The content of 30 kinds of coloring elements in Guan porcelain in the Southern Song Dynasty has been determined by neutron activation analysis (NAA). Iron is the major coloring element. Mossbauer spectroscopy has show...The content of 30 kinds of coloring elements in Guan porcelain in the Southern Song Dynasty has been determined by neutron activation analysis (NAA). Iron is the major coloring element. Mossbauer spectroscopy has shown that the iron of the glaze exists in the form of structural iron (Fe2+, Fe3+). The quantitative relationship between the main wavelength of every color glaze and the relative content (Fe2+/Fe3+) of structural iron has been determined. Thus the coloring mechanism of Guan porcelain in the Southern Song Dynasty has been revealed entirely.展开更多
34 samples of Ru Guan porcelain body and 50 samples of Jun Guan porcelain body (both kinds being in different body colors) were selected with the purpose of finding out the source of raw materials and their classifica...34 samples of Ru Guan porcelain body and 50 samples of Jun Guan porcelain body (both kinds being in different body colors) were selected with the purpose of finding out the source of raw materials and their classification relationship so as to search for ways of non-destructive discrimination. Proton induced X-ray emission (PIXE) has been applied to these samples to determine their chemical elements. The data of seven major chemical elements collected from these samples were further studied through fuzzy cluster analysis. Results indicate that the origin of raw materials of Jun Guan porcelain body samples is comparatively more concentrated in certain places, while that of Ru Guan porcelain body samples is scattered about. The places of origin of raw materials of the majority of Ru Guan and Jun Guan porcelain body samples have something in common, but some differences still exist. It might be an important way for non-destructive discrimination among Ru Guan and Jun Guan porcelains by combining PIXE with fuzzy cluster analysis.展开更多
文摘The content of 30 kinds of coloring elements in Guan porcelain in the Southern Song Dynasty has been determined by neutron activation analysis (NAA). Iron is the major coloring element. Mossbauer spectroscopy has shown that the iron of the glaze exists in the form of structural iron (Fe2+, Fe3+). The quantitative relationship between the main wavelength of every color glaze and the relative content (Fe2+/Fe3+) of structural iron has been determined. Thus the coloring mechanism of Guan porcelain in the Southern Song Dynasty has been revealed entirely.
基金This program has enjoyed the support from the National Natural Science Key Foundation of China (Grant No. 50432010) the National Natural Science Foundation of China (Grant No. 50572097)+1 种基金the Key Laboratory of Nuclear Analysis Techniques of the Chinese Academy of Sciences (K-113) Protection Center of History Culture Legacy of Zhengzhou University.
文摘34 samples of Ru Guan porcelain body and 50 samples of Jun Guan porcelain body (both kinds being in different body colors) were selected with the purpose of finding out the source of raw materials and their classification relationship so as to search for ways of non-destructive discrimination. Proton induced X-ray emission (PIXE) has been applied to these samples to determine their chemical elements. The data of seven major chemical elements collected from these samples were further studied through fuzzy cluster analysis. Results indicate that the origin of raw materials of Jun Guan porcelain body samples is comparatively more concentrated in certain places, while that of Ru Guan porcelain body samples is scattered about. The places of origin of raw materials of the majority of Ru Guan and Jun Guan porcelain body samples have something in common, but some differences still exist. It might be an important way for non-destructive discrimination among Ru Guan and Jun Guan porcelains by combining PIXE with fuzzy cluster analysis.
