A simple semi-empirical analysis method for predicting the group effect of pile group under dragload embedded in clay was described assuming an effective influence area around various locations of pile group. Various ...A simple semi-empirical analysis method for predicting the group effect of pile group under dragload embedded in clay was described assuming an effective influence area around various locations of pile group. Various pile and soil parameters such as the array of pile group, spacing of the piles (S), embedment length to diameter ratio of piles (L/D) and the soil properties such as density (γ), angle of internal friction (φ) and pile-soil interface friction coefficient (μ) were considered in the analysis. Model test for dragload of pile group on viscosity soil layer under surface load consolidation conditions was studied. The variations of dragload of pile, resistance of pile tip and the layered settlement of soil with consolidation time were measured. In order to perform comparative analysis, single pile was tested in the same conditions. The predicted group effect values of pile group under dragload were then compared with model test results carried out as a part of the present investigation and also with the values reported in literatures. The predicted values were found to be in good agreement with the measured values, validating the developed analysis method. The model test results show that negative skin friction of pile shaft will reach 80%-90% of its maximum value, when pile-soil relative displacement reaches 2 mm.展开更多
In this work, we focus on assessing the group effect of localized corrosion on the ultimate strength of the marine structural plates and study the load-deformation behaviors of plates of various slenderness and uniaxi...In this work, we focus on assessing the group effect of localized corrosion on the ultimate strength of the marine structural plates and study the load-deformation behaviors of plates of various slenderness and uniaxial compression.Meanwhile, we investigate different corroded patterns from a single circular pit to 25 circular pits distributed over the plate and carry out hundreds of nonlinear finite element simulations by combining the number, depth, distribution of pits with imperfections and slenderness of plate. The distribution of multiple pits causes scattering of stress concentration on the plate, then the plastic section of plate changes with wider distribution of damage simultaneously. The ultimate strength arises when un-loading zone comprised of the yielding strips and holes extends across the plate. It can be concluded that the corroded condition defined as group effect of pits manipulates the deformation state and the loading capacity of plate at the ultimate strength mode that coincides with the proportion of effective loading area and section in the process of post-buckling. To validate the effect of pits group, we perform the numerical experiments of the post-buckling of steel plates containing pits in a row with different orientation.展开更多
As a novel type of foundation in beach and shallow sea, the bucket structure is especially suitable for complex conditions such as soft clay ground and the worse types of sea environments. In this paper, the bearing c...As a novel type of foundation in beach and shallow sea, the bucket structure is especially suitable for complex conditions such as soft clay ground and the worse types of sea environments. In this paper, the bearing capacity of a multi-bucket structure is studied by experiments with a single bucket and four-bucket foundation in a saturated sand layer. Based on the experimental data and numerical analysis results, the bearing capacity behavior and the bucket group effect are compared and analyzed. Furthermore, some influential factors, such as the soil type, the ratio of length to diameter L/D, the ratio of the bucket spacing to the bucket diameter S/D, and the bucket number are introduced and their effects on the multi-bucket structural capacity are investigated. The vertical static capacity adjustment factor is introduced to evaluate the bucket group effects of the multi-bucket foundation.展开更多
The interfacial defects and energy barrier are main reasons for interfacial nonradiative recombination.In addition,poor perovskite crystallization and incomplete conversion of PbI_(2) to perovskite restrict further en...The interfacial defects and energy barrier are main reasons for interfacial nonradiative recombination.In addition,poor perovskite crystallization and incomplete conversion of PbI_(2) to perovskite restrict further enhancement of the photovoltaic performance of the devices using sequential deposition.Herein,a buried interface stabilization strategy that relies on the synergy of fluorine(F)and sulfonyl(S=O)functional groups is proposed.A series of potassium salts containing halide and non-halogen anions are employed to modify SnO_(2)/perovskite buried interface.Multiple