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Melting Flow Analyzation of Radiative Riga Plate Two-Phase Nano-Fluid Across Non-Flatness Plane with Chemical Reaction
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作者 Jupudi Lakshmi Rama Prasad F.Mebarek-Oudina +2 位作者 G.Dharmaiah Putta Babu Rao H.Vaidya 《Frontiers in Heat and Mass Transfer》 EI 2024年第5期1515-1532,共18页
There is a strong relationship between analytical and numerical heat transfers due to thermodynamically anticipated findings,making thermo-dynamical modeling an effective tool for estimating the ideal melting point of... There is a strong relationship between analytical and numerical heat transfers due to thermodynamically anticipated findings,making thermo-dynamical modeling an effective tool for estimating the ideal melting point of heat transfer.Under certain assumptions,the present study builds a mathematical model of melting heat transport nanofluid flow of chemical reactions and joule heating.Nanofluid flow is described by higher-order partial non-linear differential equations.Incorporating suitable similarity transformations and dimensionless parameters converts these controlling partial differential equations into the non-linear ordinary differential equations and resulting system of nonlinear equations is established.Plotted graphic visualizations in MATLAB allow for an indepth analysis of the effects of distinguishing factors on fluid flow.Innovative applications of the findings include electronic cooling,heat transfer,reaction processes,nuclear reactors,micro heat pipes,and other related fields.If the exponential index increases,however,the thermal profile becomes worse.By comparing the current findings to those already published in the literature for this particular example,we find that they are highly congruent,therefore validating the present work.Every one of the numerical findings exhibits asymptotic behavior by meeting the specified boundary conditions. 展开更多
关键词 Non-flat sheet melting surface chemical reaction 2-phase nano fluid
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Fluid-induced high-temperature metasomatism at Rundv?gshetta in the Lützow-Holm Complex, East Antarctica: Implications for the role of brine during granulite formation 被引量:2
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作者 Kazuki Takahashi Toshiaki Tsunogae Emmanuel Nwachukwu Ugwuonah 《Geoscience Frontiers》 SCIE CAS CSCD 2018年第5期1309-1323,共15页
We report new petrological, phase equilibria modeling, and fluid inclusion data for pelitic and mafic granulites from Rundv?gshetta in the highest-grade region of the Neoproterozoic Lützow-Holm Complex(LHC),East ... We report new petrological, phase equilibria modeling, and fluid inclusion data for pelitic and mafic granulites from Rundv?gshetta in the highest-grade region of the Neoproterozoic Lützow-Holm Complex(LHC),East Antarctica, and provide unequivocal evidence for fluid-rock interaction and high-temperature metasomatism in the presence of brine fluid. The studied locality is composed dominantly of well-foliated pelitic granulite(K-feldspar+quartz+sillimanite+garnet+ilmenite) with foliation-parallel bands and/or layers of mafic granulite(plagioclase+orthopyroxene+garnet+ilmenite+quartz+biotite). The boundary between the two lithologies is defined by thin(about 1 -20 cm in thick) garnet-rich layers with a common mineral assemblage of garnet+plagioclase+quartz+ilmenite+biotite ? orthopyroxene. Systematic increase of grossular and decrease of pyrope contents in garnet as well as decreasing Mg/(Fe+Mg) ratio of biotite from the pelitic granulite to garnet-rich rock and mafic granulite suggest that the garnet-rich layer was formed by metasomatic interaction between the two granulite lithologies. Phase equilibria modeling in the system NCKFMASHTO demonstrates that the metasomatism took place at 850 -860℃, which is slightly lower than the peak metamorphism of this region, and the modal abundance of garnet is the highest along the metapeliteemetabasite boundary(up to 40%), which is consistent with the field and thin section observations. The occurrence of brine(7.0 -10.9 wt.% Na Cleqfor ice melting or 25.1 -25.5 wt.% NaC leqfor hydrohalite melting) fluid inclusions as a primary phase trapped within plagioclase in the garnet-rich layer and the occurrence of Cl-rich biotite(Cl = 0.22 -0.60 wt.%) in the metasomatic rock compared to that in pelitic(0.15 -0.24 wt.%) and mafic(0.06-0.13 wt.%) granulites suggest infiltration of brine fluid could have given rise to the high-temperature metasomatism. The fluid might have been derived from external sources possibly related to the formation of major suture zones formed during the Gondwana amalgamation. 展开更多
关键词 High-temperature metasomatism BRINE Phase equilibrium modeling fluid INCLUSION GONDWANA Lützow-Holm COMPLEX
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Early Devonian Ultrapotassic Magmatism in the North China Craton: Geochemical and Isotopic Evidence for Subcontinental Lithospheric Mantle Metasomatism by Subducted Sediment–Derived Fluid 被引量:1
