Tanlu fault zone(TLFZ)is the largest active fault zone in eastern China.It is characterized by complex tectonic evolution and multiple faults and marks the boundary between the North and South China blocks.An indepth ...Tanlu fault zone(TLFZ)is the largest active fault zone in eastern China.It is characterized by complex tectonic evolution and multiple faults and marks the boundary between the North and South China blocks.An indepth understanding of the distinct crustal structures of both parts of the TLFZ will provide valuable insights into the lithospheric and crustal thinning in eastern China,extensive magmatism since the Mesozoic,and formation mechanisms of metallogenic belts along the Yangtze River.In this study,a two-layer H-κstacking approach was adopted to estimate the thicknesses of the sediment and crystalline crust as well as the corresponding vP/vS ratios based on high-quality teleseismic P-wave receiver functions recorded by permanent and temporary stations in and around the TLFZ.The geological units in the study region were delineated,especially the crustal structures beneath extensive sedimentary basins on both sides of the TLFZ.The following conclusions can be drawn:(1)The crustal thickness in and around the TLFZ greatly varies depending on the segment.In the northern segment,the crust is relatively thin beneath the eastern part of the Songliao Basin,a broad uplift of the Moho can be observed,and the Moho descends from south to north.The crust below the central and southern segments becomes thinner from west to east.The thickness of the crust is less than 30 km toward the eastern side of the boundary between the Jiangsu and Anhui provinces,that is,significantly thinner than in other areas.In terms of the vP/vS ratios,high anomalies were detected in the central-southern segments of the TLFZ,indicating the upwelling of deep mantle magma via deep faults.(2)Positive isostatic gravity anomalies were observed in the eastern part of the northern segment of the TLFZ and in the eastern part of the Suwan segment.The crustal thickness is smaller than that obtained from the Airy model of isostasy.This suggests that the lower crust in this area may have experienced intensive transformation processes,which may be related to crustal thinning(caused by crustal extension)and the strong uplift of the mantle in eastern China.The isostatic gravity anomalies between the eastern and western parts of the TLFZ indicate that the fault zone plays a dominant role in controlling the development of the deep crustal structure.(3)Significant crustal thinning was observed beneath the eastern part of the boundary between the Jiangsu and Anhui provinces in the southern segment of the TLFZ,suggesting that this area is prone to lithospheric thinning of the North China Craton.Due to the subduction,compression,and retreat of the Paleo-Pacific Plate during the Yanshanian Period as well as the dehydration of subducting oceanic crust(within subduction zones),the asthenosphere and oceanic crust in eastern China partially melted,resulting in mantle enrichment.The basic magma from the mantle is accumulated at the base of the crust,leading to magmatic underplating.In areas with weak topography toward the east of the TLFZ,magma rises to the upper crust and surface,resulting in the enrichment of multiple metal deposits in this area.展开更多
Co-free Li-rich layered oxides(LLOs)are emerging as promising cathode materials for Li-ion batteries due to their low cost and high capacity.However,they commonly face severe structural instability and poor electroche...Co-free Li-rich layered oxides(LLOs)are emerging as promising cathode materials for Li-ion batteries due to their low cost and high capacity.However,they commonly face severe structural instability and poor electrochemical activity,leading to diminished capacity and voltage performance.Herein,we introduce a Co-free LLO,Li_(1.167)Ni_(0.222)Mn_(0.611)O_(2)(Cf-L1),which features a cooperative structure of Li/Ni mixing and stacking faults.This structure regulates the crystal and electronic structures,resulting in a higher discharge capacity of 300.6 mA h g^(-1)and enhanced rate capability compared to the typical Co-free LLO,Li_(1.2)Ni_(0.2)Mn_(0.6)O_(2)(Cf-Ls).Density functional theory(DFT)indicates that Li/Ni mixing in LLOs leads to increased Li-O-Li configurations and higher anionic redox activities,while stacking faults further optimize the electronic interactions of transition metal(TM)3d and non-bonding O 2p orbitals.Moreover,stacking faults accommodate lattice strain,improving electrochemical reversibility during charge/discharge cycles,as demonstrated by the in situ XRD of Cf-L1 showing less lattice evolution than Cf-Ls.This study offers a structured approach to developing Co-free LLOs with enhanced capacity,voltage,rate capability,and cyclability,significantly impacting the advancement of the next-generation Li-ion batteries.展开更多
