Negative binomial regression is a powerful technique for modeling count data,particularly when dealing with overdispersion.However,estimating the parameters for large-dimensional sparse models is challenging due to th...Negative binomial regression is a powerful technique for modeling count data,particularly when dealing with overdispersion.However,estimating the parameters for large-dimensional sparse models is challenging due to the complexity of optimizing the mean and dispersion parameter of the negative binomial distribution.To address this issue,the authors propose a novel approach that employs two iterations of the majorize-minimize(MM)algorithm,one for estimating the dispersion parameter and the other for estimating the mean parameters.These approaches improve the convergence speed and stability of the algorithm.The authors also use group penalty for variable selection,which enhances the accuracy and efficiency of the algorithm.The proposed method provides an explicit solution,simplifies the iteration process,and maintains good stability while ensuring algorithm convergence.Furthermore,the authors apply the proposed algorithm to the zero-inflated model and demonstrate its promising predictive performance on specific data sets.The research has important implications for count data modeling and analysis in various fields,such as data mining,machine learning,and bioinformatics.展开更多
Network autoregression and factor model are effective methods for modeling network time series data.In this study,we propose a network autoregression model with a factor structure that incorporates a latent group stru...Network autoregression and factor model are effective methods for modeling network time series data.In this study,we propose a network autoregression model with a factor structure that incorporates a latent group structure to address nodal heterogeneity within the network.An iterative algorithm is employed to minimize a least-squares objective function,allowing for simultaneous estimation of both the parameters and the group structure.To determine the unknown number of groups and factors,a PIC criterion is introduced.Additionally,statistical inference of the estimated parameters is presented.To assess the validity of the proposed estimation and inference procedures,we conduct extensive numerical studies.We also demonstrate the utility of our model using a stock dataset obtained from the Chinese A-Share stock market.展开更多
A host of abiotic factors modify fish social behavior. However, few studies have characterized the effects of temperature on behavior. In this study, brown trout Salmo trutta fry were reared at 5 dif- ferent temperatu...A host of abiotic factors modify fish social behavior. However, few studies have characterized the effects of temperature on behavior. In this study, brown trout Salmo trutta fry were reared at 5 dif- ferent temperatures (4℃, 6℃, 8℃, 10℃, and 12℃). In order to characterize group structure, 3 be- havioral parameters were investigated: group social structure (based on inter-individual distances), inter-individual relationships (based on physical contacts), and individual activity. These behavioral parameters were studied at the emergence stage, which corresponds to a switch from a social gre- garious life in the gravel to a solitary one in the water column. Data analysis showed that the inter- individual distances increased with increasing temperature, particularly the nearest neighbor distance. The mean number of physical contacts between fry increased at both low and high tem- peratures. At high temperatures, most fry moved apart from each other after a physical contact. Swimming activity decreased at both the lower and upper temperatures (18% of activity at 4℃, 38% at 8℃, and 12% at 12℃). This study showed that temperature modifies brown trout fry activity, inter-individual relationships, and social behavior, which all affect group cohesion before emer- gence and can influence their survival and dispersal.展开更多
A subgroup H of a group G is said to be primitive if it is a proper subgroup of the intersection of all subgroups of G containing H as its proper subgroup. The purpose of this note is to go further into the influence ...A subgroup H of a group G is said to be primitive if it is a proper subgroup of the intersection of all subgroups of G containing H as its proper subgroup. The purpose of this note is to go further into the influence of primitive subgroups on the structure of finite groups. Some new results are obtained.展开更多