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作者 NIU Xiaolu Yildirim DILEK +2 位作者 LIU Fei FENG Guangying YANG Jingsui 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2020年第S01期43-43,共1页
The North China Craton(NCC) represents one of the oldest and largest cratons in the earth with a nearly complete record of Precambrian history. In the northern part of the NCC, the earliest phase of alkaline magmatism... The North China Craton(NCC) represents one of the oldest and largest cratons in the earth with a nearly complete record of Precambrian history. In the northern part of the NCC, the earliest phase of alkaline magmatism occurred in discrete pulses in the Early and Middle Devonian;whereas the next episode of alkaline magmatism took place in the early Mesozoic. The Gucheng pluton is exposed in the northern part of the NCC and forms a composite intrusion, consisting of K-feldspar–bearing clinopyroxenite, clinopyroxene–bearing syenite and alkali-feldspar syenite. Mineral phases in these lithologies include clinopyroxene(Wo43-48En19-35Fs18-38), sanidine(An0 Ab3-11Or89-97), and subordinate titanite, andradite and Na-feldspar. These rocks show homogeneous Sr but variable Nd isotopic compositions, and have relatively high zircon in-situ oxygen isotopes(δ18O=5.2–6.7). The Gucheng plutonic rocks formed through fractional crystallization and accumulation from ultrapotassic magmas, which were originated from partial melting of metasomatic vein systems in the subcontinental lithospheric mantle of the NCC. These vein networks developed as a result of the reactions of fluids derived from subducted pelitic sediments on the downgoing Palaeo-Asian ocean floor with the enriched, subcontinental lithospheric mantle peridotites. SHRIMP U-Pb zircon dating has revealed a crystallization age of 415 Ma for the timing of the emplacement of the Gucheng pluton that marks the early stages of alkaline magmatism associated with the Andean-type continental margin evolution along the northern edge of the NCC facing the Palaeo-Asian Ocean. 展开更多
关键词 ultrapotassic plutonism sub-continental lithospheric mantle metasomatism Palaeo-Asian Ocean Early Devonian tectonics of the Central Asian Orogenic Belt North China Craton subducted sediment melting
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Towards implementation of alloy-specific thermo-fluid modelling for laser powder-bed fusion of Mg alloys
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作者 Mohammad Hoseini-Athar Mikael Ersson Peter Hedström 《Journal of Magnesium and Alloys》 SCIE EI CAS CSCD 2024年第6期2327-2344,共18页
Multi-physics thermo-fluid modeling has been extensively used as an approach to understand melt pool dynamics and defect formation as well as optimizing the process-related parameters of laser powder-bed fusion(L-PBF)... Multi-physics thermo-fluid modeling has been extensively used as an approach to understand melt pool dynamics and defect formation as well as optimizing the process-related parameters of laser powder-bed fusion(L-PBF).However,its capabilities for being implemented as a reliable tool for material design,where minor changes in material-related parameters must be accurately captured,is still in question.In the present research,first,a thermo-fluid computational fluid dynamics(CFD)model is developed and validated against experimental data.Considering the predicted material properties of the pure Mg and commercial ZK60 and WE43 Mg alloys,parametric studies are done attempting to elucidate how the difference in some of the material properties,i.e.,saturated vapor pressure,viscosity,and solidification range,can influence the melt pool dynamics.It is found that a higher saturated vapor pressure,associated with the ZK60 alloy,leads to a deeper unstable keyhole,increasing the keyhole-induced porosity and evaporation mass loss.Higher viscosity and wider solidification range can increase the non-uniformity of temperature and velocity distribution on the keyhole walls,resulting in increased keyhole instability and formation of defects.Finally,the WE43 alloy showed the best behavior in terms of defect formation and evaporation mass loss,providing theoretical support to the extensive use of this alloy in L-PBF.In summary,this study suggests an approach to investigate the effect of materials-related parameters on L-PBF melting and solidification,which can be extremely helpful for future design of new alloys suitable for L-PBF. 展开更多
关键词 Mg alloys Laser powder-bed fusion(L-PBF) melt pool dynamics Computational fluid dynamics fluid flow
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Recycling process and proto-kimberlite melt metasomatism in the lithosphere-asthenosphere boundary beneath the Amazonian Craton recorded by garnet xenocrysts and mantle xenoliths from the Carolina kimberlite
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作者 Fernanda Gervasoni Tiago Jalowitzki +9 位作者 Marcelo Peres Rocha Ricardo Kalikowski Weska Eduardo Novais-Rodrigues Rodrigo Antonio de Freitas Rodrigues Yannick Bussweiler Elisa Soares Rocha Barbosa Jasper Berndt Elton Luiz Dantas Valmir da Silva Souza Stephan Klemme 《Geoscience Frontiers》 SCIE CAS CSCD 2022年第5期89-105,共17页
