Power-conversion-efficiencies(PCEs)of organic solar cells(OSCs)in laboratory,normally processed by spin-coating technology with toxic halogenated solvents,have reached over 19%.However,there is usually a marked PCE dr...Power-conversion-efficiencies(PCEs)of organic solar cells(OSCs)in laboratory,normally processed by spin-coating technology with toxic halogenated solvents,have reached over 19%.However,there is usually a marked PCE drop when the bladecoating and/or green-solvents toward large-scale printing are used instead,which hampers the practical development of OSCs.Here,a new series of N-alkyl-tailored small molecule acceptors named YR-SeNF with a same molecular main backbone are developed by combining selenium-fused central-core and naphthalene-fused endgroup.Thanks to the N-alkyl engineering,NIR-absorbing YR-SeNF series show different crystallinity,packing patterns,and miscibility with polymeric donor.The studies exhibit that the molecular packing,crystallinity,and vertical distribution of active layer morphologies are well optimized by introducing newly designed guest acceptor associated with tailored N-alkyl chains,providing the improved charge transfer dynamics and stability for the PM6:L8-BO:YRSeNF-based OSCs.As a result,a record-high PCE approaching 19%is achieved in the blade-coating OSCs fabricated from a greensolvent o-xylene with high-boiling point.Notably,ternary OSCs offer robust operating stability under maximum-power-point tracking and well-keep>80%of the initial PCEs for even over 400 h.Our alkyl-tailored guest acceptor strategy provides a unique approach to develop green-solvent and blade-coating processed high-efficiency and operating stable OSCs,which paves a way for industrial development.展开更多
A series of diatomite supported Cu/Ni bimetallic catalysts were prepared using the co-impregnation method to improve the efficiency and selectivity toward methyl 12-hydroxystearate in the hydrogenation of methyl ricin...A series of diatomite supported Cu/Ni bimetallic catalysts were prepared using the co-impregnation method to improve the efficiency and selectivity toward methyl 12-hydroxystearate in the hydrogenation of methyl ricinoleate.The catalysts were characterized using X-ray diffraction(XRD),transmission electron microscopy(TEM),scanning electron microscopy and energy dispersive X-ray spectroscopy(SEM-EDS),X-ray photoelectron spectroscopy(XPS)and temperature programmed reduction(H2-TPR).All the characterization results verified the formation of highly dispersed Cu/Ni alloy on support.Moreover,by subtly regulating the Ni/Cu molar ratio as well as the reaction parameters,the hydrogenation of methyl ricinoleate to methyl 12-hydroxystearate proceeded efficiently and selectively,affording 97%yield of methyl 12-hydroxystearate and nearly equivalent conversion of methyl ricinoleate under 2 MPa H2 pressure and at 130 C in 4 h with only 1 wt%of the catalyst Ni7Cu1/diatomite(based on methyl ricinoleate).Besides,the supported Cu–Ni bimetallic catalyst is stable during recycle and reuse.After five cycles of reuse,much catalytic activity is still preserved.Therefore,this low-cost and stable bimetallic catalyst would be promising for the hydrogenation of methyl ricinoleate to methyl 12-hydroxystearate,representing an example of green catalysis for efficiently conversion of biomass to value-added chemicals and materials.展开更多
Process intensification is one of the most significant trends in current chemical engineering and process industries.In recent years,the desire to become more "green" in processing has always been tied to th...Process intensification is one of the most significant trends in current chemical engineering and process industries.In recent years,the desire to become more "green" in processing has always been tied to the requirement of being profitable.This review discusses the challenges of process engineering and summarizes the key role of fundamentals for green process intensification.展开更多
The green process to recover magnesium chlor-ide from the residue solution of a potassium chloride pro-duction plant,which comes from the leach solution of a potash mine in Laos,is designed and optimized.The res-idue ...The green process to recover magnesium chlor-ide from the residue solution of a potassium chloride pro-duction plant,which comes from the leach solution of a potash mine in Laos,is designed and optimized.The res-idue solution contains magnesium chloride above 25 wt-%,potassium chloride and sodium chloride together below 5 wt-%and a few other ions such as Br-,SO_(2)-4and Ca2+.The recovery process contains two steps:the previous impurity removal operation and the two-stage evapora-tion-cooling crystallization procedure to produce magnes-ium chloride.The crystallized impurity carnallite obtained from the first step is recycled to the potassium chloride plant to recover the potassium salt.The developed process is a zero discharge one and thus fulfills the requirements for green chemical industrial production.The produced magnesium chloride is up to industrial criteria.展开更多
