A Glaser coupling reaction of terminal alkynes in the presence of nickel chloride without any organics and bases in hot water has been developed, which produces the corresponding homo-coupling products in good yields.
A Glaser coupling reaction of terminal alkynes in the presence of cupric chloride without organic solvents and bases under near-critical water has been developed.
文摘A Glaser coupling reaction of terminal alkynes in the presence of nickel chloride without any organics and bases in hot water has been developed, which produces the corresponding homo-coupling products in good yields.
基金Project supported by the National Natural Science Foundation of China (Nos. 2037202420172018)+1 种基金 the Excellent Scientist Foundation of Anhui Province (No. 2001040) the Natural Science Foundation of the Education Department of Anhui Province (No. 2002kj25
文摘A Glaser coupling reaction of terminal alkynes in the presence of cupric chloride without organic solvents and bases under near-critical water has been developed.
