The problem of how to give a unified interpretation for the electron paramagntic res-onance(EPR) parameters (the zero-field splitting parameter a and the g-tensor) and the op-tical spectrum of a cubic d^5 complex had ...The problem of how to give a unified interpretation for the electron paramagntic res-onance(EPR) parameters (the zero-field splitting parameter a and the g-tensor) and the op-tical spectrum of a cubic d^5 complex had long been open since it was put forward by VanVleck and Penny in 1934. In the 1990s, two different methods for the unified calculationof the parameter a and spectrum of a cubic d^5 complex were proposed respectively byKang and Zhou et al, respectively. However, they did not deal with how to展开更多
文摘The problem of how to give a unified interpretation for the electron paramagntic res-onance(EPR) parameters (the zero-field splitting parameter a and the g-tensor) and the op-tical spectrum of a cubic d^5 complex had long been open since it was put forward by VanVleck and Penny in 1934. In the 1990s, two different methods for the unified calculationof the parameter a and spectrum of a cubic d^5 complex were proposed respectively byKang and Zhou et al, respectively. However, they did not deal with how to
