We report on the optimal production of the Bose and Fermi mixtures with ^(87) Rb and ^(40)K in a crossed optical dipole trap(ODT).We measure the atomic number and lifetime of the mixtures in combination of the spin st...We report on the optimal production of the Bose and Fermi mixtures with ^(87) Rb and ^(40)K in a crossed optical dipole trap(ODT).We measure the atomic number and lifetime of the mixtures in combination of the spin state |F=9/2,m_F=9/2) of^(40)K and |1,1>of ^(87) Rb in the ODT,which is larger and longer compared with the combination of the spin state 19/2,9/2) of^(40)K and 12,2) of ^(87)Rb in the ODT.We observe the atomic numbers of ^(87)Rb and ^(40)K shown in each stage of the sympathetic cooling process while gradually reducing the depth of the optical trap.By optimizing the relative loading time of atomic mixtures in the MOT,we obtain the large atomic number of ^(40)K(~6 ×10^(6)) or the mixtures of atoms with an equal number(~1.6 × 10^(6)) at the end of evaporative cooling in the ODT.We experimentally investigate the evaporative cooling in an enlarged volume of the ODT via adding a third laser beam to the crossed ODT and found that more atoms(8 × 10^(6)) and higher degeneracy(T/T_(F)=0.25) of Fermi gases are obtained.The ultracold atomic gas mixtures pave the way to explore phenomena such as few-body collisions and the Bose-Fermi Hubbard model,as well as for creating ground-state molecules of ^(87)Rb^(40)K.展开更多
CF3I gas mixtures have attracted considerable attention as potential environmentally-friendly alternatives to SF6 gas,owing to their excellent insulating performance.This paper attempts to study the CF3I ternary gas m...CF3I gas mixtures have attracted considerable attention as potential environmentally-friendly alternatives to SF6 gas,owing to their excellent insulating performance.This paper attempts to study the CF3I ternary gas mixtures with c-C4F8 and buffer gases N2 and CO2 by considering dielectric strength from electron transport parameters based on the Boltzmann method and synergistic effect analysis,compared with SF6 gas mixtures.The results confirm that the critical electric field strength of CF3I/c-C4F8/70%CO2 is greater than that of 30%SF6/70%CO2 when the CF3I content is greater than 17%.Moreover,a higher content of c-C4F8 decreases the sensitivity of gas mixtures to an electric field,and this phenomenon is more obvious in CF3I/c-C4F8/CO2 gas mixtures.The synergistic effects for CF3I/c-C4F8/70%N2 were most obvious when the c-C4F8 content was approximately 20%,and for CF3I/c-C4F8/70%CO2 when the c-C4F8 content was approximately 10%.On the basis of this research,CF3I/c-C4F8/70%N2 shows better insulation performance when the c-C4F8 content is in the15%–20%range.For CF3I/c-C4F8/70%CO2,when the c-C4F8 content is in the 10%–15%range,the gas mixtures have excellent performance.Hence,these gas systems might be used as alternative gas mixtures to SF6 in high-voltage equipment.展开更多
The electron swarm parameters including the density-normalized effective ionization coefficients(α-η)/N and the electron drift velocities V e are calculated for a gas mixture of CF3I with N2 and CO2 by solving the...The electron swarm parameters including the density-normalized effective ionization coefficients(α-η)/N and the electron drift velocities V e are calculated for a gas mixture of CF3I with N2 and CO2 by solving the Boltzmann equation in the condition of a steady-state Townsend(SST) experiment.The overall density-reduced electric field strength is from 100 Td to 1000 Td(1 Td = 10-17V·cm2),while the CF3I content k in the gas mixture can be varied over the range from 0% to 100%.From the variation of(αη)/N with the CF3I mixture ratio k,the limiting field strength(E/N) lim for each CF3I concentration is derived.It is found that for the mixtures with 70% CF3I,the values of(E/N) lim are essentially the same as that for pure SF 6.Additionally,the global warming potential(GWP) and the liquefaction temperature of the gas mixtures are also taken into account to evaluate the possibility of application in the gas insulation of power equipment.展开更多
CF3I is a potential SF6 alternative gas.In order to study the insulation properties and synergistic effects of CF3I/N2 and CF3I/CO2 gas mixtures,two-term approximate Boltzmann equations were used to obtain the ionizat...CF3I is a potential SF6 alternative gas.In order to study the insulation properties and synergistic effects of CF3I/N2 and CF3I/CO2 gas mixtures,two-term approximate Boltzmann equations were used to obtain the ionization coefficient α,attachment coefficient η and the critical equivalent electrical field strength(E/N)(cr).The results show that the(E/N)(cr)of CF3I gas at 300 K is 1.2 times that of SF6 gas,and CF3I/N2 and CF3I/CO2 gas mixtures both have synergistic effect occurred.The synergistic effect coefficient of CF3I/CO2 gas mixture was higher than that of CF3I/N2 gas mixture.But the(E/N)(cr)of CF3I/N2 is higher than that of CF3I/CO2 under the same conditions.When the content of CF3I exceeds 20%,the (E/N)(cr) of CF3I/N2 and CF3I/CO2 gas mixture increase linearly with the increasing of CF3I gas content.The breakdown voltage of CF3I/N2 gas mixture is also higher than that of CF3I/CO2 gas mixture in slightly non-uniform electrical field under power frequency voltage,but the synergistic effect coefficients of the two gas mixtures are basically the same.展开更多