chemical bonds including hydrogen bond,coordination bond and ionic bond are realized,which strengthens interfacial contact and defect passivation effect.The chemical interaction between modification molecules and perovskite along with SnO_(2) heightens incessantly as the number of S=O and F augments.The chemical interaction strength between modifiers and perovskite as well as SnO_(2) gradually increases with the increase in the number of S=O and F.The defect passivation effect is positively correlated with the chemical interaction strength.The crystallization kinetics is regulated through the compromise between chemical interaction strength and wettability of substrates.Compared with Cl−,all non-halogen anions perform better in crystallization optimization,energy band regulation and defect passivation.The device with potassium bis(fluorosulfonyl)imide achieves a tempting efficiency of 24.17%.展开更多
The European Union(EU) and Organisation for Economic Co-operation and Development(OECD) aim to develop long-term policies for their respective member countries. Having observed increasing dangers to the environment po...The European Union(EU) and Organisation for Economic Co-operation and Development(OECD) aim to develop long-term policies for their respective member countries. Having observed increasing dangers to the environment posed by rising economic growth, they are seeking pathways to enable policy action on economic growth and environmental sustainability. Given the facts in theoretical and empirical studies, this study assessed the validity of the decoupling hypothesis by investigating asymmetricity in the relationship between environmental sustainability and economic growth in nine Eastern European countries from 1998 to 2017 using the cross-section augmented Dickey-Fuller(CADF) unit root, panel corrected standard error(PCSE), common correlated effect mean group(CCEMG), and Dumitrescu Hurlin causality approaches. Both population growth and drinking water are used as controlled variables. The outcomes establish strong cointegration among all the variables of interest. According to the results of CCEMG test, economic growth exerts short-term environmental degradation but has long-term environmental benefits in Eastern Europe;and population growth and drinking water exert a positive effect on environmental sustainability in both the short-and long-run. The results of Dumitrescu Hurlin causality test indicate that environmental sustainability is unidirectionally affected by economic growth. Based on these outcomes, we suggest the following policies:(1) the EU and OECD should implement member-targeted policies on economic growth and fossil-fuel use towards regulating industrial pollution, water use, and population control;and(2) the EU and OECD member countries should invest in environmental technologies through green research and development(R&D) to transform their dirty industrial processes and ensure productive energy use.展开更多
This paper aims to study the mathematical properties of the l vmodels that employ measurement matrices with correlated columns.We first show that the l_(1-2)model satisfies the grouping effect which ensures that coeff...This paper aims to study the mathematical properties of the l vmodels that employ measurement matrices with correlated columns.We first show that the l_(1-2)model satisfies the grouping effect which ensures that coefficients corresponding to highly correlated columns in a measurement matrix have small differences.Then we provide the stability analysis based on the sparse approximation property.When the entries of the vectors have different signs,we show that the grouping effect also holds for the constraint l_(1-2)minimization model which is implicated by the linearized Bregman iteration.展开更多
This is a case research on group work and the aim is to investigate the effectiveness of group work in English teaching in English major of Zhejiang Guangsha College of Applied Construction Technology(ZGC).By carrying...This is a case research on group work and the aim is to investigate the effectiveness of group work in English teaching in English major of Zhejiang Guangsha College of Applied Construction Technology(ZGC).By carrying out a 15-week experiment on 08 Applied English Class 1 and 2,questionnaires on 08 Business English Class 1-5(213 students),and interviews on 22 teachers of English major,the research results show and prove that group work is often performed in ZGC and group work is quite effective in English teaching.展开更多
