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基于GC/MS测定法的不同种植条件下代森锰锌在菜豆上的残留及消解动态 被引量:3
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作者 邵辉 程禹 +8 位作者 李辉 刘磊 李娜 林宏芳 杨云艳 杨丽静 闫琳 张玉婷 郭永泽 《植物保护》 CAS CSCD 北大核心 2020年第5期60-63,76,共5页
采用正己烷吸收,气质联用仪测定,建立了代森锰锌在菜豆中的GC/MS测定法。方法回收率为79.0%~85.6%,相对标准偏差为4.4%~9.9%,定量限以代森锰锌表示为0.04 mg/kg。在此基础上开展了不同种植条件下代森锰锌在菜豆上的消解动态试验和最终... 采用正己烷吸收,气质联用仪测定,建立了代森锰锌在菜豆中的GC/MS测定法。方法回收率为79.0%~85.6%,相对标准偏差为4.4%~9.9%,定量限以代森锰锌表示为0.04 mg/kg。在此基础上开展了不同种植条件下代森锰锌在菜豆上的消解动态试验和最终残留量试验,设施条件下和露地条件下代森锰锌在菜豆上的半衰期分别为9.4 d和5.1 d,最终残留量为0.17~0.45 mg/kg,均低于我国限量标准3 mg/kg。可为70%硫磺·锰锌可湿性粉剂用于防治菜豆病害登记提供数据支撑。 展开更多
关键词 gc/ms测定法 种植条件 代森锰锌 菜豆 残留 消解动态
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Component Analysis of Volatile Oil of Garlic from Different Districts and Assay of Allicin Content 被引量:2
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作者 WANG Ying WU Wen-li +2 位作者 WANG Bin WANG Dao-ping HAO Xiao-yan 《Chinese Food Science》 2012年第1期40-42,50,共4页
[ Objective] The aim was to study the chemical component of volatile oil of garlic in different districts. [ Method] GC-MS was used to an- alyze the composition of the garlic volatile oil in Guiyang, Guizhou Majiang, ... [ Objective] The aim was to study the chemical component of volatile oil of garlic in different districts. [ Method] GC-MS was used to an- alyze the composition of the garlic volatile oil in Guiyang, Guizhou Majiang, Shandong, Yunnan and Chongqing and the HPLC method was used to assay the content of gadicin. [ Result]Gadicin in different essential oil had the highest content but varied a lot. The sampling amount of garlicin be- tween 0.562 and 2.810 μg was in a good linear relation (R =0.999 2, n = 5 ) with peak area, the average recovery rate was 99.39, RSD = 1.76%. [ Conclusion] GC-MS can be used to analysis the composition of essential oil quickly and effectively. The liquid chromatographic analysis of garlicin was simple, reliable and reproducible. The study provided the theoretical basis for selecting garlic in gadic flavor oil production and improving quality of gadicin oil. 展开更多
关键词 GARLIC ALLICIN Volatile oil gc-MS HPLC Content assaying China
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