In this paper, we focused on the identification of the normal and abnormal glow discharge modes in a neon-xenon gas mixture at low pressure. We considered four gas mixtures: 90%Ne-10%Xe, 80%Ne-20%Xe, 70%Ne-30%Xe and ...In this paper, we focused on the identification of the normal and abnormal glow discharge modes in a neon-xenon gas mixture at low pressure. We considered four gas mixtures: 90%Ne-10%Xe, 80%Ne-20%Xe, 70%Ne-30%Xe and 50%Ne-50%Xe at 1.5 Torr. The range of the gap voltage is 150-500 V. A one-dimensional fluid model with multiple species was used in this work, and the metastable state of the atoms as well as the radiation effects were integrated into the model too. The input data changed for each percentage in the gas mixture, and was calculated by BOLSIG+ software. The parameters of particle transport and their rate coefficients strictly depend on the mean electron energy. The results show that the neon ion density is negligible compared to the xenon ion density, mostly in the case of 50%Ne-50%Xe.展开更多
Monte Carlo simulations are adopted to study the electron motion in the mixture of H2 and CH4 during diamond synthesis via Glow Plasma-assisted Chemical Vapor Deposition (GPCVD). The non-uniform electric field is used...Monte Carlo simulations are adopted to study the electron motion in the mixture of H2 and CH4 during diamond synthesis via Glow Plasma-assisted Chemical Vapor Deposition (GPCVD). The non-uniform electric field is used and the avalanche of electrons is taken into account in this simulation. The average energy distribution of electrons and the space distribution of effective species such as CH3, CH+3, CH+ and H at various gas pressures are given in this paper, and optimum experimental conditions are inferred from these results.展开更多
Paschen law and equations, which ignore the influence of the Penning ionization on the electron ionization coefficient (α), are always used as the approximation of the breakdown voltage criterion of the Penning gas...Paschen law and equations, which ignore the influence of the Penning ionization on the electron ionization coefficient (α), are always used as the approximation of the breakdown voltage criterion of the Penning gas mixture in current researches of discharge characteristics of the plasma display panel (PDP). It is doubtful that whether their results match the facts. Based on the Townsend gas self-sustaining discharge condition and the chemical kinetics analysis of the Penning gas mixture discharging in PDP, the empirical equation to describe the breakdown of the Penning gas mixture is given. It is used to calculate the breakdown voltage curves of Ne-Xe/MgO and Ne-Ar/MgO in a testing macroscopic discharge cell of AC-PDP. The effective secondary electron emission coefficients (γeff) of the MgO protective layers are derived by comparing the breakdown voltage curves obtained from the empirical equation with the experimental data of breakdown voltages. In comparison with the results calculated by the Paschen law and the equation which ignore the influence of the Penning ionization on α , the results calculated by the empirical equation have better conformity with experimental data. The empirical equation characterizes the breakdown of the Penning gas mixture in PDP effectively, and gives a convenient way to study its breakdown characteristics and the secondary electron emission behaviors.展开更多
Perfluorocyclobutane(c-C4F8) has been recently considered as a potential alternative to SF6,because of its high electro-negativity and extremely low environmental effect.However,due to its high boiling point,c-C4F8 sh...Perfluorocyclobutane(c-C4F8) has been recently considered as a potential alternative to SF6,because of its high electro-negativity and extremely low environmental effect.However,due to its high boiling point,c-C4F8 should mixed with buffer gases such as N2 or CO2 in order to avoid the liquefaction at low temperature.This paper investigates insulating properties of c-C4F8/N2 gas mixtures from two aspects including electrical strength,and Global Warming Potential(GWP).Moreover,improved electrical breakdown model of gas mixtures is founded.Breakdown temperature and breakdown electrical field in gas mixtures can be obtained from rigorous Townsend criterion expression according to gas mixtures ratio and cross section data of gas mixtures in this model.Under the condition of different gas pressure(0.1~0.4 MPa),gas mixtures ratio(0~30%),and electrode gap(2~10 mm),breakdown voltages of gas mixtures are calculated by using of this model.Insulation strength of SF6/N2 mixed gas is compared with c-C4F8/N2 mixed gas in the same conditions.Research results show that theoretical computation corresponds with experiment.If the content of c-C4F8 or SF6 in mixtures is less than 30%,insulation strength between c-C4F8/N2 and SF6/N2 is very close.Considering two indexes(breakdown voltage,GWP),it is suitable for c-C4F8 content being 15%~20% in c-C4F8/N2 gas展开更多
For dielectric barrier discharge lamps filled with various gas mixture ratios, the correlations between the excimer XeCl* emission and the sealed gas temperature have been founded, and a qualitative explication is pre...For dielectric barrier discharge lamps filled with various gas mixture ratios, the correlations between the excimer XeCl* emission and the sealed gas temperature have been founded, and a qualitative explication is presented. For gas mixture with chlorine larger than 3%, the emission intensity increases with the sealed gas temperature, while with chlorine about 2%, the emission intensity decreases with the increase in the gas temperature, and could be improved by cooling water. However, if chlorine is less than 1.5%, the discharge appears to be a mixture mode with filaments distributed in a diffused glow-like discharge, and the UV emission is independent on the gas temperature.展开更多
An array composed of sixteen gas sensors was constructed to analyze gas mixtures quantitatively. The data of responses from the sensor array to ethane, propane and propylene were treated by three-layer ANN with BP alg...An array composed of sixteen gas sensors was constructed to analyze gas mixtures quantitatively. The data of responses from the sensor array to ethane, propane and propylene were treated by three-layer ANN with BP algorithms and PLS. The analytical results indicated that the concentration predicted with ANN is better than that with PLS. The average prediction errors for ethane, propane and propylene were 5.11%, 8.28%, 2.64%, respectively.展开更多
