Tetraphenylethylene dicycle helicates: circularly polarized luminescence and chiral recognition based on emission wavelength change

Chiral tetraphenylethylene(TPE) dicycle tetraaldehyde and TPE dicycle tetraacids bearing optically pure groups on the cycles were designed and synthesized. Due to the propeller-like conformation immobilization of TPE unit, this new class of TPE dicycle was resolved into M-and P-enantiomers, which could emit strong circular polarized luminescence(CPL). Interestingly,these TPE helicates displayed exceptional ability of molecule recognition. While the TPE dicycle tetraaldehyde could detect the microscale water in anhydrous tetrahydrofuran, the chiral TPE dicycle tetraacid could display different fluorescent color after interacting with two enantiomers of a wide variety of chiral amines including monoamines, diamines, and aminols, which could be applied to chiral recognition of these chiral amines. Furthermore, the emission wavelength of TPE dicycle tetraacid was found to change linearly with the enantiomer purity of chiral amine from enantiomer excess(ee) percent-100% to +100%, for the first time showing the potential for quantitative chiral analysis of chiral amines based on emission wavelength change. The emission wavelength was affected less by environmental factors than fluorescence intensity, which would enable the chiral analysis based on wavelength change with higher accuracy and repeatability.

Suppression of Vortex-Induced Vibration Caused by A Terebridae-Inspired Cylinder with Different Helical Angles

Biomimetic design has recently received widespread attention.Inspired by the Terebridae structure,this paper provides a structural form for suppressing vortex-induced vibration(VIV)response.Four different structural forms are shown,including the traditional smooth cylinder(P0),and the Terebridae-inspired cylinder with the helical angle of 30°(P_(30)),60°(P_(60)),and 90°(P_(90)).Computational fluid dynamics(CFD)method is adopted to solve the flow pass the Terebridae-inspired structures,and the vibration equation is solved using the Newmark-βmethod.The results show that for P_(30),P_(60) and P_(90),the VIV responses are effectively suppressed in the lock-in region,and P_(60) showed the best VIV suppression performance.The transverse amplitude and the downstream amplitude can be reduced by 82.67%and 91.43%respectively for P_(60) compared with that for P0,and the peak of the mean-drag coefficient is suppressed by 53.33%.The Q-criterion vortices of P_(30),P_(60),and P_(90) are destroyed,with irregular vortices shedding.It is also found that the boundary layer separation is located on the Terebridae-inspired ribs.The twisted ribs cause the separation point to constantly change along the spanwise direction,resulting in the development of the boundary layer separation being completely destroyed.The strength of the wake flow is significantly weakened for the Terebridae-inspired cylinder.

Multi-physical fields distribution in billet during helical electromagnetic stirring:A numerical simulation research

Electromagnetic stirring is one of the widely applied techniques to modify the quality of casting billets.Different from conventional rotate stirring,the helical stirring is more professional in assisting multi-dimensional flow of molten metal and eliminating solidification defects.In this study,the single-winding helical stirring(SWHS)was introduced,offering advantages such as smaller volume and lower electromagnetic shielding compared to traditional helical stirring methods.Following a comprehensive numerical simulation,the stirring parameters of SWHS were adjusted to yoke inclination angle of 43°and frequency of 12 Hz.The higher electromagnetic force and flow velocity in drawing direction,as well as the lower temperature gradient induced by the SWHS,are positive factors for homogeneous solidification of billet.The experimental results on Al-8%Si alloy and 0.4%C-1.1%Mn steel demonstrate that compared to rotate stirring,the SWHS process can induce better billet quality and is more effective in accelerating the equiaxed expansion and reducing element segregation.The SWHS process can enhance the equiaxed ratio of the billet by 58.3%and reduce segregation degree of carbon element by 10.97%.Consequently,SWHS holds great promise as a potential approach for improving the quality of continuous casting billets.

