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Rheological study of methane gas hydrates in the presence of micron-sized sand particles
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作者 Bohui Shi Shangfei Song +6 位作者 Yuchuan Chen Shunkang Fu Lihao Liu Xinyao Yang Haihao Wu Guangjin Chen Jing Gong 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第6期149-161,共13页
Natural gas hydrates,intricate crystalline structures formed by water molecules and small gas molecules,have emerged as a significant and globally impactful clean energy resource.However,their commercial exploitation ... Natural gas hydrates,intricate crystalline structures formed by water molecules and small gas molecules,have emerged as a significant and globally impactful clean energy resource.However,their commercial exploitation faces challenges,particularly operational disruptions caused by sand-related blockages.Understanding the rheological properties of hydrate slurry,especially in the presence of micron-sized sand particles,is imperative for ensuring the flow assurance of subsea hydrate exploitation.This study extensively investigates the rheological properties of sand-containing hydrate slurries.The findings reveal that these slurries exhibit non-Newtonian fluid characteristics,including yield stress,thixotropy,and shear-thinning behavior.Solid-like elastic features are observed in sand-containing hydrate slurries before yielding,transitioning to viscous behavior after yielding.Even with a minimal amount of sand,both static yield stress and yield strain experience substantial changes,correlating with the increase in sand concentration.The research conclusively establishes the thixotropic nature of sand-hydrate slurries,where the viscosity decay rate is directly influenced by the shear rate.These insights aim to contribute comprehensively to the development of effective flow assurance strategies,ensuring the safe and stable operation of subsea hydrate exploitation. 展开更多
关键词 Natural gas hydrate production Sand-containing hydrate slurries Yield stress THIXOTROPY Shear-thinning behavior
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New insights into the deposition of natural gas hydrate on pipeline surfaces:A molecular dynamics simulation study
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作者 Jun Zhang Hai-Qiang Fu +7 位作者 Mu-Zhi Guo Zhao Wang Li-Wen Li Qi Yin You-Guo Yan Wei Wei Wei-Feng Han Jie Zhong 《Petroleum Science》 SCIE EI CAS CSCD 2024年第1期694-704,共11页
Natural gas hydrate(NGH)can cause pipeline blockages during the transportation of oil and gas under high pressures and low temperatures.Reducing hydrate adhesion on pipelines is viewed as an efficient way to prevent N... Natural gas hydrate(NGH)can cause pipeline blockages during the transportation of oil and gas under high pressures and low temperatures.Reducing hydrate adhesion on pipelines is viewed as an efficient way to prevent NGH blockages.Previous studies suggested the water film can greatly increase hydrate adhesion in gas-dominant system.Herein,by performing the molecular dynamics simulations,we find in water-dominant system,the water film plays different roles in hydrate deposition on Fe and its corrosion surfaces.Specifically,due to the strong affinity of water on Fe surface,the deposited hydrate cannot convert the adsorbed water into hydrate,thus,a water film exists.As water affinities decrease(Fe>Fe_(2)O_(3)>FeO>Fe_(3)O_(4)),adsorbed water would convert to amorphous hydrate on Fe_(2)O_(3)and form the ordered hydrate on FeO and Fe_(3)O_(4)after hydrate deposition.While absorbed water film converts to amorphous or to hydrate,the adhesion strength of hydrate continuously increases(Fe<Fe_(2)O_(3)<FeO<Fe_(3)O_(4)).This is because the detachment of deposited hydrate prefers to occur at soft region of liquid layer,the process of which becomes harder as liquid layer vanishes.As a result,contrary to gas-dominant system,the water film plays the weakening roles on hydrate adhesion in water-dominant system.Overall,our results can help to better understand the hydrate deposition mechanisms on Fe and its corrosion surfaces and suggest hydrate deposition can be adjusted by changing water affinities on pipeline surfaces. 展开更多
关键词 DEPOSITION Natural gas hydrate Pipelines Water affinity Adhesion strength
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Numerical Investigation of Combined Production of Natural Gas Hydrate and Conventional Gas
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作者 Hongzhi Xu Jian Wang +3 位作者 Shuxia Li Fengrui Zhao Chengwen Wang Yang Guo 《Fluid Dynamics & Materials Processing》 EI 2024年第3期505-523,共19页
Natural gas hydrate(NGH)is generally produced and accumulated together with the underlying conventional gas.Therefore,optimizing the production technology of these two gases should be seen as a relevant way to effecti... Natural gas hydrate(NGH)is generally produced and accumulated together with the underlying conventional gas.Therefore,optimizing the production technology of these two gases should be seen as a relevant way to effectively reduce the exploitation cost of the gas hydrate.In this study,three types of models accounting for the coexistence of these gases are considered.Type A considers the upper hydrate-bearing layer(HBL)adjacent to the lower conventional gas layer(CGL);with the Type B a permeable interlayer exists between the upper HBL and the lower CGL;with the type C there is an impermeable interlayer between the upper HBL and the lower CGL.The production performances associated with the above three models are calculated under different conditions,including only a depressurized HBL(only HBL DP);only a depressurized CGL(only CGL DP);and both the HBL and the CGL being depressurized(HBL+CGL DP).The results show that for Type A and Type B coexistence accumulation models,when only HBL or CGL is depressurized,the gas from the other layer will flow into the production layer due to the pressure difference between the two layers.In the coexistence accumulation model of type C,the cumulative gas production is much lower than that of Type A and Type B,regardless of whether only HBL DP,only CGL DP,or HBL+CGL DP are considered.This indicates that the impermeable interlayer restricts the cross-flow of gas between HBL and CGL.For three different coexistence accumulation models,CGL DP has the largest gas-to-water ratio. 展开更多