INTRODUCTION Group transfer polymerization (GTP) is a method for controlling the structure of acrylic polymers in which reactive chain ends are covalentiy bound to a trimethylsilyl group. In the presence of a catalyst...INTRODUCTION Group transfer polymerization (GTP) is a method for controlling the structure of acrylic polymers in which reactive chain ends are covalentiy bound to a trimethylsilyl group. In the presence of a catalyst, monomer inserts into these chain ends between the silyl group and the last monomer unit. The process is illustrated by equation (1) for methyl methacrylate. GTP is a living polymerization, i. e., there is little or no chain termination and no chain transfer. A significant advantage of GTP is that it展开更多
A novel D-π-A type α-cyanostilbenzene derivative,(Z)-2-(4-aminophenyl)-3-(4-bromophenyl)-acrylonitrile(ABAN), was designed and synthesized, by introducing an electrondonating amino group and a heavy atom. Th...A novel D-π-A type α-cyanostilbenzene derivative,(Z)-2-(4-aminophenyl)-3-(4-bromophenyl)-acrylonitrile(ABAN), was designed and synthesized, by introducing an electrondonating amino group and a heavy atom. The structure of ABAN was confirmed by FT-IR, 1H NMR, 13 C NMR spectra and single-crystal X-ray diffraction analysis. The ABAN is of orthorhombic system, space group P212121, with a = 8.6100(14), b = 9.6923(16), c = 15.705(3) , Mr = 299.17, V = 1310.6(4) 3, Z = 4, Dc = 1.516 g/cm-3, μ = 3.119 mm-1, F(000) = 600, Rint = 0.038, R(I 〉 2σ(I)) = 0.0276, w R(I 〉 2σ(I)) = 0.0628, R(all data) = 0.0324, wR(all data) = 0.0646, completeness to theta = 25.00 was 99.8% and GOOF = 1.04. In the crystal structure, ABAN molecules were linked with each other through intermolecular C–H···π interactions and N–H···N hydrogen bonds, by which the 1D chain, 2D plane and 3D stacking structures were constructed. The photophysical properties and calculation results confirmed that ABAN possessed an intramolecular charge transfer(ICT) process. ABAN could be applied into the optoelectronic material field due to good solvent-tuned photophysical properties and highly thermal stability.展开更多
Whether a decision group does its function or not directly depends on the rationality of its characters. The decision science, also with other correlation disciplines, wants to know how the group characters affect the...Whether a decision group does its function or not directly depends on the rationality of its characters. The decision science, also with other correlation disciplines, wants to know how the group characters affect the group performance. Although there are great deals of means to describe the group characters theoretically and practically, in this paper, we consider that the integrity character of a group is composed of the group scale, the constitution and the structure. So the research on how group characters affect the group performance should focus on the three aspects. In order to grasp the present research situation and clear the prospective direction of the studies, we will summarize the study on how the group characters affect the group performance from these three aspects.展开更多
In the paper [1] the upgrade of the structure of groups has been considered, in which the concept of HX group has been raised. In this paper we will discuss the direct product of HX groups and AX groups on direct prod...In the paper [1] the upgrade of the structure of groups has been considered, in which the concept of HX group has been raised. In this paper we will discuss the direct product of HX groups and AX groups on direct product group.展开更多
we have discussed structures of Abelian group G by order |A(G) |of automoorphism group and have obtained all types of finite Abelian grooup G when the order of A(G) equals 27pq(p,q are odd primmes).
[Objectives]The genetic diversity and population genetic structure of 107 inbred lines of maize in Yunnan were analyzed,in order to provide technical support for maize germplasm innovation,genetic improvement of germp...[Objectives]The genetic diversity and population genetic structure of 107 inbred lines of maize in Yunnan were analyzed,in order to provide technical support for maize germplasm innovation,genetic improvement of germplasm resources,variety management,and lay a solid foundation for exploring genes related to fine traits in the future.[Methods]The 107 maize inbred lines generalized in Yunnan were selected,and 45 backbone inbred lines commonly used in China were used as reference for heterotic group classification.On Axiom Maize 56K SNP Array platform,maize SNP chips(56K)were used to scan the whole maize genome,and the NJ-tree model of Treebest was used to construct a phylogenetic tree.Principal component analysis(PCA)was conducted by GCTA(genome-wide complex trait analysis)to reveal the genetic diversity and population genetic structure.