The effect of chemical composition of highly active supported Ziegler-Natta catalysts with controlled morphology on the MWD of PE has been studied.It was shown the variation of transition metal compound in the MgCl_2-...The effect of chemical composition of highly active supported Ziegler-Natta catalysts with controlled morphology on the MWD of PE has been studied.It was shown the variation of transition metal compound in the MgCl_2-supported catalyst affect of MWD of PE produced in broad range:Vanadium-magnesium catalyst(VMC)produce PE with broad and bimodal MWD(M_w/M_n=14-21).MWD of PE,produced over titanium-magnesium catalyst(TMC)is narrow or medium depending on Ti content in the catalyst(M_w/M_n=3.1-4.8).The oxidation ...展开更多
The thermal aging behavior of poly （ vinyl alcohol ） （ PVA ） hydrogel was studied at four different temperatures of 40 ℃, 50 ℃, 60 ℃ and 70 ℃ in one year. The samples of PVA hydrogel were closely covered by pl...The thermal aging behavior of poly （ vinyl alcohol ） （ PVA ） hydrogel was studied at four different temperatures of 40 ℃, 50 ℃, 60 ℃ and 70 ℃ in one year. The samples of PVA hydrogel were closely covered by plastic film. The changes of their chemical structures and physical properties during aging were measured through different measurable techniques including tensile testing, gel permeation chromatography （ GPC ）, viscosity analysis, and Fourier transform infrared （FTIR） spec- trum. The results showed that the molecular weight of PVA in hydrogel changed little with time and temperature. FTIR spectra of PVA in all the samples were similar to those of the original samples. The tensile strength of PVA hydrogel didn＇t change until the 330th days.展开更多
The ＂living＇/controlled radical polymerization （LRP） of styrene （St） at room temperature is rarely reported. In this work, copper（0） （Cu（0））-mediated radical polymerization of St at room temperature was in...The ＂living＇/controlled radical polymerization （LRP） of styrene （St） at room temperature is rarely reported. In this work, copper（0） （Cu（0））-mediated radical polymerization of St at room temperature was investigated in detail. Dimethyl sulfoxide （DMSO）, N,N-dimethylformamide （DMF） as well as a binary solvent, tetrahydrofuravdl,l,l,3,3,3-hexafluoro-2- propanol were used as the solvents, respectively. Methyl-2-bromopropionate and ethyl 2-bromoisobutyrate were used as the initiators, respectively. The polymerization proceeded smoothly with moderate conversions at room temperature. It was found that DMF was a good solvent with the essential features of LRP, while DMSO was a poor solvent with uncontrollable molecular weights. Besides, the match among the initiator, solvent and molar ratios of reactants can modulate the livingness of the polymerization, and the proper selection of ligand was also crucial to a controlled process. This work provided a first example of Cu（0）-mediated radical polymerization of St at room temperature, which would enrich and strength the LRP technique.展开更多
文摘The effect of chemical composition of highly active supported Ziegler-Natta catalysts with controlled morphology on the MWD of PE has been studied.It was shown the variation of transition metal compound in the MgCl_2-supported catalyst affect of MWD of PE produced in broad range:Vanadium-magnesium catalyst(VMC)produce PE with broad and bimodal MWD(M_w/M_n=14-21).MWD of PE,produced over titanium-magnesium catalyst(TMC)is narrow or medium depending on Ti content in the catalyst(M_w/M_n=3.1-4.8).The oxidation ...
文摘The thermal aging behavior of poly （ vinyl alcohol ） （ PVA ） hydrogel was studied at four different temperatures of 40 ℃, 50 ℃, 60 ℃ and 70 ℃ in one year. The samples of PVA hydrogel were closely covered by plastic film. The changes of their chemical structures and physical properties during aging were measured through different measurable techniques including tensile testing, gel permeation chromatography （ GPC ）, viscosity analysis, and Fourier transform infrared （FTIR） spec- trum. The results showed that the molecular weight of PVA in hydrogel changed little with time and temperature. FTIR spectra of PVA in all the samples were similar to those of the original samples. The tensile strength of PVA hydrogel didn＇t change until the 330th days.
基金supported by the National Natural Science Foundation of China (Nos. 20904036 and 21174094)the Nature Science Key Basic Research of Jiangsu Province for High Education (No. 12KJA150007)Creative Experiment Plan of Soochow University Undergraduates (57315977)
文摘The ＂living＇/controlled radical polymerization （LRP） of styrene （St） at room temperature is rarely reported. In this work, copper（0） （Cu（0））-mediated radical polymerization of St at room temperature was investigated in detail. Dimethyl sulfoxide （DMSO）, N,N-dimethylformamide （DMF） as well as a binary solvent, tetrahydrofuravdl,l,l,3,3,3-hexafluoro-2- propanol were used as the solvents, respectively. Methyl-2-bromopropionate and ethyl 2-bromoisobutyrate were used as the initiators, respectively. The polymerization proceeded smoothly with moderate conversions at room temperature. It was found that DMF was a good solvent with the essential features of LRP, while DMSO was a poor solvent with uncontrollable molecular weights. Besides, the match among the initiator, solvent and molar ratios of reactants can modulate the livingness of the polymerization, and the proper selection of ligand was also crucial to a controlled process. This work provided a first example of Cu（0）-mediated radical polymerization of St at room temperature, which would enrich and strength the LRP technique.
