To study the effects of lanthanide ions on the geometrically frustrated antiferromagnets and their magnetic properties,we grew high-quality single crystals of LnCu_(3)(OH)_(6)Br_(3)(Ln=Nd,Sm,and Eu)by hydrothermal met...To study the effects of lanthanide ions on the geometrically frustrated antiferromagnets and their magnetic properties,we grew high-quality single crystals of LnCu_(3)(OH)_(6)Br_(3)(Ln=Nd,Sm,and Eu)by hydrothermal method and studied their crystal structures and magnetic properties.The refinements of the crystal structure referred to the powder x-ray diffraction data show that LnCu_(3)(OH)_(6)Br_(3)adopt a Kapellasite-type layer structure,which is isostructural to their chlorine analogue.Magnetic susceptibilities demonstrate that LnCu_(3)(OH)_(6)Br_(3)have strong antiferromagnetic coupling and a pronounced magnetic frustration effect.Magnetization measurements indicate canted antiferromagnetic ordering of Cu^(2+)ions around 16 K within the kagoméplane and weak ferromagnetic coupling.Moreover,shoulder-like anomalies in specific heat around 16 K could be a signature of emergent of magnetic ordering.The low-temperature negative magnetization and specific heat of LnCu_(3)(OH)_(6)Br_(3)(Ln=Nd,Sm,and Eu)indicate that Ln^(3+)ions induce more exotic magnetic ground state properties.展开更多
The doping effects on the frustration and the magnetic properties in hexagonal compounds ot YMn0.9A0.1O3 (A=A1, Fe and Cu) are investigated. Experimental results indicate that both the non-magnetic and magnetic ion ...The doping effects on the frustration and the magnetic properties in hexagonal compounds ot YMn0.9A0.1O3 (A=A1, Fe and Cu) are investigated. Experimental results indicate that both the non-magnetic and magnetic ion dopants lead to the increase of magnetic moments and the decrease of the absolute value of Curie-Weiss temperature (|θcw|)- Compared with pure YMnOa, the geometrical frustration of YMn0.9 A0. 1O3 is greatly suppressed and the magnetic coupling in that exhibits dopant-dependent. In addition, for the doped YMno.gAo.103, the antiferromagnetic transition temperature (TN) is also suppressed slightly, which shows an abnormal dilution effect and it may be ascribed to the reduction of frustration due to the chemical substitution.展开更多
We synthesized a quasi-two-dimensional distorted triangular lattice antiferromagnet Ca3CoNb2O9, in which the effective spin of Co2+is 1/2 at low temperatures, whose magnetic properties were studied by dc susceptibili...We synthesized a quasi-two-dimensional distorted triangular lattice antiferromagnet Ca3CoNb2O9, in which the effective spin of Co2+is 1/2 at low temperatures, whose magnetic properties were studied by dc susceptibility and magnetization techniques. The x-ray diffraction confirms the quality of our powder samples. The large Weiss constant θCW --55 K and the low Neel temperature TN- 1.45 K give a frustration factor f =| θCW/TN|≈ 38, suggesting that Ca3 Co Nb2O9resides in strong frustration regime. Slightly below TN, deviation between the susceptibility data under zero-field cooling(ZFC)and field cooling(FC) is observed. A new magnetic state with 1/3 of the saturate magnetization Ms is suggested in the magnetization curve at 0.46 K. Our study indicates that Ca3 Co Nb2O9is an interesting material to investigate magnetism in triangular lattice antiferromagnets with weak anisotropy.展开更多
In this study, a T-maze-based frustration model in rats was established using sucrose-reward deprivation, The results revealed that rats maintained a 75% preference for the sucrose-reward arm in the reward phase. Duri...In this study, a T-maze-based frustration model in rats was established using sucrose-reward deprivation, The results revealed that rats maintained a 75% preference for the sucrose-reward arm in the reward phase. During the sucrose-deprivation frustration phase, both the preference for the sucrose-deprivation arm (62.5%) and time spent waiting in the sucrose-deprivation arm decreased. Acute injection of morphine increased the preference in a dose-dependent fashion, and prolonged the waiting duration in the sucrose-deprivation arm. These findings indicate that morphine specifically inhibited the frustration response induced by sucrose reward deprivation. To further elucidate the pharmacological mechanisms involved, the opioid receptor antagonist naloxone was given to model rats prior to the injection of morphine. The results revealed that naloxone administration markedly attenuated the anti-frustration-like effects of 3 mg/kg morphine treatment. These findings suggest that morphine attenuates the frustration-like response to reward deprivation in rats through the opioid receptor.展开更多
