Suites of granitic and metamorphic rocks form a perfect geological environment in which to investigate the source of metals related to gold deposits.In the East Province of Cameroon,the source of metals-related gold(g...Suites of granitic and metamorphic rocks form a perfect geological environment in which to investigate the source of metals related to gold deposits.In the East Province of Cameroon,the source of metals-related gold(grade~4.6 g/t)that occurs within metamorphic and granitic rocks remains ambiguous.The host rocks were subjected to XRF and ICP-MS whole-rock geochemistry and BSE/EDS mineral analyses to investigate the source(s)of metals related to gold in the Province.Petrographically,chalcopyrite-pyrite and magnetite-ilmenite are the main sulfi des and oxides of granites,respectively.The low-grade metamorphic rocks are sulfi de-rich consisting of arsenopyrite,chalcopyrite,pyrite,and sphalerite,and oxides include magnetite,ilmenite,hematite,and rutile.Cu,Ni,Co,Sb,Sc,and Zn concentrations depleted in high-grade metamorphic rocks and granites compared to low-grade metamorphic rocks.As well,Bi,Cd,Co,Cu,Ni,Sb,V,W,and Zn concentrations decrease with increasing temperatures from low-grade rocks to high-grade rocks and granites.The suite of depleted elements in high-grade rocks and granites is almost identical to those enriched in gold occurrences.We conclude that metals(Bi,Cd,Co,Cu,Ni,Sb,and Zn)related to gold mineralization in the East Province of Cameroon likely originated from metal-rich low-grade metamorphic rocks during prograde metamorphic processes prior to partial melting.展开更多
Wulonggou deposit is a large tectonoalteration gold deposit which is discovered in 1980s in East Kunlun area of Qinghai Province. The ore bodies occur in the rock series of metamorphic basement of Lower Proterozoic an...Wulonggou deposit is a large tectonoalteration gold deposit which is discovered in 1980s in East Kunlun area of Qinghai Province. The ore bodies occur in the rock series of metamorphic basement of Lower Proterozoic and granitoid Variscan to Lower Mesozoic. The shape, attitude and scale of the ore bodies are strictly controlled by the tectonoalteration belts, which show a typical characteristic of tectonoalteration deposits. A detailed discussion on typical deposits could also contribute to the evaluation of the regional gold metallogenic potential in East Kunlun area, and provide a direction for further gold prospecting between and/or near Kunzhong and Kunnan faults, and in areas of granitoid distribution of Variscan and Lower Mesozoic.展开更多
Proton-exchange membrane water electrolysis(PEM WE)is a particularly promising technology for renewable hydrogen produc-tion.However,the excessive passivation of the gas diffusion layer(GDL)will seriously affect the h...Proton-exchange membrane water electrolysis(PEM WE)is a particularly promising technology for renewable hydrogen produc-tion.However,the excessive passivation of the gas diffusion layer(GDL)will seriously affect the high surface-contact resistance and result in energy losses.Thus,a mechanism for improving the conductivity and interface stability of the GDL is an urgent issue.In this work,we have prepared a hydrophilic and corrosion resistant conductive composite protective coating.The polydopamine(PDA)film on the Ti surface,which was obtained via the solution oxidation method,ensured that neither micropores nor pinholes existed in the final hybrid coatings.In-situ reduced gold nanoparticles(AuNPs)improved the conductivity to achieve the desired interfacial contact resistance and further enhanced the corrosion resistance.The surface composition of the treated samples was investigated using scanning electron microscopy(SEM),transmis-sion electron microscopy(TEM),X-ray diffraction(XRD),and Fourier transform infrared spectroscopy(FTIR).The results indicated that the optimized reaction conditions included a pH value of 3 of HAuCl_(4) solution with PDA deposition(48 h)on papers and revealed the lowest con-tact resistance(0.5 mΩ·cm^(2))and corrosion resistance(0.001μA·cm^(−2))in a 0.5 M H_(2)SO_(4)+2 ppm F−solution(1.7 V vs.RHE)among all the modified specimens,where RHE represents reversible hydrogen electrode.These findings indicated that the Au-PDA coating is very appropriate for the modification of Ti GDLs in PEM WE systems.展开更多