文摘Tanlu fault zone(TLFZ)is the largest active fault zone in eastern China.It is characterized by complex tectonic evolution and multiple faults and marks the boundary between the North and South China blocks.An indepth understanding of the distinct crustal structures of both parts of the TLFZ will provide valuable insights into the lithospheric and crustal thinning in eastern China,extensive magmatism since the Mesozoic,and formation mechanisms of metallogenic belts along the Yangtze River.In this study,a two-layer H-κstacking approach was adopted to estimate the thicknesses of the sediment and crystalline crust as well as the corresponding vP/vS ratios based on high-quality teleseismic P-wave receiver functions recorded by permanent and temporary stations in and around the TLFZ.The geological units in the study region were delineated,especially the crustal structures beneath extensive sedimentary basins on both sides of the TLFZ.The following conclusions can be drawn:(1)The crustal thickness in and around the TLFZ greatly varies depending on the segment.In the northern segment,the crust is relatively thin beneath the eastern part of the Songliao Basin,a broad uplift of the Moho can be observed,and the Moho descends from south to north.The crust below the central and southern segments becomes thinner from west to east.The thickness of the crust is less than 30 km toward the eastern side of the boundary between the Jiangsu and Anhui provinces,that is,significantly thinner than in other areas.In terms of the vP/vS ratios,high anomalies were detected in the central-southern segments of the TLFZ,indicating the upwelling of deep mantle magma via deep faults.(2)Positive isostatic gravity anomalies were observed in the eastern part of the northern segment of the TLFZ and in the eastern part of the Suwan segment.The crustal thickness is smaller than that obtained from the Airy model of isostasy.This suggests that the lower crust in this area may have experienced intensive transformation processes,which may be related to crustal thinning(caused by crustal extension)and the strong uplift of the mantle in eastern China.The isostatic gravity anomalies between the eastern and western parts of the TLFZ indicate that the fault zone plays a dominant role in controlling the development of the deep crustal structure.(3)Significant crustal thinning was observed beneath the eastern part of the boundary between the Jiangsu and Anhui provinces in the southern segment of the TLFZ,suggesting that this area is prone to lithospheric thinning of the North China Craton.Due to the subduction,compression,and retreat of the Paleo-Pacific Plate during the Yanshanian Period as well as the dehydration of subducting oceanic crust(within subduction zones),the asthenosphere and oceanic crust in eastern China partially melted,resulting in mantle enrichment.The basic magma from the mantle is accumulated at the base of the crust,leading to magmatic underplating.In areas with weak topography toward the east of the TLFZ,magma rises to the upper crust and surface,resulting in the enrichment of multiple metal deposits in this area.
基金financially supported by the National Natural Science Foundation of China(52202046,51602246,and 51801144)the Natural Science Foundation of Shanxi Provincial(2021JQ-034)。
文摘Co-free Li-rich layered oxides(LLOs)are emerging as promising cathode materials for Li-ion batteries due to their low cost and high capacity.However,they commonly face severe structural instability and poor electrochemical activity,leading to diminished capacity and voltage performance.Herein,we introduce a Co-free LLO,Li_(1.167)Ni_(0.222)Mn_(0.611)O_(2)(Cf-L1),which features a cooperative structure of Li/Ni mixing and stacking faults.This structure regulates the crystal and electronic structures,resulting in a higher discharge capacity of 300.6 mA h g^(-1)and enhanced rate capability compared to the typical Co-free LLO,Li_(1.2)Ni_(0.2)Mn_(0.6)O_(2)(Cf-Ls).Density functional theory(DFT)indicates that Li/Ni mixing in LLOs leads to increased Li-O-Li configurations and higher anionic redox activities,while stacking faults further optimize the electronic interactions of transition metal(TM)3d and non-bonding O 2p orbitals.Moreover,stacking faults accommodate lattice strain,improving electrochemical reversibility during charge/discharge cycles,as demonstrated by the in situ XRD of Cf-L1 showing less lattice evolution than Cf-Ls.This study offers a structured approach to developing Co-free LLOs with enhanced capacity,voltage,rate capability,and cyclability,significantly impacting the advancement of the next-generation Li-ion batteries.
文摘为了解决单个神经网络预测的局限性和时间序列的波动性,提出了一种奇异谱分析(singular spectrum analysis,SSA)和Stacking框架相结合的短期负荷预测方法。利用随机森林筛选出与历史负荷相关性强烈的特征因素,采用SSA为负荷数据降噪,简化模型计算过程;基于Stacking框架,结合长短期记忆(long and short-term memory,LSTM)-自注意力机制(self-attention mechanism,SA)、径向基(radial base functions,RBF)神经网络和线性回归方法集成新的组合模型,同时利用交叉验证方法避免模型过拟合;选取PJM和澳大利亚电力负荷数据集进行验证。仿真结果表明,与其他模型比较,所提模型预测精度高。