Effect of antenna helicity on discharge characteristics of helicon plasma under a divergent magnetic field

The characteristics of the blue core phenomenon observed in a divergent magnetic field helicon plasma are investigated using two different helical antennas, namely right-handed and lefthanded helical antennas. The mode transition, discharge image, spatial profiles of plasma density and electron temperature are diagnosed using a Langmuir probe, a Nikon D90 camera,an intensified charge-coupled device camera and an optical emission spectrometer, respectively.The results demonstrated that the blue core phenomenon appeared in the upstream region of the discharge tube at a fixed magnetic field under both helical antennas. However, it is more likely to appear in a right-handed helical antenna, in which the plasma density and ionization rate of the helicon plasma are higher. The spatial profiles of the plasma density and electron temperature are also different in both axial and radial directions for these two kinds of helical antenna. The wavelength calculated based on the dispersion relation of the bounded whistler wave is consistent with the order of magnitude of plasma length. It is proved that the helicon plasma is part of the wave mode discharge mechanism.

A novel flexible nerve guidance conduit promotes nerve regeneration while providing excellent mechanical properties

Autografting is the gold standard for surgical repair of nerve defects>5 mm in length;however,autografting is associated with potential complications at the nerve donor site.As an alternative,nerve guidance conduits may be used.The ideal conduit should be flexible,resistant to kinks and lumen collapse,and provide physical cues to guide nerve regeneration.We designed a novel flexible conduit using electrospinning technology to create fibers on the innermost surface of the nerve guidance conduit and employed melt spinning to align them.Subsequently,we prepared disordered electrospun fibers outside the aligned fibers and helical melt-spun fibers on the outer wall of the electrospun fiber lumen.The presence of aligned fibers on the inner surface can promote the extension of nerve cells along the fibers.The helical melt-spun fibers on the outer surface can enhance resistance to kinking and compression and provide stability.Our novel conduit promoted nerve regeneration and functional recovery in a rat sciatic nerve defect model,suggesting that it has potential for clinical use in human nerve injuries.

Advancing high-speed train gearbox durability:enhanced bearing load and contact stress through transition from helical to herringbone gears

High-speed trains typically utilize helical gear transmissions,which significantly impact the bearing load capacity and fatigue service performance of the gearbox bearings.This paper focuses on the gearbox bearings,establishing dynamic models for both helical gear and herringbone gear transmissions in high-speed trains.The modeling particularly emphasizes the precision of the bearings at the gearbox's pinion and gear wheels.Using this model,a comparative analysis is conducted on the bearing loads and contact stresses of the gearbox bearings under uniform-speed operation between the two gear transmissions.The findings reveal that the helical gear transmission generates axial forces leading to severe load imbalance on the bearings at both sides of the large gear,and this imbalance intensifies with the increase in train speed.Consequently,this results in a significant increase in contact stress on the bearings on one side.The adoption of herringbone gear transmission effectively suppresses axial forces,resolving the load imbalance issue and substantially reducing the contact stress on the originally biased side of the bearings.The study demonstrates that employing herringbone gear transmission can significantly enhance the service performance of high-speed train gearbox bearings,thereby extending their service life.

Designing Electronic Structures of Multiscale Helical Converters for Tailored Ultrabroad Electromagnetic Absorption

Atomic-scale doping strategies and structure design play pivotal roles in tailoring the electronic structure and physicochemical property of electromagnetic wave absorption(EMWA)materials.However,the relationship between configuration and electromagnetic(EM)loss mechanism has remained elusive.Herein,drawing inspiration from the DNA transcription process,we report the successful synthesis of novel in situ Mn/N co-doped helical carbon nanotubes with ultrabroad EMWA capability.Theoretical calculation and EM simulation confirm that the orbital coupling and spin polarization of the Mn–N4–C configuration,along with cross polarization generated by the helical structure,endow the helical converters with enhanced EM loss.As a result,HMC-8 demonstrates outstanding EMWA performance,achieving a minimum reflection loss of−63.13 dB at an ultralow thickness of 1.29 mm.Through precise tuning of the graphite domain size,HMC-7 achieves an effective absorption bandwidth(EAB)of 6.08 GHz at 2.02 mm thickness.Furthermore,constructing macroscale gradient metamaterials enables an ultrabroadband EAB of 12.16 GHz at a thickness of only 5.00 mm,with the maximum radar cross section reduction value reaching 36.4 dB m2.This innovative approach not only advances the understanding of metal–nonmetal co-doping but also realizes broadband EMWA,thus contributing to the development of EMWA mechanisms and applications.

