Influence of Carbonation on Fatigue of Concrete with High Volume of Ground Granulated Blast-furnace Slag

The effect of carbonation on fatigue performance of ground granulated blast-furnace slag concrete was investigated. Based on the static compression tests of carbonated GGBS-concrete, the correlation between carbonation depth and compressive strength was analyzed and an equation between carbonation depth and compressive strength was put forward. Meanwhile, fatigue S-N curves of various carbonation depths were fitted, and the infl uence of carbonation on fatigue life and strength was studied. Carbonation has a dual effect on the fatigue behavior of GGBS-concrete. A fatigue equation based on the depth of carbonation was established. Also, the probabilistic distribution of fatigue life of carbonated concrete at a given stress level was modeled by the two-parameter Weibull distribution.

Modeling Tensile Strength of Concrete on Partial Replacement of Ce­ment and Sand with Quarry Dust Ground Granulated Blast Furnace and Slag Silica Fumes

Tensile strength of concrete were examined on its partial replacement of cement and sand using ground granulated blast furnace and quarry dust.The study examines its behaviour at different dimensions.This is to monitor the variation effect of these parameters on the growth rates of tensile to the optimum curing age.These include non linear conditions of tensile state,non-elastic and its brittle behaviour at all times as it express zero conditions in tension.This means that it has the ability to with stand pull force.It also reflects its weak ability to handle shear stress thus tends to cause deformation in material as it has poor elasticity.The reflection of its brittle influence the rate of tensile behaviour from concrete ductility.These are known to be a material on modern mechanics of concrete.These are also considered as quasi brittle material.This behaviour was reflected as the system considered evaluating the growth rate of tensile strength that replaced cement and sand with these locally sourced addictives.The developed model monitor other reflected influential parameters such as variation of concrete porosity due it compaction in placements,tensile behaviour reflects these effect that subject it to mechanical properties of concrete.The study expressed the reaction of these parameters in the simulation,the evaluation of these affected the details variation of tensile growth rate at different water cement ratios and curing age.The tensile behaviour that was monitored are based on these factors in the study.The derived model were validated with the a researcher results[24],and both parameters developed best fits correlation.The study is imperative because the system expressed the behaviour of tensile strength from concrete at different dimensions.Experts can applied these concept to monitor tensile behaviour considering these parameters in its growth rates.

A Binder of Phosphogypsum-Ground Granulated Blast Furnace Slag-Ordinary Portland Cement

A new hydraulic cementitious binder was developed by mainly utilizing industrial byproducts phosphogypsum（PG）and ground granulated blast furnace slag（GGBFS）with small addition of ordinary portland cement（OPC）.The hydration process and microstructure were studied by X-ray diffraction（XRD） and scanning electronic microscopy（SEM）.OPC hydrated first at early age to form primarily C-S-H gel,ettringite and calcium hydroxide（CH）.GGBFS activated by CH and sulfate ions hydrated continuously at later age,producing more and more hydration products,C-S-H gel and ettringite.Thus the paste developed a denser microstructure and its strength increased.The 28 d compressive strength of the mixture of 50%PG,46% GGBFS and 4%OPC exceeded 45 MPa.The setting time was faster and 3 d and 7 d strength were higher when the proportion of OPC increased.But the 28 d strength decreased when OPC exceeded 4%due to large amount of ettringite formed at late hydration age which damaged the microstructure.

Effect of Steel Slag and Granulated Blast-furnace Slag on the Mechanical Strength and Pore Structure of Cement Composites

Reuse of solid industrial wastes is an effective approach to develop low-carbon construction materials. This paper examines how two materials, steel slag（ST） and granulated blast-furnace slag（SL） impact the mechanical performance and pore structure of cement-based systems. Analysis was done on the variations of the porosity, pore size, and pore volume distribution with the curing age and replacement content, and the fractal dimensions of pore surfaces. The results suggested that systems with both supplementary materials had lower early strengths than pure cement, but could generally surpass pure cement paste after 90 d; higher SL content was particularly helpful for boosting the late strengths. The addition of ST increased the porosities and mean pore sizes at each age, and both increased with ST content; SL was helpful for decreasing the system＇s late porosity（especially harmless pores below 20 nm）; The lowest porosity and mean pore size were obtained with 20% SL. Both systems had notably fractal characteristics on pore surfaces, with ST systems showing the highest dimensions at 10% ST, and SL systems at 20% SL. Compressive strength displayed a significant linear increase with fractal dimension.

