In this paper a new kind of mid - infrared fiber material is reported. The reflective coefficients (R) of glasses in the system Na2O - ZnO - GeO2-SiO2-PbO have been measured-the refractive index becomes less than unit...In this paper a new kind of mid - infrared fiber material is reported. The reflective coefficients (R) of glasses in the system Na2O - ZnO - GeO2-SiO2-PbO have been measured-the refractive index becomes less than unity at 1180 - 900cm-1 range because of the existence of anomalous dispersion. The optical losses of hollow waveguides were calculated,the predicted losses at 940cm-1are 0. 65 and 0. 081B/ m as the inner diameter of fiber is 0. 5 and 1. 0mm respectively. The glasses can be used as the cladding materials of hol-low waveguides for transmitting CO2 laser from the measurements of characteristic temperatures, coefficient of expansion and chemical durability.展开更多
In this paper,the authors used the Mixed Coordination EXAFS Analysis Method recently published and IR to study the mixed coordination of Ge in glasses of Li_2O-ZnO-GeO_2 system,a new kind of syperionic conductor.The r...In this paper,the authors used the Mixed Coordination EXAFS Analysis Method recently published and IR to study the mixed coordination of Ge in glasses of Li_2O-ZnO-GeO_2 system,a new kind of syperionic conductor.The results show that when the content of ZnO is fixed,the ratio of [GeO_6] units is increased with the addition of Li_2O until the content of Li_2O is about 15%,and then decreased.The relationship between the ratio of [GeO_6]and the content of Li_2O is consistent with those between n,d of glass and Li_2O content, Therefore the germanium abnormalty can be explained as the change of coordination number.展开更多
为了进一步提高Bi_(2)GeO_(5)的催化活性,为炸药废水实际处理提供可借鉴的方法,采用一步溶剂热法,以一定比例的水和二乙醇胺混合物为溶剂,AgNO_(3)为Ag源,用Ag修饰Bi_(2)GeO_(5)纳米粒子,制备Ag修饰的Bi_(2)GeO_(5)光催化剂。利用X射线...为了进一步提高Bi_(2)GeO_(5)的催化活性,为炸药废水实际处理提供可借鉴的方法,采用一步溶剂热法,以一定比例的水和二乙醇胺混合物为溶剂,AgNO_(3)为Ag源,用Ag修饰Bi_(2)GeO_(5)纳米粒子,制备Ag修饰的Bi_(2)GeO_(5)光催化剂。利用X射线衍射仪(XRD)、扫描电子显微镜(SEM)、透射电子显微镜(TEM)、X射线光电子能谱仪(XPS)、N_(2)吸附-脱附和紫外-可见分光光度计(UV-Vis)对所制备的复合光催化剂进行表征,随后通过降解TNT试验测试所制备复合材料的光催化性能,评估了不同配比的Ag修饰对Bi_(2)GeO_(5)光催化剂所制备产物的光催化活性的影响。结果表明,0.1 g Ag修饰的Bi_(2)GeO_(5)光降解TNT的性能要优于其他比例修饰的Bi_(2)GeO_(5),在25 min内光催化降解率达到94%,TNT几乎被完全降解。适量Ag修饰提高了Bi_(2)GeO_(5)光催化剂的电荷分离和转移。展开更多
In the humid oral environment,3Y-TZP ceramics always suffer from low-temperature degradation(LTD)for a long time,which results in the degradation of mechanical properties and catastrophic failure.The low-temperature d...In the humid oral environment,3Y-TZP ceramics always suffer from low-temperature degradation(LTD)for a long time,which results in the degradation of mechanical properties and catastrophic failure.The low-temperature degradation(LTD)and mechanical properties of low-cost tetravalent(Ge^(4+),Ti^(4+))element-doped 3Y-TZP were investigated by analysing grain boundary segregation in samples with deferent contents.The results show that GeO_(2) is superior to TiO_(2) in limiting LTD but results in lower flexural strength and fracture toughness when the content is≥1.5 mol%.This dilemma can be improved by adding only 0.1%-0.5 wt%Al_(2)O_(3),and the flexural strength and fracture toughness of 0.25 wt% Al_(2)O_(3) zirconia are then increased to 898 MPa and 4.68 MPa·m^(1/2) compared with 1Ge-3Y,respectively.This work is expected to provide an effective reference for the development and application of budget dental materials.展开更多
Tetracyclines are refractory pollutants that cause persistent harm to the environment and human health.Therefore,it is urgently necessary to develop methods to promote the efficient degradation and conversion of tetra...Tetracyclines are refractory pollutants that cause persistent harm to the environment and human health.Therefore,it is urgently necessary to develop methods to promote the efficient degradation and conversion of tetracyclines in wastewater.This report proposes a photobiocatalytic synergistic system involving the coupling of GeO_(2)/Zn-doped phosphotungstic acid hydrate/TiO_(2)(GeO_(2)/Zn-HPW/TiO_(2))-loaded photocatalytic optical hollow fibers(POHFs)and an algalebacterial biofilm.The GeO_(2)/Zn-HPW/TiO_(2) photocatalyst exhibits a broad absorption edge extending to 1000 nm,as well as high-efficiency photoelectric conversion and electron transfer,which allow the GeO_(2)/Zn-HPW/TiO_(2)-coated POHFs to provide high light intensity to promote biofilm growth.The resulting high photocatalytic activity rapidly and stably reduces the toxicity and increases the biodegradability of tetracycline-containing wastewater.The biofilm enriched with Salinarimonas,Coelastrella sp.,and Rhizobium,maintains its activity for the rapid photocatalytic degradation and biotransformation of intermediates to generate the O_(2) required for photocatalysis.Overall,the synergistic photocatalytic biofilm system developed herein provides an effective and efficient approach for the rapid degradation and conversion of water containing high concentrations of tetracycline.展开更多
文摘In this paper a new kind of mid - infrared fiber material is reported. The reflective coefficients (R) of glasses in the system Na2O - ZnO - GeO2-SiO2-PbO have been measured-the refractive index becomes less than unity at 1180 - 900cm-1 range because of the existence of anomalous dispersion. The optical losses of hollow waveguides were calculated,the predicted losses at 940cm-1are 0. 65 and 0. 081B/ m as the inner diameter of fiber is 0. 5 and 1. 0mm respectively. The glasses can be used as the cladding materials of hol-low waveguides for transmitting CO2 laser from the measurements of characteristic temperatures, coefficient of expansion and chemical durability.
