Geometry and formation mechanism of tension gashes and their implication on the hydrocarbon accumulation in the deep-seated strata of sedimentary basin:A case from Shunnan area of Tarim Basin

With the theoretical and technological developments related to cratonic strike-slip faults,the Shuntuoguole Low Uplift in the Tarim Basin has attracted considerable attention recently.Affected by multi-stage tectonic movements,the strike-slip faults have controlled the distribution of hydrocarbon resources owing to the special fault characteristics and fault-related structures.In contrast,the kinematics and formation mechanism of strike-slip faults in buried sedimentary basins are difficult to investigate,limiting the discussion of these faults and hydrocarbon accumulation.In this study,we identified the characteristics of massive sigmoidal tension gashes(STGs)that formed in the Shunnan area of the Tarim Basin.High-resolution three-dimensional seismic data and attribute analyses were used to investigate their geometric and kinematic characteristics.Then,the stress state of each point of the STGs was calculated using seismic curvature attributes.Finally,the formation mechanism of the STGs and their roles in controlling hydrocarbon migration and accumulation were discussed.The results suggest that:(1)the STGs developed in the Shunnan area have a wide distribution,with a tensile fault arranged in an enéchelon pattern,showing an S-shaped bending.These STGs formed in multiple stages,and differential rotation occurred along the direction of strike-slip stress during formation.(2)Near the principal displacement zone of the strike-slip faults,the stress value of the STGs was higher,gradually decreasing at both ends.The shallow layer deformation was greater than the deep layer deformation.(3)STGs are critical for connecting source rocks,migrating oil and gas,sealing horizontally,and developing efficient reservoirs.This study not only provides seismic evidence for the formation and evolution of super large STGs,but also provides certain guidance for oil and gas exploration in this area.

Formation mechanism of nanopores in dense films of anodic alumina

Constant-current anodization of pure aluminum was carried out in non-corrosive capacitor working electrolytes to study the formation mechanism of nanopores in the anodic oxide films.Through comparative experiments,nanopores are found in the anodic films formed in the electrolytes after high-temperature storage(HTS)at 130°C for 240 h.A comparison of the voltage-time curves suggests that the formation of nanopores results from the decrease in formation efficiency of anodic oxide films rather than the corrosion of the electrolytes.FT-IR and UV spectra analysis shows that carboxylate and ethylene glycol in electrolytes can easily react by esterification at high temperatures.Combining the electronic current theory and oxygen bubble mold effect,the change in electrolyte composition could increase the electronic current in the anodizing process.The electronic current decreases the formation efficiency of anodic oxide films,and oxygen bubbles accompanying electronic current lead to the formation of nanopores in the dense films.The continuous electronic current and oxygen bubbles are the prerequisites for the formation of porous anodic oxides rather than the traditional field-assisted dissolution model.

Ground fissure development regularity and formation mechanism of shallow buried coal seam mining with Karst landform in Jiaozi coal mine: a case study

A comprehensive study was undertaken at Jiaozi coal mine to investigate the development regularity of ground fissures in shallow buried coal seam mining with Karst landform,shedding light on the development type,geographical distribution,dynamic development process,and failure mechanism of these ground fissures by employing field monitoring,numerical simulation,and theoretical analysis.The findings demonstrate that ground fissure development has an obvious feature of subregion,and its geographical distribution is significantly affected by topography.Tensile type,open type,and stepped type are three different categories of ground fissure.Ground fissures emerge dynamically as the panel advances,and they typically develop with a distance of less than periodic weighting step distance in advance of panel advancing position.Ground fissures present the dynamic development feature,temporary fissure has the ability of self-healing.The dynamic development process of ground fissure with closed-distance coal seam repeated mining is expounded,and the development scale is a dynamic development stage of“closure→expansion→stabilized”on the basis of the original development scale.From the perspective of topsoil deformation,the computation model considering two points movement vectors towards two directions of the gob and the ground surface is established,the development criterion considering the critical deformation value of topsoil is obtained.The mechanical model of hinged structure of inclined body is proposed to clarify the ground fissure development,and the interaction between slope activity and ground fissure development is expounded.These research results fulfill the gap of ground fissures about development regularity and formation mechanism,and can contribute to ground fissure prevention and treatment with Karst landform.

