Spatial-temporal distribution and geochemistry of highly evolved Mesozoic granites in Great Xing’an Range,NE China:Discriminant criteria and geological significance

Highly evolved granite is an important sign of the mature continent crust and closely associated with deposits of rare metals.In this work,the authors undertake systematically zircon U-Pb ages and whole rock elemental data for highly evolved granitic intrusions from the Great Xing’an Range(GXR),NE China,to elucidate their discriminant criteria,spatial-temporal distribution,differentiation and geodynamic mecha-nism.Geochemical data of these highly evolved granites suggest that high w(SiO_(2))(>70%)and differentiation index(DI>88)could be quantified indicators,while strong Eu depletion,high TE_(1,3),lowΣREE and low Zr/Hf,Nb/Ta,K/Rb could only be qualitative indicators.Zircon U-Pb ages suggest that the highly evolved gran-ites in the GXR were mainly formed in Late Mesozoic,which can be divided into two major stages:Late Ju-rassic-early Early Cretaceous(162-136 Ma,peak at 138 Ma),and late Early Cretaceous(136-106 Ma,peak at 126 Ma).The highly evolved granites are mainly distributed in the central-southern GXR,and display a weakly trend of getting younger from northwest to southeast,meanwhile indicating the metallogenic potential of rare metals within the central GXR.The spatial-temporal distribution,combined with regional geological data,indicates the highly evolved Mesozoic granites in the GXR were emplaced in an extensional environ-ment,of which the Late Jurassic-early Early Cretaceous extension was related to the closure of the Mongol-Okhotsk Ocean and roll-back of the Paleo-Pacific Plate,while the late Early Cretaceous extension was mainly related to the roll-back of the Paleo-Pacific Plate.

Zircon U-Pb geochronology,geochemistry and tectonic implication of volcanic rocks from Manketouebo Formation in Keyihe area of northern Great Xing'an Range

Zircon U-Pb isotope dating and whole-rock geochemical analyses were undertaken for the rhyolite,rhyolitic lithic crystal tuff and dacitic tuff from the Manketouebo Formation in the Keyihe area,in order to constrain their genesis and tectonic significance.Zircon LA-ICP-MS U-Pb data indicate that the rhyolite and rhyolitic lithic crystal tuff were formed during 137±5 Ma and 143±1 Ma,respectively.These volcanic rocks have high SiO2(70.03%–76.46%)and K2O+Na2O(8.10%–9.52%)contents,but low CaO(0.03%–0.95%)and MgO(0.07%–0.67%)contents,which belong to the peraluminous and high-K calc-alkaline rocks.They are enriched in light rare earth elements(REEs),and exhibit fractionation of light over heavy REEs,withδEu values of 0.37–0.83.The volcanic rocks are enriched in LILEs(e.g.,Rb,U and K)and depleted in HFSEs(e.g.,Nb,Ti,P and Ta).The chemical composition suggests that these volcanic rocks formed by partial melting of crust material.Combined with previous regional research results,the authors consider that the volcanic rocks of the Manketouebo Formation in the Keyihe area were formed under an extensional environment related to the closure of the Mongolia–Okhotsk Ocean.

Geochemical Characteristics and Geological Significance of Early Permian Baya'ertuhushuo Gabbro in South Great Xing'an Range

Field geological investigation and geochemical analysis are carried out on Baya＇ertuhushuo Gabbro in South Great Xing＇an Range. Field investigation reveals that the gabbro is a magmatic intrusion rather than a component of an ophiolite suite as previously thought. Zircon laser ablation inductively coupled plasma mass spectroscopy （LA-ICP-MS） U-Pb dating indicates the gabbro was formed in 274-275 Ma, just as the widespread volcanic rocks of Dashizhai Formation （P1d）, monzogranites and miarolitic alkali-feldspar granites in the study area. The gabbro has SiO2 content between 47.23 wt% and 50.17 wt%, high MgO and FeOT contents of 6.95-11.29 wt% and 7.32- 12.24wt%, respectively, and it belongs to low-K tholeiitic series in the SiO2-K2O diagram. The Chondrite-normalized rare earth element （REE） patterns and primitive mantle-normalized spider diagrams of the gabbro are similar to those of Normal Mid-Ocean Ridge Basalt （N-MORB） except for the enrichment of large ion lithophfle elements （LILE）, such as Rb, Ba and K. In trace element tectonic discriminative diagrams, the samples are mainly plotted in the N-MORB field, and Zircon in situ Lu-Hf isotopic analysis also indicates the gabbro originated from depleted mantle. Through synthetic studies of the geochemical characteristics and petrogenesis of Baya＇ertuhushuo gabbro, volcanic rocks of Dashizhai Formation and granitoids in the area, it is suggested that the early Permian magmatism in the Xilinhot-Xiwuqi area formed in the tectonic setting of asthenosphere upwelling, which was caused by breaking-off of the subducted Paleo-Asian Ocean slab.

