A first-principles study was reported based on density functional theory of hydrogen vacancy,metal dopants,metal dopant-vacancy complex in LiBH4,a promising material for hydrogen storage.The formation of H vacancy and...A first-principles study was reported based on density functional theory of hydrogen vacancy,metal dopants,metal dopant-vacancy complex in LiBH4,a promising material for hydrogen storage.The formation of H vacancy and metal doping in LiBH4 is difficult,and their concentrations are low.The presence of one kind of defect is helpful to the formation of other kind of defect.Based on the analysis of electronic structure,the improvement of the dehydrogenating kinetics of LiBH4 by metal catalysts is due to the weaker bonding of B—H and the new metal-like system,which makes H atom diffuse easily;H vacancy accounts for a trace amount of BH3 release during the decomposing process of LiBH4;metal dopant weakens the strength of B—H bonds,which reduces the dehydriding temperature of LiBH4.The roles of metal and vacancy in the metal dopant-vacancy complex can be added in LiBH4 system.展开更多
This paper is concerned with stochastic H_2/H_∞ control problem for Poisson jump-diffusion systems with(x, u, v)-dependent noise, which are driven by Brownian motion and Poisson random jumps. A stochastic bounded rea...This paper is concerned with stochastic H_2/H_∞ control problem for Poisson jump-diffusion systems with(x, u, v)-dependent noise, which are driven by Brownian motion and Poisson random jumps. A stochastic bounded real lemma(SBRL for short) for Poisson jump-diffusion systems is firstly established, which stands out on its own as a very interesting theoretical problem. Further, sufficient and necessary conditions for the existence of a state feedback H_2/H_∞ control are given based on four coupled matrix Riccati equations. Finally, a discrete approximation algorithm and an example are presented.展开更多
基金Project (2009AA05Z105) supported by the High-tech Research and Development Program of ChinaProject (20102173) supported by the Natural Science Foundation of Liaoning Province,China
文摘A first-principles study was reported based on density functional theory of hydrogen vacancy,metal dopants,metal dopant-vacancy complex in LiBH4,a promising material for hydrogen storage.The formation of H vacancy and metal doping in LiBH4 is difficult,and their concentrations are low.The presence of one kind of defect is helpful to the formation of other kind of defect.Based on the analysis of electronic structure,the improvement of the dehydrogenating kinetics of LiBH4 by metal catalysts is due to the weaker bonding of B—H and the new metal-like system,which makes H atom diffuse easily;H vacancy accounts for a trace amount of BH3 release during the decomposing process of LiBH4;metal dopant weakens the strength of B—H bonds,which reduces the dehydriding temperature of LiBH4.The roles of metal and vacancy in the metal dopant-vacancy complex can be added in LiBH4 system.
基金supported by the Special Funds of the National Natural Science Foundation of China(No.11426154)
文摘This paper is concerned with stochastic H_2/H_∞ control problem for Poisson jump-diffusion systems with(x, u, v)-dependent noise, which are driven by Brownian motion and Poisson random jumps. A stochastic bounded real lemma(SBRL for short) for Poisson jump-diffusion systems is firstly established, which stands out on its own as a very interesting theoretical problem. Further, sufficient and necessary conditions for the existence of a state feedback H_2/H_∞ control are given based on four coupled matrix Riccati equations. Finally, a discrete approximation algorithm and an example are presented.
