GdOHCO3 rhombic microcrystals were synthesized by hydrothermal method with urea used as the preci- pitator. Experimental parameters, such as the molar ratio of the starting reagents, reaction temperature and reaction ...GdOHCO3 rhombic microcrystals were synthesized by hydrothermal method with urea used as the preci- pitator. Experimental parameters, such as the molar ratio of the starting reagents, reaction temperature and reaction time were examined. The as-obtained product was characterized by powder X-ray diffraction（XRD）, field-emission scanning electron microscopy（FESEM）, X-ray photoelectron spectroscopy（XPS）, Fourier transform infrared spec- troscopy（FTIR） and spectrofluorometry. The main reactions to form GdOHCO3 were proposed. In addition, the pho- toluminescence（PL） properties of GdOHCO3 rhombic microcrystals were discussed. The broad band located between 350 nm and 600 nm in the emission spectrum can be attributed to the self-trapped exciton luminescence.展开更多
文摘GdOHCO3 rhombic microcrystals were synthesized by hydrothermal method with urea used as the preci- pitator. Experimental parameters, such as the molar ratio of the starting reagents, reaction temperature and reaction time were examined. The as-obtained product was characterized by powder X-ray diffraction（XRD）, field-emission scanning electron microscopy（FESEM）, X-ray photoelectron spectroscopy（XPS）, Fourier transform infrared spec- troscopy（FTIR） and spectrofluorometry. The main reactions to form GdOHCO3 were proposed. In addition, the pho- toluminescence（PL） properties of GdOHCO3 rhombic microcrystals were discussed. The broad band located between 350 nm and 600 nm in the emission spectrum can be attributed to the self-trapped exciton luminescence.