Early Cretaceous Adakitic Rocks in the Northern Great Xing’an Range, NE China: Implications for the Final Closure of Mongol-Okhotsk Ocean and Regional Extensional Setting

A large amount of igneous rocks in NE China formed in an extensional setting during Late Mesozoic. However, there is still controversy about how the Mongol-Okhotsk Ocean and the Paleo-Pacific Ocean effected the lithosphere in NE China. In this paper, we carried out a comprehensive study for andesites from the Keyihe area using LA-ICP-MS zircon UPb dating and geochemical and Hf isotopic analysis to investigate the petrogenesis and tectonic setting of these andesites. The U-Pb dating yields an Early Cretaceous crystallization age of 128.3±0.4 Ma. Geochemically, the andesites contain high Sr(686-930 ppm) and HREE contents, low Y(11.9-19.8 ppm) and Yb(1.08-1.52 ppm) contents, and they therefore have high Sr/Y(42-63) and La/Yb(24-36) ratios, showing the characteristics of adakitic rocks. Moreover, they exhibit high K2O/Na2O ratios(0.57-0.81), low Mg O contents(0.77-3.06 wt%), low Mg# value(17-49) and negative εHf(t) values(-1.7 to-8.5) with no negative Eu anomalies, indicating that they are not related to the oceanic plate subduction. Based on the geochemical and isotopic data provided in this paper and regional geological data, it can be concluded that the Keyihe adakitic rocks were affected by the Mongol-Okhotsk tectonic regime, forming in a transition setting from crustal thickening to regional extension thinning. They were derived from the partial melting of the thickened lower crust. The closure of the Mongol-Okhotsk Ocean may finish in early Early Cretaceous, followed by the collisional orogenic process. The southern part region of its suture belt was in a post-orogenic extensional setting in the late Early Cretaceous.

Recognition of Early Paleozoic Magmatisms in the Supposed Proterozoic Basements of Zhalantun, Great Xing’an Range, NE China

The Zhalantun terrane from the Xing’an massif, northeast China, was used to be considered as Proterozoic basements. However, amounts of detrital zircon ages from the meta-sedimentary rocks deny the existence of Precambrian basements recently. Notably, magmatic rocks were barely reported to limit the exact ages of the Zhalantun basements. In this study, we collected rhyolite, gabbro and quartz diorite for zircon in-situ U-Pb isotopic dating, which yield crystallization ages of ~505 Ma, ~447 Ma and ~125 Ma, respectively. Muscovite schist and siltstone define maximum depositional ages of ~499 Ma and ~489 Ma, respectively. Additionally, these dated supracrustal rocks and plutons also yield ancient detrital/xenocryst zircon ages of ~600-1000 Ma, ~1600-2220 Ma, ~2400 Ma, ~2600-2860 Ma. Based on the whole-rock major and trace element compositions, the ~505 Ma rhyolites display high SiO2 and alkaline contents, low Fe2O3T, TiO2 and Al2O3, and relatively high Mg O and Mg#, which exhibit calc-alkaline characteristics. These rhyolites yield fractionated REE patterns and negative Nb, Ta, Ti, Sr, P and Eu anomalies and positive Zr anomalies. The geochemistry, petrology and Lu-Hf isotopes imply that rhyolites were derived from the partial melting of continental basalt induced by upwelling of sub-arc mantle magmas, and then experienced fractional crystallization of plagioclase, which points to a continental arc regime. The ~447 Ma gabbros exhibit low Si O2 and alkaline contents, high Fe2 O3 T, Ti O2, Mg O and Mg#. They show minor depletions of La and Ce, flat MREE and HREE patterns, and negative Nb, Ta, Zr and Hf anomalies. Both sub-arc mantle and N-MORB-like mantle were involved in the formation of the gabbros, indicative of a probable back-arc basin tectonic setting. Given that, the previously believed Proterozoic supracrustal rocks and several plutons from the Zhalantun Precambrian basements were proved to be Paleozoic to Mesozoic rocks, among which these Paleozoic magmatic rocks were generally related to subduction regime. So far, none Proterozoic rocks have been identified from the Zhalantun Precambrian basement, though some ~600-3210 Ma ancient detrital/xenocryst zircons were reported. Combined with ancient zircon ages and newly reported ~2.5 Ga and ~1.8 Ga granites from the south of the Zhalantun, therefore, the Precambrian rocks probably once exposed in the Zhalantun while they were re-worked and consumed during later long tectonic evolutionary history, resulting in absence of Precambrian rocks in the Zhalantun.