This paper studies a spin ladder model which possesses frustrating interactions. By using both the bosonization and the density matrix renormalization group techniques, it shows that the intermediate columnar dimerize...This paper studies a spin ladder model which possesses frustrating interactions. By using both the bosonization and the density matrix renormalization group techniques, it shows that the intermediate columnar dimerized phase, which exists in a narrow parameter region of the so-called ~/1 - J2 model, vanishes if the interchain frustration is weak and anisotropic. Therefore, it concludes that the frustrating interaction indeed plays an important role in producing such a phase. As a complementary to our previous investigation, it reaches a more complete picture of the quantum phase transition in the frustrated spin ladder systems.展开更多
Background Although frustration is a common emotional reaction while playing games,an excessive level of frustration can negatively impact a user's experience,discouraging them from further game interactions.The a...Background Although frustration is a common emotional reaction while playing games,an excessive level of frustration can negatively impact a user's experience,discouraging them from further game interactions.The automatic detection of frustration can enable the development of adaptive systems that can adapt a game to a user's specific needs through real-time difficulty adjustment,thereby optimizing the player's experience and guaranteeing game success.To this end,we present a speech-based approach for the automatic detection of frustration during game interactions,a specific task that remains under explored in research.Method The experiments were performed on the Multimodal Game Frustration Database(MGFD),an audiovisual dataset-collected within the Wizard-of-Oz framework-that is specially tailored to investigate verbal and facial expressions of frustration during game interactions.We explored the performance of a variety of acoustic feature sets,including Mel-Spectrograms,Mel Frequency Cepstral Coefficients(MFCCs),and the low-dimensional knowledge-based acoustic feature set eGeMAPS.Because of the continual improvements in speech recognition tasks achieved by the use of convolutional neural networks(CNNs),unlike the MGFD baseline,which is based on the Long Short Term Memory(LSTM)architecture and Support Vector Machine(SVM)classifier-in the present work,we consider typical CNNs,including ResNet,VGG,and AlexNet.Furthermore,given the unresolved debate on the suitability of shallow and deep networks,we also examine the performance of two of the latest deep CNNs:WideResNet and EfficientNet.Results Our best result,achieved with WideResNet and Mel-Spectrogram features,increases the system performance from 58.8%unweighted average recall(UAR)to 93.1%UAR for speech-based automatic frustration recognition.展开更多
In this study, we consider the emergence of explosive synchronization in scale-free networks by considering the Kuramoto model of coupled phase oscillators. The natural frequencies of oscillators are assumed to be cor...In this study, we consider the emergence of explosive synchronization in scale-free networks by considering the Kuramoto model of coupled phase oscillators. The natural frequencies of oscillators are assumed to be correlated with their degrees and frustration is included in the system. This assumption can enhance or delay the explosive transition to synchronization. Interestingly, a de-synchronization phenomenon occurs and the type of phase transition is also changed. Furthermore, we provide an analytical treatment based on a star graph, which resembles that obtained in scale-free networks. Finally, a self-consistent approach is implemented to study the de-synchronization regime. Our findings have important implications for controlling synchronization in complex networks because frustration is a controllable parameter in experiments and a discontinuous abrupt phase transition is always dangerous in engineering in the real world.展开更多
The concept of"packing frustration"has been used to understand the self-assembly behaviors of block copolymers for decades.However,rare attention has been paid to tailoring the packing frustration.This accou...The concept of"packing frustration"has been used to understand the self-assembly behaviors of block copolymers for decades.However,rare attention has been paid to tailoring the packing frustration.This account provides a review of our recent endeavor of controlling the self-assembly of block copolymers via tailoring the packing frustration.The basic idea is to release the packing frustration of chains through the local segregation between different blocks of the same component filing different spaces of near and far.Two different majority blocks are designed to release their packing frustration in the matrix.In particular,this effect of released packing frustration has been successfullycombined with other effectss such as the stretched bridging block to stabilize many unusual low.coordinated phases.We have also proposed to release the packing frustration of minority blocks within the interface curva-ture by designing the architectures of minority blocks.The effect of released packing frustration of minority blocks is aplied to drastically expand the region of spherical phases and thus to obtain significant regions of complex Frank Kasper phases.In brief,the self.assembly of block copolymers can be largely contrlled by tailoring the packing frustration of blocks,even leading to the formation of many unusual ordered phases.展开更多
