Optical frequency combbased Fourier transform spectroscopy has the features of broad spectral bandwidth,high sensitivity,andmultiplexed trace gas detection,which has valuable application potential in the fields of pre...Optical frequency combbased Fourier transform spectroscopy has the features of broad spectral bandwidth,high sensitivity,andmultiplexed trace gas detection,which has valuable application potential in the fields of precision spectroscopy and trace gas detection.Here,we report the development of a mid-infrared Fourier transform spectrometer based on an optical frequency comb combined with a Herriott-type multipass cell.Using this instrument,the broadband absorption spectra of several important molecules,including methane,acetylene,water molecules and nitrous oxide,are measured by near real-time data acquisition in the 2800-3500 cm^(-1)spectral region.The achieved minimum detectable absorption of the instrument is 4.4×10^(-8)cm^(-1)·Hz^(-1/2)per spectral element.Broadband spectra of H_(2)0 are fited using the Voigt profile multispectral fitting technique and the consistency of the concentration inversion is 1%.Our system also enables precise spectroscopic measurements,and it allows the determination of the spectral line positions and upper state constants of N_(2)O in the(0002)-(1000)band,with results in good agreement with those reported by Toth[Appl.Opt.30,5289(1991)].展开更多
基于有机胺吸收剂的化学吸收法能够有效捕集船舶烟气中的CO_(2),但吸收剂降解失效、挥发泄漏会造成严重的环境问题。虽然傅里叶红外光谱仪能够实时监测挥发的有机胺体积分数,但受限于高饱和蒸气压有机胺类蒸气难标定问题,对胺类体积分...基于有机胺吸收剂的化学吸收法能够有效捕集船舶烟气中的CO_(2),但吸收剂降解失效、挥发泄漏会造成严重的环境问题。虽然傅里叶红外光谱仪能够实时监测挥发的有机胺体积分数,但受限于高饱和蒸气压有机胺类蒸气难标定问题,对胺类体积分数的实际监测精度较低。对此,设计两种傅里叶红外光谱仪中高饱和蒸气压有机胺蒸气体积分数标定方法,分别为固定比例校准算法和基于循环神经网络的序列映射法。结果表明,相较于固定比例法,基于循环神经网络的非线性序列映射法能够实现更好的校准性能,平均绝对误差下降了81.57%,均方误差下降了70.05%,可有效反映船舶碳捕集与封存(carbon capture and storage,CCS)系统对大气环境的影响。展开更多
基金supported by the National Natural Science Foundation China(No.42022051,No.U21A2028)Youth Innovation Promotion Association of the Chinese Academy of Sciences(No.Y202089)the HFIPS Director's Fund(No.YZJJ202101,No.BJPY2023A02).
文摘Optical frequency combbased Fourier transform spectroscopy has the features of broad spectral bandwidth,high sensitivity,andmultiplexed trace gas detection,which has valuable application potential in the fields of precision spectroscopy and trace gas detection.Here,we report the development of a mid-infrared Fourier transform spectrometer based on an optical frequency comb combined with a Herriott-type multipass cell.Using this instrument,the broadband absorption spectra of several important molecules,including methane,acetylene,water molecules and nitrous oxide,are measured by near real-time data acquisition in the 2800-3500 cm^(-1)spectral region.The achieved minimum detectable absorption of the instrument is 4.4×10^(-8)cm^(-1)·Hz^(-1/2)per spectral element.Broadband spectra of H_(2)0 are fited using the Voigt profile multispectral fitting technique and the consistency of the concentration inversion is 1%.Our system also enables precise spectroscopic measurements,and it allows the determination of the spectral line positions and upper state constants of N_(2)O in the(0002)-(1000)band,with results in good agreement with those reported by Toth[Appl.Opt.30,5289(1991)].
文摘基于有机胺吸收剂的化学吸收法能够有效捕集船舶烟气中的CO_(2),但吸收剂降解失效、挥发泄漏会造成严重的环境问题。虽然傅里叶红外光谱仪能够实时监测挥发的有机胺体积分数,但受限于高饱和蒸气压有机胺类蒸气难标定问题,对胺类体积分数的实际监测精度较低。对此,设计两种傅里叶红外光谱仪中高饱和蒸气压有机胺蒸气体积分数标定方法,分别为固定比例校准算法和基于循环神经网络的序列映射法。结果表明,相较于固定比例法,基于循环神经网络的非线性序列映射法能够实现更好的校准性能,平均绝对误差下降了81.57%,均方误差下降了70.05%,可有效反映船舶碳捕集与封存(carbon capture and storage,CCS)系统对大气环境的影响。