关键词 Natural gas hydrate conventional gas coexistence accumulation DEPRESSURIZATION combined production
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Gas hydrate saturation from NGHP 02 LWD data in the Mahanadi Basin
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作者 Uma Shankar Pradeep Kumar Yadav +1 位作者 Sneha Devi Udham Singh Yadav 《Energy Geoscience》 EI 2024年第2期279-289,共11页
During the Indian National Gas Hydrate Program(NGHP)Expedition 02,Logging-while-drilling(LWD)logs were acquired at three sites(NGHP-02-11,NGHP-02-12,and NGHP-02-13)across the Mahanadi Basin in area A.We applied rock p... During the Indian National Gas Hydrate Program(NGHP)Expedition 02,Logging-while-drilling(LWD)logs were acquired at three sites(NGHP-02-11,NGHP-02-12,and NGHP-02-13)across the Mahanadi Basin in area A.We applied rock physics theory to available sonic velocity logs to know the distribution of gas hydrate at site NGHP-02-11 and NGHP-02-13.Rock physics modeling using sonic velocity at well location shows that gas hydrate is distributed mainly within the depth intervals of 150-265 m and 100 -215 mbsf at site NGHP-02-11 and NGHP-02-13,respectively,with an average saturation of about 4%of the pore space and the maximum concentration of about 40%of the pore space at 250 m depth at site NGHP-02-11,and at site NGHP-02-13 an average saturation of about 2%of the pore space and the maximum concentration of about 20%of the pore space at 246 m depth,as gas hydrate is distributed mainly within 100-246 mbsf at this site.Saturation of gas hydrate estimated from the electrical resistivity method using density derived porosity and electrical resistivity logs from Archie's empirical formula shows high saturation compared to that from the sonic log.However,estimates of hydrate saturation based on sonic P-wave velocity may differ significantly from that based on resistivity,because gas and hydrate have higher resistivity than conductive pore fluid and sonic P-wave velocity shows strong effect on gas hydrate as a small amount of gas reduces the velocity significantly while increasing velocity due to the presence of hydrate.At site NGHP-02-11,gas hydrate saturation is in the range of 15%e30%,in two zones between 150-180 and 245-265 mbsf.Site NGHP-02-012 shows a gas hydrate saturation of 20%e30%in the zone between 100 and 207 mbsf.Site NGHP-02-13 shows a gas hydrate saturation up to 30%in the zone between 215 and 246 mbsf.Combined observations from rock physics modeling and Archie’s approximation show the gas hydrate concentrations are relatively low(<4%of the pore space)at the sites of the Mahanadi Basin in the turbidite channel system. 展开更多
关键词 Mahanadi Basin gas hydrate Sonic log Effective medium modeling Electrical resistivity log Archie’s analysis gas hydrate saturation
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Effect of Skeleton Grain Size on the Saturation of Gas Hydrate in Natural Sediments
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作者 XU Zhenqiang LI Yang 《Journal of Ocean University of China》 SCIE CAS CSCD 2024年第3期676-682,共7页
Natural gas hydrate is prospected as a new and promising,highly clean energy resource that mainly occurs in perma-frost or at continental margins.Its formation is subject to many soil conditions,such as grain size,mat... Natural gas hydrate is prospected as a new and promising,highly clean energy resource that mainly occurs in perma-frost or at continental margins.Its formation is subject to many soil conditions,such as grain size,matrix materials,pore morphology,and permeability.In this study,we propose that grain size is the most decisive parameter that affects the saturation of gas hydrate in sediments based on data from Ocean Drilling Program Leg 164 and Mallik 5L-38,which represent marine sediments and terrestrial sediments,respectively.Our study reveals that high gas hydrate saturation generally occurs in coarse-grained sand,regardless of whether sediment formation is homogeneous or inhomogeneous,and the sorting of sediments may affect the hydrate saturation to a certain degree.Using grain size and sorting of sediments may be the most intuitive proxy method for a rough estimation of hydrate saturation.Further study is necessary to fully understand the relationship between hydrate morphology and sediment grain size,even though massive hydrates are typically found in fine clayey-rich sediments. 展开更多
关键词 grain size SATURATION gas hydrates ODP Leg 164 Mallik 5L-38
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Optimization of Gas Production from Hydrate-Bearing Sediments with Fluctuation Characteristics
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作者 LI Yaobin XU Tianfu +3 位作者 XIN Xin YU Han YUAN Yilong ZHU Huixing 《Journal of Ocean University of China》 SCIE CAS CSCD 2024年第3期618-632,共15页
