Using fixed-bed reaction method and changing the gas composition and dust content,the influence of blast furnace top gas composition and dust on HCl removal with low temperature Ca-based antichlor was studied.It was f...Using fixed-bed reaction method and changing the gas composition and dust content,the influence of blast furnace top gas composition and dust on HCl removal with low temperature Ca-based antichlor was studied.It was found that,when the content of CO2 in blast furnace top gas increased,the dechlorination efficiency was getting worse obviously;when the contents of CO and N2 increased,the dechlorination efficiency was getting better to a certain extent;when the content of H2 changed,the dechlorination efficiency got no significant change;as the content of dust increased,the dechlorination efficiency got better obviously when the content was less than 15 g/m3,but it would be got worse quickly when the content was more than 20 g/m3,and the best content was 15–20 g/m3;the suitable site of the process of dechlorination was after gravity dust collector and before bag dust collector.展开更多
Combustion-generated hydrogen chloride （HCl） is considered to be a very hazardous acid gaseous pollutant. This paper presents a laboratory study on the dry adsorption of HCl. The experiments were conducted in a dual...Combustion-generated hydrogen chloride （HCl） is considered to be a very hazardous acid gaseous pollutant. This paper presents a laboratory study on the dry adsorption of HCl. The experiments were conducted in a dual-layer granular bed filter, at gas temperatures of 500℃-700℃ and n（Ca）/n（Cl）molar ratios of 1.0-5.0 using the silver nitrate titration method by dry adsorbent powders Ca（OH）2. Mainly, the adsorption efficiency of HCI and utilization efficiency of Calcium were studied, by varying relevant factors including n（Ca）/n（Cl）, tempera- ture, feeding method, water vapor and CO2. With a relatively higher HCl concentration of 1000ppm, the experimental results revealed that 600℃ may be the optimum temperature for HCl adsorption when optimum n （Ca）/n（Cl） was 2.5 in our tests. The results also demonstrated that the feeding at a constant pressure was more effective, and the HCl adsorption efficiency could rapidly reach over 90% with n（Ca）/n（Cl） = 2.5 at 600℃. Furthermore, the HCl adsorption efficiency was found to be slightly promoted by water vapor, while could be impeded by CO2, and the utilization efficiency of calcium could be up to 74.4% without CO2, while was only 36.8% with CO2 when n（Ca）/n（Cl） was 2.5 at 600℃.展开更多
基金Project(51274080)supported by the National Natural Science Foundation of ChinaProject(E2013209051)supported by the Hebei Science Foundation and the Steel and Iron Joint Research Foundation Project,China+1 种基金Project(U1502273)supported by the Joint Funds of the Natural Science Foundation of China and Yunnan Provincial GovernmentProjects(N150202001,N150203003)supported by the Fundamental Research Funds for the Central Universities,China
文摘Using fixed-bed reaction method and changing the gas composition and dust content,the influence of blast furnace top gas composition and dust on HCl removal with low temperature Ca-based antichlor was studied.It was found that,when the content of CO2 in blast furnace top gas increased,the dechlorination efficiency was getting worse obviously;when the contents of CO and N2 increased,the dechlorination efficiency was getting better to a certain extent;when the content of H2 changed,the dechlorination efficiency got no significant change;as the content of dust increased,the dechlorination efficiency got better obviously when the content was less than 15 g/m3,but it would be got worse quickly when the content was more than 20 g/m3,and the best content was 15–20 g/m3;the suitable site of the process of dechlorination was after gravity dust collector and before bag dust collector.
文摘Combustion-generated hydrogen chloride （HCl） is considered to be a very hazardous acid gaseous pollutant. This paper presents a laboratory study on the dry adsorption of HCl. The experiments were conducted in a dual-layer granular bed filter, at gas temperatures of 500℃-700℃ and n（Ca）/n（Cl）molar ratios of 1.0-5.0 using the silver nitrate titration method by dry adsorbent powders Ca（OH）2. Mainly, the adsorption efficiency of HCI and utilization efficiency of Calcium were studied, by varying relevant factors including n（Ca）/n（Cl）, tempera- ture, feeding method, water vapor and CO2. With a relatively higher HCl concentration of 1000ppm, the experimental results revealed that 600℃ may be the optimum temperature for HCl adsorption when optimum n （Ca）/n（Cl） was 2.5 in our tests. The results also demonstrated that the feeding at a constant pressure was more effective, and the HCl adsorption efficiency could rapidly reach over 90% with n（Ca）/n（Cl） = 2.5 at 600℃. Furthermore, the HCl adsorption efficiency was found to be slightly promoted by water vapor, while could be impeded by CO2, and the utilization efficiency of calcium could be up to 74.4% without CO2, while was only 36.8% with CO2 when n（Ca）/n（Cl） was 2.5 at 600℃.
