The distillery wastewater of Guangdong Jiujiang Distillery, which is characteristic of containing high organic matters and rich total nitrogen, was treated by a combination of methane fermentation and denitrification/...The distillery wastewater of Guangdong Jiujiang Distillery, which is characteristic of containing high organic matters and rich total nitrogen, was treated by a combination of methane fermentation and denitrification/nitrification processes. 80% of COD in the raw wastewater was removed by methane fermentation at the COD volumetric loading rate of 20 kg COD/（m^3·d） using the expanded granule sludge bed （EGSB） process. However, almost all the organic nitrogen in the raw wastewater was converted into ammonia by ammonification there. Ammonia and volatile fatty acids （VFA） remaining in the anaerobically treated wastewater were simultaneously removed utilizing VFA as an electron donor by denitrification occurring in the other EGSB reactor and nitrification using PEG-immobilized nitrifying bacteria with recirculation process. An aerobic biological contact oxidization reactor was designed between denitrification/nitrification reactor for further COD removal. With the above treatment system, 18000-28000 mg/L of COD in raw wastewater was reduced to less than 100 mg/L. Also, ammonia in the effluent of the system was not detected and the system had a high removal rate for 900-1200 mg/L of TN in the raw wastewater, only leaving 400 mg/L of nitrate nitrogen.展开更多
Currently distillery effluents have attracted worldwide attention for their application in agricultural land. The present investigation deals with the effect of application of various dosages of distillery effluent ir...Currently distillery effluents have attracted worldwide attention for their application in agricultural land. The present investigation deals with the effect of application of various dosages of distillery effluent irrigation on soil physicochemical, Cellulase and Urease activities in a tropical agricultural field. Experiment was designed in factorial model by using randomized block design. Soil cores were sampled from the selected pits of both polluted and non polluted (control) sites. Majority of soil physicochemical properties (e.g. silt, clay, electrical conductivity, organic matter, total nitrogen contents, cellulase and urease activities) were significantly higher in the samples from polluted site than the non polluted site just after 15 to 30 days of incubation. Although application of effluents at lower rate substantially increased the enzyme activities, the same decreased at high effluent concentration. Prolonged incubation period resulted in gradual suppression of enzyme activity in both polluted and nonpolluted soil samples. Thus, the present investigation suggest that with the passage of time substrate for enzyme activity decreases which in association with residual toxicity resulted in the reduced enzyme activity.展开更多
The current study was carried out to examine the heavy metals （Cd, Co, Cr, Cu, Mn, Ni, Pb, Zn and As） concentration in GW （groundwater） samples in the vicinity of distillery spent wash evaporation ponds and RGW （...The current study was carried out to examine the heavy metals （Cd, Co, Cr, Cu, Mn, Ni, Pb, Zn and As） concentration in GW （groundwater） samples in the vicinity of distillery spent wash evaporation ponds and RGW （reference groundwater） samples collected 2 km to 3 km away from the source. The study examines the potential health risk caused by consumption of heavy metals to local inhabitants living around distillery spent wash evaporation ponds. HM （heavy metals） concentration was determined by AAS （atomic absorption） and the results were compared with permissible limits of PEPA （pakistan environmental Protection Agency） and WHO （World Health Organization）, set for industria effluents and drinking water. The health risk assessment such as CDI （chronic daily intake） and HQ （hazard quotient） were determined on the sources ofHM concentration. The cm of heavy metals in GW were found in following decreasing order Fe, Zn, Mn, Ni, Co, Cu, Cr, Cd, Pb and As. The HQ indexes of HM in the GW samples near the distillery spent wash evaporation ponds was in the order As, C, Ni, Cu, Mn, Zn, Pb and Cr. The results showed that the distillery spent wash is the cause for the change in HM contents of the study area.展开更多
The study was conducted to assess the effect of evaporation ponds of an ethanol distillery spent wash on groundwater, with a reference to heavy metal contamination. The distillery discharging 11,880 m3 spent wash per ...The study was conducted to assess the effect of evaporation ponds of an ethanol distillery spent wash on groundwater, with a reference to heavy metal contamination. The distillery discharging 11,880 m3 spent wash per day is extremely loaded with minerals and chemical oxygen demanding organic substances. The groundwater around the evaporation ponds is used for drinking and irrigation purposes. Thirty-five representative samples （three spent wash, two drainage water and 30 groundwater） were examined for 13 different parameters： pH, TDS （total dissolved solids）, COD （chemical oxygen demand）, the heavy metal Cd, Co, Cr, Cu, Fe, Mn, Ni, Zn, Pb and As concentrations. The physico-chemical parameters were found in following range pH 7.2-7.7 ＆ 6.8-7.7, TDS 24,448-28,608 mg/L ＆ 302-4,406 mg/L, COD 20,080-24,320 mg/L ＆ 0.0-53 mg/L, Cd 190-140 μg/L ＆ 1.5-8.7 μg/L, Co 1,240-1,987 μg/L ＆ 20.5-87.2 μg/L, Cr 1,020-1,330 μg/L ＆ 14.4-38.1 