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STUDY ON THE CHAIN-EXTENDING REACTION OF POLY (ETHYLENE TEREPHTHALATE) WITH 2, 2′-BIS (4H-3, 1-BENZOXAZIN-4-ONE)
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作者 潘才元 刘华蓉 白如科 《Chinese Journal of Polymer Science》 SCIE CAS CSCD 1996年第2期142-149,共8页
2,2'-Bis (4H-3,1-benaoxazin-4-one) (BBON) has been proved to be an effective chain extender for poly (ethylene terephthalate) (PET). In order to study the reaction mechanism and kinetics of chain-extending reactio... 2,2'-Bis (4H-3,1-benaoxazin-4-one) (BBON) has been proved to be an effective chain extender for poly (ethylene terephthalate) (PET). In order to study the reaction mechanism and kinetics of chain-extending reaction, beta-bishydroxyethylene terephthalate (BHET) was selected as model compound. The NMR data, IR spectra and number average molecular weight (<(M)over bar (n)>) of the products obtained from the reaction of BBON and BHET verify that BBON is a hydroxyl-reactive extender. The mechanism was discussed. Kinetics data indicate that extending reaction is a second order reaction, and BBON has high reactivity. The activation energy (E(a)) was measured. 展开更多
关键词 2 2'-bis(4h-3 1-benzoxazin-4-one) chain-extending reaction of PET mechanism kinetics
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Selenium-catalyzed oxidative carbonylation of 2-aminobenzyl alcohol to give 1,4-dihydro-2H-3,1-benzoxazin-2-one 被引量:1
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作者 张晓鹏 王平 +3 位作者 牛雪利 李政伟 范学森 张贵生 《Chinese Journal of Catalysis》 SCIE EI CAS CSCD 北大核心 2016年第11期2034-2038,共5页
An efficient,economical,and phosgene-free approach was developed for the preparation of l,4-dihydro-2H-3,l-benzoxazin-2-one from 2-aminobenzyl alcohol.In terms of its key features,this reaction uses the cheap and recy... An efficient,economical,and phosgene-free approach was developed for the preparation of l,4-dihydro-2H-3,l-benzoxazin-2-one from 2-aminobenzyl alcohol.In terms of its key features,this reaction uses the cheap and recyclable non-metal selenium as a catalyst instead of the noble metal palladium;carbon monoxide as a carbonylation agent instead of virulent phosgene or one of its derivatives;and oxygen as an oxidant.The selenium-catalyzed oxidative carbonylation reaction of2-aminobenzyl alcohol proceeded efficiently in a single pot in the presence of triethylamine to afford l,4-dihydro-2H-3,l-benzoxazin-2-one in 87%yield.Furthermore,the selenium catalyst was readily recovered and recycled,affording a product yield of 80%after five cycles. 展开更多
关键词 SELENIUM Oxidative carbonylation 1 4-Dihydro-2h-3 1-benzoxazin-2-one 2-Aminobenzyl alcohol Phase-transfer catalysis
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冰糖草化学成分的分离与鉴定 被引量:2
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作者 刘辰鹏 孙万莹 +5 位作者 王瑞琪 黄兹宝 曹明玉 张小坡 董琳 李国玉 《沈阳药科大学学报》 CAS CSCD 北大核心 2022年第7期780-785,共6页
目的研究冰糖草(Scoparia dulcis L.)全草乙醇提取物的正丁醇萃取部位的化学成分。方法运用硅胶、Sephadex LH-20和半制备HPLC等各种方法进行分离纯化,根据理化性质和波谱数据等鉴定化合物结构。结果分离得到16个化合物,分别鉴定为(2S)-... 目的研究冰糖草(Scoparia dulcis L.)全草乙醇提取物的正丁醇萃取部位的化学成分。方法运用硅胶、Sephadex LH-20和半制备HPLC等各种方法进行分离纯化,根据理化性质和波谱数据等鉴定化合物结构。结果分离得到16个化合物,分别鉴定为(2S)-7-methoxy-2H-1,4-benzoxazin-3(4H)-one 2-O-β-glucopyranoside(1)、(2R)-7-methoxy-2H-1,4-benzoxazin-3(4H)-one 2-O-β-glucopyranoside(2)、对羟基苯甲酸甲酯(3)、对羟基苯甲醛(4)、2-唑啉酮(5)、对羟基苯乙酮(6)、薏苡素(7)、苯甲酸(8)、对羟基肉桂酸甲酯(9)、黑麦草内酯(10)、异黑麦草内酯(11)、橙酰胺乙酸酯(12)、apigenin 7-O-rutinoside(13)、hispidulin-7-O-rutinoside(14)、isoschaftoside(15)和schaftoside(16)。结论化合物1为新化合物,化合物13~16为首次从冰糖草中分离得到。 展开更多
关键词 冰糖草 (2S)-7-methoxy-2h-1 4-benzoxazin-3(4H)-one 2-O-β-glucopyranoside isoschaftoside schaftoside 化学成分 分离 鉴定
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