Effects of meteorological factors on the defoliation dynamics of the larch caterpillar(Dendrolimus superans Butler)in the Great Xing’an boreal forests

Larch caterpillars are widely distributed in the Great Xing’an boreal forests;however,the relationship between caterpillar defoliation dynamics and climatic factors is poorly understood.The aims of this study are to investigate the primary weather conditions that might influence forest defoliation and to identify the most important life stage of the larch caterpillar at which forest defoliation might be mitigated by incorporating more inhibitory influences from climatic factors.The life cycle of the larch caterpillar was partitioned into four stages and multiple linear regression and mixed effect models were combined with a relative weight analysis approach to evaluate the importance and influence of meteorological variables on defoliation dynamics.The results show that warmer temperatures in growing seasons and overwintering periods can increase the defoliation area,while rainy and humid growing seasons decrease the defoliation area.Total precipitation during the early instar larval period had the greatest power to explain the variance in defoliation dynamics and had a very strong inhibitory effect,followed by the accumulative temperatures of the late instar larval period which had a positive impact,and precipitation during the middle instar larval period which had a negative impact.Weather conditions during the early instar larval period had the greatest influence on the area defoliated and accounted for 40%of the explained variance.This study demonstrates that climatic warming and drying will increase the risk of larch caterpillar outbreaks in the Great Xing’an Mountains.

Felsic Igneous Rocks in the Hua'aobaote Pb-Zn-Ag Polymetallic Orefield,Southern Great Xing'an Range:Genesis,Metallogenetic and Tectonic Significance

The Hua’aobaote Pb-Zn-Ag Polymetallic orefield is situated in the southern section of the Great Xing’an Range(GXAR),which has experienced extensive magmatism.Since the Paleozoic,there are two stages of magmatism in Hua’aobaote orefield occurred in the Paleozoic and Mesozoic.The Mesozoic magmatism is of great significance for the PbZn-Ag Polymetallic mineralization in Hua’aobaote orefield.In this study,new geochemical data was obtained to discuss the timing and petrogenesis of the magmatic rocks and its geodynamic and metallogenic significance.Zircon U-Pb ages reveal that the felsic igneous rocks from the Hua’aobaote orefield were formed in the Early Permian(294.8±3.2 Ma)and Early Cretaceous(132.6±1.4 Ma).Geochemically,the Early Permian granodiorite porphyrite is characterized by high Sr/Y(42-63)ratios and Mg^(#)(62.24-70.74)values and low heavy rare earth element(HREE)(5.09-6.79 ppm)contents.The granodiorite porphyrite is also characterized by depleted Sr-Nd initial isotopic signatures[ε_(Nd)(t)=5.91-7.59,(^(87)Sr/^(86)Sr)i=0.7029-0.7030],exhibiting adakitic characteristics.The Early Cretaceous granite porphyry and rhyolite are A-type felsic igneous rocks,and demonstrate high SiO_(2),Na_(2)O+K_(2)O and rare earth element(REE)contents,low CaO and MgO contents,low(^(87)Sr/^(86)Sr)i ratios(0.7044-0.7058),and positive ε_(Nd)(t)values(2.57-4.65).Whole-rock Pb isotopic compositions in granodiorite porphyrite are:206Pb/204Pb=17.631-18.149,^(207)Pb/^(204)Pb=15.422-15.450,and ^(208)Pb/^(204)Pb=37.325-37.729.The granite porphyry and rhyolite have initial ^(206)Pb/^(204)Pb,^(207)Pb/^(204)Pb,and ^(208)Pb/^(204)Pb ratios of 18.106-19.309,15.489-15.539,and 37.821-38.05,respectively.Sr-Nd-Pb isotopic evidence suggests that the Early Permian granodiorite porphyrite is likely to derive from slab melts and modified by peridotitic mantle wedge in the subduction tectonic setting of the Paleo-Asian Ocean.The Early Cretaceous A-type felsic igneous rocks were derived from juvenile lower crust,accompanied by limited crustal contamination and various degree of fractional crystallisation during magma emplacement.The Early Cretaceous magmatism and related mineralization were formed in a post-orogenic tectonic setting that attributed to the closure of the Mongol-Okhotsk Ocean.Pb isotopic data for the various rock units in the study area indicate that the Mesozoic magma source contributed substantial Pb,Zn,and Ag to the Hua’aobaote deposit.

