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便携式GC-MS在应急监测工作中的应用 被引量:24
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作者 张先宝 刘晔 《分析测试学报》 CAS CSCD 北大核心 2007年第z1期206-207,共2页
It′s very useful tools for an instant analysis of organic pollutants monitoring using the HAPSITE portable GC-MS.It discusses how to use HAPSITE portable GC-MS in emergency monitoring and treatment.
关键词 hapsite portable gc-ms Emergency monitoring Organic pollutants
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Rapid on-site identification of hazardous organic compounds at fire scenes using person-portable gas chromatography-mass spectrometry(GC-MS)—part 2:water sampling and analysis 被引量:2
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作者 Rylee Lam Chris Lennard +6 位作者 Graham Kingsland Paul Johnstone Andrew Symons Laura Wythes Jeremy Fewtrell David O’Brien Val Spikmans 《Forensic Sciences Research》 CSCD 2020年第2期150-164,共15页
Building and factory fires pose a great risk to human and environmental health,due to the release of hazardous by-products of combustion.These hazardous compounds can dissipate into the environment through fire water ... Building and factory fires pose a great risk to human and environmental health,due to the release of hazardous by-products of combustion.These hazardous compounds can dissipate into the environment through fire water run-off,and the impact can be immediate or chronic.Current laboratory-based methods do not report hazardous compounds released from a fire scene at the time and location of the event.Reporting of results is often delayed due to the complexities and logistics of laboratory-based sampling and analysis.These delays pose a risk to the health and wellbeing of the environment and exposed community.Recent developments in person-portable instrumentation have the potential to provide rapid analysis of samples in the field.A portable gas chromatograph-mass spectrometer(GC-MS)was evaluated for the on-site analysis of water samples for the identification of hazardous organic compounds at fire scenes.The portable GC-MS was capable of detecting and identifying a range of volatile and semi-volatile organic compounds in fire water run-off,and can be used in conjunction with conventional laboratory analysis methods for a comprehensive understanding of hazardous organics released at fire scenes.Deployment of this portable instrumentation provides first responders with a rapid,on-site screening tool to appropriately manage the run-off water from firefighting activities.This ensures that environmental and human health is proactively protected. 展开更多
关键词 Forensic sciences portable gc-ms water pollution field analysis SPME FIRE VOCs SVOCs
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Rapid on-site identification of hazardous organic compounds at fire scenes using person-portable gas chromatography-mass spectrometry(GC-MS)—part 1:air sampling and analysis 被引量:1
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作者 Rylee Lam Chris Lennard +6 位作者 Graham Kingsland Paul Johnstone Andrew Symons Laura Wythes Jeremy Fewtrell David O’Brien Val Spikmans 《Forensic Sciences Research》 CSCD 2020年第2期134-149,共16页
Recent advancements in person-portable instrumentation have resulted in the potential to provide contemporaneous results through rapid in-field analyses.These technologies can be utilised in emergency response scenari... Recent advancements in person-portable instrumentation have resulted in the potential to provide contemporaneous results through rapid in-field analyses.These technologies can be utilised in emergency response scenarios to aid first responders in appropriate site risk assessment and management.Large metropolitan fires can pose great risk to human and environmental health due to the rapid release of hazardous compounds into the atmosphere.Understanding the release of these hazardous organics is critical in understanding their associated risks.Person-portable gas chromatography-mass spectrometry(GC-MS)was evaluated for its potential to provide rapid on-site analysis for real-time monitoring of hazardous organic compounds at fire scenes.Air sampling and analysis methods were developed for scenes of this nature.Controlled field testing demonstrated that the portable GC-MS was able to provide preliminary analytical results on the volatile organic compounds present in air samples collected from both active and extinguished fires.In-field results were confirmed using conventional laboratory-based air sampling and analysis procedures.The deployment of portable instrumentation could provide first responders with a rapid on-site assessment tool for the appropriate management of scenes,thereby ensuring environmental and human health is proactively protected and scientifically informed decisions are made for the provision of timely advice to stakeholders. 展开更多
关键词 Forensic sciences gas chromatography-mass spectrometry portable gc-ms air pollution fire volatile organic compounds field analysis needle trap
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环境应急监测中两种便携式仪器的应用 被引量:4
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作者 吴雨华 刘敬禹 《中国环境管理干部学院学报》 CAS 2012年第5期65-67,共3页
在环境应急监测中,便携式气相色谱-质谱仪HAPSITE Smart IQ和便携式气相色谱仪zNose4200主要用来监测挥发性有机物。在环境污染事故中二者的应用已较成熟、广泛,二者分别发挥各自作用,在实际工作中将二者联合应用能够取得更好的效果。HA... 在环境应急监测中,便携式气相色谱-质谱仪HAPSITE Smart IQ和便携式气相色谱仪zNose4200主要用来监测挥发性有机物。在环境污染事故中二者的应用已较成熟、广泛,二者分别发挥各自作用,在实际工作中将二者联合应用能够取得更好的效果。HAPSITE可以快速准确地对挥发性化学物质进行定性,但在定量过程中每个样品的测定过程需要数分钟,而zNose4200可以在数秒钟内对已知挥发性物质进行定量。在HAPSITE准确定性基础上,用zNose4200出具定量数据,可以有效缩短污染事故发生时环境应急监测的时间。两者联用技术,在很大程度上提高了环境应急监测能力。 展开更多
关键词 应急监测 便携气相色谱zNose4200 便携气相色谱 质谱hapsite 联合应用 挥发性有机物 环境污染 环境监测
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基于膜连续进样和脉冲进样的便携式质谱进样技术研究 被引量:1
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作者 李宝强 李翠萍 +2 位作者 张众垚 孔景临 张琳 《质谱学报》 EI CAS CSCD 北大核心 2018年第6期715-721,共7页
针对国产便携式质谱仪在维持真空条件下提高进样效率的问题,研究了膜连续进样和脉冲进样技术。利用实验室组装的膜连续进样和脉冲进样装置,使用二甲苯标气开展了在不同膜温、不同进样流量、不同脉冲频率条件下的进样实验;利用国内厂家... 针对国产便携式质谱仪在维持真空条件下提高进样效率的问题,研究了膜连续进样和脉冲进样技术。利用实验室组装的膜连续进样和脉冲进样装置,使用二甲苯标气开展了在不同膜温、不同进样流量、不同脉冲频率条件下的进样实验;利用国内厂家生产的膜替换Hapsite用进样阀中的膜,在相同膜温和不同进样流量条件下对比分析了两种膜的性能。结果表明:提高膜温度、增大进样流量可以有效提高便携式质谱仪的离子流信号强度,缩短响应时间和减少峰拖尾现象;在膜温度不变的条件下,增大进样流量可以有效地缩小两种膜性能之间的差距;采用脉冲进样时,随着脉冲电压频率的增大,既可以有效地保持仪器的真空度,又可以提高离子流信号强度、缩短响应时间。 展开更多
关键词 便携式质谱 膜进样 脉冲进样 hapsite用膜
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