A novel three dimensional fluorinated gallium phosphate has been hydrothermally synthesized by using diethylenetriamine as an organic structure directing agent. X ray single crystal structure analysis indicates this c...A novel three dimensional fluorinated gallium phosphate has been hydrothermally synthesized by using diethylenetriamine as an organic structure directing agent. X ray single crystal structure analysis indicates this compound crystallizes in the orthorhombic space group Pbca, a =1.605 6(7) nm, b = 1 011 4 (4) nm, c =1.854 6(5) nm, V =3.011 6(19) nm 3, Z =4. The three dimensional framework based on linkage of corner sharing polyhedron PO 4, GaO 4F and GaO 4F 2 delimit ten ring channels along b axis in which the triply protonated amines are located serving as charge compensating guests and supporters.展开更多
A new two dimensional 8 ring network nickle phosphate Ni 3(PO 4) 2·8H 2O was synthesized hydrothermally and its structure was determined by means of single crystal X ray diffraction. The Ni 3(PO 4) 2·8H 2O c...A new two dimensional 8 ring network nickle phosphate Ni 3(PO 4) 2·8H 2O was synthesized hydrothermally and its structure was determined by means of single crystal X ray diffraction. The Ni 3(PO 4) 2·8H 2O crystal crystallizes in the monoclinic system, space group C2/m , with M=128.13, a =0\^994 7(2) nm, b =1.321 7(3) nm; c =0.463 6(1) nm; β=104.80(3)°, V =0.589 3(2) nm 3, Z=2, R=0.027 2 and wR =0.057 5. The network structure consists of vertex sharing which results in the formation of undulating 4 ring chains and 8 ring sheets.展开更多
The novel polyoxometalate, 32[Mo8ⅣMo4ⅤV2ⅣO38(PO4)], was synthesized and characterized by elementary analysis, EPR, IR spectra and X ray diffraction. The compoundcrystallizes in triclinic system, space group with a=...The novel polyoxometalate, 32[Mo8ⅣMo4ⅤV2ⅣO38(PO4)], was synthesized and characterized by elementary analysis, EPR, IR spectra and X ray diffraction. The compoundcrystallizes in triclinic system, space group with a= 1.41999(2)nm, b=1.43467(2)nm, c=1.694610(10)nm, α=95.7250(10)°, β=92.2110(10)°, γ=92.6060(10)°, V=3.42829(7)nm3, Z=2, Dc=2.388g·cm-3, Mr=2465.10g·mol-1, μ=2.489mm-1, F(000)=2388, R1=0.0584, wR2=0.1461, S=1.164. The heteropolyanion is a bi capped pseudo Keggin complex. CCDC: 186645.展开更多
A new compound 2 6[Co(H 2O) 2(VO) 8(OH) 4(PO 4) 8] has been hydrothermally synthesized. Single crystal X-ray analysis indicates that this compound crystallizes in a monoclinic system, space group P2 1/n with a=1.438 5...A new compound 2 6[Co(H 2O) 2(VO) 8(OH) 4(PO 4) 8] has been hydrothermally synthesized. Single crystal X-ray analysis indicates that this compound crystallizes in a monoclinic system, space group P2 1/n with a=1.438 5(3) nm, b=1.012 2(2) nm, c=1.832 5(4) nm, β=90.21°, V=2\^668 2(9) nm 3, Z=2, D c=2.112 g/cm 3, R=0.055, wR=0.149 7, S=1.037. The structure of 2 6[Co(H 2O) 2(VO) 8(OH) 4(PO 4) 8] is characterized by P-V-O layers constructed by [(VO) 4(OH) 2(PO 4) 4] 6- non-symmetric units. The P-V-O layers are pillared by [Co(H 2O) 2] 2+ group, resulting in the channels within which the protonated diaminoethane and H 3O + are located.展开更多
Ga 3(PO 4) 4](H 3NCH 2CH 2) 2NH 2(abbr. to GaP 1) has been synthesized by a hydrothermal method. X ray crystal structure analysis indicates GaP 1 crystallizes in monoclinic, with space group C2/c , a =2 079 3(5) nm, b...Ga 3(PO 4) 4](H 3NCH 2CH 2) 2NH 2(abbr. to GaP 1) has been synthesized by a hydrothermal method. X ray crystal structure analysis indicates GaP 1 crystallizes in monoclinic, with space group C2/c , a =2 079 3(5) nm, b =1 194 2(2) nm, c =1 648 0(4) nm, β =117 064(14)°, V =3 644 2(13) nm 3, Z =6, D c=1 901 g/cm 3, I ≥2 σ(I )=2 274, R =0 055 6, R w=0 134 8. GaP 1 is characteristic of the intercalation of disordered fully protonated diethylenetriamine among two dimensional inorganic framework built up from PO 4, GaO 5 and GaO 6 primary structure units. The framework features 3 , 4 , 5 and 8 ring topological connectivity.展开更多
文摘A novel three dimensional fluorinated gallium phosphate has been hydrothermally synthesized by using diethylenetriamine as an organic structure directing agent. X ray single crystal structure analysis indicates this compound crystallizes in the orthorhombic space group Pbca, a =1.605 6(7) nm, b = 1 011 4 (4) nm, c =1.854 6(5) nm, V =3.011 6(19) nm 3, Z =4. The three dimensional framework based on linkage of corner sharing polyhedron PO 4, GaO 4F and GaO 4F 2 delimit ten ring channels along b axis in which the triply protonated amines are located serving as charge compensating guests and supporters.