Many times, my Chinese col- leagues, students and friends have told me how fortunate they are and how much they have ben- efited from me. Not so. I’m theone who has benefited by teaching English inChina. I have met m...Many times, my Chinese col- leagues, students and friends have told me how fortunate they are and how much they have ben- efited from me. Not so. I’m theone who has benefited by teaching English inChina. I have met many people and mademany friends. I展开更多
Many animals migrate during the breeding season.It is important to study the patterns of breeding migration of wild animals,especially rare and endangered species.However,current data acquisition methods are too coars...Many animals migrate during the breeding season.It is important to study the patterns of breeding migration of wild animals,especially rare and endangered species.However,current data acquisition methods are too coarse and imprecise for investigating the circadian rhythms of migrations in amphibians.Based on the frustrated total reflection image(FTRI),we developed a new device and recorded the precise migration time of an endangered salamander,Liangshantriton taliangensis.During the breeding period,a total of 33 individuals were effectively recorded.Analysis of the data indicated that the circadian rhythm of breeding migration in L.taliangensis was bimodal,and migration mainly occurred from 05:00 to 13:00(81.82%of the total migration records).The average relative activity intensity index(RAI)of breeding migration peaked in the temperature range of 14.0–16.0°C.With increased average relative air humidity,the activity intensity first increased and then decreased,reaching a peak in the humidity range of 91.0%–97.0%.These results demonstrate that our new device is a viable and accurate method for recording the migration time of target species.It is important to reveal the breeding migration pattern of L.taliangensis,which is important for the conservation of this species.Meanwhile,this new device can be used for field monitoring and conservation studies of amphibians,reptiles and other animals.展开更多
The magnetic and electronic properties of the geometrically frustrated triangular antiferromagnet CuCrO2 are investigated by first principles through density functional theory calculations within the generalized gradi...The magnetic and electronic properties of the geometrically frustrated triangular antiferromagnet CuCrO2 are investigated by first principles through density functional theory calculations within the generalized gradient approxi- mations (GGA)+U scheme. The spin exchange interactions up to the third nearest neighbours in the ab plane as well as the coupling between adjacent layers are calculated to examine the magnetism and spin frustration. It is found that CuCrO2 has a natural two-dimensional characteristic of the magnetic interaction. Using Monte Carlo simulation, we obtain the Neel temperature to be 29.9 K, which accords well with the experimental value of 24 K. Based on non- collinear magnetic structure calculations, we verify that the incommensurate spiral-spin structure with (110) spiral plane is believable for the magnetic ground state, which is consistent with the experimental observations. Due to intra-layer geometric spin frustration, parallel helical-spin chains arise along the a, b, or a+ b directions, each with a screw-rotation angle of about I20°. Our calculations of the density of states show that the spin frustration plays an important role in the change of d-p hybridization, while the spin-orbit coupling has a very limited influence on the electronic structure.展开更多
