This note reports a new procedure of polycrystalline synthesis and a new technique of single crystal growth on AgGaS2, i.e. two-zone temperature oscillation vapor transporting and descending crucible with rotation. A ...This note reports a new procedure of polycrystalline synthesis and a new technique of single crystal growth on AgGaS2, i.e. two-zone temperature oscillation vapor transporting and descending crucible with rotation. A single phase dense AgGaS2 polycrystalline ingot was synthesized, and a crack-free AgGaS2 single crystal with 15 mm in diameter and 30 mm in length was grown by the techniques mentioned above. Structure integrity of the crystal was studied by the X-ray diffraction technique. Six order X-ray spectra from the {011} face of the crystal were obtained, and an anomalous phenomenon was observed for the first time that intensity of the higher order diffraction peak is much stronger than that of the lower order diffraction peak. Etch-pits of the crystal were observed by the scanning electron microscopy (SEM).展开更多
A tunable continuous wave（cw） mid-infrared（MIR） laser based on difference-frequency generation（DFG） in a 1.5-cm long AgGaS2 nonlinear crystal for trace gas detection is reported.Two visible and near-infrared dio...A tunable continuous wave（cw） mid-infrared（MIR） laser based on difference-frequency generation（DFG） in a 1.5-cm long AgGaS2 nonlinear crystal for trace gas detection is reported.Two visible and near-infrared diode lasers were used as pump and signal sources.The MIR-DFG laser was tunable in a wavelength range of 4.75 μm-4.88 μm.The phase-matching（PM） condition was non-critically achieved by adjusting the temperature of the crystal for fixed pairs of input pump and signal wavelengths.The required PM temperatures of the generated MIR-DFG wavelengths have been calculated by using three sets of recent Sellmeier equations and the temperature-dispersion equations of AgGaS2 given by Willer U,et al.（Willer U,Blanke T and Schade W 2001 Appl.Opt.40 5439）.Then the calculated PM temperatures are compared with the experimental values.The performance of the MIR-DFG laser is shown by the trace detection of the P（16） carbon monoxide（12C16O） absorption line in a laboratory-fabricated absorption cell.The enhanced sensitivity of about 0.6×10 4 was obtained through the long path absorption provided by consecutive reflections between coated cylindrical mirrors of a constructed cell.展开更多
基金Supported by RFBR Project(No.10-02-01452-a)Presidium SB RAS under the Project Ⅶ.63.3.1 of Ⅶ.63.3 Prog.Integrated Projec of 2012－2014 and Join Proj. between Presidium SB RAS and Presidium NAS,Belarus No.10 of 2010
基金This work was supported by the Sichuan Provincial Research Foundation of of China (Grant No: 99-479).
文摘This note reports a new procedure of polycrystalline synthesis and a new technique of single crystal growth on AgGaS2, i.e. two-zone temperature oscillation vapor transporting and descending crucible with rotation. A single phase dense AgGaS2 polycrystalline ingot was synthesized, and a crack-free AgGaS2 single crystal with 15 mm in diameter and 30 mm in length was grown by the techniques mentioned above. Structure integrity of the crystal was studied by the X-ray diffraction technique. Six order X-ray spectra from the {011} face of the crystal were obtained, and an anomalous phenomenon was observed for the first time that intensity of the higher order diffraction peak is much stronger than that of the lower order diffraction peak. Etch-pits of the crystal were observed by the scanning electron microscopy (SEM).
文摘A tunable continuous wave（cw） mid-infrared（MIR） laser based on difference-frequency generation（DFG） in a 1.5-cm long AgGaS2 nonlinear crystal for trace gas detection is reported.Two visible and near-infrared diode lasers were used as pump and signal sources.The MIR-DFG laser was tunable in a wavelength range of 4.75 μm-4.88 μm.The phase-matching（PM） condition was non-critically achieved by adjusting the temperature of the crystal for fixed pairs of input pump and signal wavelengths.The required PM temperatures of the generated MIR-DFG wavelengths have been calculated by using three sets of recent Sellmeier equations and the temperature-dispersion equations of AgGaS2 given by Willer U,et al.（Willer U,Blanke T and Schade W 2001 Appl.Opt.40 5439）.Then the calculated PM temperatures are compared with the experimental values.The performance of the MIR-DFG laser is shown by the trace detection of the P（16） carbon monoxide（12C16O） absorption line in a laboratory-fabricated absorption cell.The enhanced sensitivity of about 0.6×10 4 was obtained through the long path absorption provided by consecutive reflections between coated cylindrical mirrors of a constructed cell.