Formation mechanisms of ethyl acetate and organic acids in Kluyveromyces marxianus L1-1 in Chinese acid rice soup

This study aims to explore the formation mechanism of ethyl acetate and organic acids in acid rice soup(rice-acid soup)inoculated with Kluyveromyces marxianus L1-1 through the complementary analysis of transcriptome and proteome.The quantity of K.marxianus L1-1 varied significantly in the fermentation process of rice-acid soup and the first and third days were the two key turning points in the growth phase of K.marxianus L1-1.Importantly,the concentrations of ethyl acetate,ethanol,acetic acid,and L-lactic acid increased from day 1 to day 3.At least 4231 genes and 2937 proteins were identified and 610 differentially expressed proteins were annotated to 30 Kyoto Encyclopedia of Genes and Genomes(KEGG)pathways based on the analysis results of transcriptome and proteome.The key genes and proteins including up-regulated alcohol dehydrogenase family,alcohol O-acetyltransferase,acetyl-CoA C-acetyltransferase,acyl-coenzyme A thioester hydrolase,and down-regulated aldehyde dehydrogenase family were involved in glycolysis/gluconeogenesis pathways,starch and sucrose metabolism pathways,amino sugar and nucleotide sugar metabolism pathways,tricarboxylic acid(TCA)cycle,and pyruvate metabolism pathways,thus promoting the formation of ethyl acetate,organic acids,alcohols,and other esters.Our results revealed the formation mechanisms of ethyl acetate and organic acids in rice-acid soup inoculated with K.marxianus L1-1.

Formation mechanism of co-axial grain boundaries in a Mg alloy

Due to the insufficient slip systems in hexagonal close-packed structure,twinning is frequently activated to support stable plastic deformation of Mg alloy.In this work,we found four typical twin-like interfaces with misorientations of 102°,109°,142°and 149°,respectively,which had not only a shared[1120]zone axis of neighboring grains,but also overlapped diffraction spots similar to twins.However,highresolution transmission electron microscope(HRTEM)analysis revealed that the interfaces in real space deviated from the supposed twinning planes in reciprocal space,i.e.their overlapped diffraction spots.We clarified that the incoherent interfaces were co-axial grain boundaries(CGBs).Additionally,a special angle ofθ,close to 90°,between the interface and one side of basal plane,was frequently formed in CGBs.We proposed that interaction of multiple twinning contributes to the formation of CGBs,and theθis formed due to alternative tensile and compression twinning under a uniaxial loading.

Formation mechanism and criterion of linear segregation in ZL205A alloy

The experiments and numerical simulation were conducted for ZL205A aluminum alloy cylindrical shell casting. The formation mechanism of the linear segregation produced by the low pressure die casting (LPDC) process was investigated. And the heat transfer of the casting during solidification process was analyzed by simulation technique, resulting from the information of linear segregation obtained by plenty of experiments. The new linear segregation criterion was proposed through the simulation and experimental results. It was found that the melting metal with high Cu contents was feeding the crack shrinkage formed by the tearing under the effect of feeding pressure during the later solidification, which led to the formation of linear segregation. The control methods for the linear segregation were suggested based on the proposed mechanism. Finally, the criterion of linear segregation was confirmed by the production of the actual castings.

Formation mechanism of MgB_2 in 2LiBH_4+MgH_2 system for reversible hydrogen storage

The formation conditions of MgB2 in 2LiBH4 ＋ MgH2 system during dehydrogenation were investigated and its mechanism was discussed. The results show that direct decomposition of LiBH4 is suppressed under relative higher initial dehydrogenation pressure of 4.0×10^5 Pa, wherein LiBH4 reacts with Mg to yield MgB2, and 9.16% （mass fraction） hydrogen is released within 9.6 h at 450 ℃. However, under relatively lower initial dehydrogenation pressure of 1.0×10^2 Pa, LiBH4 decomposes independently instead of reacting with Mg, resulting in no formation of MgB2, and 7.91% hydrogen is desorbed within 5.2 h at 450 ℃. It is found that the dehydrogenation of 2LiBH4 ＋ MgH2 system proceeds more completely and more hydrogen desorption amount can be obtained within a definite time by forming MgB2. Furthermore, it is proposed that the formation process of MgB2 includes incubation period and nucleus growth process. Experimental results show that the formation process of MgB2, especially the incubation period, is promoted by increasing initial dehydrogenation pressure at constant temperature, and the incubation period is also influenced greatly by dehydrogenation temperature.