This paper aims to present a theoretical method to study the bearing performance of vertically loaded large-diameter pipe pile groups.The interactions between group piles result in different bearing performance of bot...This paper aims to present a theoretical method to study the bearing performance of vertically loaded large-diameter pipe pile groups.The interactions between group piles result in different bearing performance of both a single pile and pile groups.Considering the pile group effect and the skin friction from both outer and inner soils,an analytical solution is developed to calculate the settlement and axial force in large-diameter pipe pile groups.The analytical solution was verified by centrifuge and field testing results.An extensive parametric analysis was performed to study the bearing performance of the pipe pile groups.The results reveal that the axial forces in group piles are not the same.The larger the distance from central pile,the larger the axial force.The axial force in the central pile is the smallest,while that in corner piles is the largest.The axial force on the top of the corner piles decreases while that in the central pile increases with increasing of pile spacing and decreasing of pile length.The axial force in side piles varies little with the variations of pile spacing,pile length,and shear modulus of the soil and is approximately equal to the average load shared by one pile.For a pile group,the larger the pile length is,the larger the influence radius is.As a result,the pile group effect is more apparent for a larger pile length.The settlement of pile groups decreases with increasing of the pile number in the group and the shear modulus of the underlying soil.展开更多
How to rationally design effective and practical CO_2 adsorbent is a great challenge. Herein, an ultra-microporous metal-organic framework(FJI-H19) with high concentration of free carboxyl groups and uncoordinated Lew...How to rationally design effective and practical CO_2 adsorbent is a great challenge. Herein, an ultra-microporous metal-organic framework(FJI-H19) with high concentration of free carboxyl groups and uncoordinated Lewis basic sites has been synthesized from a multi-dental ligand with a high proportion of polar CO_2-philic atoms. FJI-H19 displays a relatively high CO_2 volumetric uptake(120 cm^3?cm^(–3)) with high selectivity under practical atmosphere(298 K and 1 bar). Further researches demonstrate that such high adsorption results from an unusual synergistic effect from free carboxyl group and uncoordinated N atoms. This result will provide a potential strategy for developing more effective and pratical CO_2 adsorbent based on MOFs.展开更多
A new approach was proposed for grouping separation of 14 lanthanide rare-earth ions from their coexisting mixed aqueous solutions, by performing liquid-column elution using the aqueous solution containing 14 lanthani...A new approach was proposed for grouping separation of 14 lanthanide rare-earth ions from their coexisting mixed aqueous solutions, by performing liquid-column elution using the aqueous solution containing 14 lanthanide rare-earth ions as the stationary phase and the dispersed organic oil droplets containing P507 extractant as the mobile phase. It was revealed that 14 lanthanide rare-earth ions could be separated into four groups, according to the lanthanide tetrad effect, respectively eluting out from the liquid column at different time in a certain order. Various effects including the saponification degree of P507, the concentration of P507 in organic phase, the length and inner diameter of the extraction column on the performance of grouping separation of rare-earth ions were discussed. The changes of the mass transfer coefficients were also investigated. The separation efficiency of the four groups of rareearth elements(REEs) was evaluated based on the elution resolution, Rs, of the elution peaks of La(Ⅲ),Gd(Ⅲ), Ho(Ⅲ) and Lu(Ⅲ), the four representative elements respectively from each of the four groups of REEs. Experimental results demonstrated that the separation of REEs by liquid-column elution mainly depended on the competitive adsorption of different rare-earth groups onto the surface of ascending P507 oil droplets. The affinity of different rare-earth groups with P507 extractant and a limited adsorption capacity of P507 molecules at the surface of the oil droplets ascending in liquid column play the important role. The present work highlights a promising technique for grouping separation of multiple lanthanide elements co-existing complex systems.展开更多
AlCl3-mediated cleavage of ethereal methyl–oxygen bond in aroylated 2,7-dimethoxynaphthalene compounds proceeds chemospecifically and regioselectively. The ethereal bond at the β(2)-position of 1-monoaroylated 2,7-d...AlCl3-mediated cleavage of ethereal methyl–oxygen bond in aroylated 2,7-dimethoxynaphthalene compounds proceeds chemospecifically and regioselectively. The ethereal bond at the β(2)-position of 1-monoaroylated 2,7-dimethoxynaphthalene is cleaved readily and predominantly against the β(7)-position, whereas scission of β-ethereal bonds of 1,8-diaroylated 2,7-dimethoxynaphthalene hardly undergoes like the non-aroylated mother frame compound of 2,7-dimethoxynaphthalene.展开更多