Here we present new data on the major and trace element compositions of silicate and oxide minerals from mantle xenoliths brought to the surface by the Carolina kimberlite,Pimenta Bueno Kimberlitic Field,which is loca... Here we present new data on the major and trace element compositions of silicate and oxide minerals from mantle xenoliths brought to the surface by the Carolina kimberlite,Pimenta Bueno Kimberlitic Field,which is located on the southwestern border of the Amazonian Craton.We also present Sr-Nd isotopic data of garnet xenocrysts and whole-rocks from the Carolina kimberlite.Mantle xenoliths are mainly clinopyroxenites and garnetites.Some of the clinopyroxenites were classified as GPP–PP–PKP(garnet-phlogopite peridotite,phlogopite-peridotite,phlogopite-K-richterite peridotite)suites,and two clinopyroxenites(eclogites)and two garnetites are relicts of an ancient subducted slab.Temperature and pressure estimates yield 855–1102℃ and 3.6–7.0 GPa,respectively.Clinopyroxenes are enriched in light rare earth elements(LREE)(La_(N)/Yb_(N)=5–62;Ce_(N)/Sm_(N)=1–3;where N=primitive mantle normalized values),they have high Ca/Al ratios(10–410),low to medium Ti/Eu ratios(742–2840),and low Zr/Hf ratios(13–26),which suggest they were formed by metasomatic reactions with CO_(2)-rich silicate melts.Phlogopite with high TiO_(2)(>2.0 wt.%),Al_(2)O_(3)(>12.0 wt.%),and FeOt(5.0–13.0 wt.%)resemble those found in the groundmass of kimberlites,lamproites and lamprophyres.Conversely,phlogopite with low TiO_(2)(<1.0 wt.%)and lower Al_(2)O_(3)(<12.0 wt.%)are similar to those present in GPP-PP-PKP,and in MARID(mica-amphibole-rutile-ilmenite-diopside)and PIC(phlogopite-ilmenite-clinopyorxene)xenoliths.The GPP-PP-PKP suite of xenoliths,together with the clinopyroxene and phlogopite major and trace element signatures suggests that an intense proto-kimberlite melt metasomatism occurred in the deep cratonic lithosphere beneath the Amazonian Craton.The Sr-Nd isotopic ratios of pyrope xenocrysts(G3,G9 and G11)from the Carolina kimberlite are characterized by high ^(143)Nd/^(144)Nd(0.51287–0.51371)and eNd(+4.55 to+20.85)accompanied with enriched ^(87)Sr/^(86)Sr(0.70405–0.71098).These results suggest interaction with a proto-kimberlite melt compositionally similar with worldwide kimberlites.Based on Sr-Nd whole-rock compositions,the Carolina kimberlite has affinity with Group 1 kimberlites.The Sm-Nd isochron age calculated with selected eclogitic garnets yielded an age of 291.9±5.4 Ma(2σ),which represents the cooling age after the proto-kimberlite melt metasomatism.Therefore,we propose that the lithospheric mantle beneath the Amazonian Craton records the Paleozoic subduction with the attachment of an eclogitic slab into the cratonic mantle(garnetites and eclogites);with a later metasomatic event caused by proto-kimberlite melts shortly before the Carolina kimberlite erupted. 展开更多
关键词 Carolina kimberlite K-rich mantle xenoliths Ancient subducted slab Proto-kimberlite melt metasomatism
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Fluids and Melts in the Upper Mantle 被引量:4
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作者 XIA Linqi XIA Zuchun XU Xueyi 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 1999年第3期330-340,共11页
This paper presents a direct study of the fluids and melts in the upper mantle by examining the fluid inclusions, melt inclusions and glasses trapped in the mantle lherzolite xenoliths entrained by Cenozoic alkali bas... This paper presents a direct study of the fluids and melts in the upper mantle by examining the fluid inclusions, melt inclusions and glasses trapped in the mantle lherzolite xenoliths entrained by Cenozoic alkali basalts (basanite, olivine-nephelinite and alkali-olivine basalt) from eastern China. The study indicates that the volatile components, which are dissolved in high-pressure solid mineral phases of mantle peridotite at depths, may be exsolved under decompressive conditions of mantle plume upwelling to produce the initial free fluid phases in the upper mantle. The free fluid phases migrating in the upper mantle may result in lowering of the mantle solidus (and liquidus), thereby initiating partial melting of the upper mantle, and in the meantime, producing metasomatic effects on the latter. 展开更多
关键词 upper MANTLE fluid melt partial meltING MANTLE metasomatism
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Melting heat transfer effects on stagnation point flow of micropolar fluid saturated in porous medium with internal heat generation(absorption) 被引量:3
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作者 M.A.A.MAHMOUD S.E.WAHEED 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI 2014年第8期979-992,共14页
