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Green Synthesis of Titanium Oxide Nanoparticles Using Natural Extracts
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作者 Maribel Santiago Daniela Rivera Agustín Torres 《Journal of Materials Science and Chemical Engineering》 CAS 2023年第2期29-40,共12页
Green synthesis is an alternative method for obtaining nanoparticles for environmentally friendly purposes. The present work describes the synthesis and characterization of titanium oxide nanoparticles, starting from ... Green synthesis is an alternative method for obtaining nanoparticles for environmentally friendly purposes. The present work describes the synthesis and characterization of titanium oxide nanoparticles, starting from three natural sources: orange peel, hibiscus rosa sinensis and Aloe vera. Titanium (IV) tetrabutoxide in ethanol solution was used as precursor. The methodology used was based on the sol-gel technique, through which TiO<sub>2</sub> nanoparticles were obtained in the anatase phase. The characterization of the nanoparticles was carried out by means of x-ray diffraction (XRD), scanning electron microscopy (SEM) and infrared spectrophotometry (FTIR), which allowed the identification of a good degree of purity and crystallinity of the samples obtained. 展开更多
关键词 TiO2 NANOPARTICLES green synthesis Sol-Gel Methodology Natural Sources
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Green Synthesis and Antibacterial Properties of Silver Nanoparticles from Eugenia uniflora Fruit Extract
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作者 Melissa Moya Vanessa Bagnarello +1 位作者 Julio Mora Idalia Valerio 《Advances in Nanoparticles》 2023年第3期94-105,共12页
The synthesis of nanoparticles by biological methods using microorganisms, enzymes, or plant extracts has been suggested as a possible ecofriendly alternative to chemical and physical methods that involve the use of h... The synthesis of nanoparticles by biological methods using microorganisms, enzymes, or plant extracts has been suggested as a possible ecofriendly alternative to chemical and physical methods that involve the use of harmful reducing agents. Green synthesis of silver nanoparticles (AgNPs) was achieved using Eugenia uniflora ripe fruit extract, which was characterized by phytochemical screening revealing the presence of polyphenols (quinones, flavonoids, and tannins), reducing compounds, and terpenes. These excellent antioxidants reduced silver nitrate to give the AgNPs, which were characterized by transmission electron microscopy (TEM), dynamic light scattering (DLS), and ζ potential analysis. The diameter of the AgNPs ranged from 10.56 ± 1.2 nm to 107.56 ± 5.7 nm. The antibacterial activity of the AgNPs was evaluated using a modification of the Kirby-Bauer technique with Escherichia coli, Pseudomonas aeruginosa, and Staphylococcus aureus. The inhibition halos were 11.12 ± 0.02 mm, 13.96 ± 0.07 mm, and 11.29 ± 0.76 mm, respectively. The synthesis using E. uniflora is an ecofriendly and low cost method of obtaining silver nanoparticles that could be used in health sciences because of their activity against bacteria with antibiotic resistance. 展开更多
关键词 Eugenia uniflora green synthesis Silver Nanoparticles Antibacterial Activity POLYPHENOLS
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Green Synthesis and Luminescent Properties of Mn4+ Doped Red Phosphor for WLED
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作者 Xiaoyi Liu Guixia Liu 《Optics and Photonics Journal》 2023年第6期147-155,共9页
Herein, the K<sub>3</sub>MoO<sub>2</sub>F<sub>5</sub><sup>.</sup>2H<sub>2</sub>O:Mn<sup>4+</sup> phosphor was synthesized by using low toxic NH&l... Herein, the K<sub>3</sub>MoO<sub>2</sub>F<sub>5</sub><sup>.</sup>2H<sub>2</sub>O:Mn<sup>4+</sup> phosphor was synthesized by using low toxic NH<sub>4</sub>HF<sub>2</sub> and HCl instead of highly toxic HF. The K3</sub>MoO2</sub>F<sub>5</sub><sup>.</sup><sub></sub>2H2</sub>O:Mn4+</sup> phosphor has a blocky structure and exhibits sharp red emission at the range of 580 to 670 nm excited by the blue light at 470 nm. The fabricated WLED device at 20 mA current has low correlation color temperature (CCT = 3608 K) and high color rendering index (Ra = 90.1), which can significantly improve the electroluminescence performance of cold WLED devices. These results indicate that the K3</sub>MoO2</sub>F5</sub><sup>.</sup>2H2</sub>O:Mn4+</sup> phosphor has potential application value in warm WLED excited by blue light chip. . 展开更多
关键词 Mn4+ green synthesis PHOSPHOR WLED
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Green synthesis and characterization of palladium nanoparticles and its conjugates from solanum trilobatum leaf extract 被引量:4
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作者 Amarnath Kanchana Saveetha Devarajan Senniyanallur Rathakrishnan Ayyappan 《Nano-Micro Letters》 SCIE EI CAS 2010年第3期169-176,共8页