Objective: The purpose of this qualitative study was to describe the experiences of pain acceptance in Chinese cancer patients with chronic pain.Methods: Twelve hospitalized cancer patients with chronic pain participa...Objective: The purpose of this qualitative study was to describe the experiences of pain acceptance in Chinese cancer patients with chronic pain.Methods: Twelve hospitalized cancer patients with chronic pain participated in this qualitative descriptive study from August to November 2017.In-person semi-structured interviews were conducted,recorded,transcribed,and analyzed using Colaizzi's seven-step method.Results: The following four main themes and 15 subthemes emerged.Theme 1 (adaptation): pain is overwhelming and pain relief is a top priority,avoidance of pain-inducing factors,and resignation;theme 2 (emotional reactions to pain): feeling misunderstood,hopelessness,frustration,irritability,and concern for loved ones;theme 3 (functional limitations): daily life activities,social communication,and work;theme 4 (coping strategies): pharmacological therapies,behavioral strategies,social support strategies,and spiritual strategies.Conclusions: This study provides a description of cancer patients' experiences related to the need for pain acceptance.These findings provide insight into the essential role of pain acceptance and underline the need to apply acceptance-based cognitive behavioral interventions as adjunctive non-pharmacological alternatives for chronic cancer pain.展开更多
Convex polyhedral cuprate clusters are being formed through lateral frustration when the a and c lattice parameters of the tetragonal ACuO2 infinite layer structure will become identical by substitution of a large cat...Convex polyhedral cuprate clusters are being formed through lateral frustration when the a and c lattice parameters of the tetragonal ACuO2 infinite layer structure will become identical by substitution of a large cation (A = Ba2+). However, the corner-shared CuO2 plaquettes of the infinite network suffer a topotactic rearrangement forming edge-connected units, for instance Cu18O24 cages (polyhedron notation [4641238]) with 2 compound (space group P4/ nmm) will be discussed. The possibility to construct a cuprate super-cage with m3m symmetry (polyhedron notation [4641242438]) is being reported. This super-cage still consists of edge-connected CuO2 plaquettes when fully decorated with copper ions, but with different curvatures, arranged in circles of 9.39 ? of diameter with 139.2° Cu-O-Cu antiferromagnetic super-exchange interaction. On the one hand, the realization of such a quite stable cuprate super-cage as a candidate for high-Tc superconductivity depends on whether a template of suitable size such as the cation or C(CH3)4 enables its formation, and on the other hand the cage can further be stabilized by highly charged cations located along the [111] direction. Synthesis options will be proposed based on suggested cage formation pathways. An X-ray powder pattern was calculated for a less dense cluster structure of Im3m space group with a lattice parameter of a = 14.938 ? and two formula units of Cu46O51 to facilitate future identification. Characteristic X-ray scattering features as identification tool were obtained when the electron distribution of the hollow polyhedron was approximated with electron density in a spherical shell.展开更多
Large superconducting Fe Se crystals of(001) orientation have been prepared via a hydrothermal ion release/introduction route for the first time. The hydrothermally derived Fe Se crystals are up to 10 mm×5 mm...Large superconducting Fe Se crystals of(001) orientation have been prepared via a hydrothermal ion release/introduction route for the first time. The hydrothermally derived Fe Se crystals are up to 10 mm×5 mm×0.3 mm in dimension. The pure tetragonal FeSe phase has been confirmed by x-ray diffraction(XRD) and the composition determined by both inductively coupled plasma atomic emission spectroscopy(ICP-AES) and energy dispersive x-ray spectroscopy(EDX). The superconducting transition of the Fe Se samples has been characterized by magnetic and transport measurements. The zero-temperature upper critical field H(c2) is calculated to be 13.2–16.7 T from a two-band model. The normal-state cooperative paramagnetism is found to be predominated by strong spin frustrations below the characteristic temperature T(sn), where the Ising spin nematicity has been discerned in the FeSe superconductor crystals as reported elsewhere.展开更多
We study magnetic and Mott transitions of the Hubbard model on the geometrically frustrated anisotropic checkerboard lattice at half filling using cellular dynamical mean-field theory. Phase diagrams over a wide area ...We study magnetic and Mott transitions of the Hubbard model on the geometrically frustrated anisotropic checkerboard lattice at half filling using cellular dynamical mean-field theory. Phase diagrams over a wide area of the parameter space are obtained by varying the interparticle interaction strength, geometric frustration strength, and temperature. Our results show that frustration and thermal fluctuations play a competing role against the interactions and in general favor a metallic phase without antiferromagnetic order. Due to their interplay, the system exhibits competition between antiferromagnetic insulator, antiferromagnetic metal, paramagnetic insulator, and paramagnetic metal phases in the intermediateinteraction regime. In the strong-interaction limit, which reduces to the Heisenberg model, our result is consistent with previous studies.展开更多
