Fluorine in mold powder is known as harmful to human health and the environment. Being the advocate of green production, Baosteel developed an environmentally friendly mold powder without fluorine. The main problem of...Fluorine in mold powder is known as harmful to human health and the environment. Being the advocate of green production, Baosteel developed an environmentally friendly mold powder without fluorine. The main problem of fluorine-free flux film is small heat resistance and thus the heat transfer intensity of the mold is too large, which to some extent hinders the increase of the casting speed. With the heat flow simulation equipment, controlling precipitation of crystal in flux and solidification temperature properly, fluorine-free mold powder for low carbon steel,which substitutes F with B203 ,was successfully developed and applied in industrial production. The production results show that, by using boronic fluorine-free mold powder,the boron increment in molten steel is less than 1.3ppm for conventional aluminium killed low carbon steel.展开更多
The solvent debinding of water soluble binder in powder injection moulding (MIM) was investigated systematically, including the effects of solvent types, temperature and the thickness of green parts on the solvent deb...The solvent debinding of water soluble binder in powder injection moulding (MIM) was investigated systematically, including the effects of solvent types, temperature and the thickness of green parts on the solvent debinding rate. After studying the debinding of a green part with a thickness of 4.26 mm, it was found that, the debinding rate of polyethylene glycol(PEG) in water and alcohol was high initially, and then decreased; however, it would increase with temperature increasing. At room temperature, the dissolution rate of PEG in water was higher than that in alcohol, but the latter would be much faster with temperature increasing because the debinding activation energy in alcohol was 51.44 kJ·mol -1 ·K -1 , much higher than 24.23 kJ·mol -1 ·K -1 in water. With a green part thickness larger than 4.26 mm, the debinding was controlled by diffusion; but with that smaller than 2.36 mm, the debinding was controlled by both dissolution and diffusion.展开更多
Cristobalite SiO2 can be obtained from the fused silica ceramic waste of ploysilicon plant, due to the phase conversion of fused silica to cristobalite during the process of polysilicon ingot. Cristobalite powder mate...Cristobalite SiO2 can be obtained from the fused silica ceramic waste of ploysilicon plant, due to the phase conversion of fused silica to cristobalite during the process of polysilicon ingot. Cristobalite powder materials with high purity are manufactured by milling the discarded waste above. Thermal expansion rate of the cristobalite and gypsum bonding moulds were studied, which show that the thermal expansion of the cristobalite phase transition could effectively compensate for the shrinkage of the gypsum at the temperature between 200 ℃ and 400 ℃. Casting experiments with copper alloy show that the cristobalite can improve the thermal performance of moulds for precise casting of jewelry.展开更多
The gas in plastics mould has great influence on performance, appearance and lifespan of the injection molded parts. Venting channel and its appendix system should be used for gas exhausting in general. However, the d...The gas in plastics mould has great influence on performance, appearance and lifespan of the injection molded parts. Venting channel and its appendix system should be used for gas exhausting in general. However, the dependence on the venting system complicates the mould design. Furthermore in certain condition, it is difficult to integrate the venting system into the mould. Currently a kind of mold material which has gas permeability has been developed in abroad, but the applications of this mold material were restricted by its higher cost and smaller size. In this research, a porous material which was made by powder metallurgy was applied to plastic mould to replace the venting system. Permeability of the steel with different secondary processing was tested and compared with a special apparatus. The metallographic samples of the steel with different secondary processing were prepared and investigated. Finally an actual injection set was established to investigate the applications of permeable steel. The metallographies indicate that the micro-holes inside permeable steel were interconnected. Moulds made of permeable steel exhibit good permeability in the plastic-injection experiments and gas generated in the mould cavity was smoothly exhausted. The melted plastic did not penetrate into the mould or block in the micro-holes. After several times of plastic-injection experiments, the mould still retained good permeability. The strength of this permeable steel is between 200–250 MPa and suitable for industrial applications. The venting systems simplified by permeable steel in plastic-injection have simple structures, which can be applied into any place that requires gas exhausting.展开更多
A novel binder system for hardmetal powder extrusion moulding (PEM) process has been developed. The binder system comprises a major fraction of a mixture of low molecular weight components (LMWCs) and a minor fraction...A novel binder system for hardmetal powder extrusion moulding (PEM) process has been developed. The binder system comprises a major fraction of a mixture of low molecular weight components (LMWCs) and a minor fraction of very finely dispersed polymer. The feedstocks are mixed as a thick slurry at a suitable temperature and are rapidly homogenized by stirring at an adequate shear force. The binders are removed by thermal debinding. The thermal debinding mechanism has been investigated by thermogravimetry (TG) and differential thermogravimetry (DTG). At the first stage of debinding, the LMWCs are removed. These open up pore channels which allows much faster removal of the remaining polymer component during the subsequent stage. The microstructures of the moulded green parts were observed by scanning electron microscopy (SEM). The debound samples were sintered at different temperatures, and the sintered samples properties were measured.展开更多
文摘Fluorine in mold powder is known as harmful to human health and the environment. Being the advocate of green production, Baosteel developed an environmentally friendly mold powder without fluorine. The main problem of fluorine-free flux film is small heat resistance and thus the heat transfer intensity of the mold is too large, which to some extent hinders the increase of the casting speed. With the heat flow simulation equipment, controlling precipitation of crystal in flux and solidification temperature properly, fluorine-free mold powder for low carbon steel,which substitutes F with B203 ,was successfully developed and applied in industrial production. The production results show that, by using boronic fluorine-free mold powder,the boron increment in molten steel is less than 1.3ppm for conventional aluminium killed low carbon steel.