An important area of research in nanotechnology deals with the synthesis of nanoparticles of different chemical compositions,sizes and controlled monodispersity.Currently,there is a growing need to develop environment... An important area of research in nanotechnology deals with the synthesis of nanoparticles of different chemical compositions,sizes and controlled monodispersity.Currently,there is a growing need to develop environmentally benign nanoparticle synthesis in which no toxic chemicals are used in the synthesis protocol.Palladium nanoparticles(Pd Np) are of interest because of their catalytic properties and affinity for hydrogen.Our protocol for the phyto-synthesis of Pd Np under moderate p H and room temperature offers a new means to develop environmentally benign nanoparticles.Solanum trilobatum is enlightened in our present study as it is enriched with phytochemicals to reduce palladium chloride ions.Poly MVA a dietary supplement based on the nontoxic chemotherapeutic lipoic acid-palladium complex(LA-Pd) is been hypothesized as the new paradigm of cancer therapy.Hence forth we successfully conjugated lipoic acid(S-Pd Np-LA) and vitamins(S-Pd Np-Vitamin-LA) to palladium nanoparticles synthesised from Solanum trilobatum leaf extract.These nanoparticles(S-Pd Np,S-Pd Np-LA,S-Pd Np-Vitamin-LA) were characterized with UV-Vis Spectroscopy,SEM and FTIR analysis,which revealed that S-Pd Np are polydisperse and of different morphologies ranging from 60?70 nm(S-Pd Np),65?80 nm(S-Pd Np-LA) and 75?100 nm(S-Pd Np-Vitamin-LA) in size. 展开更多
关键词 NANOPARTICLES PALLADIUM Lipoic acid Palladium lipoic acid complex Poly-MVA green synthesis Solanum trilobatum
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Green Synthesis of Nitrogen-to-Ammonia Fixation: Past, Present, and Future 被引量:4
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作者 Jianyun Zheng Li Jiang +2 位作者 Yanhong Lyu San Ping Jiang Shuangyin Wang 《Energy & Environmental Materials》 SCIE EI CAS CSCD 2022年第2期452-457,共6页
The nitrogen(N2)-to-ammonia(NH3)fixation driven by renewable energy has an attractive prospect to relieve the global warming and reduce the consumption of fossil fuels.Ideally,photocatalytic,electrochemical,and photoe... The nitrogen(N2)-to-ammonia(NH3)fixation driven by renewable energy has an attractive prospect to relieve the global warming and reduce the consumption of fossil fuels.Ideally,photocatalytic,electrochemical,and photoelectrochemical approaches are developed as the next-generation NH3 synthesis technologies to substitute the Haber–Bosch method.However,the NH3 yield rate of nitrogen reduction reaction(NRR)by green approaches is extremely low,resulting in the current dilemma of NRR and contamination issues.Thus,in this mini review,the past advances on the sustainable NRR are briefly summarized in the three aspects as follows:the selectivity and adjustment of various catalysts,the type of electrolyte/solvent system,and the investigation of reaction conditions.Subsequently,the recent critical activities in the area of sustainable NH3 synthesis are analyzed and discussed deeply,and a perspective for rational and healthy development of this area is provided positively。 展开更多
关键词 current dilemma enhanced performances future challenges green synthesis nitrogen-to-ammonia fixation
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Green synthesis of bentonite-supported iron nanoparticles as a heterogeneous Fenton-like catalyst:Kinetics of decolorization of reactive blue 238 dye 被引量:2
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作者 Ahmed Khudhair Hassan Ghayda Yaseen Al-Kindi Dalal Ghanim 《Water Science and Engineering》 EI CAS CSCD 2020年第4期286-298,共13页
This study aimed to synthesize green tea nano zero-valent iron(GT-NZVI)and bentonite-supported green tea nano zero-valent iron(BGT-NZVI)nanoparticles using green tea extracts in an environmentally sustainable way.Bent... This study aimed to synthesize green tea nano zero-valent iron(GT-NZVI)and bentonite-supported green tea nano zero-valent iron(BGT-NZVI)nanoparticles using green tea extracts in an environmentally sustainable way.Bentonite was used as a support material because it disperses and stabilizes GT-NZVI,and it helps to reduce the cost,increase the adsorption capacity of GT-NZVI,and decrease the optimum amount of GT-NZVI used in Fenton-like oxidation.A scanning electron microscope,an atomic force microscope,and a Fourier transform infrared spectroscope were used to characterize GT-NZVI and B-GT-NZVI,while the zeta potential was measured to evaluate the stability of iron nanoparticles.The decolorization kinetics of reactive blue 238(RB 238)dye in the aqueous phase in the Fenton-like oxidation process were investigated as well.The effects of various experimental conditions such as reaction time,dosages of catalysts,concentration of H2O2,temperature,addition of inorganic salts,and other parameters were investigated.The results show that the oxidative degradation efficiencies of RB 238 dye catalyzed by GT-NZVI and B-GT-NZVI were 93.5%and 96.2%,respectively,at the optimum reaction conditions as follows:c(H2O2)¼5 mmol/L,r(GT-NZVI)¼0.5 g/L or r(B-GT-NZVI)¼0.5 g/L,c(RB 238 dye)¼0.05 mmol/L,and pH¼2.5 at 180 min.The best catalytic performance was exhibited when B-GT-NZVI was used.Three kinetic models were employed,and the second-order model was found to be the best model representing the experimental kinetic data of RB 238 dye.The value of activation energy decreased from 38.22 kJ/mol for GT-NZVI to 14.13 kJ/mol for B-GT-NZVI.This indicates that the effect of B-GT-NZVI in decreasing the energy barrier is more pronounced than that of the GT-NZVI catalyst,leading to improved Fenton-like oxidation processes.©2020 Hohai University.Production and hosting by Elsevier B.V.This is an open access article under the CC BY-NC-ND license(http://creativecommons.org/licenses/by-nc-nd/4.0/). 展开更多