We study the critical scaling and dynamical signatures of fractionalized excitations at two different deconfined quantum critical points(DQCPs)in an S=1/2 spin chain using the time evolution of infinite matrix product...We study the critical scaling and dynamical signatures of fractionalized excitations at two different deconfined quantum critical points(DQCPs)in an S=1/2 spin chain using the time evolution of infinite matrix product states.The scaling of the correlation functions and the dispersion of the conserved current correlations explicitly show the emergence of enhanced continuous symmetries at these DQCPs.The dynamical structure factors in several different channels reveal the development of deconfined fractionalized excitations at the DQCPs.Furthermore,we find an effective spin-charge separation at the DQCP between the ferromagnetic(FM)and valence bond solid(VBS)phases,and identify two continua associated with different types of fractionalized excitations at the DQCP between the X-direction and Z-direction FM phases.Our findings not only provide direct evidence for the DQCP in one dimension but also shed light on exploring the DQCP in higher dimensions.展开更多
基金Project supported by the Natural Science Foundation of Anhui Province,China(Grant Nos.2108085MA16 and2108085QA22)the Key Project of Anhui Provincial Department of Education(Grant No.KJ2020A0013)+1 种基金the Key Project of the Foundation of Anhui Education Committee,China(Grant No.2022AH050066)the National Natural Science Foundation of China(Grant Nos.U1832209,11874336,12274338,12104010,12104011,52102333,and 12004003)。
文摘To study the effects of lanthanide ions on the geometrically frustrated antiferromagnets and their magnetic properties,we grew high-quality single crystals of LnCu_(3)(OH)_(6)Br_(3)(Ln=Nd,Sm,and Eu)by hydrothermal method and studied their crystal structures and magnetic properties.The refinements of the crystal structure referred to the powder x-ray diffraction data show that LnCu_(3)(OH)_(6)Br_(3)adopt a Kapellasite-type layer structure,which is isostructural to their chlorine analogue.Magnetic susceptibilities demonstrate that LnCu_(3)(OH)_(6)Br_(3)have strong antiferromagnetic coupling and a pronounced magnetic frustration effect.Magnetization measurements indicate canted antiferromagnetic ordering of Cu^(2+)ions around 16 K within the kagoméplane and weak ferromagnetic coupling.Moreover,shoulder-like anomalies in specific heat around 16 K could be a signature of emergent of magnetic ordering.The low-temperature negative magnetization and specific heat of LnCu_(3)(OH)_(6)Br_(3)(Ln=Nd,Sm,and Eu)indicate that Ln^(3+)ions induce more exotic magnetic ground state properties.
基金Supported by the National Natural Science Foundation of China under Grant No 11104091
文摘The doping effects on the frustration and the magnetic properties in hexagonal compounds ot YMn0.9A0.1O3 (A=A1, Fe and Cu) are investigated. Experimental results indicate that both the non-magnetic and magnetic ion dopants lead to the increase of magnetic moments and the decrease of the absolute value of Curie-Weiss temperature (|θcw|)- Compared with pure YMnOa, the geometrical frustration of YMn0.9 A0. 1O3 is greatly suppressed and the magnetic coupling in that exhibits dopant-dependent. In addition, for the doped YMno.gAo.103, the antiferromagnetic transition temperature (TN) is also suppressed slightly, which shows an abnormal dilution effect and it may be ascribed to the reduction of frustration due to the chemical substitution.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.11374364 and 11222433)the National Basic Research Program of China(Grant No.2011CBA00112)+2 种基金Research at Mc Master University supported by the Natural Sciences and Engineering Research CouncilWork at North China Electric Power University supported by the Scientific Research Foundation for the Returned Overseas Chinese ScholarsState Education Ministry
文摘We synthesized a quasi-two-dimensional distorted triangular lattice antiferromagnet Ca3CoNb2O9, in which the effective spin of Co2+is 1/2 at low temperatures, whose magnetic properties were studied by dc susceptibility and magnetization techniques. The x-ray diffraction confirms the quality of our powder samples. The large Weiss constant θCW --55 K and the low Neel temperature TN- 1.45 K give a frustration factor f =| θCW/TN|≈ 38, suggesting that Ca3 Co Nb2O9resides in strong frustration regime. Slightly below TN, deviation between the susceptibility data under zero-field cooling(ZFC)and field cooling(FC) is observed. A new magnetic state with 1/3 of the saturate magnetization Ms is suggested in the magnetization curve at 0.46 K. Our study indicates that Ca3 Co Nb2O9is an interesting material to investigate magnetism in triangular lattice antiferromagnets with weak anisotropy.