The effect of melting heat transfer on the two dimensional boundary layer flow of a micropolar fluid near a stagnation point embedded in a porous medium in the presence of internal heat generation/absorption is invest... The effect of melting heat transfer on the two dimensional boundary layer flow of a micropolar fluid near a stagnation point embedded in a porous medium in the presence of internal heat generation/absorption is investigated. The governing non-linear partial differential equations describing the problem are reduced to a system of non-linear ordinary differential equations using similarity transformations solved numerically using the Chebyshev spectral method. Numerical results for velocity, angular velocity and temperature profiles are shown graphically and discussed for different values of the inverse Darcy number, the heat generation/absorption parameter, and the melting parameter. The effects of the pertinent parameters on the local skin-friction coefficient, the wall couple stress, and the local Nusselt number are tabulated and discussed. The results show that the inverse Darcy number has the effect of enhancing both velocity and temperature and suppressing angular velocity. It is also found that the local skin-friction coefficient decreases, while the local Nusselt number increases as the melting parameter increases. 展开更多
关键词 melting effect stagnation point micropolar fluid porous medium heat generation (absorption)
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Stagnation-point flow of couple stress fluid with melting heat transfer 被引量:3
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作者 T.HAYAT M.MUSTAFA +1 位作者 Z.IQBAL A.ALSAEDI 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI 2013年第2期167-176,共10页
Melting heat transfer in the boundary layer flow of a couple stress fluid over a stretching surface is investigated. The developed differential equations are solved for homotopic solutions. It is observed that the vel... Melting heat transfer in the boundary layer flow of a couple stress fluid over a stretching surface is investigated. The developed differential equations are solved for homotopic solutions. It is observed that the velocity and the boundary layer thickness are decreasing functions of the couple stress fluid parameter. However, the temperature and surface heat transfer increase when the values of the couple stress fluid parameter increase. The velocity and temperature fields increase with an increase in the melting process of the stretching sheet. 展开更多
关键词 couple stress fluid melting heat transfer stagnation-point flow series solution
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Melt-Fluid and Fluid-Fluid Immiscibility in a Na_(2)SO_(4)-SiO_(2)-H_(2)O System and Implications for the Formation of Rare Earth Deposits 被引量:4
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作者 CUI Hao ZHONG Richen +2 位作者 XIE Yuling WANG Xiaolin CHEN Huan 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2021年第5期1604-1610,共7页
Liquid-liquid immiscibility has crucial influences on geological processes,such as magma degassing and formation of ore deposits.Sulfate,as an important component,associates with many kinds of deposits.Two types of im... Liquid-liquid immiscibility has crucial influences on geological processes,such as magma degassing and formation of ore deposits.Sulfate,as an important component,associates with many kinds of deposits.Two types of immiscibility,including(i)fluid-melt immiscibility between an aqueous solution and a sulfate melt,and(ii)fluid-fluid immiscibility between two aqueous fluids with different sulfate concentrations,have been identified for sulfate-water systems.In this study,we investigated the immiscibility behaviors of a sulfate-and quartz-saturated Na_(2)SO_(4)-SiO_(2)-H_(2)O system at elevated temperature,to explore the phase relationships involving both types of immiscibility.The fluid-melt immiscibility appeared first when the Na_(2)SO_(4)-SiO_(2)-H_(2)O sample was heated to~270℃,and then fluid-fluid immiscibility emerged while the sample was further heated to~450℃.At this stage,the coexistence of one water-saturated sulfate melt and two aqueous fluids with distinct sulfate concentrations was observed.The three immiscible phases remain stable over a wide pressure-temperature range,and the appearance temperature of the fluid-fluid immiscibility increases with the increased pressure.Considering that sulfate components occur extensively in carbonatite-related deposits,the fluid-fluid immiscibility can result in significant sulfate fractionation and provides implications for understanding the formation of carbonatite-related rare earth deposits. 展开更多
关键词 geochemistry liquid-liquid immiscibility high sulfate concentration sulfate melt hydrothermal fluids
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Evidence of melt/rock interaction in the Cr-spinel bearing wehrlite rocks of Bangriposi, India: Implications for nature of the metasomatic agent 被引量:1
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作者 Tushar Mouli Chakraborti Arijit Ray Gautam Kumar Deb 《Geoscience Frontiers》 SCIE CAS CSCD 2018年第4期1213-1227,共15页