High mobility group box 1 protein (HMGB1) is a highly conserved, ubiquitous protein in the nuclei and cytoplasm of nearly all cell types. HMGB1 is secreted into the extracellular milieu and acts as a proinflammatory...High mobility group box 1 protein (HMGB1) is a highly conserved, ubiquitous protein in the nuclei and cytoplasm of nearly all cell types. HMGB1 is secreted into the extracellular milieu and acts as a proinflammatory cytokine. In this article we reviewed briefly the cellular immune response mediated by HMGB1 in inflammation and sepsis. This systemic review is mainly based on our own work and other related reports HMGB1 can actively affect the immune functions of many types of cells including T lymphocytes, regulatory T cells (Tregs), dendritic cells (DCs), macrophages, and natural killer cells (NK cells). Various cellular responses can be mediated by HMGB1 which binds to cell-surface receptors [e.g., the receptor for advanced glycation end products (RAGE), Toll-like receptor (TLR)2, and TLR4]. Anti-HMGB1 treatment, such as anti-HMGB1 polyclonal or monoclonal antibodies, inhibitors (e.g., ethyl pyruvate) and antagonists (e.g., A box), can protect against sepsis lethality and give a wider window for the treatment opportunity. HMGB1 is an attractive target for the development of new therapeutic strategies in the treatment of patients with septic complications.展开更多
We have calculated the transport properties of electron through an artificial quantum dot by using the numerical renormalization group technique in this paper. We obtain the conductance for the system of a quantum dot...We have calculated the transport properties of electron through an artificial quantum dot by using the numerical renormalization group technique in this paper. We obtain the conductance for the system of a quantum dot which is embedded in a one-dimensional chain in zero and finite temperature cases. The external magnetic field gives rise to a negative magnetoconductance in the zero temperature case. It increases as the external magnetic field increases, We obtain the relation between the coupling coefficient and conductance. If the interaction is big enough to prevent conduction electrons from tunnelling through the dot, the dispersion effect is dominant in this case. In the Kondo temperature regime, we obtain the conductivity of a quantum dot system with Kondo correlation.展开更多
In the present paper two contents are enclosed .First ,the Fourier analysis approach of the dispersion relation and group velocity effect of finite difference schemes is discussed.the defects of the approach is pointe...In the present paper two contents are enclosed .First ,the Fourier analysis approach of the dispersion relation and group velocity effect of finite difference schemes is discussed.the defects of the approach is pointed out and the correction is made;Second,a new systematic analysis method -remaider -effect analysis (abbr.REAM)is proposed by means of the modified partial differential equations (abbr MPDE)of finite difference schemes.The analysis is based on the synthetical study of the rational dispersion-and dissipation relations of finite difference schemes.And the method clearly possesses constructivity展开更多
Researches show that multilayer optical thin film stack can exhibit superprism effect due to their large abnormal dispersions. We investigated and simulated this effect numerically in a 1-D non-periodic film structure...Researches show that multilayer optical thin film stack can exhibit superprism effect due to their large abnormal dispersions. We investigated and simulated this effect numerically in a 1-D non-periodic film structure-Fabry-Perot filters (FPF), which possess drastic change in phase and large group delay around wavelength of peak transmittance, and fabricated this device to realize remarkable superprism effect. We tested experimentally with the maximum spatial separation shift up to 65 μm, and the experimental result is in good agreement with the theory. Compared with the traditional prism, the total thickness of our structure is only 3.3 μm, and our prism shows a stronger angular resolution of 1.8°/nm.展开更多
Accurate and reliable nuclear data libraries are essential for calculation and design of advanced nuclea systems. A 1200 fine group nuclear data library Hybrid Evaluated Nuclear Data Library/Fine Group(HENDL/FG with n...Accurate and reliable nuclear data libraries are essential for calculation and design of advanced nuclea systems. A 1200 fine group nuclear data library Hybrid Evaluated Nuclear Data Library/Fine Group(HENDL/FG with neutrons of up to 150 Me V has been developed to improve the accuracy of neutronics calculations and anal ysis. Corrections of Doppler, resonance self-shielding, and thermal upscatter effects were done for HENDL/FG Shielding and critical safety benchmarks were performed to test the accuracy and reliability of the library. The dis crepancy between calculated and measured nuclea parameters fell into a reasonable range.展开更多
