Solid-state Na metal batteries(SSNBs),known for its low cost,high safety,and high energy density,hold a significant position in the next generation of rechargeable batteries.However,the urgent challenge of poor interf...Solid-state Na metal batteries(SSNBs),known for its low cost,high safety,and high energy density,hold a significant position in the next generation of rechargeable batteries.However,the urgent challenge of poor interfacial contact in solid-state electrolytes has hindered the commercialization of SSNBs.Driven by the concept of intimate electrode-electrolyte interface design,this study employs a combination of NaK alloy and carbon nanotubes to prepare a semi-solid NaK(NKC)anode.Unlike traditional Na anodes,the paintable paste-like NKC anode exhibits superior adhesion and interface compatibility with both current collectors and gel electrolytes,significantly enhancing the intimate contact of electrode-electrolyte interface.Additionally,the filling of SiO_(2)nanoparticles improves the wettability of NaK alloy on gel polymer electrolytes,further achieving a conformal interface contact.Consequently,the overpotential of the NKC symmetric cell is markedly lower than that of the Na symmetric cell when subjected to a long cycle of 300 h.The full cell coupled with Na_(3)V_(3)(PO_(4))_(2)cathodes had an initial discharge capacity of 106.8 mAh·g^(-1)with a capacity retention of 89.61%after 300 cycles,and a high discharge capacity of 88.1 mAh·g^(-1)even at a high rate of 10 C.The outstanding electrochemical performance highlights the promising application potential of the NKC electrode.展开更多
试验了830~910℃固溶处理和480~540℃时效对Φ20 mm NAK80塑料模具钢(/%:0.15C,0.30Si,1.50Mn,3.00Ni,1.00Cu,1.00Al,0.30Mo,0.30Cr)组织和硬度的影响,并对其时效动力学行为进行了研究。结果表明,890℃固溶处理后,NAK80钢组织由板条马...试验了830~910℃固溶处理和480~540℃时效对Φ20 mm NAK80塑料模具钢(/%:0.15C,0.30Si,1.50Mn,3.00Ni,1.00Cu,1.00Al,0.30Mo,0.30Cr)组织和硬度的影响,并对其时效动力学行为进行了研究。结果表明,890℃固溶处理后,NAK80钢组织由板条马氏体和粒状贝氏体组成,HRC硬度值达到42.4,经过500℃保温4 h的时效处理后,该钢的组织为回火屈氏体和析出相,其HRC硬度值可达45.5。利用JMA方程得到480℃和500℃时效时的Avrami指数n分别为2.20和1.63,表观激活能为96.787 J/mol。展开更多
基金National Natural Science Foundation of China(52073253)。
文摘Solid-state Na metal batteries(SSNBs),known for its low cost,high safety,and high energy density,hold a significant position in the next generation of rechargeable batteries.However,the urgent challenge of poor interfacial contact in solid-state electrolytes has hindered the commercialization of SSNBs.Driven by the concept of intimate electrode-electrolyte interface design,this study employs a combination of NaK alloy and carbon nanotubes to prepare a semi-solid NaK(NKC)anode.Unlike traditional Na anodes,the paintable paste-like NKC anode exhibits superior adhesion and interface compatibility with both current collectors and gel electrolytes,significantly enhancing the intimate contact of electrode-electrolyte interface.Additionally,the filling of SiO_(2)nanoparticles improves the wettability of NaK alloy on gel polymer electrolytes,further achieving a conformal interface contact.Consequently,the overpotential of the NKC symmetric cell is markedly lower than that of the Na symmetric cell when subjected to a long cycle of 300 h.The full cell coupled with Na_(3)V_(3)(PO_(4))_(2)cathodes had an initial discharge capacity of 106.8 mAh·g^(-1)with a capacity retention of 89.61%after 300 cycles,and a high discharge capacity of 88.1 mAh·g^(-1)even at a high rate of 10 C.The outstanding electrochemical performance highlights the promising application potential of the NKC electrode.
文摘试验了830~910℃固溶处理和480~540℃时效对Φ20 mm NAK80塑料模具钢(/%:0.15C,0.30Si,1.50Mn,3.00Ni,1.00Cu,1.00Al,0.30Mo,0.30Cr)组织和硬度的影响,并对其时效动力学行为进行了研究。结果表明,890℃固溶处理后,NAK80钢组织由板条马氏体和粒状贝氏体组成,HRC硬度值达到42.4,经过500℃保温4 h的时效处理后,该钢的组织为回火屈氏体和析出相,其HRC硬度值可达45.5。利用JMA方程得到480℃和500℃时效时的Avrami指数n分别为2.20和1.63,表观激活能为96.787 J/mol。