Durability of Seawater Mixed Concrete with Different Replacement Ratio of BFS （Blast Furnace Slag） and FA （Fly Ash）

Using seawater in concrete can be considered as one of the sustainable approaches in construction industry not only to save the freshwater resource but also to promote the use of abandoned seawater resource, especially in the construction at the uninhabited area close to the sea where the procurement of fresh water is difficult. In this study, durability against chloride attack of seawater mixed concrete with different replacement ratio of BFS （blast furnace slag） and FA （fly ash） is discussed and the life time until the occurrence of corrosion crack is evaluated. The results show that： （1） Chloride penetration rate of seawater mixed specimens with BFS and FA is lower than that of freshwater mixed OPC （ordinary Portland cement） specimens; （2） Oxygen permeability of seawater mixed specimens with BFS and FA is almost the same or lower than that of freshwater mixed OPC specimens; （3） Total life time （corrosion incubation period and propagation period） of seawater mixed specimens with BFS and FA is almost the same or only slightly shorter than that of freshwater mixed OPC specimens. From the results, it was confirmed that the usage of seawater in concrete mixing is feasible in concrete with the appropriate BFS and FA replacement ratio.

Abrasion Resistance of Cement Paste with Granulated Blast Furnace Slag and Its Relations to Microhardness and Microstructure

The abrasion resistance of cement pastes with 30 wt%,40 wt%and 50 wt%granulated blast furnace slag(GBFS),and its relations to microhardness and microstructure like hydration products and pore structure were studied.Results indicated that GBFS decreased the abrasion resistance of paste,and among the pastes with GBFS,the paste with 40 wt%GBFS showed the highest abrasion resistance.The microhardness of GBFS was lower than that of the cement,and the microhardness of the hydration products in paste with GBFS was also lower than that of the hydration products in paste without GBFS,so that the abrasion resistance of paste decreased when GBFS was incorporated.The reason for the decrease of microhardness of pastes with GBFS was that the contents of Ca(OH)_(2)in pastes with GBFS was significantly lower than that in the paste without GBFS,while large amounts of calcium aluminate hydrates and hydrotalcite-like phases(HT)in pastes with GBFS were generated.Furthermore,among the pastes with GBFS,the paste with 40 wt%GBFS showed the lowest porosity which was the main reason for its highest abrasion resistance.

Sulfuric Acid Resistance of Concrete with Blast Furnace Slag Fine Aggregate

The deterioration of concrete by sulfuric acid attack in sewage environments has become a serious problem for many existing sewage structures. In this study, the properties of concrete using the blast furnace slag have been examined. It was shown that by using the blast furnace slag fine aggregate and blast furnace slag fine powder, it is possible to enhance the resistance of mortar and concrete to sulfuric acid. The resistance to sulfuric acid of mortar and concrete can be improved by using a blast-furnace slag fine aggregate in the total amount of fine aggregate. When mortar or concrete reacts to sulfuric acid, dihydrated gypsum film is formed around the particulate of the fine aggregate. This dihydrated gypsum film could retard the penetration of sulfuric acid, thus, improving the resistance to sulfuric acid. Furthermore, it has been proved that the relationship between the erosion depth by sulfuric acid attack and the product of immersion period and concentration of sulfuric acid can be expressed linearly. However, this relationship is dependent on the type of materials of concrete.

The Use of Fine Blast Furnace Slag in Improvement of Properties of Concrete

Concrete properties can be improved using Fine Blast Furnace Slag (BFS). The latter was used to replace cement in concrete at 10%, 15%, 20%, 25%, and 30% proportions and properties of both fresh and hardened concrete improved. Best workability (evaluated by slump and Table tests) was recorded at 30% of BFS addition. VEBE-time, an indication of workability of concrete, decreased to its lowest value (about 4 seconds at 30% BFS) and compaction factor attained its maximum value of 99% at BFS 25%. For density and unit weight, 30% of fine BFS in concrete mix resulted in maximum density of 2180 kg/m3 for fresh concrete, and 2430 kg/m3 for hardened concrete. Unit weight of concrete achieved a maximum of 23.9 kN/m3 at 30% BFS has achieved specified strength at 1st week and 28 days, also the late strength is high at 56 and 84 days. Bond and flexure loads come high of BFS use. The data of compressive, bond, and flexural strengths are highly related. Results of research are useful and may be applied using fine BFS to improve the properties of concrete materials.