Numerical Studies on Thermal and Hydrodynamic Characteristics of LNG in Helically Coiled Tube-in-Tube Heat Exchangers

As compact and efficient heat exchange equipment,helically coiled tube-in-tube heat exchangers(HCTT heat exchangers)are widely used in many industrial processes.However,the thermal-hydraulic research of liquefied natural gas(LNG)as the working fluid inHCTT heat exchangers is rarely reported.In this paper,the characteristics of HCTT heat exchangers,in which LNG flows in the inner tube and ethylene glycol-water solution flows in the outer tube,are studied by numerical simulations.The influences of heat transfer characteristics and pressure drops of the HCTT heat transfers are studied by changing the initial flow velocity,the helical middle diameter,and the helical pitch.The results indicate that different initial flow velocities in the inner tube and the outer tube of the HCTT heat exchanger have little influence on the secondary flow of the fluid in the helical tubes,and the overall flow characteristics tend to be stable.The smaller helical middle diameter of the HCTT heat exchanger leads to the shorter fluid flow length,the smaller resistance along the tubes and the increase of initial pressure under the condition of constant inlet velocity,which promotes the occurrence of secondary flow.The axial flow of fluid promotes the destruction of heat transfer boundary layer and gains strength of the turbulence and heat transfer efficiency.With the increase of the helical pitch of the HCTT heat exchanger,the turbulent intensity and the heat transfer efficiency are also increased.Moreover,the improvement of the flow state of the HCTT exchanger in a longer helical pitch also enhances the heat exchange efficiency.

Numerical Simulation of Liquified Natural Gas Boiling Heat Transfer Characteristics in Helically Coiled Tube-in-Tube Heat Exchangers

Helically coiled tube-in-tube(HCTT)heat exchangers are widely applied to the process technology because of their compactness and higher heat transfer efficiency.HCTT heat exchangers play an important role in liquified natural gas(LNG)use and cold energy recovery.The heat transfer characteristics,pressure distribution,and degree of vaporization of LNG in HCTT heat exchangers are numerically investigated.By comparing the simulation results of the computational model with existing experimental results,the effectiveness of the computational model is verified.The numerical simulation results show the vapor volume fraction of the HCTT heat exchanger is related to the inlet Reynolds number,inner tube diameters,and helix diameter.The vapor volume fraction increases rapidly from the fourth to the seventh equal division points of the helix tube length.On condition that the inlet Reynolds number is greater than 33500,the pressure drop rate gradually increases.When the magnitude of the vapor volume fraction is below 0.2,the heat transfer coefficient increase rate is greater than that when the vapor volume fraction is above 0.2.The heat exchange efficiency of HCTT heat exchangers increases with the decrease of the ratio of helix diameter to inner tube diameter.

Mathematical Modelling and Design of Helical Coil Heat Exchanger for Production of Hot Air for Fluidized Bed Dryer

In global industrialization, efforts have been made to increase the rate of heat transfer in heat exchanger, minimizing the size of heat exchanger to reduce cost as well as increasing the effectiveness. Helical coil heat exchanger (HCHE) has been proven to be effective in improving heat transfer due to its large surface area. In this study, HCHE was designed to provide hot air needed for fluidized bed drying processes. The HCHE design model was fabricated and evaluated to study the efficiency of the hot air output for a laboratory fluidized bed dryer. The mathematical model for estimation of the final (output) temperature of air, Taf, passing through the HCHE was developed and validated experimentally. The drying of bitter kola particulates was carried out with a drying temperature of 50C 3C and a bed height-to-bed diameter ratio (H/D) of 1.5. The time taken to dry bitter kola particulates to 0.4% moisture content was 1 hour 45 minutes. Hence, HCHE is recommended for use in the production of hot for laboratory-scale fluidized bed dryers.