文摘In this paper,the authors used the Mixed Coordination EXAFS Analysis Method recently published and IR to study the mixed coordination of Ge in glasses of Li_2O-ZnO-GeO_2 system,a new kind of syperionic conductor.The results show that when the content of ZnO is fixed,the ratio of [GeO_6] units is increased with the addition of Li_2O until the content of Li_2O is about 15%,and then decreased.The relationship between the ratio of [GeO_6]and the content of Li_2O is consistent with those between n,d of glass and Li_2O content, Therefore the germanium abnormalty can be explained as the change of coordination number.
文摘为了进一步提高Bi_(2)GeO_(5)的催化活性,为炸药废水实际处理提供可借鉴的方法,采用一步溶剂热法,以一定比例的水和二乙醇胺混合物为溶剂,AgNO_(3)为Ag源,用Ag修饰Bi_(2)GeO_(5)纳米粒子,制备Ag修饰的Bi_(2)GeO_(5)光催化剂。利用X射线衍射仪(XRD)、扫描电子显微镜(SEM)、透射电子显微镜(TEM)、X射线光电子能谱仪(XPS)、N_(2)吸附-脱附和紫外-可见分光光度计(UV-Vis)对所制备的复合光催化剂进行表征,随后通过降解TNT试验测试所制备复合材料的光催化性能,评估了不同配比的Ag修饰对Bi_(2)GeO_(5)光催化剂所制备产物的光催化活性的影响。结果表明,0.1 g Ag修饰的Bi_(2)GeO_(5)光降解TNT的性能要优于其他比例修饰的Bi_(2)GeO_(5),在25 min内光催化降解率达到94%,TNT几乎被完全降解。适量Ag修饰提高了Bi_(2)GeO_(5)光催化剂的电荷分离和转移。
文摘In the humid oral environment,3Y-TZP ceramics always suffer from low-temperature degradation(LTD)for a long time,which results in the degradation of mechanical properties and catastrophic failure.The low-temperature degradation(LTD)and mechanical properties of low-cost tetravalent(Ge^(4+),Ti^(4+))element-doped 3Y-TZP were investigated by analysing grain boundary segregation in samples with deferent contents.The results show that GeO_(2) is superior to TiO_(2) in limiting LTD but results in lower flexural strength and fracture toughness when the content is≥1.5 mol%.This dilemma can be improved by adding only 0.1%-0.5 wt%Al_(2)O_(3),and the flexural strength and fracture toughness of 0.25 wt% Al_(2)O_(3) zirconia are then increased to 898 MPa and 4.68 MPa·m^(1/2) compared with 1Ge-3Y,respectively.This work is expected to provide an effective reference for the development and application of budget dental materials.
基金supported in part by the National Natural Science Foundation of China(NSFC)(52176178,51876018)Innovation Research Group of Universities in Chongqing(CXQT21035)+2 种基金Scientific and Technological Research Programof Chongqing Municipal Education Commission of China(KJZD-M202201101)Chongqing Postgraduate Innovation Project(CYS22318)Chongqing University of Technology Graduate Education High Quality Development Project(gzlcx20222022).
文摘Tetracyclines are refractory pollutants that cause persistent harm to the environment and human health.Therefore,it is urgently necessary to develop methods to promote the efficient degradation and conversion of tetracyclines in wastewater.This report proposes a photobiocatalytic synergistic system involving the coupling of GeO_(2)/Zn-doped phosphotungstic acid hydrate/TiO_(2)(GeO_(2)/Zn-HPW/TiO_(2))-loaded photocatalytic optical hollow fibers(POHFs)and an algalebacterial biofilm.The GeO_(2)/Zn-HPW/TiO_(2) photocatalyst exhibits a broad absorption edge extending to 1000 nm,as well as high-efficiency photoelectric conversion and electron transfer,which allow the GeO_(2)/Zn-HPW/TiO_(2)-coated POHFs to provide high light intensity to promote biofilm growth.The resulting high photocatalytic activity rapidly and stably reduces the toxicity and increases the biodegradability of tetracycline-containing wastewater.The biofilm enriched with Salinarimonas,Coelastrella sp.,and Rhizobium,maintains its activity for the rapid photocatalytic degradation and biotransformation of intermediates to generate the O_(2) required for photocatalysis.Overall,the synergistic photocatalytic biofilm system developed herein provides an effective and efficient approach for the rapid degradation and conversion of water containing high concentrations of tetracycline.