关键词 green synthesis Bentonite-supported iron nanoparticles Azo dye Fenton-like process KINETICS
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Antiplasmodial activity of silver nanoparticles: A novel green synthesis approach 被引量:1
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作者 Madhur Sardana Varnika Agarwal +3 位作者 Akansha Pant Vinita Kapoor Kailash C.Pandey Sanjay Kumar 《Asian Pacific Journal of Tropical Biomedicine》 SCIE CAS 2018年第5期268-272,共5页
Objective:To synthesize silver nanoparticles using silver nitrate by a green technique which involves different compositions of aqueous leaf extracts of Azadirachta indica(neem)and Ocimum sanctum(tulsi).Methods:Their ... Objective:To synthesize silver nanoparticles using silver nitrate by a green technique which involves different compositions of aqueous leaf extracts of Azadirachta indica(neem)and Ocimum sanctum(tulsi).Methods:Their shape and size were determined using transmission electron microscopy and UV-visible spectroscopy.Their antiplasmodial activity was studied using the malarial parasite strain(Plasmodium falciparum,3D7).The parasite strain(3D7)was collected and revived in vitro using Trager and Jensen method in RPMI 1640 medium for 7-8cycles.Half maximal effective concentration values were calculated by nonlinear regression analysis.Results:Transmission electron microscopy results confirmed the formation of silver nanoparticles with size ranging from 4.74-39.32 nm and their size differs by varying the concentrations from 20%to 100%of neem extract in neem and tulsi extracts.It was observed that samples B and C showed half maximum effective concentration of about 0.3μM.Conclusions:It can be easily established that the aqueous leaf extracts of neem and tulsi in combination can be a good source for synthesis of silver nanoparticles with small size possessing appreciable antiplasmodial activity. 展开更多
关键词 MALARIA Antiplasmodial activity Silver nanoparticles green synthesis Azadirachta indica Ocimum sanctum
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Green Synthesis of Silver Nanoparticles: A Review 被引量:2
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作者 Sista Kameswara Srikar Deen Dayal Giri +2 位作者 Dan Bahadur Pal Pradeep Kumar Mishra Siddh Nath Upadhyay 《Green and Sustainable Chemistry》 2016年第1期34-56,共23页
The bio-molecules from various plant components and microbial species have been used as potential agents for the synthesis of silver nanoparticles (AgNPs). In spite of a wide range of bio-molecules assisting in the pr... The bio-molecules from various plant components and microbial species have been used as potential agents for the synthesis of silver nanoparticles (AgNPs). In spite of a wide range of bio-molecules assisting in the process, synthesizing stable and widely applicable AgNPs by many researchers still poses a considerable challenge to the researchers. The biological agents for synthesizing AgNPs cover compounds produced naturally in microbes and plants. More than 100 different biological sources for synthesizing AgNPs are reported in the past decade by various authors. Reaction parameters under which the AgNPs were being synthesized hold prominent impact on their size, shape and application. Available published information on AgNPs synthesis, effects of various parameters, characterization techniques, properties and their application are summarised and critically discussed in this review. 展开更多
关键词 AGNPS green synthesis Silver Nano Plant Extract MICROBE
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Green Synthesis of Silver Nanoparticles Using Plectranthus Amboinicus Leaf Extract for Preparation of CMC/PVA Nanocomposite Film
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作者 Nguyen Thi Thanh Thuy Le Hoang Huy +3 位作者 Truong Thuy Vy Nguyen Thi Thanh Tam Bien ThiLan Thanh Nguyen Thi My Lan 《Journal of Renewable Materials》 SCIE EI 2021年第8期1393-1411,共19页
