Two novel ligands named 4-styrylpyridine-2,6-dicarboxylic acid (4-SPDA) and 4-(4-(2-(2, 6-dicarboxypyridin-4-yl)- vinyl)styryl)pyridine-2,6-dicarboxylic acid(DSPDA) and their complexes with Tb(Ⅲ) were synthesized and...Two novel ligands named 4-styrylpyridine-2,6-dicarboxylic acid (4-SPDA) and 4-(4-(2-(2, 6-dicarboxypyridin-4-yl)- vinyl)styryl)pyridine-2,6-dicarboxylic acid(DSPDA) and their complexes with Tb(Ⅲ) were synthesized and characterized by infrared spectrometry, 1H nuclear magnetic resonance, elemental analysis and gas chromatograph-mass spectrometry. The ligand synthetic route was optimized. The fluorescence properties of the complex in solid state, in different kind of solvents and in solutions with different pH values were investigated in detail. The results show that the yields of DSPDA and 4-SPDA reach over 78% by Wittig-Horner reaction and other eight pyridine-2, 6-dicarboxylic acid derivatives with different substituents on pyridine ring, and their complexes with Tb(Ⅲ) are also obtained. The fluorescence intensities of the complexes with electron-donating groups are more intense than those of the complexes with electron-withdrawing groups on pyridine ring; fluorescence intensities of the complexes are the strongest in neutral solution (pH=7), and the less the dipole moment of solvent molecule is, the stronger the fluorescence intensity is. It is found that the two ligands (4-APDA and DSPDA) are the good sensitizers for Tb(Ⅲ) ion.展开更多
通过荧光光谱法研究了铕(Ⅲ)、铽(Ⅲ)两种稀土离子对四(3,4-亚甲二氧基苯基)卟啉(T M PP)荧光强度的影响。在中性介质中,铕(Ⅲ)和铽(Ⅲ)与T M PP相互作用使T M P P的荧光猝灭。实验表明:以DMF为溶剂、420 nm为最大激发波长、655nm为最...通过荧光光谱法研究了铕(Ⅲ)、铽(Ⅲ)两种稀土离子对四(3,4-亚甲二氧基苯基)卟啉(T M PP)荧光强度的影响。在中性介质中,铕(Ⅲ)和铽(Ⅲ)与T M PP相互作用使T M P P的荧光猝灭。实验表明:以DMF为溶剂、420 nm为最大激发波长、655nm为最大发射波长时,T MPP的荧光强度和稀土离子对其荧光猝灭均达到最大值。展开更多
基金Project(20761002) supported by the National Natural Science Foundation of China
文摘Two novel ligands named 4-styrylpyridine-2,6-dicarboxylic acid (4-SPDA) and 4-(4-(2-(2, 6-dicarboxypyridin-4-yl)- vinyl)styryl)pyridine-2,6-dicarboxylic acid(DSPDA) and their complexes with Tb(Ⅲ) were synthesized and characterized by infrared spectrometry, 1H nuclear magnetic resonance, elemental analysis and gas chromatograph-mass spectrometry. The ligand synthetic route was optimized. The fluorescence properties of the complex in solid state, in different kind of solvents and in solutions with different pH values were investigated in detail. The results show that the yields of DSPDA and 4-SPDA reach over 78% by Wittig-Horner reaction and other eight pyridine-2, 6-dicarboxylic acid derivatives with different substituents on pyridine ring, and their complexes with Tb(Ⅲ) are also obtained. The fluorescence intensities of the complexes with electron-donating groups are more intense than those of the complexes with electron-withdrawing groups on pyridine ring; fluorescence intensities of the complexes are the strongest in neutral solution (pH=7), and the less the dipole moment of solvent molecule is, the stronger the fluorescence intensity is. It is found that the two ligands (4-APDA and DSPDA) are the good sensitizers for Tb(Ⅲ) ion.
文摘通过荧光光谱法研究了铕(Ⅲ)、铽(Ⅲ)两种稀土离子对四(3,4-亚甲二氧基苯基)卟啉(T M PP)荧光强度的影响。在中性介质中,铕(Ⅲ)和铽(Ⅲ)与T M PP相互作用使T M P P的荧光猝灭。实验表明:以DMF为溶剂、420 nm为最大激发波长、655nm为最大发射波长时,T MPP的荧光强度和稀土离子对其荧光猝灭均达到最大值。