Cr-spinel bearing wehrlite rocks of Bangriposi are found within the multiply deformed metasedimentary rocks of Singhbhum Group belonging to North Singhbhum Mobile Belt of eastern India. Detailed mineralogical and geoc... Cr-spinel bearing wehrlite rocks of Bangriposi are found within the multiply deformed metasedimentary rocks of Singhbhum Group belonging to North Singhbhum Mobile Belt of eastern India. Detailed mineralogical and geochemical studies reveal that these rocks have suffered a two-stage alteration involving a deeper level modal and cryptic metasomatism and a subsequent shallower depth pervasive hydrothermal alteration. Cryptic metasomatism is defined by elevated LREE contents of the wehrlite and its clinopyroxne grains. Metasomatism induced changes in the modal mineralogy of the rocks include the absence of primary orthopyroxene grains, presence of secondary diopside-phlogopite(now present as vermiculite) defining disequilibrium reaction textures and secondary orthopyroxene rims around serpentinized olivine. The mineralogical and geochemical changes due to the metasomatic event present a contrasting picture in regard to the metasomatic history of the rocks. Possible scenarios involving a single stage or multiple stage metasomatism events have been discussed while explaining the metasomatic reactions that took place. An attempt has been made to estimate the REE concentrations of the final equilibrating melt from REE contents of clinopyroxene grains of the wehrlite. The possibility of the LREE-enriched equilibrating melt of the wehrlite rocks(the deeper level metasomatic agent) being similar to residual melts from the E-MORB type parental melts of nearby gabbro suite has been ruled out by geochemical modeling. REE abundance patterns of several natural enriched melts have been compared with REE pattern of calculated LREE-enriched equilibrating melt of the wehrlite and most resemblance has been observed with calcic and potassic melts. It is therefore suggested that the Cr-spinel bearing wehrlite rocks of Bangriposi has been affected by a calcio-potassic melt in deeper level, prior to the shallow level serpentinization event. 展开更多
关键词 WEHRLITE Modal metasomatism Cryptic metasomatism VERMICULITE Carbonated alkaline melt
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Fluid-melt Inclusions in Fluorite of the Huanggangliang Skarn Iron-Tin Deposit and Their Significance to Mineralization 被引量:12
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作者 WANG Lijuan WANG Jingbin +1 位作者 WANG Yuwang MAO Qian 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2001年第2期204-211,共8页
For the first time, fluid-melt inclusions are found in fluorite of the Huanggangliang skarn iron-tin deposit (HSID). The fluorite was formed in the main stage of mineralization, named the hydro-skarnization stage. The... For the first time, fluid-melt inclusions are found in fluorite of the Huanggangliang skarn iron-tin deposit (HSID). The fluorite was formed in the main stage of mineralization, named the hydro-skarnization stage. The inclusions contain various components such as Fe, Mg and Cr from deep sources. The melts of primary inclusions are mainly Ca- and F-rich and those of secondary inclusions tend to become Si-rich. During this evolution process, the melts and iron daughter minerals decreased and even vanished. These facts reveal that the evolution of the primary mineralizing fluids and the differentiation of the fluids and melts are the main factors leading to the deposition of Fe, Sn and other elements. This discovery confirms the magmatic genesis of the HSID and has filled in the gaps in the research of magmatogenic skarn deposits and furnished new methods for such research. Furthermore, it has enlarged the scope of the research on fluid inclusions. 展开更多
关键词 skarn deposit FLUORITE fluid-melt inclusion daughter mineral melt composition
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Experimental Study of Partial Melting of Mantle Peridotite -A Discussion about the Genesis of Sih'ca-rich Fluids (Melts) 被引量:1
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作者 LI Jianping Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou, 510640, Chinaand Kornprobst JACQUES Departement des Sciences de la Terre, Universite Blaise Pascal, 610038 Clermont-Ferrand, France 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 1999年第4期395-403,共9页
Experiments on partial melting of mantle lherzolite have been realized at 0.6 and 1.0 GPa and the chemical compositional variations of melts during different melting stages have been first discussed. The results show ... Experiments on partial melting of mantle lherzolite have been realized at 0.6 and 1.0 GPa and the chemical compositional variations of melts during different melting stages have been first discussed. The results show that the trends of variations in SiO2, CaO, Al2O3, Na2O and TiO2 are different at different melting stages. The melts produced at lower pressure are richer in SiO2 than those at higher pressure. The mantle-derived silica-rich fluids (silicate melts) are polygenetic, but the basic and intermediate-acid silicate melts in mantle peridotite xenoliths from the same host rocks, which have equivalent contents of volatile and alkali components and different contents of other components, should result from in-situ (low-degree) partial melting of mantle peridotite under different conditions (e.g. at different depths, with introduction of C-O-H fluids or in the presence of metasomatic minerals). The intermediate-acid melts may be the result of partial melting (at lower pressure) Opx + Sp + K-Na-rich fluid ±(Am-phi) ± (Phlog) = OI + melt. But the intermediate-acid magmas cannot be produced from the partial melting of normal mantle peridotite unless the crustal materials are introduced to some extent. 展开更多
