A ditopic ligand bpy-cyclam(L)and its heterometallo-binuclear complex Ru(bpy)_2(bpy-cyclam-Ni)(ClO_4)_43H_2O(3)designed for use in the catalytic photoreduction of carbon dioxide have been newly synthesized and charact...A ditopic ligand bpy-cyclam(L)and its heterometallo-binuclear complex Ru(bpy)_2(bpy-cyclam-Ni)(ClO_4)_43H_2O(3)designed for use in the catalytic photoreduction of carbon dioxide have been newly synthesized and characterized.The protonation constants of L were also determined.展开更多
文摘A ditopic ligand bpy-cyclam(L)and its heterometallo-binuclear complex Ru(bpy)_2(bpy-cyclam-Ni)(ClO_4)_43H_2O(3)designed for use in the catalytic photoreduction of carbon dioxide have been newly synthesized and characterized.The protonation constants of L were also determined.