Microstructures and formation mechanism of headstand pyrocarbon cones developed by electromagnetic-field-assisted CVD

Novel headstand pyrocarbon cones （HPCs） with hollow structure were developed on the surfaces of pyrocarbon layers of the carbon/carbon （C/C） composites at 650-750 °C by the electromagnetic-field-assisted chemical vapor deposition in the absence of catalysts. The fine microstructures of the HPCs were characterized by high-resolution transmission electron microscopy. The results show that the textural features of the HPCs directly transfer from turbostratic structure in roots to a well-ordered high texture in stems. And the degree of high texture ordering decreases gradually from the stem to the tail of the HPCs. The formation mechanism of the HPCs was inferred as the comprehensive effect of polarization induction on electromagnetic fields and particle-filler property under disruptive discharge.

Formation mechanism and organizational controlling of ultra-fine-grain copper processed by asymmetrical accumulative rolling-bond and annealing

The initial copper with large grain sizes of 60-100 μm was processed by six passes asymmetrical accumulative rolling-bond （AARB） and annealing, the ultra-fine-grained （UFG） copper with grain size of 200 nm was obtained, and the microstructures and properties were studied. The results show that there are large sub-structures and also texture component C for the UFG copper obtained by six passes AARB, possessing high strength and microhardness in company with poor elongation and conductivity. Thereafter, the UFG copper was annealed at 220 °C for 35 min, in which the sub-structures disappear, the grain boundaries are composed of big angle grain boundaries, and the textures are composed of a variety of texture components and parts of twins. Compared with the UFG copper obtained by six passes AARB, the tensile strength and yield strength for the UFG copper obtained by six passes AARB and annealing at 220 °C for 35 min are decreased slightly, the elongation and conductivity are improved obviously.

Preparation, formation mechanism and mechanical properties of multilayered TiO_2-organic nanocomposite film

Ti O2-organic multilayered nanocomposite films were deposited on a self-assembled monolayer-coated silicon substrate based on layer-by-layer technique and chemical bath deposition method by a hydrolysis of Ti Cl4 in an acid aqueous solution. The chemical compositions, surface morphologies and mechanical properties of the films were investigated by X-ray photoelectron spectrometer(XPS), scanning electron microscopy(SEM) and nanoindentation depth-sensing technique, respectively. The results indicate that the major chemical compositions of the films are Ti and O. The principal mechanism for the nucleation and growth of the films is homogeneous nucleation, and the layer number of films has great influence on the surface morphology and roughness of the films. In addition, mechanical nanoindentation testing presents a significant increase in hardness and fracture toughness of titanium dioxide multilayered films compared with single-layer titanium dioxide thin film.

Formation mechanism and crystal simulation of Na_2O-doped calcium aluminate compounds

Calcium aluminate clinkers doped with Na2O were synthesized using analytically pure reagents CaCO3, Al2O3, SiO2 and Na2CO3. The effects of Na2O-doping on the formation mechanism of calcium aluminate compounds and the crystal property of 12CaO·7Al2O3 (C12A7) cell were studied. The results show that the minerals containing Na2O mainly include 2Na2O·3CaO·5Al2O3 and Na2O·Al2O3, when the Na2O content in clinkers is less than 4.26% (mass fraction). The rest of Na2O is mainly doped in 12CaO·7Al2O3, which results in the decrease of the crystallinity of 12CaO·7Al2O3. The crystallinity of 2Na2O·3CaO·5Al2O3 is also inversely proportional to the Na2O content in clinkers. The formation processes of 2Na2O·3CaO·5Al2O3 and 12CaO·7Al2O3 can be divided into two ways, which are the direct reactions of raw materials and the transformation of CaO·Al2O3, respectively. The simulation shows that the covalency of O-Na bond in Na2O-doped 12CaO·7Al2O3 cell is weaker than those of O-Ca and O-Al bonds. The free energy of the unit cell increases because of Na2O doping, which results in the improvement of chemical activity of 12CaO·7Al2O3. The leaching efficiency of Al2O3 in clinker is improved from 34.81% to 88.17% when the Na2O content in clinkers increases from 0 to 4.26%.