In the present study,the biogenic silver nanoparticles have been synthesized using aqueous leaf extract of Plectranthus amboinicus(PA),which acted as both reducing and stabilizing agents.The PA synthesized silver nano... In the present study,the biogenic silver nanoparticles have been synthesized using aqueous leaf extract of Plectranthus amboinicus(PA),which acted as both reducing and stabilizing agents.The PA synthesized silver nanoparticles were blended with carboxymethyl cellulose/polyvinyl alcohol(CMC/PVA)biocomposite.The prepared AgNPs as well as the biogenic AgNPs incorporated CMC/PVA films were investigated using UV-visible spectrophotometry,Fourier-transform infrared spectroscopy(FT-IR),dynamic light scattering(DLS),scanning electron microscope(SEM),and X–ray diffraction(XRD).The DLS results showed that biogenic AgNPs had the average particle size of 65.70 nm with polydispersity index of 0.44.The surface plasmon resonance of AgNPs,which was determined by UV-vis spectrophotometry,showed the value of 410.00 nm.These results therefore confirmed the reduction Ag+into Ag°and the formation of AgNPs in the medium.The SEM imaging showed that AgNPs was quasi-spherical and monodisperse.The XRD peaks at 33.07°,44.19°,64.58°and 77.47°confirmed the crystalline nature and presence of AgNPs.The CMC/PVA films that incorporated with AgNPs displayed best mechanical strength and morphological properties than the pure CMC/PVA film.The film of CMC/PVA-AgNPs exhibited significant antibacterial activities against Bacillus spizizenii,Staphylococcus aureus,Salmonella typhi and Escherichia Coli. 展开更多
关键词 Carboxymethyl cellulose ANTIBACTERIAL green synthesis silver nanoparticles plectranthus amboinicus polyvinyl alcohol
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Green Synthesis of Silver Nanoparticles from Abronia villosa as an Alternative to Control of Pathogenic Microorganisms
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作者 Ali Abdelmoteleb Benjamin Valdez-Salas +1 位作者 Ernesto Beltran-Partida Daniel Gonzalez-Mendoza 《Journal of Renewable Materials》 SCIE EI 2020年第1期69-78,共10页
The aim of this study was to evaluate the antibacterial and antifungal activities of eco-friendly synthesized silver nanoparticles.The silver nanoparticles were synthesized by biological method using aqueous extract o... The aim of this study was to evaluate the antibacterial and antifungal activities of eco-friendly synthesized silver nanoparticles.The silver nanoparticles were synthesized by biological method using aqueous extract of Abronia villosa.Synthesis of silver nanoparticles was confirmed by color change and characterized using UV-visible spectroscopy,scanning electron microscope(SEM),energy dispersive X-ray spectroscopy(EDX),dynamic light scattering(DLS),and zeta potential analysis.The SEM analysis revealed the presence of spherical silver nanoparticles of the size range 21 to 33 nm.Synthesized silver nanoparticles were used to evaluate their antibacterial effects at different concentrations(25,50,75 and 100μg/ml)on gram negative and gram positive bacteria.The biggest halo zone was observed at 75 and 100μg/ml concentrations of silver nanoparticles against both gram positive and gram negative bacteria.Antifungal activity of biosynthesized silver nanoparticles was evaluated against seven different phytopathogenic fungi.AgNPs showed high inhibition of radial growth toward all tested fungi.The highest inhibition of fungal growth by AgNPs was recorded against Macrophomina phaseolina(86.06±0.92%).Biosynthesized AgNPs using plant extract are a promising to use safety for various biomedical and agricultural applications. 展开更多
关键词 Antibacterial activity antifungal activity green synthesis
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Green Synthesis of Silver Nanoparticles Using Cannabis sativa Extracts and Their Anti-Bacterial Activity
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作者 Sujata Mandal Sreekar B. Marpu +2 位作者 Roxana Hughes Mohammad A. Omary Sheldon Q. Shi 《Green and Sustainable Chemistry》 2021年第1期38-48,共11页
A procedure for the green synthesis of silver nanoparticles (AgNPs) using<span style="font-family:;" "=""> </span><i><span style="font-family:Verdana;">Cannab... A procedure for the green synthesis of silver nanoparticles (AgNPs) using<span style="font-family:;" "=""> </span><i><span style="font-family:Verdana;">Cannabis sativa</span></i><span style="font-family:;" "=""> </span><span style="font-family:Verdana;">(hemp plant) as a stabilizing media was developed and antibacterial activity was tested. Within 30 minutes of heating</span><span style="font-family:;" "=""> </span><span style="font-family:;" "=""><span style="font-family:Verdana;">the mixture of silver nitrate and hemp extract, the formation of silver nanoparticles took place under the complete absence of a chemical reducing or an additional stabilizing agent. The so-formed AgNPs were characterized using different optical spectroscopy and electron microscopy techniques. The initial formation of AgNPs was established from UV-Vis data based on </span><span style="font-family:Verdana;">surface plasmon resonance (</span><span style="font-family:Verdana;">SPR) of AgNPs at ~417 nm. The exact size, shape,</span></span><span style="font-family:;" "=""> </span><span style="font-family:Verdana;">and elemental composition of AgNPs </span><span style="font-family:Verdana;">were</span><span style="font-family:Verdana;"> established from ESEM images and EDS data.</span><span style="font-family:;" "=""> </span><span style="font-family:;" "=""><span style="font-family:Verdana;">The antibacterial activity of these nanoparticles was studied on Gram-positive </span><i><span style="font-family:Verdana;">Staphylococcus aureus</span></i><span style="font-family:Verdana;">, and Gram-negative</span><i><span style="font-family:Verdana;"> Escherichia coli</span></i></span><i><span style="font-family:;" "=""> </span></i><span style="font-family:Verdana;">following Disk diffusion and Minimum Inhibitory Concentration (MIC) tests. Results showed that the biosynthesis of silver nanoparticles using hemp extract </span><span style="font-family:Verdana;">could be</span><span style="font-family:Verdana;"> a simple,</span><span>inexpensive, and biocompatible method.</span> 展开更多