[Results]In the 107 Yunnan local inbred lines,5533 uniformly distributed high-quality SNP marker sites were finally detected.Based on the analysis of these SNP marker sites,Nei s gene diversity index(H)of 107 maize germplasm genes was 0.2981-0.5000 with an average value being 0.4832,and polymorphism information content(PIC)values were 0.2536-0.3750 with an average value being 0.3662.The minimum allele frequency value was 0.5000-0.8178 with an average value being 0.5744.The analysis of population genetic structure showed that when K=6,the maximum value of△K was the maximum,which meant that the inbred lines used in this study could be divided into six groups.They were Tangsi Pingtou blood relationship group,PB blood relationship group,335 female blood relationship group,Zi 330 and the Lüda Honggu blood relationship group,unknown group 1 and unknown group 2.No inbred lines were divided into other heterotic groups.Among them,37 inbred lines from the 2 unknown groups could not be classified into the same group as the 10 known heterotic groups in China.The results of principal component analysis showed that the 107 maize inbred lines generalized in Yunnan could be clearly distinguished from the backbone maize inbred lines commonly used in China.Most of the maize inbred lines in Yunnan were concentrated near the reference backbone inbred lines.But some Yunnan inbred lines were far away from the reference inbred lines commonly used in China.[Conclusions]The maize germplasm resources in Yunnan area were rich in genetic diversity,including multiple heterotic groups,and there was a rich genetic basis of breeding parents.They could be clearly distinguished from the backbone inbred lines commonly used in China,and some of them had a long genetic distance from the backbone inbred lines.The resources which have good application potential can be used to create new heterotic groups.展开更多
A new boroantimonate K2SbB3O8 has been synthesized by high-temperature solidstate reactions, and its crystals have been obtained by the flux method. The crystal structure has been determined from single-crystal X-ray ...A new boroantimonate K2SbB3O8 has been synthesized by high-temperature solidstate reactions, and its crystals have been obtained by the flux method. The crystal structure has been determined from single-crystal X-ray diffraction analysis. The compound crystallizes in the monoclinic space group P21/c with a = 5.8890(2), b = 11.0512(4), c = 10.8951(4)A, β =103.200(4)°, V = 690.32(4) A^3, Z = 4, F(000) = 672, ρc = 3.467 g/cm^3, Mr = 360.38 and μ = 5.215mm^-1. Its structure feature is a three-dimensional framework composed of SbO6 octahedra and isolated [B3O8]^7- groups with K+ cations residing in the one-dimensional tunnels along the a-axis.Interestingly, the isolated [B3O8]^7- groups are distinct from the known [B3O8]^7- groups, which always connect to each other. The UV-vis-NIR absorption, thermal stability and infrared spectrum are also discussed in this paper.展开更多
With the support by the National Natural Science Foundation of China,a collaboration by the research groups led by Prof.Cheng Gang(程纲)from Henan University and Prof.Wang Zhonglin(王中林)from Beijing Institute of Nan...With the support by the National Natural Science Foundation of China,a collaboration by the research groups led by Prof.Cheng Gang(程纲)from Henan University and Prof.Wang Zhonglin(王中林)from Beijing Institute of Nanoenergy and Nanosystems,Chinese Academy of Sciences,invents'a sliding-mode triboelectric nanogenerator with chemical group grated structure by shadow mask reactive ion etching',which was published in ACS Nano(2017,11(9):8796-8803).展开更多
The mechanism of 2-cyanopyrazine prepared from 2-methylpyrazine (2-MP) by catalytic ammoxidation has been explained by the theory of appropriate structure of group. A new catalyst of MoVPO was developed. The effects...The mechanism of 2-cyanopyrazine prepared from 2-methylpyrazine (2-MP) by catalytic ammoxidation has been explained by the theory of appropriate structure of group. A new catalyst of MoVPO was developed. The effects of catalyst promoter phosphorus and supports were investigated. The catalyst containing P, V and Mo in molar ratio of 1.4 : 1 : 0.02 and supported on activated alumina and prepared by impregnation method exhibits good activity and selectivity. Reaction factors such as reaction temperature, space velocity, feed composition and service life of catalyst were investigated. Optimum reaction conditions (the volume space velocity of 0.2h-1, the reaction temperature of 380 ~C and molar ratio of 1 : 7.8 : 8 : 8 for 2-MP, water, oxygen and ammonia) were obtained. Selectivity of 93% and yield of 86% could be achieved under these conditions.展开更多