海上风电螺旋桩侧向承载能力分析

The rapid development of offshore wind power and the need to move to deeper sea areas while reducing costs per kilowatt necessitate the employment of a new jacket and helical pile combination.This new combination combines the advantages of both jacket structures and helical piles and provides a superior bearing capacity and installation efficiency compared to conventional pile foundations.Foundations account for 25%-34%of the overall cost of construction,but the use of this new foundation would be highly significant for the further development of offshore wind power.This study presents numerical results for the horizontal bearing capacity when horizontal displacement is applied,focusing on the bearing capacity and characteristics of the helical pile jacket foundation as well as the differences between the bearing mechanisms and failure modes of normal pile and helical pile types.ABAQUS model parameters are obtained through trial calculations based on actual engineering data,and the finite element model(FEM)is validated using data from a model experiment.Subsequently,different FEMs are established,and numerical results are compared and presented.Through a comparison between a normal pile jacket foundation and a helical pile jacket foundation with different helical blade numbers,the differences in the bearing mechanisms and failure modes are revealed.The failure of the normal pile jacket foundation is instantaneous and sudden,whereas that of the helical pile foundation is incremental and accumulative.These data highlight the most significant contributions and vulnerabilities of the one-pile side of the foundation and suggest that the addition of blades on the one-pile side is the most effective way of improving the foundation’s bearing performance.In addition,the interaction between the compression side and tension side is analyzed in relation to differing the relative magnitudes of their bearing capacities.

Quantum control of ultrafast magnetic field in H_(3)^(2+)molecules by tricircular polarized laser pulses

We present a scheme to control the generated ultrafast magnetic field in H_(3)^(2+)molecules using multi-frequency tricircular pulses composed of co-and counter-rotating bicircular pulses.Simulations show that the field amplitude and the wavelength are two significant factors for magnetic field generation by tricircular pulses.Specifically,the strength of the magnetic field is linearly related to the field amplitude atλ_(0)=50 nm,while atλ_(0)=70 nm,the strength first increases and then decreases with the amplitude,this can be attributed to the resonance between the ground and excited states.Moreover,the phase and helicity of bicircular pulses are shown to have important effects on the magnetic field.The dependence of the magnetic field on the phase arises from the interference effect between multiple ionization pathways.These findings illustrate a guiding principle for controlling the magnetic field in molecular systems for future research in ultrafast magneto-optics.

Helically symmetric equilibria for some ideal and resistive MHD plasmas with incompressible flows

In this paper, the problem of finding exact solutions to the magnetohydrodynamic(MHD) equations in the presence of incompressible mass flows with helical symmetry is considered. For ideal flows, a similarity reduction method is used to obtain exact solutions for several MHD flows with nonlinear variable Mach number. For resistive flows parallel to a magnetic field, the governing equilibrium equation is derived. The MHD equilibrium state of a helically symmetric incompressible flow is governed by a second-order elliptic partial differential equation(PDE) for the helical magnetic flux function. Exact solutions for the latter equation are obtained. Also, the equilibrium equations of a gravitating plasma with incompressible flow are derived.

Failure Envelopes of Single-Plate Rigid Helical Anchors for Floating Offshore Wind Turbine

Helical anchor is a kind of novel foundation for floating offshore wind turbines,which should be subjected to combined tensile loading caused by wind,wave and current.However,the research about the capacity of helical anchor was mainly examined under uniaxial loading and scarcely explored under combined loading.In this study,three-dimensional finite element limit analysis is adopted to assess the bearing capacities of single-plate rigid helical anchors with different ratios of helix to shaft diameter,D_(H)/D_(S) and embedment ratios L/D_(S).Result shows that the vertical,horizontal and moment bearing capacities increase with increasing D_(H)/D_(S) and L/D_(S).The normalized V-H failure envelopes expands with increasing L/D_(S),while the normalized V-M failure envelopes tend to contract with the increase of D_(H)/D_(S).With increasing D_(H)/D_(S) or decreasing L/D_(S),the normalized H-M failure envelopes expand when the horizontal and moment loading act in the same direction and contract when they act in the opposite direction.The effect of D_(H)/D_(S) and L/D_(S) on the shape of H-M failure envelope become insignificant when L/D_(S)≥4.A series of failure mechanisms under different loading conditions were observed and can be used to explain the trend.Besides,a series of approximate expressions were proposed to fit the uniaxial bearing capacities and the failure envelopes.