关键词 HEMP Silver Nanoparticles green synthesis PATHOGENS
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Green Synthesis of Magnetite Nanoparticles Using Aqueous Leaves Extracts of <i>Azadirachta indica</i>and Its Application for the Removal of As(V) from Water
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作者 Kshama Parajuli Aravind Kumar Sah Hari Paudyal 《Green and Sustainable Chemistry》 2020年第4期117-132,共16页
<span style="font-family:Verdana;">Because of various disadvantages of chemical synthesis processes, these</span><span> </span><span style="font-family:Verdana;">days ... <span style="font-family:Verdana;">Because of various disadvantages of chemical synthesis processes, these</span><span> </span><span style="font-family:Verdana;">days people are attracting towards green synthesis processes as it is devoid of toxic by-products, cost-effective and eco-friendly. In this study, a simple green synthesis method is applied for the synthesis of magnetite (Fe</span><sub><span style="vertical-align:sub;font-family:Verdana;">3</span></sub><span style="font-family:Verdana;">O</span><sub><span style="vertical-align:sub;font-family:Verdana;">4</span></sub><span style="font-family:Verdana;">) nanoparticles (MNPs) by co-precipitation of FeCl</span><sub><span style="vertical-align:sub;font-family:Verdana;">3·</span></sub><span style="font-family:Verdana;">6H</span><sub><span style="vertical-align:sub;font-family:Verdana;">2</span></sub><span style="font-family:Verdana;">O and FeSO</span><sub><span style="vertical-align:sub;font-family:Verdana;">4·</span></sub><span style="font-family:Verdana;">7H</span><sub><span style="vertical-align:sub;font-family:Verdana;">2</span></sub><span style="font-family:Verdana;">O in the molar ratio of 2:1 using </span><span><i></i></span><i><span style="font-family:Verdana;">Azadirachta indica</span><span></span></i><span style="font-family:Verdana;"> leaves extract under nitrogen environment. FTIR, XRD, SEM etc. were used to characterize the synthesized MNPs. Batch adsorption experiments were carried out to determine adsorption equilibrium of As(V) as a function of pH, adsorbent dose, contact time and different initial concentrations. Kinetics results were best describe</span><span style="font-family:Verdana;">d</span><span style="font-family:Verdana;"> by pseudo-second order model with rate constant value 0.0052 g/(mg·min). The equilibrium adsorption isotherm was best fitted with Langmuir adsorption isotherm model. The maximum adsorption capacity was found to be 62.89 mg/g at pH 2. MNPs showed </span><span style="font-family:Verdana;">a </span><span style="font-family:Verdana;">high affinity for As(V) and avoids filtration for solid-liquid separation, thus it would be employed as a promising material </span><span style="font-family:Verdana;">for </span><span style="font-family:Verdana;">the removal of As(V) from water.</span> 展开更多
关键词 green synthesis Magnetite Nanoparticles (MNPs) Azadirachta indica Leaves Extract As(V) Adsorption
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Light Induced Green Synthesis of Silver Nanoparticles Using Aqueous Extract of Prunus amygdalus
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作者 Sista Kameswara Srikar Deen Dayal Giri +2 位作者 Dan Bahadur Pal Pradeep Kumar Mishra Siddh Nath Upadhyay 《Green and Sustainable Chemistry》 2016年第1期26-33,共8页
Light driven, photon mediated green synthesis of silver nano-particles (AgNPs) was carried out using aqueous silver nitrate solution (1 mM) and aqueous extract of almond (Prunus amygdalus). Experiments were carried ou... Light driven, photon mediated green synthesis of silver nano-particles (AgNPs) was carried out using aqueous silver nitrate solution (1 mM) and aqueous extract of almond (Prunus amygdalus). Experiments were carried out in dark, diffused sunlight and direct sunlight to study the influence of light intensity as well as by wrapping the reaction tubes with colored cellophane filters (violet, green, yellow and red) to investigate the effect of light color on AgNP synthesis. It was observed that the violet filter enhanced the AgNPs synthesis appreciably. The FTIR spectroscopic analysis confirmed participation of bio-molecules with hydroxyl and amide groups present in the almond extract as reducing and capping or stabilizing agents, respectively. Dynamic light scattering (DLS) studies revealed the particle size distribution of nano-particles as 2 – 400 nm, and scanning electron microscopy (SEM) confirmed their spherical shape with an average size of about 20 nm. Growth analysis of AgNPs revealed an increase in number of nano-particles with time, whereas their rate of growth decreased gradually. The AgNP suspension was stable even beyond 3 weeks. 展开更多