Application of General Shear Theory to the Study of Formation Mechanism of the Metamorphic Core Complex:A Case Study of Xiaoqinling in Central China

: The kinematic vorticity number and strain of the mylonitic zone related to the detachment fault increase from ESE to WNW along the moving direction of the upper plate of the Xiaoqinling metamorphic core complex (XMCC) and the geometry of quartz c-axis fabrics changes progressively from crossed girdles to single girdles in the same direction. Therefore, pure shear is dominant in the ESE part of the XMCC while simple shear becomes increasingly important towards WNW. However, the shear type does not change with the strain across the shear zone, thus the variation of shear type is of significance in indicating the formation mechanism. The granitic plutons within the XMCC came from the deep source and their emplacement was an active and forceful upwelling prior to the detachment faulting. The PTt path demonstrates that magmatism is an important cause for the formation of the XMCC. The formation mechanism of the XMCC is supposed to be active plutonism and passive detachment. Crustal thickening and magmatic doming caused necking extension with pure shear, and magmatic heating and doming resulted in detachment extension with simple shear and formed the XMCC.

Reservoir characteristics,formation mechanisms and petroleum exploration potential of volcanic rocks in China

Characterized by complex lithology and strong heterogeneity, volcanic reservoirs in China developed three reservoir space types： primary pores, secondary pores and fractures. The formation of reservoir space went through the cooling and solidification stage （including blast fragmentation, crystallization differentiation and solidification） and the epidiagenesis stage （including metasomatism, filling, weathering and leaching, formation fluid dissolution and tectonism）. Primary pores were formed at the solidification stage, which laid the foundation for the development and transformation of effective reservoirs. Secondary pores were formed at the epidiagenesis stage, with key factors as weathering and leaching, formation fluid dissolution and tectonism. In China, Mesozoic-Cenozoic volcanic rocks developed in the Songliao Basin and Bohai Bay Basin in the east and Late Paleozoic volcanic rocks developed in the Junggar Basin, Santanghu Basin and Ta- rim Basin in the west. There are primary volcanic reser- voirs and secondary volcanic reservoirs in these volcanic rocks, which have good accumulation conditions and great exploration potential.

Formation Mechanism of the Changxing Formation Gas Reservoir in the Yuanba Gas Field,Sichuan Basin,China

In a very gentle platform-margin paleogeographic environment, platform-margin reef flat facies carbonate reservoir rocks were developed in the Changxing Formation of Yuanba field. Later weak structural evolution and diagenetic evolution caused the Changxing Formation to form lithologic traps, with good reservoirs such as dissolved bioclastic dolostone and dissolved pore dolostone. The Changxing Formation gas reservoir is a pseudo-layered porous lithologic gas reservoir under pressure depletion drive, with high H2S and moderate CO2 contents. This paper predictes that the conducting system for the Changxing Formation gas reservoir is possibly composed of the pores and microfractures in the Changxing Formation reservoir, the top erosional surface of the Changxing Formation, as well as the micropores and microfractures in the underlying formations. The Changxing Formation reservoir has experienced 3 hydrocarbon charging stages. This paper suggests that diffusion is the major formation mechanism for this gas reservoir. In the Middle and Late Yanshanian, the Yuanba area entered the major gas charging stage. The gas migrated mainly through diffusion and with the assistance of seepage flow in small faults and microfractures from the source rocks and the other oil-bearing strata to the Changxing Formation carbonate reservoir rocks, forming lithologic gas pools. In the Himalayan Epoch, the lithologic traps were uplifted as a whole without strong modification or overlapping, and were favorable for gas preservation.