Influence of magnetic field on power deposition in high magnetic field helicon experiment

Based on high magnetic field helicon experiment(HMHX), HELIC code was used to study the effect of different magnetic fields on the power deposition under parabolic distribution. This paper is divided into three parts: preliminary calculation, actual discharge experiment and calculation. The results of preliminary calculation show that a magnetic field that is too small or too large cannot produce a good power deposition effect. When the magnetic field strength is 1200 Gs,a better power deposition can be obtained. The actual discharge experiment illustrates that the change of the magnetic field will have a certain influence on the discharge phenomenon. Finally, the results of verification calculation successfully verify the accuracy of the results of preliminary simulation. The results show that in the actual discharge experiment, it can achieve the best deposition effect when the magnetic field is 1185 Gs.

Improving energy storage by PCM using hybrid nanofluid[(SWCNTs-CuO)/H_(2)O]and a helical(spiral)coil:Hybrid passive techniques

The aim of this study is the numerical analysis of the melting process of the phase change material(PCM)in a spiral coil.The space between the inner tube and outer shell is filled with RT-50 as PCM.Moreover,the hybrid nanofluid(with a carbon component)flows through the inner tube.The novelty of this work is to use different configurations of fin and different percentage of hybrid nanoparticles(SWCNTs-Cu O)on the PCM melting process.In the numerical model created by ANSYS-Fluent,the effect of various inlet temperatures is investigated.The results indicate that the extended surface created by extra fin has a dominant effect on melting time,so by adding the third fin,the melting time is reduced by 39.24%.The next most influential factor in PCM melting is the inlet temperature of the working fluid,so that 10°C increment of temperature result in the PCM melting time decreased by 35.41%.

Multi-objective Optimization of a Two-Stage Helical Gearbox to Improve Efficiency and Reduce Height

The goal of this research is to look at multi-target optimization of a two-stage helical gearbox in order to determine the best key design elements for reducing gearbox height and enhancing gearbox efficiency.To do this,the method known as Taguchi and GRA(Grey Relation Analysis)were used in two stages to address the problem.The single-objective optimization problem was addressed first to close the gap between variable levels,and then the multi-objective optimization problem was solved to determine the best primary design variables.The first and second stage CWFWs(Coefficients of Wheel Face Width),ACS(Permissible Contact Stresses),and first stage gear ratio were also calculated.The study’s findings were utilized to identify the best values for five critical design aspects of a two-stage helical gearbox.

A new heat transfer correlation for flow boiling in helically coiled tubes

Based on the superposition principle of the nucleate boiling and convective heat transfer terms,a new correlation is developed for flow boiling heat transfer characteristics in helically coiled tubes.The effects of the geometric and system parameters on heat transfer characteristics in helically coiled tubes are investigated by collecting large amounts of experimental data and analyzing the heat transfer mechanisms. The existing correlations are divided into two categories,and they are calculated with the experimental data.The Dn factor is introduced to take into account the effect of a complex geometrical structure on flow boiling heat transfer.A new correlation is developed for predicting the flow boiling heat transfer coefficients in the helically coiled tubes,which is validated by the experimental data of R134a flow boiling heat transfer in them;and the average relative error and root mean square error of the new correlation are calculated.The results show that the new correlation agrees well with the experimental data,indicating that the new correlation can be used for predicting flow boiling heat transfer characteristics in the helically coiled tubes.

Analysis of the Formation Mechanism of One Cloudburst in Shandong Province

Through analyzing influence system,trigger mechanism,stability and helicity of the cloudburst on Jul.2nd to 3rd in 2006 in Shandong Province,it is showed that the cloudburst is produced by shear line in 850 hPa and ground Huanghuai cyclone.Convergence lifting movement in shear line and north of cyclone trigger release of unstable energy,and southwest wind jet stream in low altitude provide sufficient water vapor and unstable energy.

Helical Bulbous Loop推上颌磨牙向远中移动的临床应用

[目的]用Helical bulbous loop远中移动上颌磨牙,探寻该技术的临床效果以及操作要点和优势。[方法]对磨牙关系为Ⅱ类,牙列为中度拥挤,牙体牙周健康的20例正畸患者,采用该技术推上颌磨牙远中移动,测量移动的距离,每月加力1次,观察3个月。[结果]所有正畸患者的磨牙远中移动效果显著,平均每月移动1.12 mm,3个月共移动最大量为3.48 mm,最小量为3.06 mm。[结论]该技术临床效果显著,操作简单,相对于其他技术优势明显,值得临床推广使用。