The dynamics of negative surface discharges in c-C_(4)F_(8)/CF_(3)I/CO_(2) gas mixture is investigated here with a 2D fuid model.The distributions of ion concentration,electric field strength and photon flux during th...The dynamics of negative surface discharges in c-C_(4)F_(8)/CF_(3)I/CO_(2) gas mixture is investigated here with a 2D fuid model.The distributions of ion concentration,electric field strength and photon flux during the propagation of the streamer are obtained by solving the drift-diffusion equations of particles and Poisson's equation,and the photon flux variation function during the propagation is also fitted.It is found that the streamer branches occur when the streamer transitions from the upper surface of the insulator to the side surface,and then when the streamer approaches the plane electrode,the photon flux will increase significantly.On this basis,the positive and negative surface discharge models are compared in terms of streamer characteristics,particle characteristics and streamer branches.It is found that the streamer has a higher electron concentration and electric field in the positive model.The streamer develops“floating”in the positive surface discharge,while it is close to the surface of the insulator in the negative model.In addition,the negative streamer branch has a wider width and develops further.展开更多
In PASER (particle acceleration by stimulated emission of radiation), in the presence of an active medium incorporated in a Penning trap, moving electrons can become bunched, and as they get enough energy, they esca...In PASER (particle acceleration by stimulated emission of radiation), in the presence of an active medium incorporated in a Penning trap, moving electrons can become bunched, and as they get enough energy, they escape the trap forming an optical injector. These bunched electrons can enter the next PASER section filled with the same active medium to be accelerated. In this paper, electron dynamics in the presence of a gas mixture active medium incorporated in a Penning trap is analyzed by developing an idealized 1D model. We evaluate the energy exchange occurring as the train of electrons traverses into the next PASER section. The results show that the oscillating electrons can be bunched at the resonant frequency of the active medium. The influence of the trapped time and population inversion are analyzed, showing that the longer the electrons are trapped, the more energy from the medium the accelerated electrons get, and with the increase of population inversion, the decelerated electrons are virtually unchanged but the accelerated electrons more than double their peak energy values. The simulation results show that the gas active medium needs a lower population inversion to bunch the electrons compared to a solid active medium, so the experimental conditions can easily be achieved.展开更多
As group contribution method is easy to apply and has a wide application range,current study has developed this model to predict flammability limit of hydrocarbons mixed with inert gas using the Marrero/Gani group con...As group contribution method is easy to apply and has a wide application range,current study has developed this model to predict flammability limit of hydrocarbons mixed with inert gas using the Marrero/Gani group contribution method,which is significative to the safe application of hydrocarbons in the ORC system.The whole modeling process is divided into two parts:pure compound prediction and mixture prediction.The contribution factors of inert gases and dilute concentration were first introduced in the group contribution method.Moreover,the respective 95%-confidence interval of the mixture based on linear superposition method has been proposed in the developed group contribution model to improve the safety coefficient.For CO2 as inert gas,the average relative error and correlation coefficient are 5.34%and 0.88 for lower flammability limit while 6.99%and 0.95 for upper flammability limit.For N2 as inert gas,the average relative error and correlation coefficient are 7.47%and 0.84 for lower flammability limit while 6.68%and 0.97 for upper flammability limit.Most importantly,this group contribution method has extended the application range to make up the shortcomings of other flammability limit prediction methods aiming at hydrocarbon and inert gas mixtures and proposed the uncertainty analysis to provide reliable prediction range.展开更多
RGAs are widely used in molec Background RGAs are widely used in molecular component examination,impurity analysis,leak detection and test of vacuum system performance.However,RGAs have different sensitivities to diff...RGAs are widely used in molec Background RGAs are widely used in molecular component examination,impurity analysis,leak detection and test of vacuum system performance.However,RGAs have different sensitivities to different gases,and the sensitivities can change quickly and depend on so many parameters,which make its ability severely limited.Methods In thiswork we established a newpractical method to precisely measure noble gas ratio of argon-xenon gasmixture.Gaseous argon and xenon were controlled,respectively,by two mass flow controller(MFC).A variable leak valve(VLV)was used to introduce the gas mixture sample into the RGA measurement chamber.Gas mixtures with xenon concentration from 200ppm to 20000ppm(by mass)were introduced and tested by RGA.Results The time stability of RGA-measurement system was optimized to 2.1%.A good linearity of MFC-RGA response was achieved,verifying the reliability of RGA in measuring noble gas mixture with component concentration down to several hundred ppm level.Conclusions Since the approach we used in our experiment is gas-species independent,we believe that it can be popularized to other gas species when properly applied.展开更多