Formation mechanisms of Ni-Al intermetallics during heat treatment of Ni coating on 6061 Al substrate

The formation mechanisms and growth kinetics of Al3 Ni and Al3Ni2 in Ni-Al diffusion couple prepared by electrodeposition of Ni on Al substrate were investigated. The nickel coating with 20 μm thickness was applied on 6061 aluminum alloy by direct current electroplating. The samples were then heat-treated for different durations at 450, 500 and 550 °C under argon atmosphere. The intermetallic phases were identified by means of scanning electron microscopy（SEM）, energy dispersive spectrometry（EDS） and X-ray diffraction（XRD）. The results showed that the formation of intermetallic phases consisted of two important steps. The first step was the lateral growth of intermetallic phase from separate sites, resulting in the formation of a continuous layer. The second step was the growth of the continuous intermetallic layer in the direction perpendicular to the interface. However, excessive increase in thickness of intermetallic phases led to the detachment of reaction products, i.e., Al3 Ni and Al3Ni2, from the substrate. It was also observed that aluminum was the dominant diffusing element during Al3 Ni growth, while nickel diffusion was dominant during Al3Ni2 growth. The growth kinetics of both Al3 Ni and Al3Ni2 phases obeyed a parabolic law.

Formation mechanism of rockburst in deep tunnel adjacent to faults:Implication from numerical simulation and microseismic monitoring

Rockbursts were frequently encountered in the construction of deeply buried tunnels at the Jinping-II hydropower station, Southwest China. In those cases, the existence of large structural planes, such as faults, was usually observed near the excavation boundaries. The formation mechanism of the “11·28” rockburst, which was a typical rockburst and occurred in a drainage tunnel under a deep burial depth, high in-situ stress state and complex geological conditions, has been difficult to explain. Realistic failure process analysis(RFPA3D) software was adopted to numerically simulate the whole failure process of the surrounding rock mass around the tunnel subjected to excavation. The spatial distribution of acoustic emission derived from numerical simulation contributed to explaining the mechanical responses of the process. Analyses of the stress, safety reserve coefficient and damage degree were performed to reveal the effect of faults on the formation of rockbursts in the deep tunnel. The existence of faults results in the formation of stress anomaly areas between the tunnel and the fault. The surrounding rock mass failure propagates toward the fault from the initial failure, to different degrees. The relative positions and angles of faults play significant roles in the extent and development of surrounding rock mass failure, respectively. The increase in the lateral stress coefficient leads to the aggravation of the surrounding rock mass damage, especially in the roof and floor of the tunnel. Moreover, as the rock strength-stress ratio increases, the failure mode of the near-fault tunnel gradually changes from the stress-controlled type to the compound-controlled type. These findings were consistent with the microseismic monitoring results and field observations, which was helpful to understand the mechanical behavior of tunnel excavation affected by faults. The achievements of this study can provide some references for analysis of the failure mechanisms of similar deep tunnels.

Spatial Structure,Hierarchy and Formation Mechanisms of Scientific Collaboration Networks:Evidence of the Belt and Road Regions

Scientific collaboration has become an important part of the people-to-people exchanges in the Belt and Road initiative,and remarkable progress has been made since 2013.Taking the 65 countries along the Belt and Road(BRI countries)as the research areas and using collaborated Web of Science(WOS)core collection papers to construct an international scientific collaboration matrix,the paper explores the spatial structure,hierarchy and formation mechanisms of scientific collaboration networks of 65 countries along the Belt and Road.The results show that:1)Beyond the Belt and Road regions(BRI regions),Central&Eastern Europe,China and West Asia&North Africa have formed a situation in which they all have the most external links with other countries beyond BRI regions.China has the dominant role over other BRI countries in generating scientific links.The overall spatial structure has changed to a skeleton structure consisting of many dense regions,such as Europe,North America,East Asia and Oceania.2)Within the Belt and Road regions,Central&Eastern Europe has become the largest collaboration partner with other sub-regions in BRI countries.The spatial structure of scientific collaboration networks has transformed from the‘dual core’composed of China and the Central&Eastern Europe region,to the‘multi-polarization’composed of‘one zone and multi-points’.3)The hierarchical structure of scientific collaboration networks presents a typical‘core-periphery’structure,and changes from‘single core’to‘double cores’.4)Among the formation mechanisms of scientific collaboration networks,scientific research strength and social proximity play the most important roles,while geographical distance gradually weakens the hindrance to scientific collaboration.