关键词 mantle peridotite in-situ partial melting compositional variation of melt genesis of silica-rich fluid (stlicate melt)
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Multiple Genesis of Fluid and Melt during Exhumation of Deeply-Subducted UHP Eclogite 被引量:2
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作者 WANG Lu WANG Songjie +3 位作者 FENG Peng WANG Zhuocheng Michael BROWN Tim JOHNSON 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2021年第S01期65-67,共3页
Supercritical fluid and granitic melt are commonly generated as pressure decreases during exhumation of deeply subducted continental crust from mantle depths,promoting crust–mantle interaction,changing the rheology o... Supercritical fluid and granitic melt are commonly generated as pressure decreases during exhumation of deeply subducted continental crust from mantle depths,promoting crust–mantle interaction,changing the rheology of material along much of the subduction channel and,in a feedback loop,facilitating ongoing exhumation.However. 展开更多
关键词 partial melting ECLOGITE omphacite breakdown supercritical fluid Sulu belt
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Copper partitioning between granitic silicate melt and coexisting aqueous fluid at 850°C and 100 MPa 被引量:3
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作者 Shuilong Wang Hui Li +3 位作者 Linbo Shang Xianwu Bi Xinsong Wang Wenlin Fan 《Acta Geochimica》 EI CAS CSCD 2016年第4期381-390,共10页
Experiments on the partitioning of Cu between different granitic silicate melts and the respective coexisting aqueous fluids have been performed under conditions of 850 ℃, 100 MPa and oxygen fugacity (fO2) buffered... Experiments on the partitioning of Cu between different granitic silicate melts and the respective coexisting aqueous fluids have been performed under conditions of 850 ℃, 100 MPa and oxygen fugacity (fO2) buffered at approaching Ni-NiO (NNO). Partition coefficients of Cu (Dcu = Cfluid/Cmelt) were varied with different alumina/alkali mole ratios [Al2O3/(Na2O + K2O), abbreviated as Al/ Alk], Na/K mole ratios, and SiO2 mole contents. The DCu increased from 1.28 ± 0.01 to 22.18 ±0.22 with the increase of Al/Alk mole ratios (ranging from 0.64 to 1.20) and Na/K mole ratios (ranging from 0.58 to 2.56). The experimental results also showed that Dcu was positively correlated with the HCl concentration of the starting fluid. The Dcu was independent of the SiO2 mole content in the range of SiO2 content considered. No Dcu value was less than 1 in our experiments at 850 ℃ and 100 MPa, indicating that Cu preferred to enter the fluid phase rather than the coexisting melt phase under most conditions in the melt-fluid system, and thus a significant amount of Cu could be transported in the fluid phase in the magmatichydrothermal environment. The results indicated that Cu favored partitioning into the aqueous fluid rather than the melt phase if there was a high Na/K ratio, Na-rich, peraluminous granitic melt coexisting with the high Cl^- fluid. 展开更多
关键词 CU Experimental study Partition coefficient Granitic silicate melt - Aqueous fluid
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Heat and Mass Transfer of Upper Convected Maxwell Fluid Flow with Variable Thermo-Physical Properties over a Horizontal Melting Surface 被引量:1
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作者 Kolawole S. Adegbie Adeola J. Omowaye +1 位作者 Akeem B. Disu Isaac L. Animasaun 《Applied Mathematics》 2015年第8期1362-1379,共18页
The objective of this article is to present the dynamics of an Upper Convected Maxwell (UCM) fluid flow with heat and mass transfer over a melting surface. The influence of melting heat transfer, thermal and solutal s... The objective of this article is to present the dynamics of an Upper Convected Maxwell (UCM) fluid flow with heat and mass transfer over a melting surface. The influence of melting heat transfer, thermal and solutal stratification are properly accounted for by modifying the classical boundary conditions of temperature and concentration respectively. It is assumed that the ratio of inertia forces to viscous forces is high enough for boundary layer approximation to be valid. The corresponding influence of exponential space dependent internal heat source on viscosity and thermal conductivity of UCM is properly considered. The dynamic viscosity and thermal conductivity of UCM are temperature dependent. Classical temperature dependent viscosity and thermal conductivity models were modified to suit the case of both melting heat transfer and thermal stratification. The governing non-linear partial differential equations describing the problem are reduced to a system of nonlinear ordinary differential equations using similarity transformations and completed the solution numerically using the Runge-Kutta method along with shooting technique. For accurate and correct analysis of the effect of variable viscosity on fluid flow in which (Tw or Tm) T∞ , the mathematical models of variable viscosity and thermal conductivity must be modified. 展开更多