Magmatic Evolution and Mineralization Process of the Super-Large Shihuiyao Rb–Nb–Ta Deposit,Southern Great Xing'an Range,China

Rare metal ore reserves are an important strategic resource, and their metallogenic mechanism and mineralization studies have also been received widespread international attention.

The Cu-Mo Mineralization of the Late Jurassic Porphyry in the Northern Great Xing'an Range: Constraints from Zircon U-Pb Ages of the Ore-Causative Granites

The Great Xing’an Range(GXAR)is one of the most important metallogenic belts in China.Previous study has shown that porphyry Cu-Mo deposit distributed in the northern Great Xing’an Range formed mainly in two stages:(1)Early Ordovician,such as Duobaoshan and Tongshan deposits(Liu et al.,2017);2)Triassic-Early Jurassic,including Wunugetushan,Taipingchuan and Badaguan deposits(Tang et al.,2016).In recent years,two potential porphyry Cu-Mo deposits,Huoluotai and Xiaokele,were discovered in the Erguna Block,northern GXAR(Figs.1a–b).However,the ore formation ages and regional metallogenic regularity are ambiguous due to the lack of isotopic ages.Two zircon U-Pb ages from the ore-causative granites were reported in this paper,with the aims to constrain the metallogenic ages and provide evidence for study of the regional metallogenic regularity and ore prospect prediction.

New Discovery of the Late Triassic Terrigenous Sediments in the Great Xing＇＇an Range Region,NE China and its Geological Significance

Objective The Great Xing＇an Range is located in the eastern section of Central Asian Orogenic Belt（CAOB）.As a superposed position of multiple tectonic domains,its structural evoIlution has always been a focused issue of geological research.

Supercritical extracts of forest fuels in Great Xing＇an Mountains

Extracts are important components of fuels. Fatty-extracts with high heating value （HV） are hypothe- sized by researchers as positively related to the HV of fuels. The Soxhlet extractor is typically used to extract fatty-extracts but it has shortcomings, including long processing time （8-10 h） and the requirement for large amounts of organic solvent. Supercritical extraction is an alternate and useful technique for extraction of natural products. However, published studies rarely discuss the relationship between extracts and HV. In this study, we assessed the supercritical extracts （SUE） of forest fuels in the Great Xing＇an Mountains. Our results indicated that the optimum conditions for extraction of SuEs were 40-60 mesh, 40-50 MPa, 45℃, 80 min and a CO2 flow rate of 1.5-2.0 dm3/min. The Soxhlet extracts contents and the SuE contents were all related to HV. However, R2 of the coniferous samples （0.8499） and needle samples （0.9722） demonstrated that the correlation between HV and the SuE content was closer. We conclude that supercritical fatty-extracts provide a useful index of the HV of fuels, especially coniferous fuels. SuE data can be used in fire management, for example to estimate the rate of fire spread or fire intensity.

Six new chrysophycean stomatocysts ornamented with reticulum from the Great Xing'an Mountains, China

Six new chrysophycean stomatocysts ornamented with reticulum were illustrated based on SEM observation. They were described following the guidelines of the International Statospore Working Group (ISWG). All samples were collected from the Great Xing'an Mountains, China. Their taxonomic characteristics and habitats were described to provide new information on the biodiversity of chrysophycean stomatocysts. As is common with many morphotypes, their biological affinities remain unknown.

