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Magnetic and luminescent properties of bifunctional composite Fe_(3)O_(4)@Y_(2)O_(2)S:Eu^(3+)
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作者 Zhiqi Liang Zhili Zhang +2 位作者 Liu Li Wen Xu Decai Li 《Journal of Rare Earths》 SCIE EI CAS CSCD 2024年第8期1568-1576,I0006,共10页
As a kind of non-destructive testing method,magnetic particle inspection is widely used in the fields of aviation and high-speed rail.The properties of magnetic fluorescent bifunctional composites,such as fluorescence... As a kind of non-destructive testing method,magnetic particle inspection is widely used in the fields of aviation and high-speed rail.The properties of magnetic fluorescent bifunctional composites,such as fluorescence intensity and magnetic properties,have increasing demands in magnetic particle inspection.Rare earth compounds offer potential as novel materials for fluorescent magnetic bifunctional composites due to their excellent optical properties and extremely narrow emission spectra.In this work,the rare earth fluorescent material Y_(2)O_(2)S:Eu^(3+) was synthesized by solid-state reaction method.Fe_(3)O_(4)nanoparticles prepared by hydrothermal method were uniformly coated on the Y_(2)O_(2)S:Eu^(3+) particles through physical adsorption of surfactants.The obtained Fe_(3)O_(4)@Y_(2)O_(2)S:Eu^(3+) exhibits dark red color under the ultraviolet light.In additio n,X-ray diffractio n,morphology,photoluminescence and hyste resis loop of Fe_(3)O_(4)@Y_(2)O_(2)S:Cu^(3+) were investigated.The luminescence mechanism of Y_(2)O_(2)S:Eu^(3+) is described in detail Fe_(3)O_(4)@Y_(2)O_(2)S:Cu^(3+) displays good paramagnetism and has a good controllability under a magnetic field.The magnetic particle inspection of Fe_(3)O_(4)@Y_(2)O_(2)S:Eu^(3+) was performed using a 4-pole electromagnet and a test piece shim.The magnetic fluorescent bifunctional composite presented in this work can be applied for non-destructive testing. 展开更多
关键词 Bifunctional material Fe_(3)o_(4) Y_(2)o_(2)S:Eu^(3+) luminescence solid-state reaction Rare earths
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微波辐射法合成Gd_(2)O_(2)SO_(4)∶Eu^(3+)发光材料及性能研究
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作者 文小强 王玉香 赖华生 《稀土》 EI CAS CSCD 北大核心 2021年第1期105-110,共6页
以Gd_(2)O_(3)、Eu_(2)O_(3)和NH_(4)HSO_(4)为原料,采用微波辐射法合成了Gd_(2)O_(2)SO_(4)∶Eu^(3+)发光材料。并用X射线衍射仪、扫描电镜、荧光光谱仪对所得发光材料的物相、形貌和发光性能进行了表征。结果表明,微波辐射30 min可以... 以Gd_(2)O_(3)、Eu_(2)O_(3)和NH_(4)HSO_(4)为原料,采用微波辐射法合成了Gd_(2)O_(2)SO_(4)∶Eu^(3+)发光材料。并用X射线衍射仪、扫描电镜、荧光光谱仪对所得发光材料的物相、形貌和发光性能进行了表征。结果表明,微波辐射30 min可以合成纯相Gd_(2)O_(2)SO_(4)∶Eu^(3+)发光材料,晶体结构为正交晶系,与Gd_(2)O_(2)SO_(4)结构相同;其形貌不规则,存在团聚现象;Gd_(2)O_(2)SO_(4)∶Eu^(3+)发光材料呈红光发射,发射光谱由一系列铕离子的^(5)D_(0)→^(7)F_(j)(j=0,1,2,3,4)能级跃迁的尖峰组成,激发光谱主要由处于200 nm~350 nm的宽激发带和位于397 nm和466 nm的窄激发带组成。 展开更多
关键词 微波辐射法 gd_(2)o_(2)so_(4)∶Eu^(3+)发光材料 红光发射
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