Lubricant transfer and distribution at the head/disk interface in air-helium gas mixtures is investigated using a developed model that combines an air-bearing model with a molecular dynamics model. The pressure distri...Lubricant transfer and distribution at the head/disk interface in air-helium gas mixtures is investigated using a developed model that combines an air-bearing model with a molecular dynamics model. The pressure distribution is calculated by the air-bearing model at the head/disk interface with respect to the helium content and the pressure obtained is then input to the molecular dynamics model to understand the lubricant transfer mechanism. Finally, the effects of pressure at the boundary condition and disk velocity on lubricant transfer are discussed in relation to the helium fraction within the air-helium gas mixtures. Results show there is a decrease in the pressure difference with an increase in the helium percentage, which leads to a decrease in the volume of the lubricant transferred. The results also suggest that the lubricant is not easily to transfer in gas mixtures with a high percentage of helium, even when both higher disk velocities and pressure boundary conditions are applied.展开更多
In this paper,we extend the unified gas-kinetic wave-particle(UGKWP)methods to the multi-species gas mixture and multiscale plasma transport.The construction of the scheme is based on the direct modeling on the mesh s...In this paper,we extend the unified gas-kinetic wave-particle(UGKWP)methods to the multi-species gas mixture and multiscale plasma transport.The construction of the scheme is based on the direct modeling on the mesh size and time step scales,and the local cell’s Knudsen number determines the flow physics.The proposed scheme has the multiscale and asymptotic complexity diminishing properties.The multiscale property means that according to the cell’s Knudsen number the scheme can capture the non-equilibrium flow physics when the cell size is on the kinetic mean free path scale,and preserve the asymptotic Euler,Navier-Stokes,and magnetohydrodynamics(MHD)when the cell size is on the hydrodynamic scale and is much larger than the particle mean free path.The asymptotic complexity diminishing property means that the total degrees of freedom of the scheme reduce automatically with the decreasing of the cell’s Knudsen number.In the continuum regime,the scheme automatically degenerates from a kinetic solver to a hydrodynamic solver.In the UGKWP,the evolution of microscopic velocity distribution is coupled with the evolution of macroscopic variables,and the particle evolution as well as the macroscopic fluxes is modeled from a time accumulating solution of kinetic scale particle transport and collision up to a time step scale.For plasma transport,the current scheme provides a smooth transition from particle-in-cell(PIC)method in the rarefied regime to the magnetohydrodynamic solver in the continuum regime.In the continuum limit,the cell size and time step of the UGKWP method are not restricted by the particle mean free path and mean collision time.In the highly magnetized regime,the cell size and time step are not restricted by the Debye length and plasma cyclotron period.The multiscale and asymptotic complexity diminishing properties of the scheme are verified by numerical tests in multiple flow regimes.展开更多
A new approach to simulation of stationary flows by Direct Simulation Monte Carlo method is proposed.The idea is to specify an individual time step for each component of a gas mixture.The approach consists of modifica...A new approach to simulation of stationary flows by Direct Simulation Monte Carlo method is proposed.The idea is to specify an individual time step for each component of a gas mixture.The approach consists of modifications mainly to collision phase simulation and recommendations on choosing time step ratios.It allows lowering the demands on the computational resources for cases of disparate collision diameters of molecules and/or disparate molecular masses.These are cases important e.g.,in vacuum deposition technologies.Few tests of the new approach are made.Finally,the usage of new approach is demonstrated on a problem of silver nanocluster diffusion in argon carrier gas under conditions of silver deposition experiments.展开更多
In this paper we used MOF-5 and Cu3(BTC)2 to separate CO2/CH4 and CI-I4/N2 mixtures under dynamic conditions. Both materials were synthesized and pelletized, thus allowing for a meaningful characterization in view o...In this paper we used MOF-5 and Cu3(BTC)2 to separate CO2/CH4 and CI-I4/N2 mixtures under dynamic conditions. Both materials were synthesized and pelletized, thus allowing for a meaningful characterization in view of process scale-up. The materials were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). By performing breakthrough experiments, we found that Cu3(BTC)2 separated CO2/CH4 slightly better than MOF-5. Because the crystal structure of Cu3 (BTC)2 includes unsaturated accessible metal sites formed via dehydration, it predominantly interacted with CO2 molecules and more easily captured them. Conversely, MOF-5 with a suitable pore size separated CH4/N2 more efficiently in our breakthrough test.展开更多