μg/L, Cu 5,200-6,300 μg/L ＆ 15.0-109.3 μg/L, Fe 2,910-3,242 μg/L ＆ 0-860 μg/L, Mn 49,900-59,500 μg/L ＆ 16.3-138.7 μg/L, Ni 1,430-1,760 μg/L ＆ 8.0-107.7 μg/L, Zn 3,359-5,250 μg/L ＆ 0.0-850 μg/L, Pb 8.9-9.8 μg/L ＆ BD （below detection）-8.7 μg/L, As 5.0 μg/L ＆ BD-10.0 μg/L for spent wash and groundwater samples, respectively. The drainage water samples had parameters within limits for industrial effluents. The spent wash samples contained metal ions higher than the permissible limits for industrial effluents and the samples of groundwater collected around the evaporation ponds contained higher concentrations of metal ions as compared to samples collected away from the evaporation ponds. Coefficient of correμtion among 11 parameters was calcuμted and contamination index was also determined, 33.3% of groundwater samples mostly collected around evaporation ponds had a contamination index above 3 and are considered extremely polluted.展开更多
Electrochemical treatment of distillery .spentwash was carried out using different combinations of aluminum and iron electrodes in batch mode of operation. The spent wash was characterized for various parameters as pe...Electrochemical treatment of distillery .spentwash was carried out using different combinations of aluminum and iron electrodes in batch mode of operation. The spent wash was characterized for various parameters as per standard method of analysis and the treatment results were analyzed in terms of chemical oxygen demand （COD） removal efficiency o.f thespent.wash. The experiments were performed to s.tudy the effect of operating parameterssuch as current density, pH of the spent wash, agitation speed, electrolysis time and the distance between the elec- trodes on the COD removal efficiency of the spent wash. It was observed that aluminum electrodes were more suitable for treatment of distillery spent wash as compared to iron electrodes. The maximum COD removal effi- ciency of 81.3% was obtained with A1-A1 electrodes at the current density of 0.187 A.cm-2 and pH 3 for an elec-trolysis time of 2 h.展开更多
Solid-liquid separation of the wastewater is very difficult because of high viscosity and high SS concentration. In this study, the effectiveness of preozonation on improving the settleability of the solids in wheat a...Solid-liquid separation of the wastewater is very difficult because of high viscosity and high SS concentration. In this study, the effectiveness of preozonation on improving the settleability of the solids in wheat and sweet potato wastewaters was investigated using a bench-scale system and pilot treatment system respectively. Results showed that solid-liquid separation in the wheat wastewater was greatly improved by the decanter in the system(SS reduction from 24100 mg/L to 100 mg/L). However, preozonation practice did not show a significant effect on solid-liquid separation of the sweet potato wastewater. Effect of preozonation on solid-liquid separation between wheat and sweet potato wastewater showed different.展开更多
文摘The distillery wastewater of Guangdong Jiujiang Distillery, which is characteristic of containing high organic matters and rich total nitrogen, was treated by a combination of methane fermentation and denitrification/nitrification processes. 80% of COD in the raw wastewater was removed by methane fermentation at the COD volumetric loading rate of 20 kg COD/（m^3·d） using the expanded granule sludge bed （EGSB） process. However, almost all the organic nitrogen in the raw wastewater was converted into ammonia by ammonification there. Ammonia and volatile fatty acids （VFA） remaining in the anaerobically treated wastewater were simultaneously removed utilizing VFA as an electron donor by denitrification occurring in the other EGSB reactor and nitrification using PEG-immobilized nitrifying bacteria with recirculation process. An aerobic biological contact oxidization reactor was designed between denitrification/nitrification reactor for further COD removal. With the above treatment system, 18000-28000 mg/L of COD in raw wastewater was reduced to less than 100 mg/L. Also, ammonia in the effluent of the system was not detected and the system had a high removal rate for 900-1200 mg/L of TN in the raw wastewater, only leaving 400 mg/L of nitrate nitrogen.
文摘Currently distillery effluents have attracted worldwide attention for their application in agricultural land. The present investigation deals with the effect of application of various dosages of distillery effluent irrigation on soil physicochemical, Cellulase and Urease activities in a tropical agricultural field. Experiment was designed in factorial model by using randomized block design. Soil cores were sampled from the selected pits of both polluted and non polluted (control) sites. Majority of soil physicochemical properties (e.g. silt, clay, electrical conductivity, organic matter, total nitrogen contents, cellulase and urease activities) were significantly higher in the samples from polluted site than the non polluted site just after 15 to 30 days of incubation. Although application of effluents at lower rate substantially increased the enzyme activities, the same decreased at high effluent concentration. Prolonged incubation period resulted in gradual suppression of enzyme activity in both polluted and nonpolluted soil samples. Thus, the present investigation suggest that with the passage of time substrate for enzyme activity decreases which in association with residual toxicity resulted in the reduced enzyme activity.