基金the National Natural Science Foundation of China,No.30870894the National Basic Research Program of China,No.2009CB522000National Key Technology R&D Program in the 12th Five-Year Plan of China,No.2011BAK04B08
文摘In this study, a T-maze-based frustration model in rats was established using sucrose-reward deprivation, The results revealed that rats maintained a 75% preference for the sucrose-reward arm in the reward phase. During the sucrose-deprivation frustration phase, both the preference for the sucrose-deprivation arm (62.5%) and time spent waiting in the sucrose-deprivation arm decreased. Acute injection of morphine increased the preference in a dose-dependent fashion, and prolonged the waiting duration in the sucrose-deprivation arm. These findings indicate that morphine specifically inhibited the frustration response induced by sucrose reward deprivation. To further elucidate the pharmacological mechanisms involved, the opioid receptor antagonist naloxone was given to model rats prior to the injection of morphine. The results revealed that naloxone administration markedly attenuated the anti-frustration-like effects of 3 mg/kg morphine treatment. These findings suggest that morphine attenuates the frustration-like response to reward deprivation in rats through the opioid receptor.
基金supported by the National Natural Science Foundation of China (Grant No. 10874003)Ministry of Science and Technology of China (Grant No. 2006CB921300)
文摘This paper studies a spin ladder model which possesses frustrating interactions. By using both the bosonization and the density matrix renormalization group techniques, it shows that the intermediate columnar dimerized phase, which exists in a narrow parameter region of the so-called ~/1 - J2 model, vanishes if the interchain frustration is weak and anisotropic. Therefore, it concludes that the frustrating interaction indeed plays an important role in producing such a phase. As a complementary to our previous investigation, it reaches a more complete picture of the quantum phase transition in the frustrated spin ladder systems.
基金the European Union's Horizon 2020 Programmes Under Grant Agreement(826506,sustAGE).
文摘Background Although frustration is a common emotional reaction while playing games,an excessive level of frustration can negatively impact a user's experience,discouraging them from further game interactions.The automatic detection of frustration can enable the development of adaptive systems that can adapt a game to a user's specific needs through real-time difficulty adjustment,thereby optimizing the player's experience and guaranteeing game success.To this end,we present a speech-based approach for the automatic detection of frustration during game interactions,a specific task that remains under explored in research.Method The experiments were performed on the Multimodal Game Frustration Database(MGFD),an audiovisual dataset-collected within the Wizard-of-Oz framework-that is specially tailored to investigate verbal and facial expressions of frustration during game interactions.We explored the performance of a variety of acoustic feature sets,including Mel-Spectrograms,Mel Frequency Cepstral Coefficients(MFCCs),and the low-dimensional knowledge-based acoustic feature set eGeMAPS.Because of the continual improvements in speech recognition tasks achieved by the use of convolutional neural networks(CNNs),unlike the MGFD baseline,which is based on the Long Short Term Memory(LSTM)architecture and Support Vector Machine(SVM)classifier-in the present work,we consider typical CNNs,including ResNet,VGG,and AlexNet.Furthermore,given the unresolved debate on the suitability of shallow and deep networks,we also examine the performance of two of the latest deep CNNs:WideResNet and EfficientNet.Results Our best result,achieved with WideResNet and Mel-Spectrogram features,increases the system performance from 58.8%unweighted average recall(UAR)to 93.1%UAR for speech-based automatic frustration recognition.
文摘In this study, we consider the emergence of explosive synchronization in scale-free networks by considering the Kuramoto model of coupled phase oscillators. The natural frequencies of oscillators are assumed to be correlated with their degrees and frustration is included in the system. This assumption can enhance or delay the explosive transition to synchronization. Interestingly, a de-synchronization phenomenon occurs and the type of phase transition is also changed. Furthermore, we provide an analytical treatment based on a star graph, which resembles that obtained in scale-free networks. Finally, a self-consistent approach is implemented to study the de-synchronization regime. Our findings have important implications for controlling synchronization in complex networks because frustration is a controllable parameter in experiments and a discontinuous abrupt phase transition is always dangerous in engineering in the real world.
基金We thank the National Natural Science Foundation of China(Nos.21925301 and 22103016).
文摘The concept of"packing frustration"has been used to understand the self-assembly behaviors of block copolymers for decades.However,rare attention has been paid to tailoring the packing frustration.This account provides a review of our recent endeavor of controlling the self-assembly of block copolymers via tailoring the packing frustration.The basic idea is to release the packing frustration of chains through the local segregation between different blocks of the same component filing different spaces of near and far.Two different majority blocks are designed to release their packing frustration in the matrix.In particular,this effect of released packing frustration has been successfullycombined with other effectss such as the stretched bridging block to stabilize many unusual low.coordinated phases.We have also proposed to release the packing frustration of minority blocks within the interface curva-ture by designing the architectures of minority blocks.The effect of released packing frustration of minority blocks is aplied to drastically expand the region of spherical phases and thus to obtain significant regions of complex Frank Kasper phases.In brief,the self.assembly of block copolymers can be largely contrlled by tailoring the packing frustration of blocks,even leading to the formation of many unusual ordered phases.
