Quantitative Gas-in-place Comparison of Original and Bitumen-free Lacustrine Shale

Residual bitumen in organic-rich shale of oil windows exists widely, and its effect on the gas storage capacity of shale could be two-fold. Bitumen could occupy and block the nanopores of shale, thereby reducing the gas storage capacity. On the other hand, gas could be dissolved in bitumen in shale gas reservoirs, leading to enhanced gas storage capacity. To quantify the effect of bitumen on the gas-in-place(GIP) estimation of lacustrine organic-rich shale, the micropore characteristics and methane sorption capacity of original and bitumen-free shale from the Triassic Yangchang Formation of the Ordos Basin, combined with the methane dissolution capacity for the isolated bitumen, were analyzed and compared. GIP for the original and bitumen-free shale in the depth range of 500–2500 m was evaluated. The results show that micropores in the shale samples were mainly related to organic matter. Clay mineral-hosted pores contributed slightly to microporosity. Bitumen significantly reduced the micropore surface area and volume of the original shale, with average percentages of 28.09% and 51.26%, respectively. The methane sorption capacity decreased after bitumen removal. When normalized to the original shale mass, the sum of the methane sorption capacity for bitumen-free shale and the methane dissolution capacity for isolated bitumen was similar to the methane sorption capacity of the original shale, indicating that the lack of methane absorbed on bitumen is the main reason for the decrease in methane sorption capacity after bitumen removal. The contribution of absorbed methane on bitumen to sorbed methane in shale could be higher than 36.23%. Dual effects of bitumen on shale GIP were observed. A high content of bitumen(1.12%) increased the GIP of the shale samples, with an average percentage of 23.5% in the depth range of 500–2500 m, while a low content of bitumen(0.06%) decreased the GIP, with an average percentage of 13.6%.

Main controlling factor and mechanism of gas-in-place content of the Lower Cambrian shale from different sedimentary facies in the western Hubei area, South China

The Lower Cambrian shale gas in the western Hubei area,South China has a great resource prospect,but the gas-in-place(GIP)content in different sedimentary facies varies widely,and the relevant mechanism has been not well understood.In the present study,two sets of the Lower Cambrian shale samples from the Wells YD4 and YD5 in the western Hubei area,representing the deep-water shelf facies and shallowwater platform facies,respectively,were investigated on the differences of pore types,pore structure and methane adsorption capacity between them,and the main controlling factor and mechanism of their methane adsorption capacities and GIP contents were discussed.The results show that the organic matter(OM)pores in the YD4 shale samples are dominant,while the inorganic mineral(IM)pores in the YD5 shale samples are primary,with underdeveloped OM pores.The pore specific surface area(SSA)and pore volume(PV)of the YD4 shale samples are mainly from micropores and mesopores,respectively,while those of the YD5 shale samples are mainly from micropores and macropores,respectively.The methane adsorption capacity of the YD4 shale samples is significantly higher than that of the YD5 shale samples,with a maximum absolute adsorption capacity of 3.13 cm^(3)/g and 1.31 cm^(3)/g in average,respectively.Compared with the shallow-water platform shale,the deep-water shelf shale has a higher TOC content,a better kerogen type and more developed OM pores,which is the main mechanism for its higher adsorption capacity.The GIP content models based on two samples with a similar TOC content selected respectively from the Wells YD4 and YD5 further indicate that the GIP content of the deep-water shelf shale is mainly 34 m^(3)/t within a depth range of 1000—4000 m,with shale gas exploration and development potential,while the shallow-water platform shale has normally a GIP content of<1 m^(3)/t,with little shale gas potential.Considering the geological and geochemical conditions of shale gas formation and preservation,the deep-water shelf facies is the most favorable target for the Lower Cambrian shale gas exploration and development in the western Hubei area,South China.