Let G be a finite group and π be a set of primes including at least two elements. We write cd(G) and cs(G) to denote the set of complex irreducible character degrees and conjugacy class sizes of G , respectively,...Let G be a finite group and π be a set of primes including at least two elements. We write cd(G) and cs(G) to denote the set of complex irreducible character degrees and conjugacy class sizes of G , respectively, and write π(m)to denote the set of all prime divisors of a positive integer m . For any 1≠m∈cd(G) and 1≠m∈cs(G), in this note, we shall present the corresponding group structures of finite group G in the case π(m)=π , respectively, which generalizes the result of finite groups with character degrees of two distinct primes. Furthermore, we shall see that the influence of the two sets on the group structure is analogous.展开更多
Existing groupwise dimension reduction requires given group structure to be non-overlapped. This confines its application scope. We aim at groupwise dimension reduction with overlapped group structure or even unknown ...Existing groupwise dimension reduction requires given group structure to be non-overlapped. This confines its application scope. We aim at groupwise dimension reduction with overlapped group structure or even unknown group structure. To this end, existing groupwise dimension reduction concept is extended to be compatible with overlapped group structure. Then, the envelope method is ameliorated to deal with overlapped groupwise dimension reduction. As an application, Gaussian graphic model is employed to estimate the structure between predictors when the group structure is not given, and the amended envelope method is used for groupwise dimension reduction with graphic structure. Furthermore, the rationale of the proposed estimation procedure is explained at the population level and the estimation consistency is proved at the sample level. Finally, the finite sample performance of the proposed methods is examined via numerical simulations and a body fat data analysis.展开更多
Sequence alignment is a common method for finding protein structurally conserved/similar regions. However, sequence alignment is often not accurate if sequence identities between to-be-aligned se- quences are less tha...Sequence alignment is a common method for finding protein structurally conserved/similar regions. However, sequence alignment is often not accurate if sequence identities between to-be-aligned se- quences are less than 30%. This is because that for these sequences, different residues may play similar structural roles and they are incorrectly aligned during the sequence alignment using substitu- tion matrix consisting of 20 types of residues. Based on the similarity of physicochemical features, residues can be clustered into a few groups. Using such simplified alphabets, the complexity of protein sequences is reduced and at the same time the key information encoded in the sequences remains. As a result, the accuracy of sequence alignment might be improved if the residues are properly clustered. Here, by using a database of aligned protein structures (DAPS), a new clustering method based on the substitution scores is proposed for the grouping of residues, and substitution matrices of residues at different levels of simplification are constructed. The validity of the reduced alphabets is confirmed by relative entropy analysis. The reduced alphabets are applied to recognition of protein structurally conserved/similar regions by sequence alignment. The results indicate that the accuracy or efficiency of sequence alignment can be improved with the optimal reduced alphabet with N around 9.展开更多
基金supported in part by the National Natural Science Foundation of China under Grant Nos.72111530199,12231017 and 72293573in part by the Natural Science Foundation of Anhui Province of China under Grant No.2108085J02。
文摘Negative binomial regression is a powerful technique for modeling count data,particularly when dealing with overdispersion.However,estimating the parameters for large-dimensional sparse models is challenging due to the complexity of optimizing the mean and dispersion parameter of the negative binomial distribution.To address this issue,the authors propose a novel approach that employs two iterations of the majorize-minimize(MM)algorithm,one for estimating the dispersion parameter and the other for estimating the mean parameters.These approaches improve the convergence speed and stability of the algorithm.The authors also use group penalty for variable selection,which enhances the accuracy and efficiency of the algorithm.The proposed method provides an explicit solution,simplifies the iteration process,and maintains good stability while ensuring algorithm convergence.Furthermore,the authors apply the proposed algorithm to the zero-inflated model and demonstrate its promising predictive performance on specific data sets.The research has important implications for count data modeling and analysis in various fields,such as data mining,machine learning,and bioinformatics.