文摘The current study was carried out to examine the heavy metals （Cd, Co, Cr, Cu, Mn, Ni, Pb, Zn and As） concentration in GW （groundwater） samples in the vicinity of distillery spent wash evaporation ponds and RGW （reference groundwater） samples collected 2 km to 3 km away from the source. The study examines the potential health risk caused by consumption of heavy metals to local inhabitants living around distillery spent wash evaporation ponds. HM （heavy metals） concentration was determined by AAS （atomic absorption） and the results were compared with permissible limits of PEPA （pakistan environmental Protection Agency） and WHO （World Health Organization）, set for industria effluents and drinking water. The health risk assessment such as CDI （chronic daily intake） and HQ （hazard quotient） were determined on the sources ofHM concentration. The cm of heavy metals in GW were found in following decreasing order Fe, Zn, Mn, Ni, Co, Cu, Cr, Cd, Pb and As. The HQ indexes of HM in the GW samples near the distillery spent wash evaporation ponds was in the order As, C, Ni, Cu, Mn, Zn, Pb and Cr. The results showed that the distillery spent wash is the cause for the change in HM contents of the study area.
文摘The study was conducted to assess the effect of evaporation ponds of an ethanol distillery spent wash on groundwater, with a reference to heavy metal contamination. The distillery discharging 11,880 m3 spent wash per day is extremely loaded with minerals and chemical oxygen demanding organic substances. The groundwater around the evaporation ponds is used for drinking and irrigation purposes. Thirty-five representative samples （three spent wash, two drainage water and 30 groundwater） were examined for 13 different parameters： pH, TDS （total dissolved solids）, COD （chemical oxygen demand）, the heavy metal Cd, Co, Cr, Cu, Fe, Mn, Ni, Zn, Pb and As concentrations. The physico-chemical parameters were found in following range pH 7.2-7.7 ＆ 6.8-7.7, TDS 24,448-28,608 mg/L ＆ 302-4,406 mg/L, COD 20,080-24,320 mg/L ＆ 0.0-53 mg/L, Cd 190-140 μg/L ＆ 1.5-8.7 μg/L, Co 1,240-1,987 μg/L ＆ 20.5-87.2 μg/L, Cr 1,020-1,330 μg/L ＆ 14.4-38.1 μg/L, Cu 5,200-6,300 μg/L ＆ 15.0-109.3 μg/L, Fe 2,910-3,242 μg/L ＆ 0-860 μg/L, Mn 49,900-59,500 μg/L ＆ 16.3-138.7 μg/L, Ni 1,430-1,760 μg/L ＆ 8.0-107.7 μg/L, Zn 3,359-5,250 μg/L ＆ 0.0-850 μg/L, Pb 8.9-9.8 μg/L ＆ BD （below detection）-8.7 μg/L, As 5.0 μg/L ＆ BD-10.0 μg/L for spent wash and groundwater samples, respectively. The drainage water samples had parameters within limits for industrial effluents. The spent wash samples contained metal ions higher than the permissible limits for industrial effluents and the samples of groundwater collected around the evaporation ponds contained higher concentrations of metal ions as compared to samples collected away from the evaporation ponds. Coefficient of correμtion among 11 parameters was calcuμted and contamination index was also determined, 33.3% of groundwater samples mostly collected around evaporation ponds had a contamination index above 3 and are considered extremely polluted.
文摘Electrochemical treatment of distillery .spentwash was carried out using different combinations of aluminum and iron electrodes in batch mode of operation. The spent wash was characterized for various parameters as per standard method of analysis and the treatment results were analyzed in terms of chemical oxygen demand （COD） removal efficiency o.f thespent.wash. The experiments were performed to s.tudy the effect of operating parameterssuch as current density, pH of the spent wash, agitation speed, electrolysis time and the distance between the elec- trodes on the COD removal efficiency of the spent wash. It was observed that aluminum electrodes were more suitable for treatment of distillery spent wash as compared to iron electrodes. The maximum COD removal effi- ciency of 81.3% was obtained with A1-A1 electrodes at the current density of 0.187 A.cm-2 and pH 3 for an elec-trolysis time of 2 h.
文摘Solid-liquid separation of the wastewater is very difficult because of high viscosity and high SS concentration. In this study, the effectiveness of preozonation on improving the settleability of the solids in wheat and sweet potato wastewaters was investigated using a bench-scale system and pilot treatment system respectively. Results showed that solid-liquid separation in the wheat wastewater was greatly improved by the decanter in the system(SS reduction from 24100 mg/L to 100 mg/L). However, preozonation practice did not show a significant effect on solid-liquid separation of the sweet potato wastewater. Effect of preozonation on solid-liquid separation between wheat and sweet potato wastewater showed different.
