During past few years,the construction of fluorescent metallacycles featuring the fluorescenceresonance energy transfer behavior has attracted extensive attention due to their diverse applications such as real-time mo...During past few years,the construction of fluorescent metallacycles featuring the fluorescenceresonance energy transfer behavior has attracted extensive attention due to their diverse applications such as real-time monitoring the dynamics of coordination-driven self-assembly,photoswitching fluorescence-resonance energy transfer,and light-controlled generation of singlet oxygen for cancer therapy.This review focuses on the recent advances on the design principles,preparation methods,optical properties,and the wide applications of fluorescent metallacycles with the FRET property.展开更多
基金the National Nature Science Foundation of China(Nos.21922506,21871092,21672070 and31702070)Shanghai Pujiang Program(No.18PJD015)+1 种基金the Fundamental Research Funds for the Central Universities,Shanghai Municipal Natural Science Foundation(No.19ZR1437900)the Opening Projects of Shanghai Key Laboratory of Green Chemistry and Chemical Processes,and State Key Laboratory of Fine Chemicals(No.KF 1801)。
文摘During past few years,the construction of fluorescent metallacycles featuring the fluorescenceresonance energy transfer behavior has attracted extensive attention due to their diverse applications such as real-time monitoring the dynamics of coordination-driven self-assembly,photoswitching fluorescence-resonance energy transfer,and light-controlled generation of singlet oxygen for cancer therapy.This review focuses on the recent advances on the design principles,preparation methods,optical properties,and the wide applications of fluorescent metallacycles with the FRET property.