The system of mineral deposit statistical prediction methods , based on the similarity - analogy theory , searching anomaly theory and the theory of ore - controlling by quantitative assemblage of metallotects , can b...The system of mineral deposit statistical prediction methods , based on the similarity - analogy theory , searching anomaly theory and the theory of ore - controlling by quantitative assemblage of metallotects , can be summarized into the following aspects : (1) concluding main ore - controlling conditions and ore - hunting indicators from typical deposits; (2)establishing geological concept model of deposits ; (3)selecting geological variable and dividing study units and granting specific value for each variable; (4) by the use of geological and mathematical geology method , building predication model , delineating prospective area for exploration and estimating the total resources; (5) evaluating the prospecting work . It is good practice to use this system for metallogenic prognosis and regional prospecting of gold deposit in East Junggar , Xinjiang and has achieved great success . As a result , we discovered the Kubusu gold mineralized belt . delineated prospective area - estimated total resources of gold in the belt and found out Kubusu gold deposit .展开更多
To assess the water quality in the locality of Bétaré-Oya affected by an intensive artisanal and semi mechanized mining activities, 71 samples were collected from sixteen points during the 2015-2016 hydrolog...To assess the water quality in the locality of Bétaré-Oya affected by an intensive artisanal and semi mechanized mining activities, 71 samples were collected from sixteen points during the 2015-2016 hydrological year. These points include: three in Lom river which is the main stream of the study area, five in Mari river which is one of the left bank tributaries of the Lom, in Bétaré-Oya and eight in the left and the right bank of Mari. Different physicochemical parameters such as pH, electrical conductivity (EC), alkalinity, turbidity, total suspended solids (TSS), cyanide (CN-), major elements and heavy metals (Pb, Zn, Cd, Fe, Cu, As, Mn and Cr) were analyzed. Water Quality Indices (WQI), Heavy metal Pollution Index (HPI), sodium adsorption ratio (SAR) and percent sodium (Na%) were also computed to evaluate the suitability of water for drinking and irrigation. The results showed that the surface water from Bétaré-Oya was acidic to basic (5.40 < pH < 8.84), weakly mineralized (11.60 < EC < 122.10 μS/cm) with a high concentration of TSS (2 < TSS < 8996.00 mg/L) and turbidity (1.22 to 4758.00 NTU). The WQI scores show excellently to unsuitable quality in almost all the sampling sites. The water quality is found to be most deteriorated in Lom river and in the downstream of Mari river where an extensive mining activity is carried out, with the high WQI value of 5137.40. Based on heavy metal pollution index, the mean value was 1195.36 and thus under the critical pollution index. We thus notice a serious physical degradation by organic and mineral suspended particles as well as chemical degradation by heavy metals. This results from mining activities in the Lom river and its main tributaries such as the Mari river in the upstream part of the Sanaga basin. According to the percentage of sodium and SAR, these waters can be used for irrigation purposes in almost all types of soils.展开更多
The territory of the Balkan Peninsula in SE Europe is reviewed, from the point of gemmology, as the cradle of gem and decorative minerals and metals in European prehistory. During the local Neolithic period (end of 7 ...The territory of the Balkan Peninsula in SE Europe is reviewed, from the point of gemmology, as the cradle of gem and decorative minerals and metals in European prehistory. During the local Neolithic period (end of 7 th -6 th millennium BC), as material for tools or for beads, nephrite (with the earliest known Balkan nephrite culture), jadeite-omphacite and quartz (different varieties) were introduced to make pendants and idols. Large quantities of copper and gold artifacts are known since the Chalcolithic period (5 th millennium BC)(unique for the region;the largest in number of gold artifacts is the Varna I Chalcolithic necropolis in Bulgaria). The gemmological materials in the Balkans are known for malachite, antigorite serpentinite, turquoise, rock crystal, carnelian, jasper, jet and obsidian. In the Varna I necropolis (mid 5 th millennium BC) are recorded the first known complex faceted carnelian beads with 32 facets, as well as some of the most important gemmological techniques and procedures such as faceting, tumbling, annealing, miniaturization and standardization. As pigments for pottery, cinnabar, graphite and gold were used in different prehistoric sites. The earliest salt production in the Balkans is known from sites in Romania and Bulgaria, and because of its trade, salt is positively linked to a population rich with prestigious goods. The introduced possible Chalcolithic weight unit “van”(2 carats) is supposed to be the earliest known in prehistoric times.展开更多
基金funded by the Ministry of Science and Technology of the People’s Republic of China(State Key Research Plan,No.2017YFC0601302).