Effects of Al_2O_3 nanoparticles on properties of self compacting concrete with ground granulated blast furnace slag (GGBFS) as binder

In this work, strength assessments and percentage of water absorption of self compacting concrete containing ground granulated blast furnace slag （GGBFS） and A1203 nanoparticles as binder have been investigated. Portland cement was replaced by different amounts of GGBFS and the properties of concrete specimens were investigated. Although it negatively impacts the physical and mechanical properties of concrete at early ages of curing, GGBFS was found to improve the physical and mechanical properties of concrete up to 45 wt% at later ages. A1203 nanoparticles with the average particle size of 15 nm were added partially to concrete with the optimum content of GGBFS and physical and mechanical properties of the specimens were measured. A1203 nanoparticle as a partial replacement of cement up to 3.0 wt% could accelerate C-S-H gel formation as a result of increased crystalline Ca（OH）2 amount at the early ages and hence increase strength and improve the resistance to water permeability of concrete specimens. The increase of the A1203 nanoparticles＇ content by more than 3.0 wt% would cause the reduction of the strength because of the decreased crystalline Ca（OH）2 content required for C-S-H gel formation. Several empirical relationships have been presented to predict flexural and split tensile strength of the specimens by means of the corresponding compressive strength at a certain age of curing. Accelerated peak appearance in conduction calorimetry tests, more weight loss in thermogravimetric analysis and more rapid appearance of the peaks related to hydrated products in X-ray diffraction results, all indicate that A1203 nanoparticles could improve mechanical and physical properties of the concrete specimens.

TiO_2 nanoparticles' effects on properties of concrete using ground granulated blast furnace slag as binder

In the present study, compressive strength, pore structure, thermal behavior and microstrncture characteristics of concrete containing ground granulated blast furnace slag and TiO2 nanoparticles as binder were investigated. Portland cement was replaced by different amounts of ground granulated blast furnace slag and the properties of concrete specimens were investigated. Al- though it negatively impacts the properties of concrete at early ages, ground granulated blast furnace slag up to 45 wt% was found to improve the physical and mechanical properties of concrete at later ages. TiO2 nanoparticles with the average particle size of 15 nm were partially added to concrete with the optimum content of ground granulated blast furnace slag and physical and mechanical properties of the specimens were measured. TiO2 nanoparticle as a partial replacement of cement up to 3 wt% could accelerate C-S-H gel formation as a result of increased crystalline Ca（OH）2 amount at the early age of hydration and hence increase compressive strength of concrete. The increased TiO2 nanoparticles＇ content of more than 3 wt% may cause reduced compressive strength because of the decreased crystalline Ca（OH）2 content required for C-S-H gel formation and unsuitable dispersed nanoparticles in the concrete matrix. TiO2 nanoparticles could improve the pore structure of concrete and shift the distributed pores to harmless and less-harm pores.

Tests on Alkali-Activated Slag Foamed Concrete with Various Water-Binder Ratios and Substitution Levels of Fly Ash

To provide basic data for the reasonable mixing design of the alkali-activated (AA) foamed concrete as a thermal insulation material for a floor heating system, 9 concrete mixes with a targeted dry density less than 400 kg/m3 were tested. Ground granulated blast-furnace slag (GGBS) as a source material was activated by the following two types of alkali activators: 10% Ca(OH)2 and 4% Mg(NO3)2, and 2.5% Ca(OH)2 and 6.5% Na2SiO3. The main test parameters were water-to-binder (W/B) ratio and the substitution level (RFA) of fly ash (FA) for GGBS. Test results revealed that the dry density of AA GGBS foamed concrete was independent of the W/B ratio an RFA, whereas the compressive strength increased with the decrease in W/B ratio and with the increase in RFA up to 15%, beyond which it decreased. With the increase in the W/B ratio, the amount of macro capillaries and artificial air pores increased, which resulted in the decrease of compressive strength. The magnitude of the environmental loads of the AA GGBS foamed concrete is independent of the W/B ratio and RFA. The largest reduction percentage was found in the photochemical oxidation potential, being more than 99%. The reduction percentage was 87% - 93% for the global warming potential, 81% - 84% for abiotic depletion, 79% - 84% for acidification potential, 77% - 85% for eutrophication potential, and 73% - 83% for human toxicity potential. Ultimately, this study proved that the developed AA GGBS foamed concrete has a considerable promise as a sustainable construction material for nonstructural element.