关键词 meltING Heat Transfer VISCOELASTIC fluid VARIABLE VISCOSITY Solutal STRATIFICATION
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Fluid-Melt and Fluid Inclusions in Mianning REE Deposit,Sichuan,Southwest China 被引量:1
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作者 牛贺才 单强 林茂青 《Chinese Journal Of Geochemistry》 EI CAS 1997年第3期256-262,共7页
Abundant fluid-melt inc1usions are found in the aegirine-augite-barite pegmatite andcarbonatite veins in the Mianning REE deposit, Sichuan. They were trapped in early stage flu-orite and quartz from a salt-melt system... Abundant fluid-melt inc1usions are found in the aegirine-augite-barite pegmatite andcarbonatite veins in the Mianning REE deposit, Sichuan. They were trapped in early stage flu-orite and quartz from a salt-melt system at temperatures higher than 500℃. Meanwhile, fluidinclusions are also present in large amounts in bastnaesite. Homogenized between 150 and270℃, these inclusions are thought to be representative of the physiccrchemical conditions ofREE minera1ization. These results show that the Mianning REE deposit is of tyPical hy-drothermal origin developed from a salt-melt system. 展开更多
关键词 流体熔融包裹体 稀土元素矿床 矿化作用 四川 碱性岩浆
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An experimental determination of W,Nb,and Ta partition coefficients between P-rich peraluminous granitic melt and coexisting aqueous fluid 被引量:1
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作者 Yong Tang Hui Zhang 《Chinese Journal Of Geochemistry》 EI CAS CSCD 2015年第2期194-200,共7页
The partition coefficients of W,Nb,and Ta between the P-rich peraluminous granitic melt and the coexisting aqueous fluid were determined at 800-850 °C and 0.5-1.5 kbar.The experimental results showed that the par... The partition coefficients of W,Nb,and Ta between the P-rich peraluminous granitic melt and the coexisting aqueous fluid were determined at 800-850 °C and 0.5-1.5 kbar.The experimental results showed that the partition coefficients D_w,D_(Nb) and D_(Ta)(D_i^(v/m) = C_i^V/C_i^m,where C_i^V and C_i^m denote the concentrations of an element,i,in the aqueous fluid and the melt,respectively) were less than 0.1.All partition coefficients were affected by pressure,but there was no evidence for the complexation of P2O5 with these elements in the granitic melt or aqueous fluid,except for with W in the fluid.The results showed that W,Nb,and Ta tended to partition into the granitic melt and,in the late period of crystallization of P-rich magma,they formed independent minerals. 展开更多
关键词 分配系数 实验测定 水流体 过铝质 熔体 NB 共存
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Genesis of Rare Element Mineralized Granites in Southern China:Evidence from Melt and Fluid Inclusions
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作者 Chen Ziying Xia WeihuaChina University of Geosciences, Wuhan 430074Anthony E.Williams-JonesDepartment of Earth and Planetary Sciences, McGill University, 3450 University Street, Montreal,Quebec, Canada, H3A 2A7 《Journal of Earth Science》 SCIE CAS CSCD 1993年第1期64-69,138,共7页
Rare element mineralized granites of me Yanshan period in Southern China are characterized by high contents of SiO2,Na2o,K2O,and F and are enriched in Nb,Ta,REE,W,Sn,Be and Li .Opinions differed over whether they are ... Rare element mineralized granites of me Yanshan period in Southern China are characterized by high contents of SiO2,Na2o,K2O,and F and are enriched in Nb,Ta,REE,W,Sn,Be and Li .Opinions differed over whether they are of metasomatk or magmatic origin .In this paper ,we present results of a study on melt and fluid inclusions in topaz-albite feldspar granite from Limo Nb-Ta-W-Sn granite and 414 Ta-Li albhe granite .Our data, which come from 15 mineralized granites, provide strong support magmatic origin .Mett inclusions are recognized in both topaz and quartz, and are associated with primary gas-rich incluaons.Crystallites of a Nb (Ta) -bearing mineral and cassiterite are also commonly present as inclusions in the topaz .Multiphase (mett+fluid) inclusions are observed in some quartz from granites and granite-related pegmatite .Mett inclusions start to mett at a temperature of approximately 540 ℃ in topaz and 650 ℃ in quartz .Final homogenization temperature is 700-900 ℃ in quartz ,700-800℃ in topaz and 440-550 ℃ for primary gas-rich inclusions coexisting with mett inclusions in topaz .The fluid inclusion data show that there was a continuous evobtion of the fluid from Nb-Ta granites and pegmatites to W-Sh hydrothermal vein. The coexistence of mett .vapour-rich fluid inclusions, and rare element crystaffites in topaz and quartz indicates that these minerals crystallized from a vapour-saturated mett enriched in Na.K,F and rare elements (Li,Be,Nb,Ta) .The evidence from fluid inclusion study shows that the possible genesis of the rare dement mineralization inLi-F granites of Yanshan period in Southern China results from magmatic differentiation . 展开更多
关键词 Nb-Ta granite GENESIS fluid inclusion melt indnskn TOPAZ Southem China .