文摘Suites of granitic and metamorphic rocks form a perfect geological environment in which to investigate the source of metals related to gold deposits.In the East Province of Cameroon,the source of metals-related gold(grade~4.6 g/t)that occurs within metamorphic and granitic rocks remains ambiguous.The host rocks were subjected to XRF and ICP-MS whole-rock geochemistry and BSE/EDS mineral analyses to investigate the source(s)of metals related to gold in the Province.Petrographically,chalcopyrite-pyrite and magnetite-ilmenite are the main sulfi des and oxides of granites,respectively.The low-grade metamorphic rocks are sulfi de-rich consisting of arsenopyrite,chalcopyrite,pyrite,and sphalerite,and oxides include magnetite,ilmenite,hematite,and rutile.Cu,Ni,Co,Sb,Sc,and Zn concentrations depleted in high-grade metamorphic rocks and granites compared to low-grade metamorphic rocks.As well,Bi,Cd,Co,Cu,Ni,Sb,V,W,and Zn concentrations decrease with increasing temperatures from low-grade rocks to high-grade rocks and granites.The suite of depleted elements in high-grade rocks and granites is almost identical to those enriched in gold occurrences.We conclude that metals(Bi,Cd,Co,Cu,Ni,Sb,and Zn)related to gold mineralization in the East Province of Cameroon likely originated from metal-rich low-grade metamorphic rocks during prograde metamorphic processes prior to partial melting.
文摘Wulonggou deposit is a large tectonoalteration gold deposit which is discovered in 1980s in East Kunlun area of Qinghai Province. The ore bodies occur in the rock series of metamorphic basement of Lower Proterozoic and granitoid Variscan to Lower Mesozoic. The shape, attitude and scale of the ore bodies are strictly controlled by the tectonoalteration belts, which show a typical characteristic of tectonoalteration deposits. A detailed discussion on typical deposits could also contribute to the evaluation of the regional gold metallogenic potential in East Kunlun area, and provide a direction for further gold prospecting between and/or near Kunzhong and Kunnan faults, and in areas of granitoid distribution of Variscan and Lower Mesozoic.
基金supported by the National Key Research and Development Program of China(No.2018 YFB1502403)。
文摘Proton-exchange membrane water electrolysis(PEM WE)is a particularly promising technology for renewable hydrogen produc-tion.However,the excessive passivation of the gas diffusion layer(GDL)will seriously affect the high surface-contact resistance and result in energy losses.Thus,a mechanism for improving the conductivity and interface stability of the GDL is an urgent issue.In this work,we have prepared a hydrophilic and corrosion resistant conductive composite protective coating.The polydopamine(PDA)film on the Ti surface,which was obtained via the solution oxidation method,ensured that neither micropores nor pinholes existed in the final hybrid coatings.In-situ reduced gold nanoparticles(AuNPs)improved the conductivity to achieve the desired interfacial contact resistance and further enhanced the corrosion resistance.The surface composition of the treated samples was investigated using scanning electron microscopy(SEM),transmis-sion electron microscopy(TEM),X-ray diffraction(XRD),and Fourier transform infrared spectroscopy(FTIR).The results indicated that the optimized reaction conditions included a pH value of 3 of HAuCl_(4) solution with PDA deposition(48 h)on papers and revealed the lowest con-tact resistance(0.5 mΩ·cm^(2))and corrosion resistance(0.001μA·cm^(−2))in a 0.5 M H_(2)SO_(4)+2 ppm F−solution(1.7 V vs.RHE)among all the modified specimens,where RHE represents reversible hydrogen electrode.These findings indicated that the Au-PDA coating is very appropriate for the modification of Ti GDLs in PEM WE systems.
