The growth process of GeOx films formed by plasma post-oxidation (PPO) at room temperature (RT) is investigated using angle-resolved x-ray photoelectron spectroscopy (AR-XPS). The experimental results show that ...The growth process of GeOx films formed by plasma post-oxidation (PPO) at room temperature (RT) is investigated using angle-resolved x-ray photoelectron spectroscopy (AR-XPS). The experimental results show that the distributions of the Ge4+ states, a mixture of the Ge^2+ and Ge^3+ states, and the Ge^1+ states are localized from the GeOx surface to the GeOx/Ge interface. Moreover, the Ge^1+ states are predominant when the two outermost layers of Ge atoms are oxidized. These findings are helpful for establishing in-depth knowledge of the growth mechanism of the GeOx layer and valuable for the optimization of Ge-based gate stacks for future complementary metal-oxide-semiconductor (MOS) field-effect transistor (CMOSFET) devices.展开更多
基金supported by the National Natural Science Foundation of China(Grant Nos.61574168 and 61504163)
文摘The growth process of GeOx films formed by plasma post-oxidation (PPO) at room temperature (RT) is investigated using angle-resolved x-ray photoelectron spectroscopy (AR-XPS). The experimental results show that the distributions of the Ge4+ states, a mixture of the Ge^2+ and Ge^3+ states, and the Ge^1+ states are localized from the GeOx surface to the GeOx/Ge interface. Moreover, the Ge^1+ states are predominant when the two outermost layers of Ge atoms are oxidized. These findings are helpful for establishing in-depth knowledge of the growth mechanism of the GeOx layer and valuable for the optimization of Ge-based gate stacks for future complementary metal-oxide-semiconductor (MOS) field-effect transistor (CMOSFET) devices.