As an important source of low-carbon,clean fossil energy,natural gas hydrate plays an important role in improving the global energy consumption structure.Developing the hydrate industry in the South China Sea is impor... As an important source of low-carbon,clean fossil energy,natural gas hydrate plays an important role in improving the global energy consumption structure.Developing the hydrate industry in the South China Sea is important to achieving‘carbon peak and carbon neutrality’goals as soon as possible.Deep-water areas subjected to the action of long-term stress and tectonic movement have developed complex and volatile terrains,and as such,the morphologies of hydrate-bearing sediments(HBSs)fluctuate correspondingly.The key to numerically simulating HBS morphologies is the establishment of the conceptual model,which represents the objective and real description of the actual geological body.However,current numerical simulation models have characterized HBSs into horizontal strata without considering the fluctuation characteristics.Simply representing the HBS as a horizontal element reduces simulation accuracy.Therefore,the commonly used horizontal HBS model and a model considering the HBS’s fluctuation characteristics with the data of the SH2 site in the Shenhu Sea area were first constructed in this paper.Then,their production behaviors were compared,and the huge impact of the fluctuation characteristics on HBS production was determined.On this basis,the key parameters affecting the depressurization production of the fluctuating HBSs were studied and optimized.The research results show that the fluctuation characteristics have an obvious influence on the hydrate production of HBSs by affecting their temperatures and pressure distributions,as well as the transmission of the pressure drop and methane gas discharge.Furthermore,the results show that the gas productivity of fluctuating HBSs was about 5%less than that of horizontal HBSs.By optimizing the depressurization amplitude,well length,and layout location of vertical wells,the productivity of fluctuating HBSs increased by about 56.6%. 展开更多
关键词 natural gas hydrate numerical simulation fluctuation characteristics depressurization production production well optimization
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Deep-large faults controlling on the distribution of the venting gas hydrate system in the middle of the Qiongdongnan Basin, South China Sea
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作者 Jin-feng Ren Hai-jun Qiu +6 位作者 Zeng-gui Kuang Ting-wei Li Yu-lin He Meng-jie Xu Xiao-xue Wang Hong-fei Lai Jin Liang 《China Geology》 CAS CSCD 2024年第1期36-50,共15页
Many locations with concentrated hydrates at vents have confirmed the presence of abundant thermogenic gas in the middle of the Qiongdongnan Basin(QDNB).However,the impact of deep structures on gasbearing fluids migra... Many locations with concentrated hydrates at vents have confirmed the presence of abundant thermogenic gas in the middle of the Qiongdongnan Basin(QDNB).However,the impact of deep structures on gasbearing fluids migration and gas hydrates distribution in tectonically inactive regions is still unclear.In this study,the authors apply high-resolution 3D seismic and logging while drilling(LWD)data from the middle of the QDNB to investigate the influence of deep-large faults on gas chimneys and preferred gasescape pipes.The findings reveal the following:(1)Two significant deep-large faults,F1 and F2,developed on the edge of the Songnan Low Uplift,control the dominant migration of thermogenic hydrocarbons and determine the initial locations of gas chimneys.(2)The formation of gas chimneys is likely related to fault activation and reactivation.Gas chimney 1 is primarily arises from convergent fluid migration resulting from the intersection of the two faults,while the gas chimney 2 benefits from a steeper fault plane and shorter migration distance of fault F2.(3)Most gas-escape pipes are situated near the apex of the two faults.Their reactivations facilitate free gas flow into the GHSZ and contribute to the formation of fracture‐filling hydrates. 展开更多
关键词 Venting gas hydrates Deep-large faults gas chimney gas-escape pipes High-resolution 3D seismic Logging while drilling Qiongdongnan Basin South China Sea
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Geological reservoir and resource potential(10^(13)m^(3))of gas hydrates in the South China Sea
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作者 Pi-bo Su Wei Wei +5 位作者 Yun-bao Sun Yao-yao Lü Huai Cheng Wei-feng Han Wei Zhang Jin-qiang Liang 《China Geology》 CAS CSCD 2024年第3期422-444,共23页
A detailed understanding of the distribution and potential of natural gas hydrate(NGHs)resources is crucial to fostering the industrialization of those resources in the South China Sea,where NGHs are abundant.In this ... A detailed understanding of the distribution and potential of natural gas hydrate(NGHs)resources is crucial to fostering the industrialization of those resources in the South China Sea,where NGHs are abundant.In this study,this study analyzed the applicability of resource evaluation methods,including the volumetric,genesis,and analogy methods,and estimated NGHs resource potential in the South China Sea by using scientific resource evaluation methods based on the factors controlling the geological accumulation and the reservoir characteristics of NGHs.Furthermore,this study compared the evaluation results of NGHs resource evaluations in representative worldwise sea areas via rational analysis.The results of this study are as follows:(1)The gas hydrate accumulation in the South China Sea is characterized by multiple sources of gas supply,multi-channel migration,and extensive accumulation,which are significantly different from those of oil and gas and other unconventional resources.(2)The evaluation of gas hydrate resources in the South China Sea is a highly targeted,stratified,and multidisciplinary evaluation of geological resources under the framework of a multi-type gas hydrate resource evaluation system and focuses on the comprehensive utilization of multi-source heterogeneous data.(3)Global NGHs resources is n×10^(15)m^(3),while the NGHs resources in the South China Sea are estimated to be 10^(13)m^(3),which is comparable to the abundance of typical marine NGHs deposits in other parts of the world.In the South China Sea,the NGHs resources have a broad prospect and provide a substantial resource base for production tests and industrialization of NGHs. 展开更多