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Carbon Enrichment in the Lithospheric Mantle:Evidence from the Melt Inclusions in Mantle Xenoliths from the Hainan Basalts 被引量:1
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作者 XU Xin TIAN Wei +1 位作者 ZHANG Lifei LI Huijuan 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2023年第1期358-375,共18页
It is generally believed that the lithospheric mantle and the mantle transition zone are important carbon reservoirs.However,the location of carbon storage in Earth's interior and the reasons for carbon enrichment... It is generally believed that the lithospheric mantle and the mantle transition zone are important carbon reservoirs.However,the location of carbon storage in Earth's interior and the reasons for carbon enrichment remain unclear.In this study,we report CO_(2)-rich olivine-hosted melt inclusions in the mantle xenoliths of late Cenozoic basalts from the Penglai area,Hainan Province,which may shed some light on the carbon enrichment process in the lithospheric mantle.We also present a detailed petrological and geochemical investigation of the late Cenozoic basalts and mantle xenoliths from northern Hainan Island.The collected samples of late Cenozoic Hainan Island basalts belong to both alkaline and subalkaline series,showing fractionated REE patterns with high(La/Yb)_(N)values of 3.52–11.77,which are typical for OIB.Based on Al-in-olivine thermometry,the temperatures estimated for the mantle xenoliths can be divided into two groups.One group has temperatures of less than 1050℃,and the other group has temperature ranging from 1050℃to 1282℃.Clinopyroxene(La/Yb)_(N)–Ti/Eu and clinopyroxene Ca/Al–Mg^(#)diagrams indicate that the mantle peridotite experienced metasomatism from both silicate and carbonate melts.Melt inclusions in the olivine of mantle xenoliths include(1)CO_(2)bubble–rich melt inclusions;(2)multiphase melt inclusions(glass+CO_(2)bubble+daughter minerals);(3)pure glass melt inclusions.Magnesite is a daughter mineral in the olivine-hosted melt inclusions,which could be interpreted as a secondary mineral formed by the interactions of CO_(2)-rich fluids with an olivine host,due to post-entrapment effects.The glasses in olivine-hosted melt inclusions have high SiO_(2)contents(60.21–77.72 wt%).Our results suggest that a considerable amount of CO_(2)-rich melt inclusions are captured in the lithospheric mantle during metasomatism.The lithospheric mantle can therefore act as is a‘carbon trap',with much CO_(2)being absorbed by the lithospheric mantle in this way. 展开更多
关键词 melt inclusions lithospheric mantle metasomatism carbon trap Hainan Island
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OBTAINING THE CRITICAL DRAW RATIO OF DRAW RESONANCE IN MELT SPINNING FOR POWER LAW POLYMER FLUIDS
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作者 Jinan Cao 《Chinese Journal of Polymer Science》 SCIE CAS CSCD 2007年第5期501-507,共7页
A direct difference method has been developed for Non-Newtonian power law fluids to solve the simultaneous non-linear partial differential equations of melt spinning, and to determine the critical draw ratio for draw ... A direct difference method has been developed for Non-Newtonian power law fluids to solve the simultaneous non-linear partial differential equations of melt spinning, and to determine the critical draw ratio for draw resonance. The results show that for shear thin fluids, the logarithm of the critical draw ratio has a well defined linear relationship with the power index for isothermal and uniform tension melt spinning. When the power index approaches zero, the critical draw ratio points at unity, indicating no melt spinning can be processed stably for such fluids. For shear thick fluids, the critical draw ratio increases in a more rapid way with increasing the power index. 展开更多
关键词 Draw resonance melt spinning Power law fluid Numerical simulation.
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