The pulp and froth zones are the main components of froth flotation as it defines both quality of the end product and overall efficiency. The importance of the properties of the two zones, which include pulp hydrodyna...The pulp and froth zones are the main components of froth flotation as it defines both quality of the end product and overall efficiency. The importance of the properties of the two zones, which include pulp hydrodynamics, froth bubble coalescence rate, water overflow rate, air recovery, etc., is being increasingly recognized. The properties are depending not only on the type and concentration of the frother but also on the nature and amount of the particles present in the flotation system, and as well as the frother-particle interactions and potentially of bubble-particle interactions. To date, there is no specific criterion to quantify pulp and froth properties through the interactions between frothers and particles because the various related mechanisms occurring in the pulp and froth are not fully understood. Linking the properties to the metallurgical performance is also challenged. In order to better understand the effect of these issues in flotation, in this review paper, the past and recently published articles relevant to characterizations of pulp and froth properties are widely reviewed;the findings and the gap of knowledge in this area are highlighted for further research.展开更多
The size of bubbles created in the flotation process is of great importance to the efficiency of the mineral separation achieved.Meanwhile,it is believed that frother transport between phases is perhaps the most impor...The size of bubbles created in the flotation process is of great importance to the efficiency of the mineral separation achieved.Meanwhile,it is believed that frother transport between phases is perhaps the most important reason for the interactive nature of the phenomena occurring in the bulk and froth phases in flotation,as frother adsorbed in the surface of rising bubbles is removed from the bulk phase and then released into the froth as a fraction of the bubbles burst.This causes the increased concentration in the froth compared to the bulk concentration,named as frother partitioning.Partitioning reflects the adsorption of frother on bubbles and how to influence bubble size is not known.There currently exists no such a topic aiming to link these two key parameters.To fill this vacancy,the correspondence between bubble size and frother partitioning was examined.Bubble size was measured by sampling-for-imaging(SFI)technique.Using total organic carbon(TOC)analysis to measure the frother partitioning between froth and bulk phases was determined.Measurements have shown,with no exceptions including four different frothers,higher frother concentration is in the bulk than in the froth.The results also show strong partitioning giving an increase in bubble size which implies there is a compelling relationship between these two,represented by CFroth/CBulk and D32.The CFroth/CBulkand D32 curves show similar exponential decay relationships as a function of added frother in the system,strongly suggesting that the frother concentration gradient between the bulk solution and the bubble interface is the driving force contributing to bubble size reduction.展开更多
A new visual method for quantitative measurement of frothers effect and flotation efficiency was presented. A self-designed electrolytic cell was chosen as the reaction environment with sodium chloride (NaCl) as the e...A new visual method for quantitative measurement of frothers effect and flotation efficiency was presented. A self-designed electrolytic cell was chosen as the reaction environment with sodium chloride (NaCl) as the electrolyte. Constant current, supplied by a self-designed power supplier and fixed cathode and anode equipment, guaranteed the constant bubble volume per unit time. Even aperture of the cathode material guaranteed the original bubbles size to be uniform. Bubble generating equipment was connected with a microscopical camera. Statistic data collected by high speed charge-coupled device (CCD) and processed by software Sigmascan and Matlab could reflect bubble characteristics. The efficiency of dipropylene glycol monomethyl ether (DPM) and tripropylene glycol n-butyl ethel (TPnB) were measured at the same condition, and 2×10-4 mol/L and 5×10-2 mol/L were found to be the inflexions of bubble size changes.展开更多
文摘The pulp and froth zones are the main components of froth flotation as it defines both quality of the end product and overall efficiency. The importance of the properties of the two zones, which include pulp hydrodynamics, froth bubble coalescence rate, water overflow rate, air recovery, etc., is being increasingly recognized. The properties are depending not only on the type and concentration of the frother but also on the nature and amount of the particles present in the flotation system, and as well as the frother-particle interactions and potentially of bubble-particle interactions. To date, there is no specific criterion to quantify pulp and froth properties through the interactions between frothers and particles because the various related mechanisms occurring in the pulp and froth are not fully understood. Linking the properties to the metallurgical performance is also challenged. In order to better understand the effect of these issues in flotation, in this review paper, the past and recently published articles relevant to characterizations of pulp and froth properties are widely reviewed;the findings and the gap of knowledge in this area are highlighted for further research.
基金Project supported by the Collaborative Research and Development Program of Natural Sciences and Engineering Research Council of Canada
文摘The size of bubbles created in the flotation process is of great importance to the efficiency of the mineral separation achieved.Meanwhile,it is believed that frother transport between phases is perhaps the most important reason for the interactive nature of the phenomena occurring in the bulk and froth phases in flotation,as frother adsorbed in the surface of rising bubbles is removed from the bulk phase and then released into the froth as a fraction of the bubbles burst.This causes the increased concentration in the froth compared to the bulk concentration,named as frother partitioning.Partitioning reflects the adsorption of frother on bubbles and how to influence bubble size is not known.There currently exists no such a topic aiming to link these two key parameters.To fill this vacancy,the correspondence between bubble size and frother partitioning was examined.Bubble size was measured by sampling-for-imaging(SFI)technique.Using total organic carbon(TOC)analysis to measure the frother partitioning between froth and bulk phases was determined.Measurements have shown,with no exceptions including four different frothers,higher frother concentration is in the bulk than in the froth.The results also show strong partitioning giving an increase in bubble size which implies there is a compelling relationship between these two,represented by CFroth/CBulk and D32.The CFroth/CBulkand D32 curves show similar exponential decay relationships as a function of added frother in the system,strongly suggesting that the frother concentration gradient between the bulk solution and the bubble interface is the driving force contributing to bubble size reduction.
基金Project(50834006) supported by National Natural of Science Foundation of China
文摘A new visual method for quantitative measurement of frothers effect and flotation efficiency was presented. A self-designed electrolytic cell was chosen as the reaction environment with sodium chloride (NaCl) as the electrolyte. Constant current, supplied by a self-designed power supplier and fixed cathode and anode equipment, guaranteed the constant bubble volume per unit time. Even aperture of the cathode material guaranteed the original bubbles size to be uniform. Bubble generating equipment was connected with a microscopical camera. Statistic data collected by high speed charge-coupled device (CCD) and processed by software Sigmascan and Matlab could reflect bubble characteristics. The efficiency of dipropylene glycol monomethyl ether (DPM) and tripropylene glycol n-butyl ethel (TPnB) were measured at the same condition, and 2×10-4 mol/L and 5×10-2 mol/L were found to be the inflexions of bubble size changes.