关键词 Reservoir characteristics Natural gas hydrates gas migration Resource potential Resource evaluation methods Hierarchical evaluation system Volumetric method South China Sea Clean energy exploration engineering
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Three dimensional discrete element modelling of the conventional compression behavior of gas hydrate bearing coal
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作者 Xia Gao Nannan Wang +4 位作者 Baoyong Zhang Qiqi Lin Qiang Wu Wei Meng Xia Liu 《International Journal of Coal Science & Technology》 EI CAS CSCD 2024年第1期61-77,共17页
To analyze the relationship between macro and meso parameters of the gas hydrate bearing coal(GHBC)and to calibrate the meso-parameters,the numerical tests were conducted to simulate the laboratory triaxial compressio... To analyze the relationship between macro and meso parameters of the gas hydrate bearing coal(GHBC)and to calibrate the meso-parameters,the numerical tests were conducted to simulate the laboratory triaxial compression tests by PFC3D,with the parallel bond model employed as the particle contact constitutive model.First,twenty simulation tests were conducted to quantify the relationship between the macro–meso parameters.Then,nine orthogonal simulation tests were performed using four meso-mechanical parameters in a three-level to evaluate the sensitivity of the meso-mechanical parameters.Furthermore,the calibration method of the meso-parameters were then proposed.Finally,the contact force chain,the contact force and the contact number were examined to investigate the saturation effect on the meso-mechanical behavior of GHBC.The results show that:(1)The elastic modulus linearly increases with the bonding stiffness ratio and the friction coefficient while exponentially increasing with the normal bonding strength and the bonding radius coefficient.The failure strength increases exponentially with the increase of the friction coefficient,the normal bonding strength and the bonding radius coefficient,and remains constant with the increase of bond stiffness ratio;(2)The friction coefficient and the bond radius coefficient are most sensitive to the elastic modulus and the failure strength;(3)The number of the force chains,the contact force,and the bond strength between particles will increase with the increase of the hydrate saturation,which leads to the larger failure strength. 展开更多
关键词 gas hydrate bearing coal Discrete element method Triaxial compression test Macro-meso mechanical propertie
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Evaluation of the Shallow Gas Hydrate Production Based on the Radial Drilling-Heat Injection-Back Fill Method
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作者 CHEN Qiang WAN Yizhao +6 位作者 WU Nengyou SUN Jianye WANG Jian LIU Changling LI Yanlong LI Chengfeng HU Gaowei 《Journal of Ocean University of China》 CAS CSCD 2024年第1期119-128,共10页
It has been evidenced that shallow gas hydrate resources are abundant in deep oceans worldwide.Their geological back-ground,occurrence,and other characteristics differ significantly from deep-seated hydrates.Because o... It has been evidenced that shallow gas hydrate resources are abundant in deep oceans worldwide.Their geological back-ground,occurrence,and other characteristics differ significantly from deep-seated hydrates.Because of the high risk of well construction and low production efficiency,they are difficult to be recovered by using conventional oil production methods.As a result,this paper proposes an alternative design based on a combination of radial drilling,heat injection,and backfilling methods.Multi-branch holes are used to penetrate shallow gas hydrate reservoirs to expand the depressurization area,and heat injection is utilized as a supplement to improve gas production.Geotechnical information collected from an investigation site close to the offshore production well in the South China Sea is used to assess the essential components of this plan,including well construction stability and gas production behavior.It demonstrates that the hydraulic fracturing of the 60mbsf overburden layer can be prevented by regulating the drilling fluid densities.However,the traditional well structure is unstable,and the suction anchor is advised for better mechanical performance.The gas produc-tion rate can be significantly increased by combining hot water injection and depressurization methods.Additionally,the suitable produc-tion equipment already in use is discussed. 展开更多
关键词 shallow gas hydrate trail production radial drilling-heat injection-back fill method experimental and numerical simulation
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3D and 2D topographic correction to estimated geothermal gradient from the base of gas hydrate stability zone in the Andaman Forearc Basin
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作者 Uma Shankar 《Energy Geoscience》 EI 2024年第2期314-320,共7页
