to by SO2 adsorbent researchers due to their huge specific surface area. In this paper, 13X zeolite was modified with Cu(NO3) 2·3H2O to obtain 13x-Xwt %CuO (calculated by the amount of CuO loaded). The adsorption time and capacity of SO2 penetration sorbent and the isothermal curve of N2 adsorption-desorption were studied. The results are as follows: 13X-3wt%CuO has the best adsorption effect, the penetration adsorption time is 110 min, the penetration adsorption capacity is 43.41 mg·g-1, the saturation adsorption capacity is 49.27 mg·g-1;The amount of CuO loading has a great influence on the adsorption effect of modified 13X molecular sieve on SO2. SEM and BET characterization showed that CuO modification did not change the external morphology of 13X molecular sieve, changed the pore size, but did not block the original channel of the molecular sieve, before and after modification belong to the type I adsorption isothermal curve. The pore size distribution and type of molecular sieve, as well as the content and type of alkali metal cations jointly control the adsorption process of SO2 by 13X-xwt %CuO. XPS characterization showed that Cu(NO3) 2 decomposed into CuO and Cu2O during roasting at 450°C, CuO/Cu2O ≈ 1.5. The R2 values of the quasi-second-order kinetic models obtained from the 13X-Xwt %CuO particle diffusion kinetic models were all above 0.99, indicating that the quasi-second-order kinetic equations were more relevant. Particle diffusion dynamics model in fitting results show that the adsorption process can be divided into two stages, the first phase of surface adsorption and diffusion rate in the granules common control process, more accurate dynamics model of the secondary in the second phase particle diffusion rate control stage, mainly for the micropore adsorption or chemical adsorption, quasi level 2 dynamic model conformity of variation;C is a constant not equal to 0, indicating that the adsorption of SO2 is not completely through the form of intra-particle diffusion, and a small amount of chemisorption exists. And it is the compound effect of multiple adsorption mechanisms.

Systematic control technologies for gaseous pollutants from non-ferrous metallurgy

Air pollutant emissions represent a critical challenge in the green development of the non-ferrous metallurgy industry.This work studied the emission characteristics,formation mechanisms,phase transformation and separation of typical air pollutants,such as heavy metal particles,mercury,sulfur oxides and fluoride,during non-ferrous smelting.A series of purification technologies,including optimization of the furnace throat and hightemperature discharge,were developed to collaboratively control and recover fine particles from the flue gas of heavy metal smelting processes,including copper,lead and zinc.Significant improvements have been realized in wet scrubbing technology for removing mercury,fluoride and SO_(2)from flue gas.Gas-liquid sulfidation technology by applying H_(2)S was invented to recycle the acid scrubbing wastewater more efficiently and in an eco-friendly manner.Based on digital technology,a source reduction method was designed for sulfur and fluoride control during the whole aluminum electrolysis process.New desulfurization technologies were developed for catalytic reduction of the sulfur content in petroleum coke at low temperature and catalytic reduction of SO_(2)to elemental sulfur.This work has established the technology for coupling multi-pollutant control and resource recovery from the flue gas from non-ferrous metallurgy,which provides the scientific theoretical basis and application technology for the treatment of air pollutants in the non-ferrous metallurgy industry.