A modified particle bed model derived from the two-fluid momentum balance equations was employed to predict the gas-fluidised bed behaviour. Additional terms are included in both the fluid and the particle momentum ba...A modified particle bed model derived from the two-fluid momentum balance equations was employed to predict the gas-fluidised bed behaviour. Additional terms are included in both the fluid and the particle momentum balance equations to take into account the effect of the dispersed solid phase. This model has been extended to two-dimensional formulations and has been implemented in the commercial code CFX 4.3. The model correctly simulates the homogeneous fluidisation of Geldart Group A and the bubbling fluidisation of Geldart Group B in gas-solid fluidised beds.展开更多
Coal bed methane has been considered as an important energy resource.One major difficulty of purifying coal bed methane comes from the similar physical properties of CH_4 and N_2.The ZIF-8/water-glycol slurry was used...Coal bed methane has been considered as an important energy resource.One major difficulty of purifying coal bed methane comes from the similar physical properties of CH_4 and N_2.The ZIF-8/water-glycol slurry was used as a medium to separate coal bed methane by fluidifying the solid adsorbent material.The sorption equilibrium experiment of binary mixture(CH_4/N_2)and slurry was conducted.The selectivity of CH_4 to N_2 is within the range of 2-6,which proved the feasibility of the slurry separation method.The modified Langmuir equation was used to describe the gas-slurry phase equilibrium behavior,and the calculated results were in good agreement with the experimental data.A continuous absorption-adsorption and desorption process on the separation of CH_4/N_2 in slurry is proposed and its mathematical model is also developed.Sensitivity analysis is conducted to determine the operation conditions and the energy performance of the proposed process was also evaluated.Feed gas contains 30 mol%of methane and the methane concentration in product gas is 95.46 mol%with the methane recovery ratio of 90.74%.The total energy consumption for per unit volume of product gas is determined as 1.846 kWh Nm^(-3).Experimental results and process simulation provide basic data for the design and operation of pilot and industrial plant.展开更多
A three-phase reactor mathematical model was set up to simulate and design a three-phase bubble column reactor for direct synthesis of dimethyl ether （DME） from syngas, considering both the influence of part inert c...A three-phase reactor mathematical model was set up to simulate and design a three-phase bubble column reactor for direct synthesis of dimethyl ether （DME） from syngas, considering both the influence of part inert carrier backmixing on transfer and the influence of catalyst grain sedimentation on reaction. On the basis of this model, the influences of the size and reaction conditions of a 100000 t/a DME reactor on capacity were investigated. The optimized size of the 10000 t/a DME synthesis reactor was proposed as follows： diameter 3.2 m, height 20 m, built-in 400 tube heat exchanger （Ф 38×2 mm）, and inert heat carrier paraffin oil 68 t and catalyst 34.46 t. Reaction temperature and pressure were important factors influencing the reaction conversion for different size reactors. Under the condition of uniform catalyst concentration distribution, higher pressure and temperature were proposed to achieve a higher production capacity of DME. The best ratio of fresh syngas for DME synthesis was 2.04.展开更多
A two-dimensional mathematical model was built to describe the melting process of cylindrical basalt particle bed in a crucible. The melting processes with respect to the factors of thermal boundary conditions and par...A two-dimensional mathematical model was built to describe the melting process of cylindrical basalt particle bed in a crucible. The melting processes with respect to the factors of thermal boundary conditions and particle sizes of basalt were simulated by using the numerical method (FDM). The governing equations were discretized in tridiagonal matrix form and were solved by using the tridiagonal matrix algorithm (TDMA) as well as the alternative direction implicit (ADI) solver. The temperature distribution, the moving law of the two dimensional phase-change boundaries, the thermal current distribution were given through the numerical simulation. The results provided a theoretical basis for deciding heating procedure, for evaluating power import and controlling furnace temperature and for predicting basalt melting states etc. In the experiment, an electrical furnace was designed based on the computations. It has been proved that the simulation results are reasonably coincident with the experimental data.展开更多
The salt-gradient operation mode used in ion-exchange simulated moving bed chromatography (SMBC) can improve the efficiency of protein separations. A detailed model that takes into account any kind of adsorption/ion-e...The salt-gradient operation mode used in ion-exchange simulated moving bed chromatography (SMBC) can improve the efficiency of protein separations. A detailed model that takes into account any kind of adsorption/ion-exchange equilibrium, salt gradient, size exclusion, mass transfer resistance, and port periodic switching mechanism, was developed to simulate the complex dynamics. The model predictions were verified by the experimental data on upward and downward gradients for protein separations reported in the literature. All design and operating parameters (number, configuration, length and diameter of columns, particle size, switching period, flow rates of feed, raffinate, desorbent and extract, protein concentrations in feed, different salt concentrations in desorbent and feed) can be chosen correctly by numerical simulation. This model can facilitate the design, operation, optimization, control and scale-up of salt-gradient ion-exchange SMBC for protein separations.展开更多
In this paper, the erosion-resisting coefficient was introduced to computebed deformation in a crush bedrock river. In the case of crush bedrock, there has been no propercontrol equation to describe bed stability, whi...In this paper, the erosion-resisting coefficient was introduced to computebed deformation in a crush bedrock river. In the case of crush bedrock, there has been no propercontrol equation to describe bed stability, which leads to difficulty in calculation of the beddeformation with conventional methods. The data from field survey were used to give thee-rosion-resisting capability with an appropriate coefficient. After the determination oflongitudinal distribution expressed by polynomial regression and transversal distribution expressedby normal distribution function, the plane distribution of erosion-resisting coefficient in a crushbedrock river was obtained. With the computational results from a 2-D horizontal flow mathematicalmodel, the erosion-resisting coefficient and controlling condition of local stability were employedto compute the values of bed deformation when riverbed is stable. The above method was applied in acase study, and the computational results of flow and bed deformations are in good a-greement withphysical model test data.展开更多
基金Supported by EU Comm ission(No.ENK5 - CT2 0 0 0 - 0 0 314 )
文摘A modified particle bed model derived from the two-fluid momentum balance equations was employed to predict the gas-fluidised bed behaviour. Additional terms are included in both the fluid and the particle momentum balance equations to take into account the effect of the dispersed solid phase. This model has been extended to two-dimensional formulations and has been implemented in the commercial code CFX 4.3. The model correctly simulates the homogeneous fluidisation of Geldart Group A and the bubbling fluidisation of Geldart Group B in gas-solid fluidised beds.