Methane gas hydrate related bottom-simulating reflectors(BSRs)are imaged based on the in-line and cross-line multi-channel seismic(MCS)data from the Andaman Forearc Basin.The depth of the BSR depends on pressure and t... Methane gas hydrate related bottom-simulating reflectors(BSRs)are imaged based on the in-line and cross-line multi-channel seismic(MCS)data from the Andaman Forearc Basin.The depth of the BSR depends on pressure and temperature and pore water salinity.With these assumptions,the BSR depth can be used to estimate the geothermal gradient(GTG)based on the availability of in-situ temperature measurements.This calculation is done assuming a 1D conductive model based on available in-situ temperature measurement at site NGHP-01-17 in the study area.However,in the presence of seafloor topography,the conductive temperature field in the subsurface is affected by lateral refraction of heat,which focuses heat in topographic lows and away from topographic highs.The 1D estimate of GTG in the Andaman Forearc Basin has been validated by drilling results from the NGHP-01 expedition.2D analytic modeling to estimate the effects of topography is performed earlier along selected seismic profiles in the study area.The study extended to estimate the effect of topography in 3D using a numerical model.The corrected GTG data allow us to determine GTG values free of topographic effect.The difference between the estimated GTG and values corrected for the 3D topographic effect varies up to~5℃/km.These conclude that the topographic correction is relatively small compared to other uncertainties in the 1D model and that apparent GTG determined with the 1D model captures the major features,although the correction is needed prior to interpreting subtle features of the derived GTG maps. 展开更多
关键词 gas hydrate BSR Geothermal gradient 3D and 2D topographic modeling Andaman Forearc Basin
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Numerical study on gas production via a horizontal well from hydrate reservoirs with different slope angles in the South China Sea
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作者 Tingting Luo Jianlin Song +5 位作者 Xiang Sun Fanbao Cheng Madhusudhan Bangalore Narasimha Murthy Yulu Chen Yi Zhao Yongchen Song 《Deep Underground Science and Engineering》 2024年第2期171-181,共11页
It is important to study the effect of hydrate production on the physical and mechanical properties of low-permeability clayey–silty reservoirs for the largescale exploitation of hydrate reservoirs in the South China... It is important to study the effect of hydrate production on the physical and mechanical properties of low-permeability clayey–silty reservoirs for the largescale exploitation of hydrate reservoirs in the South China Sea.In this study,a multiphysical-field coupling model,combined with actual exploration drilling data and the mechanical experimental data of hydrate cores in the laboratory,was established to investigate the physical and mechanical properties of low-permeability reservoirs with different slope angles during 5-year hydrate production by the depressurization method via a horizontal well.The result shows that the permeability of reservoirs severely affects gas production rate,and the maximum gas production amount of a 20-m-long horizontal well can reach186.8 m3/day during the 5-year hydrate production.Reservoirs with smaller slope angles show higher gas production rates.The depressurization propagation and hydrate dissociation mainly develop along the direction parallel to the slope.Besides,the mean effective stress of reservoirs is concentrated in the near-wellbore area with the on-going hydrate production,and gradually decreases with the increase of the slope angle.Different from the effective stress distribution law,the total reservoir settlement amount first decreases and then increases with the increase of the slope angle.The maximum settlement of reservoirs with a 0°slope angle is up to 3.4 m,and the displacement in the near-wellbore area is as high as2.2 m after 5 years of hydrate production.It is concluded that the pore pressure drop region of low-permeability reservoirs in the South China Sea is limited,and various slope angles further lead to differences in effective stress and strain of reservoirs during hydrate production,resulting in severe uneven settlement of reservoirs. 展开更多
关键词 effective stress low‐permeability reservoirs natural gas hydrate production numerical simulation SETTLEMENT slope angle the South China
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Mechanical Modeling and Analysis of Stability Deterioration of Production Well During Marine Hydrate Depressurization Production 被引量:1
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作者 SUN Huan-zhao CHANG Yuan-jiang +4 位作者 SUN Bao-jiang WANG Kang CHEN Guo-ming LI Hao DAI Yong-guo 《China Ocean Engineering》 SCIE EI CSCD 2024年第2期338-351,共14页
Different from oil and gas production,hydrate reservoirs are shallow and unconsolidated,whose mechanical properties deteriorate with hydrate decomposition.Therefore,the formations will undergo significant subsidence d... Different from oil and gas production,hydrate reservoirs are shallow and unconsolidated,whose mechanical properties deteriorate with hydrate decomposition.Therefore,the formations will undergo significant subsidence during depressurization,which will destroy the original force state of the production well.However,existing research on the stability of oil and gas production wells assumes the formation to be stable,and lacks consideration of the force exerted on the hydrate production well by formation subsidence caused by hydrate decomposition during production.To fill this gap,this paper proposes an analytical method for the dynamic evolution of the stability of hydrate production well considering the effects of hydrate decomposition.Based on the mechanical model of the production well,the basis for stability analysis has been proposed.A multi-field coupling model of the force state of the production well considering the effect of hydrate decomposition and formation subsidence is established,and a solver is developed.The analytical approach is verified by its good agreement with the results from the numerical method.A case study found that the decomposition of hydrate will increase the pulling-down force and reduce the supporting force,which is the main reason for the stability deterioration.The higher the initial hydrate saturation,the larger the reservoir thickness,and the lower the production pressure,the worse the stability or even instability.This work can provide a theoretical reference for the stability maintaining of the production well. 展开更多