大兴安岭南段北大山岩体的年代学和地球化学:对岩石成因及成矿潜力的指示

大兴安岭南段发育包括维拉斯托、黄岗、安乐、大井、毛登和边家大院等锡多金属矿床,是我国北方最重要的锡多金属成矿带。北大山岩体是该锡多金属成矿带规模最大,出露最完全的花岗质侵入体,其北部主要为石英二长斑岩,南部为黑云母花岗岩,且南部岩相中常见电气石和绿柱石,被认为是区内锡多金属矿床的成矿母岩。然而,目前对该岩体岩石成因及其稀有金属成矿潜力的认识却存在较大争议。本文在对北大山岩体开展岩相学观察和锆石U-Pb定年的基础上,通过全岩地球化学和锆石Hf同位素分析,结合MELTS热力学模拟计算,试图阐明该岩体的成因类型、源区特征和演化过程,并讨论其成矿潜力。锆石U-Pb定年结果显示,北大山岩体北部的石英二长斑岩形成于143.4±1.3Ma,南部黑云母花岗岩形成于142.6±1.3Ma,与大兴安岭南段早白垩世锡多金属成矿年龄峰值相一致。北大山岩体中含自形富水矿物角闪石及黑云母、富碱(K_(2)O+Na_(2)O=8.58%~9.34%)、ACNK/CNK值介于0.97~1.02,P_(2)O_(5)含量低(<0.14%)且与SiO_(2)含量呈负相关,指示该岩体为高钾钙碱性I型花岗岩。岩体的锆石Hf同位素组成较为亏损(ε_(Hf)(t)值平均6.81,n=20),且全岩锆饱和温度较高(平均值为813℃),指示其为新生地壳物质高温熔融的产物。主量元素变化关系和MELTS模拟结果表明,北大山岩体为高钾钙碱性岩浆体系不同程度分离结晶的产物,其中北部石英二长斑岩样品之间结晶分异程度较低,而南部黑云母花岗岩的结晶分异程度较高。北大山岩体的形成时代、源区特征和氧化还原条件(△FMQ-2.5)与大兴安岭南段稀有金属花岗岩类似,具有一定的锡多金属成矿潜力,但其初融温度、挥发分组成(相对富B贫F)、分异演化程度(结晶分异和熔体-流体相互作用程度相对较低)明显不同于维拉斯托矿床成矿碱长花岗斑岩,不会是该矿床的成矿母岩。

大兴安岭北段霍洛台地区辉绿玢岩的锆石U-Pb年龄、岩石成因和构造背景

对于大兴安岭北段中生代火成岩的研究,在中酸性花岗岩和火山岩等方面已有诸多成果,相比之下,对于该区中生代基性岩浆岩具体的形成时代和岩石成因仍不明确。而且,大兴安岭北段晚侏罗世-早白垩世的构造背景也存在争议。为此,本文对大兴安岭北段霍洛台地区辉绿玢岩进行了锆石U-Pb年代学和岩石地球化学特征研究,以达到进一步明确大兴安岭北段晚中生代基性岩浆岩的形成时代、岩石成因及其构造背景的目的。结果表明:霍洛台地区辉绿玢岩锆石的加权平均年龄为(129.1±1.3) Ma,属于早白垩世;辉绿玢岩稀土元素配分曲线为平坦型,Eu异常不明显;富集大离子亲石元素(如Ba、Sr),亏损高场强元素(如Th、Ce、Ti)。霍洛台辉绿玢岩可能起源于俯冲流体交代的岩石圈地幔源区,其形成可能受到了古太平洋板块俯冲作用的影响。

开库康-依西肯地区原生晕地球化学特征及找矿意义

为指导水系沉积物测量等化探异常的解释评价,分析成矿元素地球化学特征,评价主要地质单元含矿性,在开展1∶5万水系沉积物测量的同时系统采集了研究区内各地质单元原生晕样品,并对成矿元素进行了地球化学参数统计与对比研究。原生晕地球化学特征表明:区内以中低温热液成矿作用为主,找寻Au矿化或矿床希望较大,As、Sb等元素可作为指示元素;主要地质单元含矿性评价结果显示,研究区内上侏罗统二十二站组、下白垩统龙江组为区内成矿有利部位,主成矿元素为Au,Ag为伴生元素;水系与岩石样品对比分析表明,As、Sb、Mn、Mo 4种元素表现明显次生富集,Zn、Cu、Ti 3种元素明显贫化,在水系异常圈定时应适当提高、降低异常下限。