关键词 AGNPS NANO-PARTICLES green synthesis Prunus amygdalus
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Spirooxindoles:Recent report of green synthesis approach
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作者 Agus Rimus Liandi Antonius Herry Cahyana +3 位作者 Diva Naufal Alfariza Rahma Nuraini Renita Wulan Sari Tio Putra Wendari 《Green Synthesis and Catalysis》 2024年第1期1-13,共13页
Spirooxindole is a compound with a unique framework and broad bioactivities in medicine.In this study,we have reviewed various approaches or methods in synthesizing spirooxindole derivatives focused on green synthesis... Spirooxindole is a compound with a unique framework and broad bioactivities in medicine.In this study,we have reviewed various approaches or methods in synthesizing spirooxindole derivatives focused on green synthesis.Synthesis of spirooxindoles is mainly carried out through multicomponent reactions combined with various green approaches such as the use of heterogeneous catalysts(nano-sized,magnetic,metal-complex,and metal-organic framework catalysts),deep eutectic solvent,solvent-free reactions,catalyst-free reactions,as well as the use of ultrasonic and microwaves irradiation.The green method is carried out in addition to obtaining high yields,it also offers reductions in the use of hazardous chemicals,energy use,purification processes,and waste generation.As a result,green synthesis methods in the synthesis of spirooxindole derivatives are more environmentally friendly. 展开更多
关键词 SPIROOXINDOLES green synthesis CATALYSIS NANOPARTICLE Ultrasonic irradiation
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Enhancing Green Ammonia Electrosynthesis Through Tuning Sn Vacancies in Sn‑Based MXene/ MAX Hybrids
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作者 Xinyu Dai Zhen‑Yi Du +10 位作者 Ying Sun Ping Chen Xiaoguang Duan Junjun Zhang Hui Li Yang Fu Baohua Jia Lei Zhang Wenhui Fang Jieshan Qiu Tianyi Ma 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第5期154-168,共15页
Renewable energy driven N_(2) electroreduction with air as nitrogen source holds great promise for realizing scalable green ammonia production.However,relevant out-lab research is still in its infancy.Herein,a novel S... Renewable energy driven N_(2) electroreduction with air as nitrogen source holds great promise for realizing scalable green ammonia production.However,relevant out-lab research is still in its infancy.Herein,a novel Sn-based MXene/MAX hybrid with abundant Sn vacancies,Sn@Ti_(2)CTX/Ti_(2)SnC–V,was synthesized by controlled etching Sn@Ti_(2)SnC MAX phase and demonstrated as an efficient electrocatalyst for electrocatalytic N2 reduction.Due to the synergistic effect of MXene/MAX heterostructure,the existence of Sn vacancies and the highly dispersed Sn active sites,the obtained Sn@Ti2CTX/Ti_(2)SnC–V exhibits an optimal NH_(3) yield of 28.4μg h^(−1) mg_(cat)^(−1) with an excellent FE of 15.57% at−0.4 V versus reversible hydrogen electrode in 0.1 M Na_(2)SO_(4),as well as an ultra-long durability.Noticeably,this catalyst represents a satisfactory NH3 yield rate of 10.53μg h^(−1) mg^(−1) in the home-made simulation device,where commercial electrochemical photovoltaic cell was employed as power source,air and ultrapure water as feed stock.The as-proposed strategy represents great potential toward ammonia production in terms of financial cost according to the systematic technical economic analysis.This work is of significance for large-scale green ammonia production. 展开更多
关键词 green ammonia synthesis N2 electroreduction Renewable energy SN MXene/MAX hybrid
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Green Synthesis of Silver Nanoparticles Using Aqueous Orange and Lemon Peel Extract and Evaluation of Their Antimicrobial Properties
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作者 Amra Bratovcic Amna Dautovic 《Advances in Nanoparticles》 CAS 2024年第2期11-28,共18页
Green synthesis of silver nanoparticles (AgNPs) using aqueous extracts of orange and lemon peels, as a reducing agent, and silver nitrate salts as a source of silver ions is a promising field of research due to the ve... Green synthesis of silver nanoparticles (AgNPs) using aqueous extracts of orange and lemon peels, as a reducing agent, and silver nitrate salts as a source of silver ions is a promising field of research due to the versatility of biomedical applications of metal nanoparticles. In this paper, AgNPs were synthetized at different reaction parameters such as the type and concentration of the extracts, metal salt concentration, temperature, speed stirring, and pH. The antibacterial properties of the obtained silver nanoparticles against E. coli, as well as the physical and chemical characteristics of the synthesized