Municipal institutions operate in all sectors of the urban economy, creating jobs, providing services, and creating income for their own development and the municipal budget. Market environment and innovative vector o...Municipal institutions operate in all sectors of the urban economy, creating jobs, providing services, and creating income for their own development and the municipal budget. Market environment and innovative vector of megapolis development include the establishment municipal institutions and improve the forms of their activities. One of the strategic objectives for the government is to increase the effectiveness of municipal institutions. Problems integrated estimation of these institutions are under intense scrutiny of statistical science in management decisions. This paper discussed the problems of effectiveness estimation of municipal institutions and proposed a new approach to solving this task.展开更多
基金Project(50679015) supported by the National Natural Science Foundation of China
文摘A simple semi-empirical analysis method for predicting the group effect of pile group under dragload embedded in clay was described assuming an effective influence area around various locations of pile group. Various pile and soil parameters such as the array of pile group, spacing of the piles (S), embedment length to diameter ratio of piles (L/D) and the soil properties such as density (γ), angle of internal friction (φ) and pile-soil interface friction coefficient (μ) were considered in the analysis. Model test for dragload of pile group on viscosity soil layer under surface load consolidation conditions was studied. The variations of dragload of pile, resistance of pile tip and the layered settlement of soil with consolidation time were measured. In order to perform comparative analysis, single pile was tested in the same conditions. The predicted group effect values of pile group under dragload were then compared with model test results carried out as a part of the present investigation and also with the values reported in literatures. The predicted values were found to be in good agreement with the measured values, validating the developed analysis method. The model test results show that negative skin friction of pile shaft will reach 80%-90% of its maximum value, when pile-soil relative displacement reaches 2 mm.
基金financially supported by the National Natural Science Foundation of China(Grant Nos.51490670 and 11572300)R&D Plan(Grant No.2017GHY15120)Fundamental Research Fund for Central Universities(Ocean University of China)
文摘In this work, we focus on assessing the group effect of localized corrosion on the ultimate strength of the marine structural plates and study the load-deformation behaviors of plates of various slenderness and uniaxial compression.Meanwhile, we investigate different corroded patterns from a single circular pit to 25 circular pits distributed over the plate and carry out hundreds of nonlinear finite element simulations by combining the number, depth, distribution of pits with imperfections and slenderness of plate. The distribution of multiple pits causes scattering of stress concentration on the plate, then the plastic section of plate changes with wider distribution of damage simultaneously. The ultimate strength arises when un-loading zone comprised of the yielding strips and holes extends across the plate. It can be concluded that the corroded condition defined as group effect of pits manipulates the deformation state and the loading capacity of plate at the ultimate strength mode that coincides with the proportion of effective loading area and section in the process of post-buckling. To validate the effect of pits group, we perform the numerical experiments of the post-buckling of steel plates containing pits in a row with different orientation.
文摘As a novel type of foundation in beach and shallow sea, the bucket structure is especially suitable for complex conditions such as soft clay ground and the worse types of sea environments. In this paper, the bearing capacity of a multi-bucket structure is studied by experiments with a single bucket and four-bucket foundation in a saturated sand layer. Based on the experimental data and numerical analysis results, the bearing capacity behavior and the bucket group effect are compared and analyzed. Furthermore, some influential factors, such as the soil type, the ratio of length to diameter L/D, the ratio of the bucket spacing to the bucket diameter S/D, and the bucket number are introduced and their effects on the multi-bucket structural capacity are investigated. The vertical static capacity adjustment factor is introduced to evaluate the bucket group effects of the multi-bucket foundation.
基金supported by the Defense Industrial Technology Development Program(JCKY2017110C0654)National Natural Science Foundation of China(11974063,61904023,62274018)+1 种基金Chongqing Special Postdoctoral Science Foundation(cstc2019jcyj-bsh0026)Fundamental Research Funds for the Central Universities(2021CDJQY-022).