基于“目标-成本-效益”协同优化的山水林田湖草沙一体化生态保护与修复格局

当前以“山水林田湖草沙一体化保护与修复”为代表的国土空间生态修复工程已在全国范围内陆续开展,但相关规划的理论和方法支撑仍较为薄弱,如何确定合理的保护修复目标,并对生态保护与修复格局进行整合优化,是实现山水林田湖草沙一体化保护与修复规划需要解决的关键问题。基于系统保护规划理论和方法,初步构建了基于“目标-成本-效益”协同优化的一体化保护修复规划构架,以大兴安岭中段嫩江-哈拉哈河源头区为例,依托空间优化模型(Marxan)对一体化保护修复格局进行了优化模拟,结果表明:(1)绰尔河流域的生态系统保护优先级最高,其次是哈拉哈河流域和洮儿河流域,最后是霍林河流域。当预算不足时,优先保护绰尔河流域可以最大限度的提升研究区内的生态系统服务功能;(2)当优化目标低于50%,优化格局中以林地保护和草地保护为主,需要修复格局规模较小,当优化目标比例超过50%,需要采取生态修复的面积明显增加。随着优化目标比例的提升,优化格局所需面积越来越大,优化后区域中各类生态系统服务功能均有所提高;(3)依据目标-成本-效益曲线,60%的保护修复水平(即1980—2020年退化损失的生态系统服务的60%)为最高效的保护修复目标,所需生态保护修复总成本为50.6亿,但产生的生态效益可达为66.4亿;(4)60%目标水平下,需要林地、草地和湿地保护面积分别为20400.27 km^(2)、11919.45 km^(2)和25.23 km^(2);林地、草地和湿地修复面积分别为272.18 km^(2)、1695.23 km^(2)和3.71 km^(2),分别占1980—2020年期间林地、草地和河湖湿地退化消失比例40.9%、23.5%和6.3%。本研究提出的一体化生态保护修复格局整合优化方法可以确定不同目标和成本约束下,获取最佳综合生态效益的生态保护与修复实施策略和优化布局,为山水林田湖草沙一体化生态保护修复规划相关理论和方法提供一定的科学支撑。

明长城军事聚落地理景观模式

【目的】长城是中国古代伟大的军事工程,不同地段的地形特征与人工修筑的工事巧妙融合,形成独特的地理景观。为揭示古人营建思想与选址智慧,剖析长城军事地理蕴含的文化内涵。【方法】系统梳理古代9部描述“形胜”和“冲缓”的代表性著作,梳理出“极冲”“最冲”“次冲”“又次冲”“冲”“稍缓”“缓”7种军事地理类型,以其中3部著作中的4种军事地理类型为样本,利用ArcGIS软件,分析军堡与长城边墙的距离、与水系的距离、高程、坡度、起伏度,解释冲缓等级的地形特征。【结果】发现离边墙越远,军堡“冲缓”等级越低,规模越大;交通通道越窄,敌军同时通过的人数越少,军堡“冲缓”等级越低。【结论】揭示了古人从全局视角进行九边重镇规划布局的形胜智慧,以及从微观视角的“因地形用险制塞”的选址智慧,为长城价值研究和国家文化公园展示策略提供借鉴。

大兴安岭南段小孤山锡锌矿床锡石U-Pb年龄、流体包裹体和H-O-S-Pb同位素特征

毛登-小孤山地区是大兴安岭南段锡多金属成矿带代表性矿区,由小孤山锡锌矿床和毛登锡钼铋多金属矿床组成。小孤山矿床锡石U-Pb Tera-Wasserburg谐和年龄为134.8±1.9Ma,表明其形成于早白垩世。该矿床成矿过程可划分为4个阶段:锡石-黄铁矿-石英-电气石阶段(Ⅰ阶段)、锡石-黄铜矿-闪锌矿-石英-萤石阶段(Ⅱ阶段)、闪锌矿-方铅矿-石英-萤石阶段(Ⅲ阶段)、黄铁矿-石英-方解石阶段(Ⅳ阶段)。小孤山矿床主要发育富液两相包裹体(WL型)、富气两相包裹体(WG型)及含子矿物包裹体(S型)。Ⅰ、Ⅱ和Ⅲ阶段均发育WL、WG和S型包裹体,Ⅳ阶段仅出现WL型包裹体。从Ⅰ至Ⅳ阶段流体包裹体均一温度/盐度分别为420-443℃/8.3%-52.0%NaCleqv、286-379℃/4.0%-40.2%NaCleqv、214-299℃/3.8%-36.1%NaCleqv、178-195℃/2.1%-3.3%NaCleqv,表明从早阶段到晚阶段成矿流体由高温高盐度向低温低盐度转化,且前三个阶段流体盐度波动大,暗示成矿流体发生了多次沸腾。矿床的δ18O水介于-2.6‰-11.0‰,δD介于-107‰--91‰,Ⅰ和Ⅱ阶段的成矿流体以岩浆水为主,Ⅲ阶段开始有大气降水的加入。硫化物的δ34SCDT值介于-3.3‰--0.6‰,206Pb/204Pb介于17.772-18.427,207Pb/204Pb介于15.482-15.679,208Pb/204Pb介于37.668-38.622,表明成矿物质来源于早白垩世花岗质岩浆。流体沸腾和降温是矿质沉淀的两种主要机制。