Effect of ground granulated blast-furnace slag(GGBFS) and silica fume(SF) on chloride migration through concrete subjected to repeated loading

The effect of ground granulated blast-furnace slag(GGBFS) and silica fume(SF) on the chloride migration through concrete subjected to repeated loading was examined.Portland cement was replaced by 20%,30%,40% GGBFS and 5%,10% SF,respectively.Five times repeated loadings were applied to specimens,the maximum loadings were 40% and 80% of the axial cylinder compressive strength(f′c),respectively.Chloride migration through concretes was evaluated using the rapid chloride migration test and the chloride concentration in the anode chamber was measured.The results indicate that the transport number of chloride through concrete containing 20% and 30% GGBFS replacements and 5% and 10% SF replacements is lower than that of the control concrete,but 40% GGBFS replacement increases the transport number of chloride.Five loadings at 40% f′cor 80% f′c increase the transport number of chloride for all mixes investigated in this study.5% SF replacement has a very close effect on the chloride permeability of concrete with 20% GGBFS when concrete is subjected to 40% f′cor 80% f′c.

Effects of Steel Slag Powder on Workability and Durability of Concrete

The workability and durability of a type of sustainable concrete made with steel slag powder were investigated. The hydrated products of cement paste with ground granulated blast furnace slag（GGBFS） alone or with a combined admixture of GGBFS-steel slag powder were investigated by X-ray diffraction（XRD）. Furthermore, the mechanism of chemically activated steel slag powder was also studied. The experimental results showed that when steel slag powder was added to concrete, the slumps through the same time were lower. The initial and fi nal setting times were slightly retarded. The dry shrinkages were lower, and the abrasion resistance was better. The chemically activated steel slag powder could improve compressive strengths, resistance to chloride permeation and water permeation, as well as carbonization resistance. XRD patterns indicated that the activators enhanced the formation of calcium silicate hydrate（C-S-H） gel and ettringite（AFt）. This research contributes to sustainable disposal of wastes and has the potential to provide several important environmental benefi ts.

Properties and Mechanism on Flexural Fatigue of Polypropylene Fiber Reinforced Concrete Containing Slag

Properties and mechanism were investigated on flexural fatigue of concrete containing polypropylene fibers and ground granulated blast furnace slag（GGBFS）.Four polypropylene fibers’volume fractions and five slag proportions were considered.An experiment was conducted to obtain the fatigue lives at three stress levels in 20 Hz frequency and at a constant stress level of 0.59 in four frequency respectively.Mechanism and evaluation were investigated based on the experimental data.Fatigue life span models were established.The results show that the addition of polypropylene fibers improves the flexural fatigue cumulative strength and fatigue life span.It is proposed that the slag particles and hydrated products improve Interfacial Transition Zone（ITZ）structure and benefit flexural fatigue performance.A composite reinforce effect is found with the incorporation of slag and polypropylene fibers.The optimum mixture contents 55%slag with 0.6%polypropylene fiber for the cumulative fatigue stress.Fatigue properties are decreased as the stress level increasing,the higher frequency reduces the fatigue strength more than lower frequency at a constant stress level.

Setting and Strength Characteristics of Alkali-activated Carbonatite Cementitious Materials with Ground Slag Replacement

The effect of the ground granulated blast-furnace slag （ GGBFS ） addition, the modulus n （ mole rutio of SiO2 to Na2O ） and the concentrution of sodium silicate solution on the compressive strength of the material, i e alkuli-activated carbonatite cemeutitious material （ AACCM for short ） was investiguted. In addition, it is found that barium chloride has a sutisfiwtory retarding effect on the setting of AACCM in which more than 20% （ by mass ） ground carbonatite was replaced by GGBFS. As a result, a cementitious material, in which ground carbonatite rock served as dominative starting material, with 3-day and 28-day compressive strength greuter them 30 MPa and 60 MPa and with continuous strength gain beyond 90 days was obtained.

APPLICATION OF SLAG HIGH PERFORMANCE CONCRETE (SHPC) IN A CAR PARKING BUILDING

Using ground granulated blast furnace slag as the active stuff of high performance concrete (HPC), the C60 SHPC was prepared. The behaviour of the C60 SHPC and its application in the Car Parking Building of Beijing Capital International Airport were described. Also, the manufacturing techniques of reducing cement consumption, lowering hydration heat, minimizing shrinkage cracks and improving durability of the C60 SHPC were discussed. (Author abstract) 3 Refs.