关键词 natural gas hydrate production well depressurization production formation deformation stability deterioration
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Rate-limiting factors in hydrate decomposition through depressurization across various scales:A mini-review
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作者 Xian Sun Peng Xiao +7 位作者 Qinfeng Shi Lingban Wang Zhenbin Xu Yuhao Bu Xiaohui Wang Yifei Sun Changyu Sun Guangjin Chen 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第3期206-219,共14页
Natural gas hydrate is an energy resource for methane that has a carbon quantity twice more than all traditional fossil fuels combined.However,their practical application in the field has been limited due to the chall... Natural gas hydrate is an energy resource for methane that has a carbon quantity twice more than all traditional fossil fuels combined.However,their practical application in the field has been limited due to the challenges of long-term preparation,high costs and associated risks.Experimental studies,on the other hand,offer a safe and cost-effective means of exploring the mechanisms of hydrate dissociation and optimizing exploitation conditions.Gas hydrate decomposition is a complicated process along with intrinsic kinetics,mass transfer and heat transfer,which are the influencing factors for hydrate decomposition rate.The identification of the rate-limiting factor for hydrate dissociation during depressurization varies with the scale of the reservoir,making it challenging to extrapolate findings from laboratory experiments to the actual exploitation.This review aims to summarize current knowledge of investigations on hydrate decomposition on the subject of the research scale(core scale,middle scale,large scale and field tests)and to analyze determining factors for decomposition rate,considering the various research scales and their associated influencing factors. 展开更多
关键词 gas hydrate Rate-limiting factors Research scale DEPRESSURIZATION DECOMPOSITION
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Saturation Estimation with Complex Electrical Conductivity for Hydrate-Bearing Clayey Sediments:An Experimental Study
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作者 XING Lanchang ZHANG Shuli +8 位作者 ZHANG Huanhuan WU Chenyutong WANG Bin LAO Liyun WEI Wei HAN Weifeng WEI Zhoutuo GE Xinmin DENG Shaogui 《Journal of Ocean University of China》 CAS CSCD 2024年第1期173-189,共17页
Clays have considerable influence on the electrical properties of hydrate-bearing sediments.It is desirable to understand the electrical properties of hydrate-bearing clayey sediments and to build hydrate saturation(S... Clays have considerable influence on the electrical properties of hydrate-bearing sediments.It is desirable to understand the electrical properties of hydrate-bearing clayey sediments and to build hydrate saturation(S_(h))models for reservoir evaluation and monitoring.The electrical properties of tetrahydrofuran-hydrate-bearing sediments with montmorillonite are characterized by complex conductivity at frequencies from 0.01 Hz to 1 kHz.The effects of clay and Sh on the complex conductivity were analyzed.A decrease and increase in electrical conductance result from the clay-swelling-induced blockage and ion migration in the electrical double layer(EDL),respectively.The quadrature conductivity increases with the clay content up to 10%because of the increased surface site density of counterions in EDL.Both the in-phase conductivity and quadrature conductivity decrease consistently with increasing Sh from 0.50 to 0.90.Three sets of models for Sh evaluation were developed.The model based on the Simandoux equation outperforms Archie’s formula,with a root-mean-square error(E_(RMS))of 1.8%and 3.9%,respectively,highlighting the clay effects on the in-phase conductivity.The fre-quency effect correlations based on in-phase and quadrature conductivities exhibit inferior performance(E_(RMS)=11.6%and 13.2%,re-spectively)due to the challenge of choosing an appropriate pair of frequencies and intrinsic uncertainties from two measurements.The second-order Cole-Cole formula can be used to fit the complex-conductivity spectra.One pair of inverted Cole-Cole parameters,i.e.,characteristic time and chargeability,is employed to predict S_(h) with an E_(RMS) of 5.05%and 9.05%,respectively. 展开更多
关键词 gas hydrate complex electrical conductivity hydrate-bearing clayey sediment hydrate saturation Simandoux equation frequency dispersion Cole-Cole formula
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Experimental Study on Consolidation Properties of Hydrate-Bearing Fine-Grained Sediments Collected from the Shenhu Area of the Northern South China Sea
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作者 WEI Ruchun LIU Lele +5 位作者 JIA Chao DONG Xiao BU Qingtao ZHANG Yongchao LIU Changling WU Nengyou 《Journal of Ocean University of China》 SCIE CAS CSCD 2024年第4期981-990,共10页