We calculated the uniform dielectric breakdown field strength of residual 30% CF3I/CO2 gas mixtures during the arc extinction process over the temperature range 300-3500 K at 0.1 MPa. The limiting reduced field streng...We calculated the uniform dielectric breakdown field strength of residual 30% CF3I/CO2 gas mixtures during the arc extinction process over the temperature range 300-3500 K at 0.1 MPa. The limiting reduced field strengths are decided by a balance of electron generation and loss based on chemical reactions estimated by the electron energy distribution function (EEDF), which employs the Boltzmann equation method with two-term expanding approximation in the steady-state Townsend (SST) condition. During the insulation recovery phase, the hot CF3I/CO2 gas mixtures have maximum dielectric strength at a temperature of about 1500 K. At room temperature 300 K, the electric strength after arc extinction (90.3 Td, 1 Td=10-21 V.m2) is only 38% of the original value before arc (234.9 Td). The adverse insulation recovery ability of CF3I/CO2 gas mixtures in arc extinction hinders its application in electric circuit breakers and other switchgears as an arc quenching and insulating medium.展开更多
The effects of the Xe gas content and total gas pressure on the discharge characteristics of colour plasma display panels including the sustaining voltage margin, white-field chromaticity, discharge time lag (DTL), ...The effects of the Xe gas content and total gas pressure on the discharge characteristics of colour plasma display panels including the sustaining voltage margin, white-field chromaticity, discharge time lag (DTL), discharge current peak, and full-width-at-half-maximum (FWHM) of the discharge current pulse, are experimentally studied. The results indicate that as the Xe gas content in the He-Ne-Xe gas mixture or total pressure increases, the sustaining voltage margin increases, the white-field chromaticity improves, and the discharge current peak has a maximum value, while DTL and FWHM have a minimum value. The mean electron energy in the gas mixture discharge is also calculated through a numerical solution of Boltzmann equation. The experimental results are explained from a view of the mean electron energy variations with the Xe gas content and total gas pressure.展开更多
基金supported by the Innovation Program for Quantum Science and Technology (Grant No. 2021ZD0302003)the National Natural Science Foundation of China (Grant Nos. 12034011, U23A6004, 12374245,12322409, 92065108, 11974224, and 12022406)+1 种基金the National Key Research and Development Program of China (Grant Nos. 2022YFA1404101 and 2021YFA1401700)the Fund for Shanxi 1331 Project Key Subjects Construction。
文摘We report on the optimal production of the Bose and Fermi mixtures with ^(87) Rb and ^(40)K in a crossed optical dipole trap(ODT).We measure the atomic number and lifetime of the mixtures in combination of the spin state |F=9/2,m_F=9/2) of^(40)K and |1,1>of ^(87) Rb in the ODT,which is larger and longer compared with the combination of the spin state 19/2,9/2) of^(40)K and 12,2) of ^(87)Rb in the ODT.We observe the atomic numbers of ^(87)Rb and ^(40)K shown in each stage of the sympathetic cooling process while gradually reducing the depth of the optical trap.By optimizing the relative loading time of atomic mixtures in the MOT,we obtain the large atomic number of ^(40)K(~6 ×10^(6)) or the mixtures of atoms with an equal number(~1.6 × 10^(6)) at the end of evaporative cooling in the ODT.We experimentally investigate the evaporative cooling in an enlarged volume of the ODT via adding a third laser beam to the crossed ODT and found that more atoms(8 × 10^(6)) and higher degeneracy(T/T_(F)=0.25) of Fermi gases are obtained.The ultracold atomic gas mixtures pave the way to explore phenomena such as few-body collisions and the Bose-Fermi Hubbard model,as well as for creating ground-state molecules of ^(87)Rb^(40)K.
基金supported by National Natural Science Foundation of China(No.51337006)。
文摘CF3I gas mixtures have attracted considerable attention as potential environmentally-friendly alternatives to SF6 gas,owing to their excellent insulating performance.This paper attempts to study the CF3I ternary gas mixtures with c-C4F8 and buffer gases N2 and CO2 by considering dielectric strength from electron transport parameters based on the Boltzmann method and synergistic effect analysis,compared with SF6 gas mixtures.The results confirm that the critical electric field strength of CF3I/c-C4F8/70%CO2 is greater than that of 30%SF6/70%CO2 when the CF3I content is greater than 17%.Moreover,a higher content of c-C4F8 decreases the sensitivity of gas mixtures to an electric field,and this phenomenon is more obvious in CF3I/c-C4F8/CO2 gas mixtures.The synergistic effects for CF3I/c-C4F8/70%N2 were most obvious when the c-C4F8 content was approximately 20%,and for CF3I/c-C4F8/70%CO2 when the c-C4F8 content was approximately 10%.On the basis of this research,CF3I/c-C4F8/70%N2 shows better insulation performance when the c-C4F8 content is in the15%–20%range.For CF3I/c-C4F8/70%CO2,when the c-C4F8 content is in the 10%–15%range,the gas mixtures have excellent performance.Hence,these gas systems might be used as alternative gas mixtures to SF6 in high-voltage equipment.
基金Project supported by the National Natural Science Foundation of China (Grant No. 51177101)
文摘The electron swarm parameters including the density-normalized effective ionization coefficients(α-η)/N and the electron drift velocities V e are calculated for a gas mixture of CF3I with N2 and CO2 by solving the Boltzmann equation in the condition of a steady-state Townsend(SST) experiment.The overall density-reduced electric field strength is from 100 Td to 1000 Td(1 Td = 10-17V·cm2),while the CF3I content k in the gas mixture can be varied over the range from 0% to 100%.From the variation of(αη)/N with the CF3I mixture ratio k,the limiting field strength(E/N) lim for each CF3I concentration is derived.It is found that for the mixtures with 70% CF3I,the values of(E/N) lim are essentially the same as that for pure SF 6.Additionally,the global warming potential(GWP) and the liquefaction temperature of the gas mixtures are also taken into account to evaluate the possibility of application in the gas insulation of power equipment.
