The fast and high response detection of neurotoxic H_(2)S is of great importance for the environment.In this paper,directly electrospinning technology on the ceramic tube is developed to improve the response of H_(2)S...The fast and high response detection of neurotoxic H_(2)S is of great importance for the environment.In this paper,directly electrospinning technology on the ceramic tube is developed to improve the response of H_(2)S detector based on superlong SnO_(2)fibers.The submillimeter continuous fibers are deposited directly on ceramic tubes by in-situ electrospinning method and can keep morphology of fibers during calcination.By employing this technology,CuO-doped SnO_(2)fiber H_(2)S detectors are fabricated,and 10%atom CuO-doped SnO_(2)H_(2)S detector shows the highest response of 40 toward 1 ppm H_(2)S at 150℃while the response is only 3.6 for the H_(2)S detector prepared in traditional route.In addition,the in-situ electrospinning H_(2)S detectors show faster response and recovery compared to the H_(2)S detectors fabricated by the conventional way.The high and fast response of H_(2)S detectors based on in-situ electrospinning can be ascribed to the continuous fiber structure and CuO modification.The present in-situ electrospinning technology may provide a new strategy for the development of other gasdetectors and bio-detectors with fast and high response.展开更多
基金supported by National Natural Science Foundation of China(51772082,51804106,51572078,51772086 and 51872087)。
文摘The fast and high response detection of neurotoxic H_(2)S is of great importance for the environment.In this paper,directly electrospinning technology on the ceramic tube is developed to improve the response of H_(2)S detector based on superlong SnO_(2)fibers.The submillimeter continuous fibers are deposited directly on ceramic tubes by in-situ electrospinning method and can keep morphology of fibers during calcination.By employing this technology,CuO-doped SnO_(2)fiber H_(2)S detectors are fabricated,and 10%atom CuO-doped SnO_(2)H_(2)S detector shows the highest response of 40 toward 1 ppm H_(2)S at 150℃while the response is only 3.6 for the H_(2)S detector prepared in traditional route.In addition,the in-situ electrospinning H_(2)S detectors show faster response and recovery compared to the H_(2)S detectors fabricated by the conventional way.The high and fast response of H_(2)S detectors based on in-situ electrospinning can be ascribed to the continuous fiber structure and CuO modification.The present in-situ electrospinning technology may provide a new strategy for the development of other gasdetectors and bio-detectors with fast and high response.