Mechanical properties of hydrate-bearing fine-grained sediments are crucial to effectively mitigate environmental risks caused by artificial and natural decomposition of natural gas hydrates,and the decomposition can ... Mechanical properties of hydrate-bearing fine-grained sediments are crucial to effectively mitigate environmental risks caused by artificial and natural decomposition of natural gas hydrates,and the decomposition can induce laterally confined deformation.To explore the effect of natural gas hydrates on laterally confined compression properties,consolidation tests are conducted on remolded hydrate-free and hydrate-bearing samples by using natural fine-grained sediments collected from the northern South China Sea as the host sediments,and empirical equations are developed based on the analyses of consolidation characteristics.The results show that vertical loading induces a reduction in void ratio,and the reduction increases with decreasing hydrate saturation when samples are subjected to the same vertical stress change.The compression index of samples is about 0.53 whether there is hydrate or not,but the yield stress of samples increases sharply with increasing hydrate saturation once beyond the critical value.The coefficient of volume compression and the coefficient of consolidation of hydrate-bearing samples both increase firstly and then decrease to a relative stable level with increasing vertical stress,and the transition occurs at 200 kPa.The average consolidation degree with elapsed time increases rapidly under low vertical stresses,slowly under median vertical stresses,and under high vertical stresses,the consolidation increases a little faster but still slower than those under low vertical stresses. 展开更多
关键词 natural gas hydrate STIFFNESS compression index hydraulic permeability GEOHAZARD
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Deformation Characteristics of Hydrate-Bearing Sediments
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作者 DONG Lin LI Yanlong +4 位作者 ZHANG Yajuan HU Gaowei LIAO Hualin CHEN Qiang WU Nengyou 《Journal of Ocean University of China》 CAS CSCD 2024年第1期149-156,共8页
The safe and efficient development of natural gas hydrate requires a deep understanding of the deformation behaviors of reservoirs.In this study,a series of triaxial shearing tests are carried out to investigate the d... The safe and efficient development of natural gas hydrate requires a deep understanding of the deformation behaviors of reservoirs.In this study,a series of triaxial shearing tests are carried out to investigate the deformation properties of hydrate-bearing sediments.Variations of volumetric and lateral strains versus hydrate saturation are analyzed comprehensively.Results indicate that the sediments with high hydrate saturation show dilative behaviors,which lead to strain-softening characteristics during shearing.The volumetric strain curves have a tendency to transform gradually from dilatation to compression with the increase in effective confining pressure.An easy prediction model is proposed to describe the relationship between volumetric and axial strains.The model coefficientβis the key dominating factor for the shape of volumetric strain curves and can be determined by the hydrate saturation and stress state.Moreover,a modified model is established for the calculation of lateral strain.The corresponding determination method is provided for the easy estimation of model coefficients for medium sand sediments containing hydrate.This study provides a theoretical and experimental reference for deformation estimation in natural gas hydrate development. 展开更多
关键词 gas hydrate deformation characteristics volumetric strain lateral strain prediction model
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Numerical Simulation on Production Trials by Using Depressurization for Typical Marine Hydrate Reservoirs:Well Type and Formation Dip
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作者 QIN Fanfan SUN Jiaxin +4 位作者 GU Yuhang CAO Xinxin MAO Peixiao NING Fulong JIANG Guosheng 《Journal of Ocean University of China》 SCIE CAS CSCD 2024年第3期661-675,共15页
Natural gas hydrate has huge reserves and is widely distributed in marine environment.Its commercial development is of great significance for alleviating the contradiction between energy supply and demand.As an effici... Natural gas hydrate has huge reserves and is widely distributed in marine environment.Its commercial development is of great significance for alleviating the contradiction between energy supply and demand.As an efficient research method,numerical simulation can provide valuable insights for the design and optimization of hydrate development.However,most of the current production models simplify the reservoir as a two-dimensional(2D)horizontal layered model,often ignoring the impact of formation dip angle.To improve the accuracy of production prediction and provide theoretical support for the optimization of production well design,two three-dimensional(3D)geological models with different dip angles based on the geological data from two typical sites are constructed.The vertical well,horizontal well and multilateral wells are deployed in these reservoirs with different permeabilities to perform production trial,and the sensitivity analysis of dip angles is also carried out.The short-term production behaviors in high and low permeability reservoirs with different dip angles are exhibited.The simulation results show that 1)the gas and water production behaviors for different well types in the two typical reservoirs show obviously different variation laws when the short-term depressurization is conducted in the inclined formation;2)the inclined formation will reduce the gas production and increase the water extraction,and the phenomena becomes pronounced as the dip angle increases,particularly in the low-permeability reservoirs;3)and the impact of formation dip on hydrate recovery does not change significantly with the variation of well type. 展开更多