基金Supported by National Natural Science Foundation of China(72222009,71991472)。
文摘Network autoregression and factor model are effective methods for modeling network time series data.In this study,we propose a network autoregression model with a factor structure that incorporates a latent group structure to address nodal heterogeneity within the network.An iterative algorithm is employed to minimize a least-squares objective function,allowing for simultaneous estimation of both the parameters and the group structure.To determine the unknown number of groups and factors,a PIC criterion is introduced.Additionally,statistical inference of the estimated parameters is presented.To assess the validity of the proposed estimation and inference procedures,we conduct extensive numerical studies.We also demonstrate the utility of our model using a stock dataset obtained from the Chinese A-Share stock market.
文摘A host of abiotic factors modify fish social behavior. However, few studies have characterized the effects of temperature on behavior. In this study, brown trout Salmo trutta fry were reared at 5 dif- ferent temperatures (4℃, 6℃, 8℃, 10℃, and 12℃). In order to characterize group structure, 3 be- havioral parameters were investigated: group social structure (based on inter-individual distances), inter-individual relationships (based on physical contacts), and individual activity. These behavioral parameters were studied at the emergence stage, which corresponds to a switch from a social gre- garious life in the gravel to a solitary one in the water column. Data analysis showed that the inter- individual distances increased with increasing temperature, particularly the nearest neighbor distance. The mean number of physical contacts between fry increased at both low and high tem- peratures. At high temperatures, most fry moved apart from each other after a physical contact. Swimming activity decreased at both the lower and upper temperatures (18% of activity at 4℃, 38% at 8℃, and 12% at 12℃). This study showed that temperature modifies brown trout fry activity, inter-individual relationships, and social behavior, which all affect group cohesion before emer- gence and can influence their survival and dispersal.
文摘A subgroup H of a group G is said to be primitive if it is a proper subgroup of the intersection of all subgroups of G containing H as its proper subgroup. The purpose of this note is to go further into the influence of primitive subgroups on the structure of finite groups. Some new results are obtained.
文摘INTRODUCTION Group transfer polymerization (GTP) is a method for controlling the structure of acrylic polymers in which reactive chain ends are covalentiy bound to a trimethylsilyl group. In the presence of a catalyst, monomer inserts into these chain ends between the silyl group and the last monomer unit. The process is illustrated by equation (1) for methyl methacrylate. GTP is a living polymerization, i. e., there is little or no chain termination and no chain transfer. A significant advantage of GTP is that it
基金Supported by the Educational Commission of Anhui Province(KJ2014ZD02)the National Natural Science Foundation of China(51432001)
文摘A novel D-π-A type α-cyanostilbenzene derivative,(Z)-2-(4-aminophenyl)-3-(4-bromophenyl)-acrylonitrile(ABAN), was designed and synthesized, by introducing an electrondonating amino group and a heavy atom. The structure of ABAN was confirmed by FT-IR, 1H NMR, 13 C NMR spectra and single-crystal X-ray diffraction analysis. The ABAN is of orthorhombic system, space group P212121, with a = 8.6100(14), b = 9.6923(16), c = 15.705(3) , Mr = 299.17, V = 1310.6(4) 3, Z = 4, Dc = 1.516 g/cm-3, μ = 3.119 mm-1, F(000) = 600, Rint = 0.038, R(I 〉 2σ(I)) = 0.0276, w R(I 〉 2σ(I)) = 0.0628, R(all data) = 0.0324, wR(all data) = 0.0646, completeness to theta = 25.00 was 99.8% and GOOF = 1.04. In the crystal structure, ABAN molecules were linked with each other through intermolecular C–H···π interactions and N–H···N hydrogen bonds, by which the 1D chain, 2D plane and 3D stacking structures were constructed. The photophysical properties and calculation results confirmed that ABAN possessed an intramolecular charge transfer(ICT) process. ABAN could be applied into the optoelectronic material field due to good solvent-tuned photophysical properties and highly thermal stability.
基金This paper is supported by the National Nature Science Foundation (NSF) (No.70371038), and Excellent Innovative Research Group Funds Project from the NSF of China (No. 70121001).
文摘Whether a decision group does its function or not directly depends on the rationality of its characters. The decision science, also with other correlation disciplines, wants to know how the group characters affect the group performance. Although there are great deals of means to describe the group characters theoretically and practically, in this paper, we consider that the integrity character of a group is composed of the group scale, the constitution and the structure. So the research on how group characters affect the group performance should focus on the three aspects. In order to grasp the present research situation and clear the prospective direction of the studies, we will summarize the study on how the group characters affect the group performance from these three aspects.