文摘The interfacial defects and energy barrier are main reasons for interfacial nonradiative recombination.In addition,poor perovskite crystallization and incomplete conversion of PbI_(2) to perovskite restrict further enhancement of the photovoltaic performance of the devices using sequential deposition.Herein,a buried interface stabilization strategy that relies on the synergy of fluorine(F)and sulfonyl(S=O)functional groups is proposed.A series of potassium salts containing halide and non-halogen anions are employed to modify SnO_(2)/perovskite buried interface.Multiple chemical bonds including hydrogen bond,coordination bond and ionic bond are realized,which strengthens interfacial contact and defect passivation effect.The chemical interaction between modification molecules and perovskite along with SnO_(2) heightens incessantly as the number of S=O and F augments.The chemical interaction strength between modifiers and perovskite as well as SnO_(2) gradually increases with the increase in the number of S=O and F.The defect passivation effect is positively correlated with the chemical interaction strength.The crystallization kinetics is regulated through the compromise between chemical interaction strength and wettability of substrates.Compared with Cl−,all non-halogen anions perform better in crystallization optimization,energy band regulation and defect passivation.The device with potassium bis(fluorosulfonyl)imide achieves a tempting efficiency of 24.17%.
文摘The European Union(EU) and Organisation for Economic Co-operation and Development(OECD) aim to develop long-term policies for their respective member countries. Having observed increasing dangers to the environment posed by rising economic growth, they are seeking pathways to enable policy action on economic growth and environmental sustainability. Given the facts in theoretical and empirical studies, this study assessed the validity of the decoupling hypothesis by investigating asymmetricity in the relationship between environmental sustainability and economic growth in nine Eastern European countries from 1998 to 2017 using the cross-section augmented Dickey-Fuller(CADF) unit root, panel corrected standard error(PCSE), common correlated effect mean group(CCEMG), and Dumitrescu Hurlin causality approaches. Both population growth and drinking water are used as controlled variables. The outcomes establish strong cointegration among all the variables of interest. According to the results of CCEMG test, economic growth exerts short-term environmental degradation but has long-term environmental benefits in Eastern Europe;and population growth and drinking water exert a positive effect on environmental sustainability in both the short-and long-run. The results of Dumitrescu Hurlin causality test indicate that environmental sustainability is unidirectionally affected by economic growth. Based on these outcomes, we suggest the following policies:(1) the EU and OECD should implement member-targeted policies on economic growth and fossil-fuel use towards regulating industrial pollution, water use, and population control;and(2) the EU and OECD member countries should invest in environmental technologies through green research and development(R&D) to transform their dirty industrial processes and ensure productive energy use.
基金supported by the Zhejiang Provincial Natural Science Foundation of China(LR19A010001)the NSF of China(12022112)Research of Hu Ruifang was supported by the general research project of Jiaxing Nanhu University(62107YL)。
文摘This paper aims to study the mathematical properties of the l vmodels that employ measurement matrices with correlated columns.We first show that the l_(1-2)model satisfies the grouping effect which ensures that coefficients corresponding to highly correlated columns in a measurement matrix have small differences.Then we provide the stability analysis based on the sparse approximation property.When the entries of the vectors have different signs,we show that the grouping effect also holds for the constraint l_(1-2)minimization model which is implicated by the linearized Bregman iteration.
文摘This is a case research on group work and the aim is to investigate the effectiveness of group work in English teaching in English major of Zhejiang Guangsha College of Applied Construction Technology(ZGC).By carrying out a 15-week experiment on 08 Applied English Class 1 and 2,questionnaires on 08 Business English Class 1-5(213 students),and interviews on 22 teachers of English major,the research results show and prove that group work is often performed in ZGC and group work is quite effective in English teaching.