关键词 natural gas hydrate inclined formation DEPRESSURIZATION production well type
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Spatial distribution and inventory of natural gas hydrate in the Qiongdongnan Basin,northern South China Sea 被引量:1
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作者 Zhongxian ZHAO Ning QIU +4 位作者 Zhen SUN Wen YAN Genyuan LONG Pengchun LI Haiteng ZHUO 《Journal of Oceanology and Limnology》 SCIE CAS CSCD 2023年第2期729-739,共11页
Natural gas hydrate is a potential clean energy source and is related to submarine geohazard,climate change,and global carbon cycle.Multidisciplinary investigations have revealed the occurrence of hydrate in the Qiong... Natural gas hydrate is a potential clean energy source and is related to submarine geohazard,climate change,and global carbon cycle.Multidisciplinary investigations have revealed the occurrence of hydrate in the Qiongdongnan Basin,northern South China Sea.However,the spatial distribution,controlling factors,and favorable areas are not well defined.Here we use the available high-resolution seismic lines,well logging,and heat flow data to explore the issues by calculating the thickness of gas hydrate stability zone(GHSZ)and estimating the inventory.Results show that the GHSZ thickness ranges between mostly~200 and 400 m at water depths>500 m.The gas hydrate inventory is~6.5×109-t carbon over an area of~6×104 km2.Three areas including the lower uplift to the south of the Lingshui sub-basin,the Songnan and Baodao sub-basins,and the Changchang sub-basin have a thick GHSZ of~250-310 m,250-330 m,and 350-400 m,respectively,where water depths are~1000-1600 m,1000-2000 m,and2400-3000 m,respectively.In these deep waters,bottom water temperatures vary slightly from~4 to 2℃.However,heat flow increases significantly with water depth and reaches the highest value of~80-100 mW/m2 in the deepest water area of Changchang sub-basin.High heat flow tends to reduce GHSZ thickness,but the thickest GHSZ still occurs in the Changchang sub-basin,highlighting the role of water depth in controlling GHSZ.The lower uplift to the south of the Lingshui sub-basin has high deposition rate(~270-830 m/Ma in 1.8-0 Ma);the thick Cenozoic sediment,rich biogenic and thermogenic gas supplies,and excellent transport systems(faults,diapirs,and gas chimneys)enables it a promising area of hydrate accumulation,from which hydrate-related bottom simulating reflectors,gas chimneys,and active cold seeps were widely revealed. 展开更多
关键词 gas hydrate stability zone gas hydrate inventory Qiongdongnan Basin South China Sea
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Experimental study on solid particle migration and production behaviors during marine natural gas hydrate dissociation by depressurization 被引量:1
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作者 Yan-Long Li Fu-Long Ning +5 位作者 Meng Xu Min-Hui Qi Jia-Xin Sun Alireza Nouri De-Li Gao Neng-You Wu 《Petroleum Science》 SCIE EI CAS CSCD 2023年第6期3610-3623,共14页
Sand production is one of the main obstacles restricting gas extraction efficiency and safety from marine natural gas hydrate(NGH)reservoirs.Particle migration within the NGH reservoir dominates sand production behavi... Sand production is one of the main obstacles restricting gas extraction efficiency and safety from marine natural gas hydrate(NGH)reservoirs.Particle migration within the NGH reservoir dominates sand production behaviors,while their relationships were rarely reported,severely constrains quantitative evaluation of sand production risks.This paper reports the optical observations of solid particle migration and production from micrometer to mesoscopic scales conditioned to gravel packing during depressurization-induced NGH dissociation for the first time.Theoretical evolutionary modes of sand migration are established based on experimental observations,and its implications on field NGH are comprehensively discussed.Five particle migration regimes of local borehole failure,continuous collapse,wormhole expansion,extensive slow deformation,and pore-wall fluidization are proved to occur during depressurization.The types of particle migration regimes and their transmission modes during depressurization are predominantly determined by initial hydrate saturation.In contrast,the depressurization mainly dominates the transmission rate of the particle migration regimes.Furthermore,both the cumulative mass and the medium grain size of the produced sand decrease linearly with increasing initial methane hydrate(MH)saturation.Discontinuous gas bubble emission,expansion,and explosion during MH dissociation delay sand migration into the wellbore.At the same time,continuous water flow is a requirement for sand production during hydrate dissociation by depressurization.The experiments enlighten us that a constitutive model that can illustrate visible particle migration regimes and their transmission modes is urgently needed to bridge numerical simulation and field applications.Optimizing wellbore layout positions or special reservoir treatment shall be important for mitigating sand production tendency during NGH exploitation. 展开更多
关键词 Natural gas hydrate Solid particle migration Sand production Sand control SANDING hydrate exploitation
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