基金The financial supports received from the National Natural Science Foundation of China(21522609,21636009 and 21878328)the National Key Research and Development Program of China(Nos.2017YFC0307302,2016YFC0304003)+1 种基金the Science Foundation of China University of Petroleum,Beijing(No.2462018BJC004)Beijing Science and Technology Program,China(No.Z181100005118010)。
文摘Coal bed methane has been considered as an important energy resource.One major difficulty of purifying coal bed methane comes from the similar physical properties of CH_4 and N_2.The ZIF-8/water-glycol slurry was used as a medium to separate coal bed methane by fluidifying the solid adsorbent material.The sorption equilibrium experiment of binary mixture(CH_4/N_2)and slurry was conducted.The selectivity of CH_4 to N_2 is within the range of 2-6,which proved the feasibility of the slurry separation method.The modified Langmuir equation was used to describe the gas-slurry phase equilibrium behavior,and the calculated results were in good agreement with the experimental data.A continuous absorption-adsorption and desorption process on the separation of CH_4/N_2 in slurry is proposed and its mathematical model is also developed.Sensitivity analysis is conducted to determine the operation conditions and the energy performance of the proposed process was also evaluated.Feed gas contains 30 mol%of methane and the methane concentration in product gas is 95.46 mol%with the methane recovery ratio of 90.74%.The total energy consumption for per unit volume of product gas is determined as 1.846 kWh Nm^(-3).Experimental results and process simulation provide basic data for the design and operation of pilot and industrial plant.
基金This work was supported by the National Basic Research Program of China (2005CB221205)
文摘A three-phase reactor mathematical model was set up to simulate and design a three-phase bubble column reactor for direct synthesis of dimethyl ether （DME） from syngas, considering both the influence of part inert carrier backmixing on transfer and the influence of catalyst grain sedimentation on reaction. On the basis of this model, the influences of the size and reaction conditions of a 100000 t/a DME reactor on capacity were investigated. The optimized size of the 10000 t/a DME synthesis reactor was proposed as follows： diameter 3.2 m, height 20 m, built-in 400 tube heat exchanger （Ф 38×2 mm）, and inert heat carrier paraffin oil 68 t and catalyst 34.46 t. Reaction temperature and pressure were important factors influencing the reaction conversion for different size reactors. Under the condition of uniform catalyst concentration distribution, higher pressure and temperature were proposed to achieve a higher production capacity of DME. The best ratio of fresh syngas for DME synthesis was 2.04.
文摘A two-dimensional mathematical model was built to describe the melting process of cylindrical basalt particle bed in a crucible. The melting processes with respect to the factors of thermal boundary conditions and particle sizes of basalt were simulated by using the numerical method (FDM). The governing equations were discretized in tridiagonal matrix form and were solved by using the tridiagonal matrix algorithm (TDMA) as well as the alternative direction implicit (ADI) solver. The temperature distribution, the moving law of the two dimensional phase-change boundaries, the thermal current distribution were given through the numerical simulation. The results provided a theoretical basis for deciding heating procedure, for evaluating power import and controlling furnace temperature and for predicting basalt melting states etc. In the experiment, an electrical furnace was designed based on the computations. It has been proved that the simulation results are reasonably coincident with the experimental data.
文摘The salt-gradient operation mode used in ion-exchange simulated moving bed chromatography (SMBC) can improve the efficiency of protein separations. A detailed model that takes into account any kind of adsorption/ion-exchange equilibrium, salt gradient, size exclusion, mass transfer resistance, and port periodic switching mechanism, was developed to simulate the complex dynamics. The model predictions were verified by the experimental data on upward and downward gradients for protein separations reported in the literature. All design and operating parameters (number, configuration, length and diameter of columns, particle size, switching period, flow rates of feed, raffinate, desorbent and extract, protein concentrations in feed, different salt concentrations in desorbent and feed) can be chosen correctly by numerical simulation. This model can facilitate the design, operation, optimization, control and scale-up of salt-gradient ion-exchange SMBC for protein separations.
文摘In this paper, the erosion-resisting coefficient was introduced to computebed deformation in a crush bedrock river. In the case of crush bedrock, there has been no propercontrol equation to describe bed stability, which leads to difficulty in calculation of the beddeformation with conventional methods. The data from field survey were used to give thee-rosion-resisting capability with an appropriate coefficient. After the determination oflongitudinal distribution expressed by polynomial regression and transversal distribution expressedby normal distribution function, the plane distribution of erosion-resisting coefficient in a crushbedrock river was obtained. With the computational results from a 2-D horizontal flow mathematicalmodel, the erosion-resisting coefficient and controlling condition of local stability were employedto compute the values of bed deformation when riverbed is stable. The above method was applied in acase study, and the computational results of flow and bed deformations are in good a-greement withphysical model test data.
