A new Gd（Ⅱ） complex [Gd2（μ-phth）3（b-pd）（H2O）5], （phth = o-phthalato, b-pd = N,Nbipyridine） has been ＇synthesized by the reaction of GdO2 with o-phthalate, H2O and 2,2＇-bipyridine. The crystal structure h...A new Gd（Ⅱ） complex [Gd2（μ-phth）3（b-pd）（H2O）5], （phth = o-phthalato, b-pd = N,Nbipyridine） has been ＇synthesized by the reaction of GdO2 with o-phthalate, H2O and 2,2＇-bipyridine. The crystal structure has been determined by single-crystal X-ray diffraction. The crystal is of triclinic, space group P1^- with a = 11.82920（10）, b = 13.53550（10）, c = 13.7381（2）A^°, α= 88.99,β= 66.9120（10）, γ = 66.2370（10）°, V = 1826.02（3） ,A^°3, Dc= 1.915 g/cm^3, C34H30N2O17Gd2, Mr= 1053.10, F（000） = 1024,μ = 3.680 mm^-1, Z = 2, R = 0.0612 and wR = 0.1320 for 6259 observed reflections （I〉 2σ（I））. In the title complex, the Gd（Ⅱ） ions are bridged by o-phthalate ligands in a bidentate mode, producing a 1D infinite chain structure. Each eight-coordinated Gd（Ⅱ） center is coordinated by eight oxygen atoms from phth to give a distorted dodecahedral geometry, and each nine-coordinated Gd（Ⅱ） center is coordinated by two N atoms from b-pd and seven oxygen atoms from phth to give a distorted geometry of capped square antiprism. The chains are linked by π-π interactions and hydrogen bonds between oxygen atoms of carboxylate groups and H2O molecules and hydrogen atoms of H2O, b-pd and o-phth molecules, forming an unusual three-dimensional coordination polymer.展开更多
基金This work was supported by National Natural Science Foundation of China (20472085)
文摘A new Gd（Ⅱ） complex [Gd2（μ-phth）3（b-pd）（H2O）5], （phth = o-phthalato, b-pd = N,Nbipyridine） has been ＇synthesized by the reaction of GdO2 with o-phthalate, H2O and 2,2＇-bipyridine. The crystal structure has been determined by single-crystal X-ray diffraction. The crystal is of triclinic, space group P1^- with a = 11.82920（10）, b = 13.53550（10）, c = 13.7381（2）A^°, α= 88.99,β= 66.9120（10）, γ = 66.2370（10）°, V = 1826.02（3） ,A^°3, Dc= 1.915 g/cm^3, C34H30N2O17Gd2, Mr= 1053.10, F（000） = 1024,μ = 3.680 mm^-1, Z = 2, R = 0.0612 and wR = 0.1320 for 6259 observed reflections （I〉 2σ（I））. In the title complex, the Gd（Ⅱ） ions are bridged by o-phthalate ligands in a bidentate mode, producing a 1D infinite chain structure. Each eight-coordinated Gd（Ⅱ） center is coordinated by eight oxygen atoms from phth to give a distorted dodecahedral geometry, and each nine-coordinated Gd（Ⅱ） center is coordinated by two N atoms from b-pd and seven oxygen atoms from phth to give a distorted geometry of capped square antiprism. The chains are linked by π-π interactions and hydrogen bonds between oxygen atoms of carboxylate groups and H2O molecules and hydrogen atoms of H2O, b-pd and o-phth molecules, forming an unusual three-dimensional coordination polymer.