基金supported by the Joint High Speed Railway Key Program of National Natural Science Foundation of China (Grant No.U1134207)the National Natural Science Foundation of China (Grant No.51378177)+1 种基金the Program for Excellent University Talents in New Century (Grant No.NCET-12-0843)the Fundamental Research Fund for the Central Universities (Grant No.106112014CDJZR200007)
文摘This paper aims to present a theoretical method to study the bearing performance of vertically loaded large-diameter pipe pile groups.The interactions between group piles result in different bearing performance of both a single pile and pile groups.Considering the pile group effect and the skin friction from both outer and inner soils,an analytical solution is developed to calculate the settlement and axial force in large-diameter pipe pile groups.The analytical solution was verified by centrifuge and field testing results.An extensive parametric analysis was performed to study the bearing performance of the pipe pile groups.The results reveal that the axial forces in group piles are not the same.The larger the distance from central pile,the larger the axial force.The axial force in the central pile is the smallest,while that in corner piles is the largest.The axial force on the top of the corner piles decreases while that in the central pile increases with increasing of pile spacing and decreasing of pile length.The axial force in side piles varies little with the variations of pile spacing,pile length,and shear modulus of the soil and is approximately equal to the average load shared by one pile.For a pile group,the larger the pile length is,the larger the influence radius is.As a result,the pile group effect is more apparent for a larger pile length.The settlement of pile groups decreases with increasing of the pile number in the group and the shear modulus of the underlying soil.
基金supported by the National Natural Science Foundation of China(21390392,21471148)the Youth Innovation Promotion Association CAS
文摘How to rationally design effective and practical CO_2 adsorbent is a great challenge. Herein, an ultra-microporous metal-organic framework(FJI-H19) with high concentration of free carboxyl groups and uncoordinated Lewis basic sites has been synthesized from a multi-dental ligand with a high proportion of polar CO_2-philic atoms. FJI-H19 displays a relatively high CO_2 volumetric uptake(120 cm^3?cm^(–3)) with high selectivity under practical atmosphere(298 K and 1 bar). Further researches demonstrate that such high adsorption results from an unusual synergistic effect from free carboxyl group and uncoordinated N atoms. This result will provide a potential strategy for developing more effective and pratical CO_2 adsorbent based on MOFs.
基金Supported by the National Natural Science Foundation of China(51574213,51074150)the Key Project of Chinese National Programs for Fundamental Research and Development(2012CBA01203)
文摘A new approach was proposed for grouping separation of 14 lanthanide rare-earth ions from their coexisting mixed aqueous solutions, by performing liquid-column elution using the aqueous solution containing 14 lanthanide rare-earth ions as the stationary phase and the dispersed organic oil droplets containing P507 extractant as the mobile phase. It was revealed that 14 lanthanide rare-earth ions could be separated into four groups, according to the lanthanide tetrad effect, respectively eluting out from the liquid column at different time in a certain order. Various effects including the saponification degree of P507, the concentration of P507 in organic phase, the length and inner diameter of the extraction column on the performance of grouping separation of rare-earth ions were discussed. The changes of the mass transfer coefficients were also investigated. The separation efficiency of the four groups of rareearth elements(REEs) was evaluated based on the elution resolution, Rs, of the elution peaks of La(Ⅲ),Gd(Ⅲ), Ho(Ⅲ) and Lu(Ⅲ), the four representative elements respectively from each of the four groups of REEs. Experimental results demonstrated that the separation of REEs by liquid-column elution mainly depended on the competitive adsorption of different rare-earth groups onto the surface of ascending P507 oil droplets. The affinity of different rare-earth groups with P507 extractant and a limited adsorption capacity of P507 molecules at the surface of the oil droplets ascending in liquid column play the important role. The present work highlights a promising technique for grouping separation of multiple lanthanide elements co-existing complex systems.
文摘AlCl3-mediated cleavage of ethereal methyl–oxygen bond in aroylated 2,7-dimethoxynaphthalene compounds proceeds chemospecifically and regioselectively. The ethereal bond at the β(2)-position of 1-monoaroylated 2,7-dimethoxynaphthalene is cleaved readily and predominantly against the β(7)-position, whereas scission of β-ethereal bonds of 1,8-diaroylated 2,7-dimethoxynaphthalene hardly undergoes like the non-aroylated mother frame compound of 2,7-dimethoxynaphthalene.