silver nanoparticles, were investigated. UV-Vis spectroscopy was used to confirm the formation of AgNPs. In addition to green biogenic synthesis, chemical synthesis of silver nanoparticles was also carried out. The optimal temperature for extraction was 65˚C, while for the synthesis of AgNPs was 35˚C. The synthesis is carried out in an acidic environment (pH = 4.7 orange and pH = 3.8 lemon), neutral (pH = 7) and alkaline (pH = 10), then for different concentrations of silver nitrate solution (0.5 mM - 1 mM), optimal time duration of the reaction was 60 min and optimal stirring speed rotation was 250 rpm on the magnetic stirrer. The physical properties of the synthesized silver nanoparticles (conductivity, density and refractive index) were also studied, and the passage of laser light through the obtained solution and distilled water was compared. Positive inhibitory effect on the growth of new Escherichia coli colonies have shown AgNPs synthesized at a basic pH value and at a 0.1 mM AgNO<sub>3</sub> using orange or lemon peel extract, while for a 0.5 mM AgNO<sub>3 </sub>using lemon peel extract. 展开更多
关键词 green synthesis Silver Nanoparticles Orange and Lemon Peel Extract Antibacterial Activity Escherichia coli
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Green synthesis of novel conjugated poly(perylene diimide)as cathode with stable sodium storage
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作者 Jinyun Zheng Xinxin Liu +3 位作者 Wenbin Li Wenjie Li Xiangming Feng Weihua Chen 《Nano Research》 SCIE EI CSCD 2023年第7期9538-9545,共8页
Conjugated polymers of organic carbonyl compounds are promising electrode materials for energy storage devices owing to the renewable development prospects,structural variability,and better insolubility in electrolyte... Conjugated polymers of organic carbonyl compounds are promising electrode materials for energy storage devices owing to the renewable development prospects,structural variability,and better insolubility in electrolyte.However,the synthesis methods in solution are cumbersome and complicated in separation and purification,and require the introduction of functional groups and use of expensive catalysts.In this work,a novel conjugated poly(3,4,9,10-perylenetetracarboxylic diimide)(PPI)with superior thermal stability and lower solubility was prepared successfully by a green facile mechanical ball milling strategy.The PPI exhibits enhanced electrochemical dynamics performance,preferable rate capability,higher discharge capacity,and excellent cycling stability of 450 cycles at 0.2 C with higher capacity retention of 85.7%when used as cathode material for sodium-ion battery.Furthermore,the in-situ X-ray diffraction(XRD)and in-situ Raman investigations combined with the Fourier transform infrared(FT-IR)and X-ray photoelectron spectroscopy(XPS)were carried out to investigate the sodium storage mechanism.The results indicate that only two sodium ions are bound to two opposite carbonyl groups of PPI monomer to form sodium enolates during normal charging and discharging and to deliver available reversible capacity. 展开更多
关键词 sodium-ion battery organic cathode carbonyl compound stability green synthesis
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Green Hydrothermal Synthesis and Applications of Sorbus pohuashanensis/Aronia melanocarpa Extracts Functionalized-Au/Ag/AuAg Nanoparticles
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作者 Jin Huang Jixiang Sun +4 位作者 Kai Shao Yamei Lin Zhiguo Liu Yujie Fu Liqiang Mu 《Journal of Renewable Materials》 SCIE EI 2023年第4期1807-1821,共15页
Nanoparticles(NPs)have already been widely used in catalysis,antibacterial and coating fields.Compared with the traditional toxic and harmful reducing reagents,green synthesis of NPs by using plant extracts is not onl... Nanoparticles(NPs)have already been widely used in catalysis,antibacterial and coating fields.Compared with the traditional toxic and harmful reducing reagents,green synthesis of NPs by using plant extracts is not only environmental-friendly and cost-effective but also conducive to the multi-level and efficient utilization of wild plant resources.In this study,the aqueous extracts from Sorbus pohuashanensis(SP)and Aronia melanocarpa(AM)fruits were used as the reducing and protective reagents for synthesizing Au/AgNPs,with the characteristics of originality operation and high repeatability.The SP/AM fruit extracts functionalized Au/AgNPs were characterized by UV-vis spectroscopy(UV-vis),transmission electron microscopy(TEM),energy dispersive spectroscopy(EDS),scanning electron microscope(SEM),X-ray diffraction(XRD)and Fourier transform infrared spectroscopy(FTIR).UV-vis spectrums showed the NPs peaks verified by the presence between 400–550 nm;TEM and SEM demonstrated NPs displayed approximately spherical structures;EDS confirmed the existence of Au/Ag elements;XRD measurements confirmed that the obtained NPs showed highly crystalline structures;FTIR demonstrated the fruits extracts were adsorbed on the surface of NPs.Primary experiments indicated that SP/AM fruit extracts functionalized-NPs could be used as the reagents for removing the organic dyes efficiently;Zone of inhibition tests(ZOI)explained that NPs have slow-release antibacterial activity. 展开更多