基金The study is supported by the key project of the State Education Committee of China
文摘The system of mineral deposit statistical prediction methods , based on the similarity - analogy theory , searching anomaly theory and the theory of ore - controlling by quantitative assemblage of metallotects , can be summarized into the following aspects : (1) concluding main ore - controlling conditions and ore - hunting indicators from typical deposits; (2)establishing geological concept model of deposits ; (3)selecting geological variable and dividing study units and granting specific value for each variable; (4) by the use of geological and mathematical geology method , building predication model , delineating prospective area for exploration and estimating the total resources; (5) evaluating the prospecting work . It is good practice to use this system for metallogenic prognosis and regional prospecting of gold deposit in East Junggar , Xinjiang and has achieved great success . As a result , we discovered the Kubusu gold mineralized belt . delineated prospective area - estimated total resources of gold in the belt and found out Kubusu gold deposit .
文摘To assess the water quality in the locality of Bétaré-Oya affected by an intensive artisanal and semi mechanized mining activities, 71 samples were collected from sixteen points during the 2015-2016 hydrological year. These points include: three in Lom river which is the main stream of the study area, five in Mari river which is one of the left bank tributaries of the Lom, in Bétaré-Oya and eight in the left and the right bank of Mari. Different physicochemical parameters such as pH, electrical conductivity (EC), alkalinity, turbidity, total suspended solids (TSS), cyanide (CN-), major elements and heavy metals (Pb, Zn, Cd, Fe, Cu, As, Mn and Cr) were analyzed. Water Quality Indices (WQI), Heavy metal Pollution Index (HPI), sodium adsorption ratio (SAR) and percent sodium (Na%) were also computed to evaluate the suitability of water for drinking and irrigation. The results showed that the surface water from Bétaré-Oya was acidic to basic (5.40 < pH < 8.84), weakly mineralized (11.60 < EC < 122.10 μS/cm) with a high concentration of TSS (2 < TSS < 8996.00 mg/L) and turbidity (1.22 to 4758.00 NTU). The WQI scores show excellently to unsuitable quality in almost all the sampling sites. The water quality is found to be most deteriorated in Lom river and in the downstream of Mari river where an extensive mining activity is carried out, with the high WQI value of 5137.40. Based on heavy metal pollution index, the mean value was 1195.36 and thus under the critical pollution index. We thus notice a serious physical degradation by organic and mineral suspended particles as well as chemical degradation by heavy metals. This results from mining activities in the Lom river and its main tributaries such as the Mari river in the upstream part of the Sanaga basin. According to the percentage of sodium and SAR, these waters can be used for irrigation purposes in almost all types of soils.
文摘The territory of the Balkan Peninsula in SE Europe is reviewed, from the point of gemmology, as the cradle of gem and decorative minerals and metals in European prehistory. During the local Neolithic period (end of 7 th -6 th millennium BC), as material for tools or for beads, nephrite (with the earliest known Balkan nephrite culture), jadeite-omphacite and quartz (different varieties) were introduced to make pendants and idols. Large quantities of copper and gold artifacts are known since the Chalcolithic period (5 th millennium BC)(unique for the region;the largest in number of gold artifacts is the Varna I Chalcolithic necropolis in Bulgaria). The gemmological materials in the Balkans are known for malachite, antigorite serpentinite, turquoise, rock crystal, carnelian, jasper, jet and obsidian. In the Varna I necropolis (mid 5 th millennium BC) are recorded the first known complex faceted carnelian beads with 32 facets, as well as some of the most important gemmological techniques and procedures such as faceting, tumbling, annealing, miniaturization and standardization. As pigments for pottery, cinnabar, graphite and gold were used in different prehistoric sites. The earliest salt production in the Balkans is known from sites in Romania and Bulgaria, and because of its trade, salt is positively linked to a population rich with prestigious goods. The introduced possible Chalcolithic weight unit “van”(2 carats) is supposed to be the earliest known in prehistoric times.