大兴安岭锂-铍-铌-钽等关键金属矿床类型、成矿规律与资源展望

大兴安岭地区是我国东部重要稀有金属成矿带之一,以发育大规模显生宙花岗岩和多期次叠合金属成矿作用为主要特征。稀有金属成矿作用主要发生在晚中生代,与高分异花岗岩密切相关。本文对大兴安岭地区锂铍铌钽矿床时空分布特征、成矿规律进行了系统总结,构筑了矿床成矿模型,指明了找矿方向,探讨了有待解决的若干重要科学问题。研究表明,大兴安岭锂铍铌钽矿床主要集中大兴安岭南段,锂、铌钽矿具有独立分布特点,而铍矿主要呈带状沿林西-甘珠尔庙断裂分布。矿化时代集中在150~130Ma之间,呈现出晚侏罗世铌钽矿化-早白垩世锂铍矿化的特征。锂铍铌钽矿床类型丰富,以花岗岩型为主,兼有火山岩型、碱性岩型、云英岩型和矽卡岩型矿化。本次研究认为大兴安岭地区具有良好的锂铍铌钽(锡钨)成矿潜力,不同矿化均与岩浆分异和后期热液交代作用相关,同时水-岩反应也会影响流体的组成和演化。岩浆流体出溶、地幔物质参与、流体溶蚀-再沉淀过程对锂铍铌钽成矿起到关键作用。未来重点勘查方向应关注与锡林郭勒杂岩体周边的高分异花岗岩有关的锂锡多金属,以及与大兴安岭火山岩和碱性岩有关的铍和铌钽矿化。

内蒙古花敖包特银多金属矿床成矿作用:来自锆石和锡石U-Pb年龄的约束

花敖包特超大型银多金属矿床位于大兴安岭南段,矿体主要呈脉状赋存于二叠系寿山沟组的断裂中,部分矿体呈囊状产于寿山沟组与华力西期蛇绿岩的接触带中。矿体主要包括银铅锌锑矿体、锡铜矿体、铜铅锌矿体、锡矿体和银矿体。花敖包特矿床可划分为4个成矿阶段,分别为石英-锡石-毒砂-黄铁矿阶段(Ⅰ阶段)、石英-绢云母-锡石-黄铜矿-毒砂-磁黄铁矿-闪锌矿-黝铜矿阶段(Ⅱ阶段)、石英-绢云母-萤石-方解石-闪锌矿-方铅矿-黄铁矿-辉锑矿-含银硫盐矿物阶段(Ⅲ阶段)和石英-方解石-黄铁矿-辉银矿-深红银矿阶段(Ⅳ阶段)。对花敖包特矿区2件次流纹岩样品开展了LA-ICP-MS锆石U-Pb定年,分别获得135.4±0.8Ma和134.8±0.8Ma的年龄。对成矿Ⅰ阶段锡矿石和Ⅱ阶段锡铜矿石进行了LA-ICP-MS锡石U-Pb定年,分别获得136.3±2.0Ma和134.3±1.7Ma的加权平均年龄。定年结果表明,花敖包特矿床次流纹岩、锡矿体和锡铜矿体均形成于早白垩世。尽管二者形成时间相近,但脉体穿切关系及矿化分带特征均表明次流纹岩并非成矿物质和成矿流体的主要来源。本文认为,花敖包特矿床真正的成矿地质体为隐伏于矿区深部的次火山岩钟,其矿床成因类型为与次火山岩相关的热液矿床。