文摘A new two dimensional 8 ring network nickle phosphate Ni 3(PO 4) 2·8H 2O was synthesized hydrothermally and its structure was determined by means of single crystal X ray diffraction. The Ni 3(PO 4) 2·8H 2O crystal crystallizes in the monoclinic system, space group C2/m , with M=128.13, a =0\^994 7(2) nm, b =1.321 7(3) nm; c =0.463 6(1) nm; β=104.80(3)°, V =0.589 3(2) nm 3, Z=2, R=0.027 2 and wR =0.057 5. The network structure consists of vertex sharing which results in the formation of undulating 4 ring chains and 8 ring sheets.
文摘The novel polyoxometalate, 32[Mo8ⅣMo4ⅤV2ⅣO38(PO4)], was synthesized and characterized by elementary analysis, EPR, IR spectra and X ray diffraction. The compoundcrystallizes in triclinic system, space group with a= 1.41999(2)nm, b=1.43467(2)nm, c=1.694610(10)nm, α=95.7250(10)°, β=92.2110(10)°, γ=92.6060(10)°, V=3.42829(7)nm3, Z=2, Dc=2.388g·cm-3, Mr=2465.10g·mol-1, μ=2.489mm-1, F(000)=2388, R1=0.0584, wR2=0.1461, S=1.164. The heteropolyanion is a bi capped pseudo Keggin complex. CCDC: 186645.
文摘A new compound 2 6[Co(H 2O) 2(VO) 8(OH) 4(PO 4) 8] has been hydrothermally synthesized. Single crystal X-ray analysis indicates that this compound crystallizes in a monoclinic system, space group P2 1/n with a=1.438 5(3) nm, b=1.012 2(2) nm, c=1.832 5(4) nm, β=90.21°, V=2\^668 2(9) nm 3, Z=2, D c=2.112 g/cm 3, R=0.055, wR=0.149 7, S=1.037. The structure of 2 6[Co(H 2O) 2(VO) 8(OH) 4(PO 4) 8] is characterized by P-V-O layers constructed by [(VO) 4(OH) 2(PO 4) 4] 6- non-symmetric units. The P-V-O layers are pillared by [Co(H 2O) 2] 2+ group, resulting in the channels within which the protonated diaminoethane and H 3O + are located.
文摘Ga 3(PO 4) 4](H 3NCH 2CH 2) 2NH 2(abbr. to GaP 1) has been synthesized by a hydrothermal method. X ray crystal structure analysis indicates GaP 1 crystallizes in monoclinic, with space group C2/c , a =2 079 3(5) nm, b =1 194 2(2) nm, c =1 648 0(4) nm, β =117 064(14)°, V =3 644 2(13) nm 3, Z =6, D c=1 901 g/cm 3, I ≥2 σ(I )=2 274, R =0 055 6, R w=0 134 8. GaP 1 is characteristic of the intercalation of disordered fully protonated diethylenetriamine among two dimensional inorganic framework built up from PO 4, GaO 5 and GaO 6 primary structure units. The framework features 3 , 4 , 5 and 8 ring topological connectivity.
基金supported by the Fund for Young Scientists of Sichuan University, China (2011SCU11081)Research Fund for the Doctoral Program of Higher Education, Ministry of Education of China (20120181120103)~~
