Studied the harmonic control of the 6 kV power grid in a coal mine substation.Taking harmonic suppression and reactive power compensation into account, and complyingwith the economic and efficient technical line of th...Studied the harmonic control of the 6 kV power grid in a coal mine substation.Taking harmonic suppression and reactive power compensation into account, and complyingwith the economic and efficient technical line of the smart grid, a new hybrid activefilter was proposed and applied to the power grid in the coal mine with the advantagessuch as large capacity, low cost and low loss.In order to improve detection speed and reducethe succeeding errors to improve the filtering performance of the active power filter,the DFT (Discrete Fourier Transform) sliding window algorithm based on coordinatetransformation and improved hysteresis control method was proposed.The Matlab simulationresults show that the hybrid active filter is satisfactory, can improve the grid powerfactor and can meet the requirements of improving the power quality in the coal mine.展开更多
In this study, in order to explain the solvent and spin state effects on the molecular structure of catechol-Fe complex [Fe(cat)3]n﹣?where n = 2 and 3, Hartree Fock (HF)-Density Functional Theory (DFT) hybrid calcula...In this study, in order to explain the solvent and spin state effects on the molecular structure of catechol-Fe complex [Fe(cat)3]n﹣?where n = 2 and 3, Hartree Fock (HF)-Density Functional Theory (DFT) hybrid calculations are performed at the B3LYP/6-311g(d,p) level of theory. The binding energies of Fe2+ and Fe3+ in high-spin state are higher than intermediate and low-spin states which show that the complex formation in a high spin state is more favorable. The calculated binding energies at different solvents indicate that the binding energies in polar solvents are lower than non-polar solvents. Furthermore, spectroscopic studies including FTIR and Raman spectrum in various solvents reveal that the formation of intermolecular bonds between the oxygen atom of carbonyl group and the hydrogen atom of solvent causes a spectral red shift. The calculated FTIR and geometry parameters are in good agreement with previous experimental data. Donor-acceptor interaction energies are evaluated due to the importance of the charge transfer in the complex formation. It is observed that the free electrons of oxygen atom interact with the antibonding orbitals of the iron. Finally, some correlations between the quantum chemical reactivity indices of the complexes and solvent polarity are considered. The study indicates a linear correlation between chemical hardness and binding energies of [Fe(cat)3]3﹣?complex.展开更多
文摘Studied the harmonic control of the 6 kV power grid in a coal mine substation.Taking harmonic suppression and reactive power compensation into account, and complyingwith the economic and efficient technical line of the smart grid, a new hybrid activefilter was proposed and applied to the power grid in the coal mine with the advantagessuch as large capacity, low cost and low loss.In order to improve detection speed and reducethe succeeding errors to improve the filtering performance of the active power filter,the DFT (Discrete Fourier Transform) sliding window algorithm based on coordinatetransformation and improved hysteresis control method was proposed.The Matlab simulationresults show that the hybrid active filter is satisfactory, can improve the grid powerfactor and can meet the requirements of improving the power quality in the coal mine.
文摘In this study, in order to explain the solvent and spin state effects on the molecular structure of catechol-Fe complex [Fe(cat)3]n﹣?where n = 2 and 3, Hartree Fock (HF)-Density Functional Theory (DFT) hybrid calculations are performed at the B3LYP/6-311g(d,p) level of theory. The binding energies of Fe2+ and Fe3+ in high-spin state are higher than intermediate and low-spin states which show that the complex formation in a high spin state is more favorable. The calculated binding energies at different solvents indicate that the binding energies in polar solvents are lower than non-polar solvents. Furthermore, spectroscopic studies including FTIR and Raman spectrum in various solvents reveal that the formation of intermolecular bonds between the oxygen atom of carbonyl group and the hydrogen atom of solvent causes a spectral red shift. The calculated FTIR and geometry parameters are in good agreement with previous experimental data. Donor-acceptor interaction energies are evaluated due to the importance of the charge transfer in the complex formation. It is observed that the free electrons of oxygen atom interact with the antibonding orbitals of the iron. Finally, some correlations between the quantum chemical reactivity indices of the complexes and solvent polarity are considered. The study indicates a linear correlation between chemical hardness and binding energies of [Fe(cat)3]3﹣?complex.