文摘In the paper [1] the upgrade of the structure of groups has been considered, in which the concept of HX group has been raised. In this paper we will discuss the direct product of HX groups and AX groups on direct product group.
文摘we have discussed structures of Abelian group G by order |A(G) |of automoorphism group and have obtained all types of finite Abelian grooup G when the order of A(G) equals 27pq(p,q are odd primmes).
基金Study on Maize Variety Management Based on DUS Test and SNP Molecular Fingerprint.
文摘[Objectives]The genetic diversity and population genetic structure of 107 inbred lines of maize in Yunnan were analyzed,in order to provide technical support for maize germplasm innovation,genetic improvement of germplasm resources,variety management,and lay a solid foundation for exploring genes related to fine traits in the future.[Methods]The 107 maize inbred lines generalized in Yunnan were selected,and 45 backbone inbred lines commonly used in China were used as reference for heterotic group classification.On Axiom Maize 56K SNP Array platform,maize SNP chips(56K)were used to scan the whole maize genome,and the NJ-tree model of Treebest was used to construct a phylogenetic tree.Principal component analysis(PCA)was conducted by GCTA(genome-wide complex trait analysis)to reveal the genetic diversity and population genetic structure.[Results]In the 107 Yunnan local inbred lines,5533 uniformly distributed high-quality SNP marker sites were finally detected.Based on the analysis of these SNP marker sites,Nei s gene diversity index(H)of 107 maize germplasm genes was 0.2981-0.5000 with an average value being 0.4832,and polymorphism information content(PIC)values were 0.2536-0.3750 with an average value being 0.3662.The minimum allele frequency value was 0.5000-0.8178 with an average value being 0.5744.The analysis of population genetic structure showed that when K=6,the maximum value of△K was the maximum,which meant that the inbred lines used in this study could be divided into six groups.They were Tangsi Pingtou blood relationship group,PB blood relationship group,335 female blood relationship group,Zi 330 and the Lüda Honggu blood relationship group,unknown group 1 and unknown group 2.No inbred lines were divided into other heterotic groups.Among them,37 inbred lines from the 2 unknown groups could not be classified into the same group as the 10 known heterotic groups in China.The results of principal component analysis showed that the 107 maize inbred lines generalized in Yunnan could be clearly distinguished from the backbone maize inbred lines commonly used in China.Most of the maize inbred lines in Yunnan were concentrated near the reference backbone inbred lines.But some Yunnan inbred lines were far away from the reference inbred lines commonly used in China.[Conclusions]The maize germplasm resources in Yunnan area were rich in genetic diversity,including multiple heterotic groups,and there was a rich genetic basis of breeding parents.They could be clearly distinguished from the backbone inbred lines commonly used in China,and some of them had a long genetic distance from the backbone inbred lines.The resources which have good application potential can be used to create new heterotic groups.
基金Supported by NSFC(21171166,21222102,21301172,21373220,21571178,21525104,51277091,51402296,51502288 and 51502290)Chunmiao Project of Haixi Institute of Chinese Academy of Sciences(CMZX-2015-003)NSF of Fujian Province(2015J01219,2015J05040)
文摘A new boroantimonate K2SbB3O8 has been synthesized by high-temperature solidstate reactions, and its crystals have been obtained by the flux method. The crystal structure has been determined from single-crystal X-ray diffraction analysis. The compound crystallizes in the monoclinic space group P21/c with a = 5.8890(2), b = 11.0512(4), c = 10.8951(4)A, β =103.200(4)°, V = 690.32(4) A^3, Z = 4, F(000) = 672, ρc = 3.467 g/cm^3, Mr = 360.38 and μ = 5.215mm^-1. Its structure feature is a three-dimensional framework composed of SbO6 octahedra and isolated [B3O8]^7- groups with K+ cations residing in the one-dimensional tunnels along the a-axis.Interestingly, the isolated [B3O8]^7- groups are distinct from the known [B3O8]^7- groups, which always connect to each other. The UV-vis-NIR absorption, thermal stability and infrared spectrum are also discussed in this paper.