Through a case study of Shenzhen City,China,this study focused on a quantitative method for analyzing the spatial processes involved in green infrastructure changes associated with rapid urbanization.Based on RS,GIS a...Through a case study of Shenzhen City,China,this study focused on a quantitative method for analyzing the spatial processes involved in green infrastructure changes associated with rapid urbanization.Based on RS,GIS and SPSS statistics software,the approach includes selection of the square analysis units and representative landscape metrics,quantification of the change types of landscape metrics in all analysis units through two indices and hierarchical cluster analysis of the above analysis units with different landscape metric change types(i.e.spatial attributes).The analyses verify that there is a significant sequence of continuous changes in green infrastructure in Shenzhen.They are the perforation,the segmentation,the fragmentation,the evanescence and the filling-in processes,which have a good spatio-temporal correspondence with urbanization and reflect the synthetic influence of urban planning,government policies and landforms.Compared with other studies on quantifying the spatial pattern,this study provides an alternative probe into linking the spatial pattern to spatial processes and the corresponding ecological processes in the future.These spatio-temporal processes offer many opportunities for identifying,protecting and restoring key elements in an urban green infrastructure network for areas in the early stages of urbanization or for non-urbanized areas.展开更多
In this paper, the concept of “green processing” will be applied, while explaining the role of sustainable development strategy with respect to the environmental issue. Two parameters are considered in the study by ...In this paper, the concept of “green processing” will be applied, while explaining the role of sustainable development strategy with respect to the environmental issue. Two parameters are considered in the study by utilizing carbon dioxide and reject brine from desalination plants as raw materials to produce valuable chemical products and partially desalinated water.展开更多
A decision-making model of gear process for green manufacturing is presented, which integrates the five objectives including the time, quality, cost, resource consumption and environmental impact of gear process toget...A decision-making model of gear process for green manufacturing is presented, which integrates the five objectives including the time, quality, cost, resource consumption and environmental impact of gear process together into the development of a strategy. Mathematical description is provided for the multi-objectives decision-making model. The expert judgment and the multi-fuzzy assessment theory are introduced to do sensible comparisons and give quantitative results. A case study on practical cutting tool selection in gear machining demonstrates that the proposed model is applicable.展开更多
The aim of this research was to explore the effect of fixation,rolling,and drying processing technology on the retention rate of green tea catechins components and tea polyphenol.Different fixation processes(rotary dr...The aim of this research was to explore the effect of fixation,rolling,and drying processing technology on the retention rate of green tea catechins components and tea polyphenol.Different fixation processes(rotary drumfiring,microwave,steam-blasting),rolling process(weight of rolling,gently press rolling and traditional rolling),drying process(stove drying,roasting dehydration,baked fried drying) were adopted.The effect of different tea processing technology on the retention rate of catechins component and tea polyphenol was analyzed.It showed that the microwave fixation process,gently press rolling process,baked fried dry process were beneficial to keep high levels of EGCG,C,EGC,EC,ECG.展开更多
