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三重四极杆电感耦合等离子体串联质谱法测定铁镍基高温合金中15种杂质元素含量 被引量:1
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作者 杨萌 李鹰 +2 位作者 李剑 李维涵 刘岩 《分析测试学报》 CAS CSCD 北大核心 2023年第7期870-875,共6页
高温合金中的痕量杂质元素会对高温合金的性能产生一定影响,因此高温合金中杂质含量的严格控制和准确测定尤为重要。该文基于三重四极杆电感耦合等离子体串联质谱(ICP-MS/MS)直接测定了铁镍基高温合金中的15种杂质元素。采用硝酸、盐酸... 高温合金中的痕量杂质元素会对高温合金的性能产生一定影响,因此高温合金中杂质含量的严格控制和准确测定尤为重要。该文基于三重四极杆电感耦合等离子体串联质谱(ICP-MS/MS)直接测定了铁镍基高温合金中的15种杂质元素。采用硝酸、盐酸、氢氟酸混合酸消解样品,定容后直接上机测试,无需萃取和分离,大大提高了前处理分析效率。在氦气碰撞模式下,实现了高纯铁镍基高温合金中干扰较小的杂质元素的测试分析。由于Mo含量较高的高温合金样品中,^(95)Mo^(16)O^(+)会对^(111)Cd的测定造成强烈质谱干扰,导致单四极杆质谱仪测试受限。基于此,该文利用ICP-MS/MS优越的反应池技术,在O_(2)原位质量模式下,通过设置一级质量过滤器(Q1)的质荷比(m/z)为111,并向碰撞反应池中加入O_(2),使^(95)Mo^(16)O^(+)与O_(2)反应生成^(95)Mo^(16)O^(16)O^(+),再设置二级质量过滤器(Q2)的m/z也为111,使^(111)Cd被通过和检测,从而避免了质谱重叠干扰,实现了Cd含量的稳定测试。该研究以铁镍基高温合金标准物质(GBW01620)为样本进行验证,结果表明,各元素的线性相关系数均大于0.999,方法检出限为0.001~1.24 mg/kg,相对标准偏差不大于3.5%,15种元素的测试值均在认定值的不确定度范围内。该方法为高纯合金样品的准确测试分析提供了思路和借鉴。 展开更多
关键词 ICP-MS/MS 铁镍基高温合金 O_(2)原位质量模式 He碰撞模式 杂质元素 ^(111)Cd
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DS GTD111合金及YSZ/CoCrAlY型热障涂层在950℃的热腐蚀行为 被引量:2
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作者 任维鹏 齐闯 +3 位作者 范少敏 梁照森 肖程波 何利民 《铸造技术》 CAS 2019年第12期1235-1241,共7页
采用EB-PVD技术在DS GTD111合金表面沉积制备YSZ/CoCrAlY热障涂层,研究了DSGTD111合金及热障涂层在950℃的热腐蚀行为,进行了腐蚀动力学及腐蚀产物分析。结果表明:950℃涂盐条件下热腐蚀100 h,热障涂层试样粘结层表面氧化物或腐蚀产物... 采用EB-PVD技术在DS GTD111合金表面沉积制备YSZ/CoCrAlY热障涂层,研究了DSGTD111合金及热障涂层在950℃的热腐蚀行为,进行了腐蚀动力学及腐蚀产物分析。结果表明:950℃涂盐条件下热腐蚀100 h,热障涂层试样粘结层表面氧化物或腐蚀产物层的厚度与试验合金相比有很大程度的减小,施加热障涂层在很大程度上改善了合金抗950℃熔盐热腐蚀能力,热障涂层失效开裂部位为TGO与粘结层界面。950℃涂盐条件下热腐蚀100 h,YSZ/CoCrAlY型热障涂层的热腐蚀行为受合金基体影响作用不显著。 展开更多
关键词 DS GTD111 高温合金 热障涂层 热腐蚀
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New insights into microstructural changes during transient liquid phase bonding of GTD-111 superalloy 被引量:2
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作者 Javad ASADI Seyed Abdolkarim SAJJADI Hamid OMIDVAR 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2021年第9期2703-2715,共13页
The effects of joining temperature(TJ)and time(tJ)on microstructure of the transient liquid phase(TLP)bonding of GTD-111 superalloy were investigated.The bonding process was applied using BNi-3 filler at temperatures ... The effects of joining temperature(TJ)and time(tJ)on microstructure of the transient liquid phase(TLP)bonding of GTD-111 superalloy were investigated.The bonding process was applied using BNi-3 filler at temperatures of 1080,1120,and 1160℃ for isothermal solidification time of 195,135,and 90 min,respectively.Homogenization heat treatment was also applied to all of the joints.The results show that intermetallic and eutectic compounds such as Ni-rich borides,Ni−B−Si ternary compound and eutectic-γcontinuously are formed in the joint region during cooling.By increasing tJ,intermetallic phases are firstly reduced and eventually eliminated and isothermal solidification is completed as well.With the increase of the holding time at all of the three bonding temperatures,the thickness of the athermally solidified zone(ASZ)and the volume fraction of precipitates in the bonding area decrease and the width of the diffusion affected zone(DAZ)increases.Similar results are also obtained by increasing TJ from 1080 to 1160℃ at tJ=90 min.Furthermore,increasing the TJ from 1080 to 1160℃ leads to the faster elimination of intermetallic phases from the ASZ.However,these phases are again observed in the joint region at 1180℃.It is observed that by increasing the bonding temperature,the bonding width and the rate of dissolution of the base metal increase.Based on these results,increasing the homogenization time from 180 to 300 min leads to the elimination of boride precipitates in the DAZ and a high uniformity of the concentration of alloying elements in the joint region and the base metal. 展开更多
关键词 TLP bonding joint gtd-111 superalloy isothermal solidification MICROSTRUCTURE HOMOGENIZATION
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