基金supported by National Natural Science Foundation of China (Grant No.51337006)China Postdoctoral Science Foundation (2016M602728)the Science and Technology Project of SGCC ‘Research on SF_6 Alternative Gas for Insulation and Arc Quenching Application’
文摘CF3I is a potential SF6 alternative gas.In order to study the insulation properties and synergistic effects of CF3I/N2 and CF3I/CO2 gas mixtures,two-term approximate Boltzmann equations were used to obtain the ionization coefficient α,attachment coefficient η and the critical equivalent electrical field strength(E/N)(cr).The results show that the(E/N)(cr)of CF3I gas at 300 K is 1.2 times that of SF6 gas,and CF3I/N2 and CF3I/CO2 gas mixtures both have synergistic effect occurred.The synergistic effect coefficient of CF3I/CO2 gas mixture was higher than that of CF3I/N2 gas mixture.But the(E/N)(cr)of CF3I/N2 is higher than that of CF3I/CO2 under the same conditions.When the content of CF3I exceeds 20%,the (E/N)(cr) of CF3I/N2 and CF3I/CO2 gas mixture increase linearly with the increasing of CF3I gas content.The breakdown voltage of CF3I/N2 gas mixture is also higher than that of CF3I/CO2 gas mixture in slightly non-uniform electrical field under power frequency voltage,but the synergistic effect coefficients of the two gas mixtures are basically the same.
文摘In this paper, we focused on the identification of the normal and abnormal glow discharge modes in a neon-xenon gas mixture at low pressure. We considered four gas mixtures: 90%Ne-10%Xe, 80%Ne-20%Xe, 70%Ne-30%Xe and 50%Ne-50%Xe at 1.5 Torr. The range of the gap voltage is 150-500 V. A one-dimensional fluid model with multiple species was used in this work, and the metastable state of the atoms as well as the radiation effects were integrated into the model too. The input data changed for each percentage in the gas mixture, and was calculated by BOLSIG+ software. The parameters of particle transport and their rate coefficients strictly depend on the mean electron energy. The results show that the neon ion density is negligible compared to the xenon ion density, mostly in the case of 50%Ne-50%Xe.
基金This work was supported by Doctor Foundation of Hebei Education Committee Hebei Natural Science Foundation(599091 ) of China
文摘Monte Carlo simulations are adopted to study the electron motion in the mixture of H2 and CH4 during diamond synthesis via Glow Plasma-assisted Chemical Vapor Deposition (GPCVD). The non-uniform electric field is used and the avalanche of electrons is taken into account in this simulation. The average energy distribution of electrons and the space distribution of effective species such as CH3, CH+3, CH+ and H at various gas pressures are given in this paper, and optimum experimental conditions are inferred from these results.
基金Science and Technology Research Foundation of the Ministry of Education, China (No. 0205-[2002]78)
文摘Paschen law and equations, which ignore the influence of the Penning ionization on the electron ionization coefficient (α), are always used as the approximation of the breakdown voltage criterion of the Penning gas mixture in current researches of discharge characteristics of the plasma display panel (PDP). It is doubtful that whether their results match the facts. Based on the Townsend gas self-sustaining discharge condition and the chemical kinetics analysis of the Penning gas mixture discharging in PDP, the empirical equation to describe the breakdown of the Penning gas mixture is given. It is used to calculate the breakdown voltage curves of Ne-Xe/MgO and Ne-Ar/MgO in a testing macroscopic discharge cell of AC-PDP. The effective secondary electron emission coefficients (γeff) of the MgO protective layers are derived by comparing the breakdown voltage curves obtained from the empirical equation with the experimental data of breakdown voltages. In comparison with the results calculated by the Paschen law and the equation which ignore the influence of the Penning ionization on α , the results calculated by the empirical equation have better conformity with experimental data. The empirical equation characterizes the breakdown of the Penning gas mixture in PDP effectively, and gives a convenient way to study its breakdown characteristics and the secondary electron emission behaviors.
基金Project Supported by the National Natural Science Foundation of China(No.:50777041)
文摘Perfluorocyclobutane(c-C4F8) has been recently considered as a potential alternative to SF6,because of its high electro-negativity and extremely low environmental effect.However,due to its high boiling point,c-C4F8 should mixed with buffer gases such as N2 or CO2 in order to avoid the liquefaction at low temperature.This paper investigates insulating properties of c-C4F8/N2 gas mixtures from two aspects including electrical strength,and Global Warming Potential(GWP).Moreover,improved electrical breakdown model of gas mixtures is founded.Breakdown temperature and breakdown electrical field in gas mixtures can be obtained from rigorous Townsend criterion expression according to gas mixtures ratio and cross section data of gas mixtures in this model.Under the condition of different gas pressure(0.1~0.4 MPa),gas mixtures ratio(0~30%),and electrode gap(2~10 mm),breakdown voltages of gas mixtures are calculated by using of this model.Insulation strength of SF6/N2 mixed gas is compared with c-C4F8/N2 mixed gas in the same conditions.Research results show that theoretical computation corresponds with experiment.If the content of c-C4F8 or SF6 in mixtures is less than 30%,insulation strength between c-C4F8/N2 and SF6/N2 is very close.Considering two indexes(breakdown voltage,GWP),it is suitable for c-C4F8 content being 15%~20% in c-C4F8/N2 gas
基金This work is supported by Jiangsu Suzhou Purification Group Co.Ltd.
文摘For dielectric barrier discharge lamps filled with various gas mixture ratios, the correlations between the excimer XeCl* emission and the sealed gas temperature have been founded, and a qualitative explication is presented. For gas mixture with chlorine larger than 3%, the emission intensity increases with the sealed gas temperature, while with chlorine about 2%, the emission intensity decreases with the increase in the gas temperature, and could be improved by cooling water. However, if chlorine is less than 1.5%, the discharge appears to be a mixture mode with filaments distributed in a diffused glow-like discharge, and the UV emission is independent on the gas temperature.