文摘The solvent debinding of water soluble binder in powder injection moulding (MIM) was investigated systematically, including the effects of solvent types, temperature and the thickness of green parts on the solvent debinding rate. After studying the debinding of a green part with a thickness of 4.26 mm, it was found that, the debinding rate of polyethylene glycol(PEG) in water and alcohol was high initially, and then decreased; however, it would increase with temperature increasing. At room temperature, the dissolution rate of PEG in water was higher than that in alcohol, but the latter would be much faster with temperature increasing because the debinding activation energy in alcohol was 51.44 kJ·mol -1 ·K -1 , much higher than 24.23 kJ·mol -1 ·K -1 in water. With a green part thickness larger than 4.26 mm, the debinding was controlled by diffusion; but with that smaller than 2.36 mm, the debinding was controlled by both dissolution and diffusion.
文摘Cristobalite SiO2 can be obtained from the fused silica ceramic waste of ploysilicon plant, due to the phase conversion of fused silica to cristobalite during the process of polysilicon ingot. Cristobalite powder materials with high purity are manufactured by milling the discarded waste above. Thermal expansion rate of the cristobalite and gypsum bonding moulds were studied, which show that the thermal expansion of the cristobalite phase transition could effectively compensate for the shrinkage of the gypsum at the temperature between 200 ℃ and 400 ℃. Casting experiments with copper alloy show that the cristobalite can improve the thermal performance of moulds for precise casting of jewelry.
基金supported by Guangdong-Hong Kong Key Project of China (Grant No. 2007Z010)National Basic Research Program of China (973 Program, Grant No. 2007CB616905)
文摘The gas in plastics mould has great influence on performance, appearance and lifespan of the injection molded parts. Venting channel and its appendix system should be used for gas exhausting in general. However, the dependence on the venting system complicates the mould design. Furthermore in certain condition, it is difficult to integrate the venting system into the mould. Currently a kind of mold material which has gas permeability has been developed in abroad, but the applications of this mold material were restricted by its higher cost and smaller size. In this research, a porous material which was made by powder metallurgy was applied to plastic mould to replace the venting system. Permeability of the steel with different secondary processing was tested and compared with a special apparatus. The metallographic samples of the steel with different secondary processing were prepared and investigated. Finally an actual injection set was established to investigate the applications of permeable steel. The metallographies indicate that the micro-holes inside permeable steel were interconnected. Moulds made of permeable steel exhibit good permeability in the plastic-injection experiments and gas generated in the mould cavity was smoothly exhausted. The melted plastic did not penetrate into the mould or block in the micro-holes. After several times of plastic-injection experiments, the mould still retained good permeability. The strength of this permeable steel is between 200–250 MPa and suitable for industrial applications. The venting systems simplified by permeable steel in plastic-injection have simple structures, which can be applied into any place that requires gas exhausting.
基金This research was supported by the National Natural Science Foundation of China (grant No.5964120, No.69971007). The financial support is gratefully acknowledged.
文摘A novel binder system for hardmetal powder extrusion moulding (PEM) process has been developed. The binder system comprises a major fraction of a mixture of low molecular weight components (LMWCs) and a minor fraction of very finely dispersed polymer. The feedstocks are mixed as a thick slurry at a suitable temperature and are rapidly homogenized by stirring at an adequate shear force. The binders are removed by thermal debinding. The thermal debinding mechanism has been investigated by thermogravimetry (TG) and differential thermogravimetry (DTG). At the first stage of debinding, the LMWCs are removed. These open up pore channels which allows much faster removal of the remaining polymer component during the subsequent stage. The microstructures of the moulded green parts were observed by scanning electron microscopy (SEM). The debound samples were sintered at different temperatures, and the sintered samples properties were measured.