文摘Many times, my Chinese col- leagues, students and friends have told me how fortunate they are and how much they have ben- efited from me. Not so. I’m theone who has benefited by teaching English inChina. I have met many people and mademany friends. I
基金supported by the National Key Programme of Research and Development,Ministry of Science and Technology(No.2022YFF1301401)the National Natural Science Foundation of China(No.32170428)+2 种基金Research on monitoring technology system of amphibians and reptile in national parks(Research project of the National Park Research Institute)China Biodiversity Observation Networks(Sino BON-Amphibian and Reptile)the Species Conservation Project of Sichuan Liziping National Nature Reserve(2022).
文摘Many animals migrate during the breeding season.It is important to study the patterns of breeding migration of wild animals,especially rare and endangered species.However,current data acquisition methods are too coarse and imprecise for investigating the circadian rhythms of migrations in amphibians.Based on the frustrated total reflection image(FTRI),we developed a new device and recorded the precise migration time of an endangered salamander,Liangshantriton taliangensis.During the breeding period,a total of 33 individuals were effectively recorded.Analysis of the data indicated that the circadian rhythm of breeding migration in L.taliangensis was bimodal,and migration mainly occurred from 05:00 to 13:00(81.82%of the total migration records).The average relative activity intensity index(RAI)of breeding migration peaked in the temperature range of 14.0–16.0°C.With increased average relative air humidity,the activity intensity first increased and then decreased,reaching a peak in the humidity range of 91.0%–97.0%.These results demonstrate that our new device is a viable and accurate method for recording the migration time of target species.It is important to reveal the breeding migration pattern of L.taliangensis,which is important for the conservation of this species.Meanwhile,this new device can be used for field monitoring and conservation studies of amphibians,reptiles and other animals.
基金Project supported by the National Natural Science Foundation of China (Grant No. 10874021)
文摘The magnetic and electronic properties of the geometrically frustrated triangular antiferromagnet CuCrO2 are investigated by first principles through density functional theory calculations within the generalized gradient approxi- mations (GGA)+U scheme. The spin exchange interactions up to the third nearest neighbours in the ab plane as well as the coupling between adjacent layers are calculated to examine the magnetism and spin frustration. It is found that CuCrO2 has a natural two-dimensional characteristic of the magnetic interaction. Using Monte Carlo simulation, we obtain the Neel temperature to be 29.9 K, which accords well with the experimental value of 24 K. Based on non- collinear magnetic structure calculations, we verify that the incommensurate spiral-spin structure with (110) spiral plane is believable for the magnetic ground state, which is consistent with the experimental observations. Due to intra-layer geometric spin frustration, parallel helical-spin chains arise along the a, b, or a+ b directions, each with a screw-rotation angle of about I20°. Our calculations of the density of states show that the spin frustration plays an important role in the change of d-p hybridization, while the spin-orbit coupling has a very limited influence on the electronic structure.
基金This study was supported by the Hunan Provincial Natural Science Fund,China,grant number 2018JJ6110
文摘Objective: The purpose of this qualitative study was to describe the experiences of pain acceptance in Chinese cancer patients with chronic pain.Methods: Twelve hospitalized cancer patients with chronic pain participated in this qualitative descriptive study from August to November 2017.In-person semi-structured interviews were conducted,recorded,transcribed,and analyzed using Colaizzi's seven-step method.Results: The following four main themes and 15 subthemes emerged.Theme 1 (adaptation): pain is overwhelming and pain relief is a top priority,avoidance of pain-inducing factors,and resignation;theme 2 (emotional reactions to pain): feeling misunderstood,hopelessness,frustration,irritability,and concern for loved ones;theme 3 (functional limitations): daily life activities,social communication,and work;theme 4 (coping strategies): pharmacological therapies,behavioral strategies,social support strategies,and spiritual strategies.Conclusions: This study provides a description of cancer patients' experiences related to the need for pain acceptance.These findings provide insight into the essential role of pain acceptance and underline the need to apply acceptance-based cognitive behavioral interventions as adjunctive non-pharmacological alternatives for chronic cancer pain.