文摘An array composed of sixteen gas sensors was constructed to analyze gas mixtures quantitatively. The data of responses from the sensor array to ethane, propane and propylene were treated by three-layer ANN with BP algorithms and PLS. The analytical results indicated that the concentration predicted with ANN is better than that with PLS. The average prediction errors for ethane, propane and propylene were 5.11%, 8.28%, 2.64%, respectively.
基金the National Natural Science Foundation of China(No.62075045)。
文摘The dynamics of negative surface discharges in c-C_(4)F_(8)/CF_(3)I/CO_(2) gas mixture is investigated here with a 2D fuid model.The distributions of ion concentration,electric field strength and photon flux during the propagation of the streamer are obtained by solving the drift-diffusion equations of particles and Poisson's equation,and the photon flux variation function during the propagation is also fitted.It is found that the streamer branches occur when the streamer transitions from the upper surface of the insulator to the side surface,and then when the streamer approaches the plane electrode,the photon flux will increase significantly.On this basis,the positive and negative surface discharge models are compared in terms of streamer characteristics,particle characteristics and streamer branches.It is found that the streamer has a higher electron concentration and electric field in the positive model.The streamer develops“floating”in the positive surface discharge,while it is close to the surface of the insulator in the negative model.In addition,the negative streamer branch has a wider width and develops further.
基金Supported by National Natural Science Foundation of China(10675116)Major State Basic Research Development Programme of China(2011CB808301)
文摘In PASER (particle acceleration by stimulated emission of radiation), in the presence of an active medium incorporated in a Penning trap, moving electrons can become bunched, and as they get enough energy, they escape the trap forming an optical injector. These bunched electrons can enter the next PASER section filled with the same active medium to be accelerated. In this paper, electron dynamics in the presence of a gas mixture active medium incorporated in a Penning trap is analyzed by developing an idealized 1D model. We evaluate the energy exchange occurring as the train of electrons traverses into the next PASER section. The results show that the oscillating electrons can be bunched at the resonant frequency of the active medium. The influence of the trapped time and population inversion are analyzed, showing that the longer the electrons are trapped, the more energy from the medium the accelerated electrons get, and with the increase of population inversion, the decelerated electrons are virtually unchanged but the accelerated electrons more than double their peak energy values. The simulation results show that the gas active medium needs a lower population inversion to bunch the electrons compared to a solid active medium, so the experimental conditions can easily be achieved.
基金This work was supported by a grant from the National Natural Science Foundation of China(No.51676133)。
文摘As group contribution method is easy to apply and has a wide application range,current study has developed this model to predict flammability limit of hydrocarbons mixed with inert gas using the Marrero/Gani group contribution method,which is significative to the safe application of hydrocarbons in the ORC system.The whole modeling process is divided into two parts:pure compound prediction and mixture prediction.The contribution factors of inert gases and dilute concentration were first introduced in the group contribution method.Moreover,the respective 95%-confidence interval of the mixture based on linear superposition method has been proposed in the developed group contribution model to improve the safety coefficient.For CO2 as inert gas,the average relative error and correlation coefficient are 5.34%and 0.88 for lower flammability limit while 6.99%and 0.95 for upper flammability limit.For N2 as inert gas,the average relative error and correlation coefficient are 7.47%and 0.84 for lower flammability limit while 6.68%and 0.97 for upper flammability limit.Most importantly,this group contribution method has extended the application range to make up the shortcomings of other flammability limit prediction methods aiming at hydrocarbon and inert gas mixtures and proposed the uncertainty analysis to provide reliable prediction range.
基金the science and technology innovation Project of Institute of High Energy Physics,Chinese Academy of Sciences(2017IHEPZZBS116).
文摘RGAs are widely used in molec Background RGAs are widely used in molecular component examination,impurity analysis,leak detection and test of vacuum system performance.However,RGAs have different sensitivities to different gases,and the sensitivities can change quickly and depend on so many parameters,which make its ability severely limited.Methods In thiswork we established a newpractical method to precisely measure noble gas ratio of argon-xenon gasmixture.Gaseous argon and xenon were controlled,respectively,by two mass flow controller(MFC).A variable leak valve(VLV)was used to introduce the gas mixture sample into the RGA measurement chamber.Gas mixtures with xenon concentration from 200ppm to 20000ppm(by mass)were introduced and tested by RGA.Results The time stability of RGA-measurement system was optimized to 2.1%.A good linearity of MFC-RGA response was achieved,verifying the reliability of RGA in measuring noble gas mixture with component concentration down to several hundred ppm level.Conclusions Since the approach we used in our experiment is gas-species independent,we believe that it can be popularized to other gas species when properly applied.
基金supported by the National Natural Science Foundation of China (51505093, 51605113)the Young Talents Project of Education Department of Guizhou Province (KY[2016]116)+1 种基金the Science and Technology Project of Guizhou Province ([2016]1035)the Science and Technology Innovation Project for Overseas Scholars of Guizhou Province
文摘Lubricant transfer and distribution at the head/disk interface in air-helium gas mixtures is investigated using a developed model that combines an air-bearing model with a molecular dynamics model. The pressure distribution is calculated by the air-bearing model at the head/disk interface with respect to the helium content and the pressure obtained is then input to the molecular dynamics model to understand the lubricant transfer mechanism. Finally, the effects of pressure at the boundary condition and disk velocity on lubricant transfer are discussed in relation to the helium fraction within the air-helium gas mixtures. Results show there is a decrease in the pressure difference with an increase in the helium percentage, which leads to a decrease in the volume of the lubricant transferred. The results also suggest that the lubricant is not easily to transfer in gas mixtures with a high percentage of helium, even when both higher disk velocities and pressure boundary conditions are applied.