文摘With the support by the National Natural Science Foundation of China,a collaboration by the research groups led by Prof.Cheng Gang(程纲)from Henan University and Prof.Wang Zhonglin(王中林)from Beijing Institute of Nanoenergy and Nanosystems,Chinese Academy of Sciences,invents'a sliding-mode triboelectric nanogenerator with chemical group grated structure by shadow mask reactive ion etching',which was published in ACS Nano(2017,11(9):8796-8803).
文摘The mechanism of 2-cyanopyrazine prepared from 2-methylpyrazine (2-MP) by catalytic ammoxidation has been explained by the theory of appropriate structure of group. A new catalyst of MoVPO was developed. The effects of catalyst promoter phosphorus and supports were investigated. The catalyst containing P, V and Mo in molar ratio of 1.4 : 1 : 0.02 and supported on activated alumina and prepared by impregnation method exhibits good activity and selectivity. Reaction factors such as reaction temperature, space velocity, feed composition and service life of catalyst were investigated. Optimum reaction conditions (the volume space velocity of 0.2h-1, the reaction temperature of 380 ~C and molar ratio of 1 : 7.8 : 8 : 8 for 2-MP, water, oxygen and ammonia) were obtained. Selectivity of 93% and yield of 86% could be achieved under these conditions.
基金Supported by the Youth Project of Hubei Provincial Department of Education (Q20112807)the Outstanding Young Team Project of Hubei Provincial Higher School (T201009)
文摘Let G be a finite group and π be a set of primes including at least two elements. We write cd(G) and cs(G) to denote the set of complex irreducible character degrees and conjugacy class sizes of G , respectively, and write π(m)to denote the set of all prime divisors of a positive integer m . For any 1≠m∈cd(G) and 1≠m∈cs(G), in this note, we shall present the corresponding group structures of finite group G in the case π(m)=π , respectively, which generalizes the result of finite groups with character degrees of two distinct primes. Furthermore, we shall see that the influence of the two sets on the group structure is analogous.
基金supported by a grant from the University Grant Council of Hong Kong of ChinaNational Natural Science Foundation of China (Grant No. 11371013)Tian Yuan Foundation for Mathematics
文摘Existing groupwise dimension reduction requires given group structure to be non-overlapped. This confines its application scope. We aim at groupwise dimension reduction with overlapped group structure or even unknown group structure. To this end, existing groupwise dimension reduction concept is extended to be compatible with overlapped group structure. Then, the envelope method is ameliorated to deal with overlapped groupwise dimension reduction. As an application, Gaussian graphic model is employed to estimate the structure between predictors when the group structure is not given, and the amended envelope method is used for groupwise dimension reduction with graphic structure. Furthermore, the rationale of the proposed estimation procedure is explained at the population level and the estimation consistency is proved at the sample level. Finally, the finite sample performance of the proposed methods is examined via numerical simulations and a body fat data analysis.
基金the National Natural Science Foundation of China (Grant Nos. 90403120, 10474041 and 10021001)the Nonlinear Project (973) of the NSM
文摘Sequence alignment is a common method for finding protein structurally conserved/similar regions. However, sequence alignment is often not accurate if sequence identities between to-be-aligned se- quences are less than 30%. This is because that for these sequences, different residues may play similar structural roles and they are incorrectly aligned during the sequence alignment using substitu- tion matrix consisting of 20 types of residues. Based on the similarity of physicochemical features, residues can be clustered into a few groups. Using such simplified alphabets, the complexity of protein sequences is reduced and at the same time the key information encoded in the sequences remains. As a result, the accuracy of sequence alignment might be improved if the residues are properly clustered. Here, by using a database of aligned protein structures (DAPS), a new clustering method based on the substitution scores is proposed for the grouping of residues, and substitution matrices of residues at different levels of simplification are constructed. The validity of the reduced alphabets is confirmed by relative entropy analysis. The reduced alphabets are applied to recognition of protein structurally conserved/similar regions by sequence alignment. The results indicate that the accuracy or efficiency of sequence alignment can be improved with the optimal reduced alphabet with N around 9.