The index system, code system, and weights of indexes are established to assess the effects of green construction. The index system consists of index level, factor level and sub-factor level. The analytic hierarchy pr...The index system, code system, and weights of indexes are established to assess the effects of green construction. The index system consists of index level, factor level and sub-factor level. The analytic hierarchy process is used to determine the weights of indexes, and the consistency test indicate that the weight assignment is reasonable. Using fuzzy synthetic judgment method, the assessment model is built, which includes factor set, weight set and conclusion set. An example is given to demonstrate the assessment procedures.展开更多
基金the support from the NSFC (22209131, 22005121, 21875182, and 52173023)National Key Research and Development Program of China (2022YFE0132400)+4 种基金Key Scientific and Technological Innovation Team Project of Shaanxi Province (2020TD-002)111 project 2.0 (BP0618008)Open Fund of Jiangsu Engineering Laboratory of Light-Electricity-Heat Energy-Converting Materials and Applications (Changzhou University, GDRGCS2022002)Open Fund of Key Laboratory of Fluorine and Silicon for Energy Materials and Chemistry of Ministry of Education (Jiangxi Normal University, KFSEMC-202201)acquired at beamlines 7.3.3 and 11.0.1.2 at the Advanced Light Source, which is supported by the Director, Office of Science, Office of Basic Energy Sciences, of the U.S. Department of Energy under Contract No. DE-AC0205CH11231
文摘Power-conversion-efficiencies(PCEs)of organic solar cells(OSCs)in laboratory,normally processed by spin-coating technology with toxic halogenated solvents,have reached over 19%.However,there is usually a marked PCE drop when the bladecoating and/or green-solvents toward large-scale printing are used instead,which hampers the practical development of OSCs.Here,a new series of N-alkyl-tailored small molecule acceptors named YR-SeNF with a same molecular main backbone are developed by combining selenium-fused central-core and naphthalene-fused endgroup.Thanks to the N-alkyl engineering,NIR-absorbing YR-SeNF series show different crystallinity,packing patterns,and miscibility with polymeric donor.The studies exhibit that the molecular packing,crystallinity,and vertical distribution of active layer morphologies are well optimized by introducing newly designed guest acceptor associated with tailored N-alkyl chains,providing the improved charge transfer dynamics and stability for the PM6:L8-BO:YRSeNF-based OSCs.As a result,a record-high PCE approaching 19%is achieved in the blade-coating OSCs fabricated from a greensolvent o-xylene with high-boiling point.Notably,ternary OSCs offer robust operating stability under maximum-power-point tracking and well-keep>80%of the initial PCEs for even over 400 h.Our alkyl-tailored guest acceptor strategy provides a unique approach to develop green-solvent and blade-coating processed high-efficiency and operating stable OSCs,which paves a way for industrial development.
基金supported by the National Program on Key Research Project(2016YFA0602900)Nankai University Engineering Research Center for Castor and also supported by"the Fundamental Research Funds for the Central Universities",Nankai University(000082).
文摘A series of diatomite supported Cu/Ni bimetallic catalysts were prepared using the co-impregnation method to improve the efficiency and selectivity toward methyl 12-hydroxystearate in the hydrogenation of methyl ricinoleate.The catalysts were characterized using X-ray diffraction(XRD),transmission electron microscopy(TEM),scanning electron microscopy and energy dispersive X-ray spectroscopy(SEM-EDS),X-ray photoelectron spectroscopy(XPS)and temperature programmed reduction(H2-TPR).All the characterization results verified the formation of highly dispersed Cu/Ni alloy on support.Moreover,by subtly regulating the Ni/Cu molar ratio as well as the reaction parameters,the hydrogenation of methyl ricinoleate to methyl 12-hydroxystearate proceeded efficiently and selectively,affording 97%yield of methyl 12-hydroxystearate and nearly equivalent conversion of methyl ricinoleate under 2 MPa H2 pressure and at 130 C in 4 h with only 1 wt%of the catalyst Ni7Cu1/diatomite(based on methyl ricinoleate).Besides,the supported Cu–Ni bimetallic catalyst is stable during recycle and reuse.After five cycles of reuse,much catalytic activity is still preserved.Therefore,this low-cost and stable bimetallic catalyst would be promising for the hydrogenation of methyl ricinoleate to methyl 12-hydroxystearate,representing an example of green catalysis for efficiently conversion of biomass to value-added chemicals and materials.