关键词 green synthesis NANOPARTICLES Sorbus pohuashanensis Aronia melanocarpa plant extracts dye removal
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Green synthesis of magnetically separable and reusable Fe_(3)O_(4)/Cdots nanocomposites photocatalyst utilizing Moringa oleifera extract and watermelon peel for rapid dye degradation
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作者 Emi Kurnia Sari Rivaldo Marsel Tumbelaka +3 位作者 Harlina Ardiyanti Nurul Imani Istiqomah Chotimah Edi Suharyadi 《Carbon Resources Conversion》 EI 2023年第4期274-286,共13页
This study focused on green-synthesized magnetite/carbon dots nanocomposites(GS-Fe_(3)O_(4)/Cdots)utilizing Moringa oleifera leaf extract and watermelon peel waste for rapid degradation of methylene blue(MB)dye.Co-pre... This study focused on green-synthesized magnetite/carbon dots nanocomposites(GS-Fe_(3)O_(4)/Cdots)utilizing Moringa oleifera leaf extract and watermelon peel waste for rapid degradation of methylene blue(MB)dye.Co-precipitation and hydrothermal method were used to synthesize GS-Fe_(3)O_(4) and Cdots,respectively.In addition,the sonication method was used to link Cdots on Fe_(3)O_(4) surface.X-ray diffraction spectrum of GS-Fe_(3)O_(4)/Cdots inform the cubic inverse spinel and has crystallite size in the range of 10.1-7.2 nm.The crystallite size also decreased with the increase of Cdots concentration.The transmission electron microscope showed the most uniform size of nanocomposites at around 13.4 nm.The functional group of Fe-O was detected on the nanocomposites,proof that Fe_(3)O_(4) still exists after fabrication.The presence of C=C,C-O,and C-O-C also indicates the existence of Cdots on the surface of Fe_(3)O_(4).The addition of Cdots affected the saturation magnetization and coercivity value in the range of 29.2-38.3 emu/g and 59-65 Oe,respectively,which showed a good magnetic properties.As an organic dye,MB was used for a photocatalytic process under UV irradiation.The degradation efficiency was raised to 98% for 30 min photocatalytic process.The magnetically separable capability makes nanocomposites could be recycled and reused three times with high degradation.Furthermore,GS-Fe_(3)O_(4)/Cdots potential as a low-cost and environmentally friendly reusable photocatalyst for rapid wastewater degradation. 展开更多
关键词 green synthesis Fe_(3)O_(4)nanoparticles Cdots Nanocomposite MB degradation
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Synthesis of Silver Nanoparticles from Honeybees and Its Antibacterial Potential
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作者 Akamu J. Ewunkem Niore’s Johnson +3 位作者 A’lyiha F. Beard Ilunga Tshimanga Brittany Justice Jeffery Meixner 《Open Journal of Medical Microbiology》 2024年第1期77-92,共16页
Honeybees (Apis mellifera) are important pollinators of flowering plants and agricultural crops contributing annually to billions of dollars in revenues to crop production. Honeybees have an average lifespan between 8... Honeybees (Apis mellifera) are important pollinators of flowering plants and agricultural crops contributing annually to billions of dollars in revenues to crop production. Honeybees have an average lifespan between 8 weeks to 5 years. Dead honeybees are abundantly available in beehives and can be utilized as an alternative source to synthesize nanoparticles. In recent years, biologically synthesized nanoparticles have been preferred over their chemical counterparts. However, honeybee-based-green synthesis of nanoparticles has not been explored yet. Herein, we report the biosynthesis of silver nanoparticles from honeybees and its antibacterial activity. The synthesis of silver nanoparticles was monitored visually through a gradual change in color. Furthermore, the biosynthesized nanoparticles were confirmed and characterized by UV-visible spectroscopy. Scanning Electron Microscope was utilized to analyze the average size and morphologies of the biosynthesized nanoparticles. Subsequently, the antibacterial potential of the biosynthesized silver nanoparticles was tested against selected Gram-positive and Gram-negative bacterial strains. It was found that a distinct color change from yellow to brown in the reaction solution suggested the formation of silver nanoparticles. The biosynthesized nanoparticles exhibited absorption maxima at 430 nm. The SEM analysis confirmed the spherical and cuboidal shape of the biosynthesized silver nanoparticles with a size range between 10 - 40 nm. Furthermore, the biosynthesized silver nanoparticles exhibited strong antimicrobial potential against tested Gram-positive and Gram-negative bacteria strains by aggregating on the cell surface. This study showcases the biomedical and agricultural applications of biosynthesized silver nanoparticles from honeybee wings. . 展开更多
关键词 HONEYBEE BACTERIA green synthesis Nanoparticles ANTIMICROBIAL
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