文摘Convex polyhedral cuprate clusters are being formed through lateral frustration when the a and c lattice parameters of the tetragonal ACuO2 infinite layer structure will become identical by substitution of a large cation (A = Ba2+). However, the corner-shared CuO2 plaquettes of the infinite network suffer a topotactic rearrangement forming edge-connected units, for instance Cu18O24 cages (polyhedron notation [4641238]) with 2 compound (space group P4/ nmm) will be discussed. The possibility to construct a cuprate super-cage with m3m symmetry (polyhedron notation [4641242438]) is being reported. This super-cage still consists of edge-connected CuO2 plaquettes when fully decorated with copper ions, but with different curvatures, arranged in circles of 9.39 ? of diameter with 139.2° Cu-O-Cu antiferromagnetic super-exchange interaction. On the one hand, the realization of such a quite stable cuprate super-cage as a candidate for high-Tc superconductivity depends on whether a template of suitable size such as the cation or C(CH3)4 enables its formation, and on the other hand the cage can further be stabilized by highly charged cations located along the [111] direction. Synthesis options will be proposed based on suggested cage formation pathways. An X-ray powder pattern was calculated for a less dense cluster structure of Im3m space group with a lattice parameter of a = 14.938 ? and two formula units of Cu46O51 to facilitate future identification. Characteristic X-ray scattering features as identification tool were obtained when the electron distribution of the hollow polyhedron was approximated with electron density in a spherical shell.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.11574370,11274358,and 11190020)the National Basic Research Program of China(Grant No.2013CB921700)the Strategic Priority Research Program(B)of the Chinese Academy of Sciences(Grant No.XDB07020100)
文摘Large superconducting Fe Se crystals of(001) orientation have been prepared via a hydrothermal ion release/introduction route for the first time. The hydrothermally derived Fe Se crystals are up to 10 mm×5 mm×0.3 mm in dimension. The pure tetragonal FeSe phase has been confirmed by x-ray diffraction(XRD) and the composition determined by both inductively coupled plasma atomic emission spectroscopy(ICP-AES) and energy dispersive x-ray spectroscopy(EDX). The superconducting transition of the Fe Se samples has been characterized by magnetic and transport measurements. The zero-temperature upper critical field H(c2) is calculated to be 13.2–16.7 T from a two-band model. The normal-state cooperative paramagnetism is found to be predominated by strong spin frustrations below the characteristic temperature T(sn), where the Ising spin nematicity has been discerned in the FeSe superconductor crystals as reported elsewhere.
文摘We study magnetic and Mott transitions of the Hubbard model on the geometrically frustrated anisotropic checkerboard lattice at half filling using cellular dynamical mean-field theory. Phase diagrams over a wide area of the parameter space are obtained by varying the interparticle interaction strength, geometric frustration strength, and temperature. Our results show that frustration and thermal fluctuations play a competing role against the interactions and in general favor a metallic phase without antiferromagnetic order. Due to their interplay, the system exhibits competition between antiferromagnetic insulator, antiferromagnetic metal, paramagnetic insulator, and paramagnetic metal phases in the intermediateinteraction regime. In the strong-interaction limit, which reduces to the Heisenberg model, our result is consistent with previous studies.
基金Project supported by the National Science Foundation of China(Grant No.12174441)the Fundamental Research Funds for the Central Universities,Chinathe Research Funds of Remnin University of China(Grant No.18XNLG24)。
文摘We study the critical scaling and dynamical signatures of fractionalized excitations at two different deconfined quantum critical points(DQCPs)in an S=1/2 spin chain using the time evolution of infinite matrix product states.The scaling of the correlation functions and the dispersion of the conserved current correlations explicitly show the emergence of enhanced continuous symmetries at these DQCPs.The dynamical structure factors in several different channels reveal the development of deconfined fractionalized excitations at the DQCPs.Furthermore,we find an effective spin-charge separation at the DQCP between the ferromagnetic(FM)and valence bond solid(VBS)phases,and identify two continua associated with different types of fractionalized excitations at the DQCP between the X-direction and Z-direction FM phases.Our findings not only provide direct evidence for the DQCP in one dimension but also shed light on exploring the DQCP in higher dimensions.