Characteristics and Formation Mechanism of Giant Long-Runout Landslide: A Case Study of the Gamisi Ancient Landslide in the Upper Minjiang River, China

The upper reaches of the Minjiang River are in the eastern margin of the Tibetan Plateau,where active faults are well developed and earthquakes frequently occur.Anomalous climate change and the extremely complex geomechanical properties of rock and soil have resulted in a number of geohazards.Based on the analysis of remote sensing interpretations,geological field surveys,geophysical prospecting and geological dating results,this paper discusses the developmental characteristics of the Gamisi ancient landslide in Songpan County,Sichuan Province,and investigates its geological age and formation mechanism.This study finds that the Gamisi ancient landslide is in the periglacial region of the Minshan Mountain and formed approximately 25 ka BP.The landslide initiation zone has a collapse and slide zone of approximately 22.65×106–31.7×106 m3 and shows a maximum sliding distance of approximately 1.42 km,with an elevation difference of approximately 310 m between the back wall of the landslide and the leading edge of the accumulation area.The landslide movement was characterized by a high speed and long runout.During the sliding process,the landslide body eroded and dammed the ancient Minjiang River valley.The ancient river channel was buried 30-60 m below the surface of the landslide accumulation area.Geophysical prospecting and drilling observations revealed that the ancient riverbed was approximately 80-100 m thick.After the dam broke,the Minjiang River was migrated to the current channel at the leading edge of the landslide.The Gamisi ancient landslide was greatly affected by the regional crustal uplift,topography,geomorphology and paleoclimatic change.The combined action of periglacial karstification and climate change caused the limestone at the rear edge of the landslide fractured,thus providing a lithological foundation for landslide occurrence.Intense tectonic activity along the Minjiang Fault,which runs through the middle and trailing parts of the Gamisi ancient landslide,may have been the main factor inducing landsliding.Studying the Gamisi ancient landslide is of great significance for investigating the regional response to paleoclimatic change and geomorphologic evolution of the Minjiang Fault since the late Pleistocene and for disaster prevention and mitigation.

Reservoir differences and formation mechanisms in the Ke-Bai overthrust belt,northwestern margin of the Junggar Basin,China

There are some differences in reservoir quality of clastic rock between the hanging wall and the foot wall of the Ke-Bai overthrust belt, northwestern margin of the Junggar Basin, western China, which affect the efficient petroleum exploration in this highly mature exploration area. Based on a large number of thin-sections, cast thin-sections, and physical property analysis of cores, we systematically discuss the Permian-Jurassic reservoir differences between the hanging wall and the foot wall of the Ke- Bai overthrust fault from the aspects of structural evolution, time-space distribution of the depositional system, diagenesis characteristics, and reservoir quality and analyzed the reasons for the differences in reservoir properties. The overthrusting of the Ke-Bai fault directly results in different burial histories, diagenesis evolution, and porosity evolution between the hanging wall and the foot wall. The diflbrences of reservoir characteristics are mainly embodied in buried depth, grain size, sedimentary facies, diagenetic stage, and reservoir quality. The analysis results showed that burial history and depositional characteristics controlled by overthrusting are direct influencing factors of reservoir differences. Because of shallow burial depth of the hanging wall, the reservoir compaction is weak and primary pores are preserved well. The porosity of reservoir on the hanging wall is generally 10%-25%. The strata on the foot wall are deeply buried, and there are mainly mixed pores with the average porosity of 5%-20%. The favorable reservoir on the foot wall is generally developed near faults or in the channel sand bodies, which are usually dissolution development areas.

Formation mechanism and wear behavior of gradient nanostructured Inconel 625 alloy

The formation mechanism and wear behavior of a gradient nanostructured(GNS) Inconel 625 alloy were investigated using SEM, TEM and ball-on-disc sliding wear tester. The results show that surface mechanical grinding treatment(SMGT) induced an approximately 800 μm-deep gradient microstructure, consisting of surface nano-grained,nano-laminated, nano-twined, and severely deformed layers, which resulted in a reduced gradient in micro-hardness from 6.95 GPa(topmost surface) to 2.77 GPa(coarse-grained matrix). The nano-grained layer resulted from the formation of high-density nano-twins and subsequent interaction between nano-twins and dislocations. The width and depth of the wear scar, wear loss volume, and wear rate of the SMGT-treated sample were smaller than those of untreated coarse-grained sample. Moreover, the wear mechanisms for both samples were mainly abrasive wear and adhesive wear, accompanied with mild oxidation wear. The notable wear resistance enhancement of the GNS Inconel 625 alloy was attributed to the high micro-hardness, high residual compressive stress, and high strain capacity of the GNS surface layer.