基金supported,in part,by grants from the National Natural Science Foundation(Nos.81130035,30901561,30971192,81071545)the National Basic Research Program of China(No.2012CB518102)the China Postdoctoral Science Foundation(Nos.20100480347,201104125)
文摘High mobility group box 1 protein (HMGB1) is a highly conserved, ubiquitous protein in the nuclei and cytoplasm of nearly all cell types. HMGB1 is secreted into the extracellular milieu and acts as a proinflammatory cytokine. In this article we reviewed briefly the cellular immune response mediated by HMGB1 in inflammation and sepsis. This systemic review is mainly based on our own work and other related reports HMGB1 can actively affect the immune functions of many types of cells including T lymphocytes, regulatory T cells (Tregs), dendritic cells (DCs), macrophages, and natural killer cells (NK cells). Various cellular responses can be mediated by HMGB1 which binds to cell-surface receptors [e.g., the receptor for advanced glycation end products (RAGE), Toll-like receptor (TLR)2, and TLR4]. Anti-HMGB1 treatment, such as anti-HMGB1 polyclonal or monoclonal antibodies, inhibitors (e.g., ethyl pyruvate) and antagonists (e.g., A box), can protect against sepsis lethality and give a wider window for the treatment opportunity. HMGB1 is an attractive target for the development of new therapeutic strategies in the treatment of patients with septic complications.
基金Project supported by the National Natural Science Foundation of China (Grant Nos 10074029 and 60276005), and by the State Key Development Program for Basic Research of China (Grant No G1999064509).
文摘We have calculated the transport properties of electron through an artificial quantum dot by using the numerical renormalization group technique in this paper. We obtain the conductance for the system of a quantum dot which is embedded in a one-dimensional chain in zero and finite temperature cases. The external magnetic field gives rise to a negative magnetoconductance in the zero temperature case. It increases as the external magnetic field increases, We obtain the relation between the coupling coefficient and conductance. If the interaction is big enough to prevent conduction electrons from tunnelling through the dot, the dispersion effect is dominant in this case. In the Kondo temperature regime, we obtain the conductivity of a quantum dot system with Kondo correlation.
文摘In the present paper two contents are enclosed .First ,the Fourier analysis approach of the dispersion relation and group velocity effect of finite difference schemes is discussed.the defects of the approach is pointed out and the correction is made;Second,a new systematic analysis method -remaider -effect analysis (abbr.REAM)is proposed by means of the modified partial differential equations (abbr MPDE)of finite difference schemes.The analysis is based on the synthetical study of the rational dispersion-and dissipation relations of finite difference schemes.And the method clearly possesses constructivity
文摘Researches show that multilayer optical thin film stack can exhibit superprism effect due to their large abnormal dispersions. We investigated and simulated this effect numerically in a 1-D non-periodic film structure-Fabry-Perot filters (FPF), which possess drastic change in phase and large group delay around wavelength of peak transmittance, and fabricated this device to realize remarkable superprism effect. We tested experimentally with the maximum spatial separation shift up to 65 μm, and the experimental result is in good agreement with the theory. Compared with the traditional prism, the total thickness of our structure is only 3.3 μm, and our prism shows a stronger angular resolution of 1.8°/nm.
基金supported by the Natural Science Foundation of China(Nos.11405204 11305205 and 10675123)Special Program for Informatization of Chinese Academy of Sciences(No.XXH12504-1-09)the National Special Program for ITER(No.2014GB1120001)
文摘Accurate and reliable nuclear data libraries are essential for calculation and design of advanced nuclea systems. A 1200 fine group nuclear data library Hybrid Evaluated Nuclear Data Library/Fine Group(HENDL/FG with neutrons of up to 150 Me V has been developed to improve the accuracy of neutronics calculations and anal ysis. Corrections of Doppler, resonance self-shielding, and thermal upscatter effects were done for HENDL/FG Shielding and critical safety benchmarks were performed to test the accuracy and reliability of the library. The dis crepancy between calculated and measured nuclea parameters fell into a reasonable range.
文摘Municipal institutions operate in all sectors of the urban economy, creating jobs, providing services, and creating income for their own development and the municipal budget. Market environment and innovative vector of megapolis development include the establishment municipal institutions and improve the forms of their activities. One of the strategic objectives for the government is to increase the effectiveness of municipal institutions. Problems integrated estimation of these institutions are under intense scrutiny of statistical science in management decisions. This paper discussed the problems of effectiveness estimation of municipal institutions and proposed a new approach to solving this task.