An unusual formal oxy transposition of vinylogous β-silyloxy-cyclobutanone 1（a 1,5-difunctionalized substrate） under mild acidic conditions（aqueous HF in CH3CN at 0℃） to the decalinic y-lactone 2 was described.A...An unusual formal oxy transposition of vinylogous β-silyloxy-cyclobutanone 1（a 1,5-difunctionalized substrate） under mild acidic conditions（aqueous HF in CH3CN at 0℃） to the decalinic y-lactone 2 was described.A plausible mechanistic pathway involving the Grob-type fragmentation and intramolecularγ-Iactonization was proposed.展开更多
基金financial support from National Natural Science Foundation of China(NSFC,Nos.21302177,21672049 and 21672030)
文摘An unusual formal oxy transposition of vinylogous β-silyloxy-cyclobutanone 1（a 1,5-difunctionalized substrate） under mild acidic conditions（aqueous HF in CH3CN at 0℃） to the decalinic y-lactone 2 was described.A plausible mechanistic pathway involving the Grob-type fragmentation and intramolecularγ-Iactonization was proposed.