基金supported by National Numerical Windtunnel project and National Science Foundation of China 11772281,91852114.
文摘In this paper,we extend the unified gas-kinetic wave-particle(UGKWP)methods to the multi-species gas mixture and multiscale plasma transport.The construction of the scheme is based on the direct modeling on the mesh size and time step scales,and the local cell’s Knudsen number determines the flow physics.The proposed scheme has the multiscale and asymptotic complexity diminishing properties.The multiscale property means that according to the cell’s Knudsen number the scheme can capture the non-equilibrium flow physics when the cell size is on the kinetic mean free path scale,and preserve the asymptotic Euler,Navier-Stokes,and magnetohydrodynamics(MHD)when the cell size is on the hydrodynamic scale and is much larger than the particle mean free path.The asymptotic complexity diminishing property means that the total degrees of freedom of the scheme reduce automatically with the decreasing of the cell’s Knudsen number.In the continuum regime,the scheme automatically degenerates from a kinetic solver to a hydrodynamic solver.In the UGKWP,the evolution of microscopic velocity distribution is coupled with the evolution of macroscopic variables,and the particle evolution as well as the macroscopic fluxes is modeled from a time accumulating solution of kinetic scale particle transport and collision up to a time step scale.For plasma transport,the current scheme provides a smooth transition from particle-in-cell(PIC)method in the rarefied regime to the magnetohydrodynamic solver in the continuum regime.In the continuum limit,the cell size and time step of the UGKWP method are not restricted by the particle mean free path and mean collision time.In the highly magnetized regime,the cell size and time step are not restricted by the Debye length and plasma cyclotron period.The multiscale and asymptotic complexity diminishing properties of the scheme are verified by numerical tests in multiple flow regimes.
文摘A new approach to simulation of stationary flows by Direct Simulation Monte Carlo method is proposed.The idea is to specify an individual time step for each component of a gas mixture.The approach consists of modifications mainly to collision phase simulation and recommendations on choosing time step ratios.It allows lowering the demands on the computational resources for cases of disparate collision diameters of molecules and/or disparate molecular masses.These are cases important e.g.,in vacuum deposition technologies.Few tests of the new approach are made.Finally,the usage of new approach is demonstrated on a problem of silver nanocluster diffusion in argon carrier gas under conditions of silver deposition experiments.
基金supported by the National Natural Science Foundation of China(No.21136007 and 51302184)
文摘In this paper we used MOF-5 and Cu3(BTC)2 to separate CO2/CH4 and CI-I4/N2 mixtures under dynamic conditions. Both materials were synthesized and pelletized, thus allowing for a meaningful characterization in view of process scale-up. The materials were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). By performing breakthrough experiments, we found that Cu3(BTC)2 separated CO2/CH4 slightly better than MOF-5. Because the crystal structure of Cu3 (BTC)2 includes unsaturated accessible metal sites formed via dehydration, it predominantly interacted with CO2 molecules and more easily captured them. Conversely, MOF-5 with a suitable pore size separated CH4/N2 more efficiently in our breakthrough test.
基金supported by National Natural Science Foundation of China(No.10875093)
文摘We calculated the uniform dielectric breakdown field strength of residual 30% CF3I/CO2 gas mixtures during the arc extinction process over the temperature range 300-3500 K at 0.1 MPa. The limiting reduced field strengths are decided by a balance of electron generation and loss based on chemical reactions estimated by the electron energy distribution function (EEDF), which employs the Boltzmann equation method with two-term expanding approximation in the steady-state Townsend (SST) condition. During the insulation recovery phase, the hot CF3I/CO2 gas mixtures have maximum dielectric strength at a temperature of about 1500 K. At room temperature 300 K, the electric strength after arc extinction (90.3 Td, 1 Td=10-21 V.m2) is only 38% of the original value before arc (234.9 Td). The adverse insulation recovery ability of CF3I/CO2 gas mixtures in arc extinction hinders its application in electric circuit breakers and other switchgears as an arc quenching and insulating medium.
基金supported by Natural Science Foundation of Shannxi Province (No.2004F16)the On-the-job Doctoral Foundation of Xi'an Jiaotong University (for the year 2004)
文摘The effects of the Xe gas content and total gas pressure on the discharge characteristics of colour plasma display panels including the sustaining voltage margin, white-field chromaticity, discharge time lag (DTL), discharge current peak, and full-width-at-half-maximum (FWHM) of the discharge current pulse, are experimentally studied. The results indicate that as the Xe gas content in the He-Ne-Xe gas mixture or total pressure increases, the sustaining voltage margin increases, the white-field chromaticity improves, and the discharge current peak has a maximum value, while DTL and FWHM have a minimum value. The mean electron energy in the gas mixture discharge is also calculated through a numerical solution of Boltzmann equation. The experimental results are explained from a view of the mean electron energy variations with the Xe gas content and total gas pressure.