基金supported by the State Major Basic Research Development Program of China (2007CB613507)National Natural Science Key Fund (20490200)Innovative Research Group Science Fund (20221603)
文摘Process intensification is one of the most significant trends in current chemical engineering and process industries.In recent years,the desire to become more "green" in processing has always been tied to the requirement of being profitable.This review discusses the challenges of process engineering and summarizes the key role of fundamentals for green process intensification.
文摘The green process to recover magnesium chlor-ide from the residue solution of a potassium chloride pro-duction plant,which comes from the leach solution of a potash mine in Laos,is designed and optimized.The res-idue solution contains magnesium chloride above 25 wt-%,potassium chloride and sodium chloride together below 5 wt-%and a few other ions such as Br-,SO_(2)-4and Ca2+.The recovery process contains two steps:the previous impurity removal operation and the two-stage evapora-tion-cooling crystallization procedure to produce magnes-ium chloride.The crystallized impurity carnallite obtained from the first step is recycled to the potassium chloride plant to recover the potassium salt.The developed process is a zero discharge one and thus fulfills the requirements for green chemical industrial production.The produced magnesium chloride is up to industrial criteria.
基金Under the auspices of National Natural Science Foundation of China (No. 41001112,40635028)
文摘Through a case study of Shenzhen City,China,this study focused on a quantitative method for analyzing the spatial processes involved in green infrastructure changes associated with rapid urbanization.Based on RS,GIS and SPSS statistics software,the approach includes selection of the square analysis units and representative landscape metrics,quantification of the change types of landscape metrics in all analysis units through two indices and hierarchical cluster analysis of the above analysis units with different landscape metric change types(i.e.spatial attributes).The analyses verify that there is a significant sequence of continuous changes in green infrastructure in Shenzhen.They are the perforation,the segmentation,the fragmentation,the evanescence and the filling-in processes,which have a good spatio-temporal correspondence with urbanization and reflect the synthetic influence of urban planning,government policies and landforms.Compared with other studies on quantifying the spatial pattern,this study provides an alternative probe into linking the spatial pattern to spatial processes and the corresponding ecological processes in the future.These spatio-temporal processes offer many opportunities for identifying,protecting and restoring key elements in an urban green infrastructure network for areas in the early stages of urbanization or for non-urbanized areas.
文摘In this paper, the concept of “green processing” will be applied, while explaining the role of sustainable development strategy with respect to the environmental issue. Two parameters are considered in the study by utilizing carbon dioxide and reject brine from desalination plants as raw materials to produce valuable chemical products and partially desalinated water.
文摘A decision-making model of gear process for green manufacturing is presented, which integrates the five objectives including the time, quality, cost, resource consumption and environmental impact of gear process together into the development of a strategy. Mathematical description is provided for the multi-objectives decision-making model. The expert judgment and the multi-fuzzy assessment theory are introduced to do sensible comparisons and give quantitative results. A case study on practical cutting tool selection in gear machining demonstrates that the proposed model is applicable.
文摘The aim of this research was to explore the effect of fixation,rolling,and drying processing technology on the retention rate of green tea catechins components and tea polyphenol.Different fixation processes(rotary drumfiring,microwave,steam-blasting),rolling process(weight of rolling,gently press rolling and traditional rolling),drying process(stove drying,roasting dehydration,baked fried drying) were adopted.The effect of different tea processing technology on the retention rate of catechins component and tea polyphenol was analyzed.It showed that the microwave fixation process,gently press rolling process,baked fried dry process were beneficial to keep high levels of EGCG,C,EGC,EC,ECG.
基金The Doctoral Program of Higher Educa-tion Institution of China (No.20050487017)
文摘The index system, code system, and weights of indexes are established to assess the effects of green construction. The index system consists of index level, factor level and sub-factor level. The analytic hierarchy process is used to determine the weights of indexes, and the consistency test indicate that the weight assignment is reasonable. Using fuzzy synthetic judgment method, the assessment model is built, which includes factor set, weight set and conclusion set. An example is given to demonstrate the assessment procedures.