Evaluating Simultaneous Impact of Slag and Tire Rubber Powder on Mechanical Characteristics and Durability of Concrete

In this experimental study,the impact of Portland cement replacement by ground granulated blast furnace slag(GGBFS)and micronized rubber powder(MRP)on the compressive,flexural,tensile strengths,and rapid chloride migration test(RCMT)of concrete were assessed.In this study,samples with different binder content and water to binder ratios,including the MRP with the substitution levels of 0%,2.5%and 5%,and the GGBFS with the substitution ratios of 0%,20%and 40%by weight of Portland cement were made.According to the results,in the samples containing slag and rubber powder in the early ages,on average,a 12.2%decrease in the mechanical characteristics of concrete was observed,nonetheless with raising the age of the samples,the impact of slag on reducing the porosity of concrete lowered the negative impact of rubber powder.Regarding durability characteristics,the RCMT results of the samples were enhanced by using rubber powder because of its insulation impact.Moreover,adding slag into the MRP-included mixtures results in a 23%reduction in the migration rate of the chloride ion averagely.At last,four mathematical statements were derived for the mechanical and durability of concrete containing the MRP and GGBFS utilizing the genetic programming method.

Dry Mix Slag—High-Calcium Fly Ash Binder. Part Two: Durability

This work investigates durability of cement-free mortars with a binder comprised of ground granulated blast furnace slag (GGBFS) activated by high-calcium fly ash (HCFA) and sodium carbonate (Na2CO3): the soundness, sulfate resistance, alkali-silica reactivity and efflorescence factors are considered. Results of tests show that such mortars are resistant to alkali-silica expansion. Mortars are also sulfate-resistant when the amount of HCFA in the complex binder is within a limit of 10 wt%. The fineness of fly ash determines its’ ability to activate GGBFS hydration, and influence soundness of the binder, early strength development, sulfate resistance and efflorescence behavior. The present article is a continuation of authors’ work, previously published in MSA, Vol. 14, 240-254.

碱激发高炉矿渣固化/稳定化Cr(Ⅵ)污染土试验研究

碱激发高炉矿渣(GGBFS)替代水泥(PC)用于污染土固化处置,具有能耗低、碳排放少的特点,同时GGBFS中含的还原性硫可以将铬(Cr)从六价还原成三价,从而显著提高固化/稳定化效率。使用碱激发GGBFS固化/稳定化总Cr含量2000mg/kg(其中Cr(Ⅵ)1210mg/kg)的污染土,并与PC固化进行对比。通过浸出毒性、固定效率和无侧限抗压强度分析处理效果,借助pH、还原效率、化学形态、矿物成分和微观图像分析揭示了相关机理。结果表明,GGBFS固化污染土的Cr浸出浓度明显低于PC固化土,GGBFS掺量20%,养护龄期28 d时总Cr和Cr(Ⅵ)浸出浓度分别降至2.12,1.09 mg/L,满足填埋场进场浓度限值要求,且GGBFS固化污染土的强度明显高于PC固化土;还原效率分析表明,GGBFS中的S^(2-)可以有效地将Cr(Ⅵ)还原成Cr(Ⅲ),还原效率可达96.0%,从而很大程度上避免了Cr(Ⅵ)对水化过程的抑制作用,使用GGBFS固化/稳定化该含量的Cr(Ⅵ)污染土时不需额外添加还原剂;微观分析表明,与PC相比,GGBFS固化后更多不稳定态的Cr转化成稳定形态,Cr的迁移性显著降低,同时生成了更多水化凝胶,土颗粒胶结程度更高,因此具有更好的封固效果和更高强度。该研究为GGBFS固化/稳定化Cr(Ⅵ)污染土提供了科学依据。

多元固废地聚物干粉砂浆制备与性能研究

为实现工业固废应用于实体工程中,实现废物利用、节能减排的目标,以粉煤灰、粒化高炉矿渣粉、电石渣为主要原料,在室温条件下采用固体碱激发剂制备了地聚物干粉砂浆。以原粉煤灰和细粉煤灰掺量比、矿渣掺量、电石渣掺量和碱激发剂掺量为因子设计正交试验,通过测试地聚物干粉砂浆的力学性能,得出干粉砂浆的最佳配合比;通过最优配合比制备M10等级的砂浆,并进行微观分析,揭示强度增强机理。结果表明:当原粉煤灰与细粉煤灰的比例为2∶8、粉煤灰与矿渣的掺加比例为9∶1、电石渣掺量为6%、激发剂掺量为2%时,M10等级砌筑砂浆的7 d抗压强度为11.9 MPa,28 d抗压强度达到15.9 MPa,保水性和稠度均符合现行规范要求。结合SEM分析表明,地聚物砂浆中生成大量C–(A)–S–H和N–A–S–H凝胶产物,促使样品结构紧密、砂浆强度显著提升。