Geochemistry of Harappan potteries from Kalibangan and sediments in the Ghaggar River： Clues for a dying river

The ephemeral Ghaggar-Hakra River of northwestern India has always been considered to be the remnant of an ancient perennial glacier-fed river（Vedic Saraswati）. The exact reason and timing of major hydrological change of this river remains speculative. The river＇s purported association with the zenith of the Harappan civilisation remains a conjecture because the timings of its fluvial past are still being debated. In this study we have made an attempt to resolve this issue using geochemical provenance of sediments from some dated horizons in the Ghaggar flood plain and that of the material used in the potteries from the Mature Harappan period（4600-3900 yr BP） at Kalibangan. Sampled sedimentary horizons were dated by radiocarbon and optically stimulated luminescence（OSL） methods. Results of our study from the Ghaggar alluvium indicate that the river did have glacial sources during the early Holocene. However, the data from the potteries suggest that during the Mature Harappan period, the sediments in the Ghaggar as used by the potters did not have a higher Himalayan provenance and hence, were not derived from glaciated Himalayas.These findings imply that during the time of the Mature Harappans the Ghaggar had already become a foothill-fed river.

Hydrochemical evolution of groundwater in northwestern part of the Indo-Gangetic Basin,India:A geochemical and isotopic approach

The present study aims to understand the hydrochemical evolution of groundwater in the Ghaggar River Basin,representing a zone of excessive abstraction of groundwater in the northwestern Indo-Gangetic Basin.The study comprises a regional scale and high-resolution sampling of groundwater during preand post-monsoon seasons of 2013 and their analyses for major ions,δ^(18)O,δ^(2)H,and 3 H.Variation in hydrochemical and isotopic data is found both in spatial and vertical scales.The significant vertical variation of TDS,NO_(3)and K^(+)allowed the classification of the aquifer system into two major groups:shallow(depth<80 m bgl)and deep(depth>80 m bgl).The depthwise variations ofδ^(18)O andδ^(2)H support this categorization of the aquifers.The Ca-HCO_(3)and Ca-Mg-Na-HCO_(3)water facies with higher values of 3 H in the proximal part of the basin characterize recharge areas under humid conditions.The dominance of Mg-Na-HCO_(3)and Na-HCO_(3)facies in shallow and deep aquifers in central part of the basin,illustrate the intermediate to advanced stages of hydrochemical evolution in the system.Dominance of brackish Ca-Mg-Cl-SO_(4)and Na-Cl-SO_(4)water types in the discharge areas is due to the prevailing geological conditions and anthropogenic activities.Geochemical modelling supports the reverse cation exchange and mixing during lateral and vertical flows,weathering of silicate minerals,dissolution of crustal salts,and evaporative enrichment are the natural processes governing the evolution of groundwater chemistry along the flowpaths.The developed process-based conceptual model will aid in the formulation of a suitable plan for groundwater resource management in the region.