The multiphoton ionization dissociation of HFC 152a and HFC 134a under the irradiation of 355 nm and 266 nm was studied in this work. Their photolyzed products were analyzed by time of flight mass spectrum instrument....The multiphoton ionization dissociation of HFC 152a and HFC 134a under the irradiation of 355 nm and 266 nm was studied in this work. Their photolyzed products were analyzed by time of flight mass spectrum instrument. The photolyzed products of HFC 152a include H +( m/z =1), C +( m/z =12), CH + 3( m/z =15), C + 2( m/z =24), CF 2H +( m/z =51), and CF +( m/z =31), whereas there is no clear products for HFC 134a photolyzation. Further, the application prospects of HFC 152a and HFC 134a in refrigeration sector were also evaluated from the view point of environmental protection, synthesis conditions and usage performance. It is suggested that HFC 152a is a better alternative compared to HFC 134a in refrigeration sector.展开更多
HFC-134a被认为是取代CFC-12的较为理想的替代工质。国外近两年公开发表的HFC-134a的饱和蒸气压数据,主要包括Wilson et al.,Piao et al.,Kubota,Weber等发表的四组数据,这四组数据的温度范围、精度等各不相同。他们同时发表的蒸气压方...HFC-134a被认为是取代CFC-12的较为理想的替代工质。国外近两年公开发表的HFC-134a的饱和蒸气压数据,主要包括Wilson et al.,Piao et al.,Kubota,Weber等发表的四组数据,这四组数据的温度范围、精度等各不相同。他们同时发表的蒸气压方程是在各自数据的基础上拟合而成,精度和适用范围也不一样,其概况见表1。展开更多
文摘The multiphoton ionization dissociation of HFC 152a and HFC 134a under the irradiation of 355 nm and 266 nm was studied in this work. Their photolyzed products were analyzed by time of flight mass spectrum instrument. The photolyzed products of HFC 152a include H +( m/z =1), C +( m/z =12), CH + 3( m/z =15), C + 2( m/z =24), CF 2H +( m/z =51), and CF +( m/z =31), whereas there is no clear products for HFC 134a photolyzation. Further, the application prospects of HFC 152a and HFC 134a in refrigeration sector were also evaluated from the view point of environmental protection, synthesis conditions and usage performance. It is suggested that HFC 152a is a better alternative compared to HFC 134a in refrigeration sector.
基金Project (SJ08-ZT05) supported by the Natural Science Basic Research Plan in Shaanxi Province of ChinaProject (ZK1050) supported by the Key Scientific Research Plan of Baoji University of Arts and Science, China
文摘HFC-134a被认为是取代CFC-12的较为理想的替代工质。国外近两年公开发表的HFC-134a的饱和蒸气压数据,主要包括Wilson et al.,Piao et al.,Kubota,Weber等发表的四组数据,这四组数据的温度范围、精度等各不相同。他们同时发表的蒸气压方程是在各自数据的基础上拟合而成,精度和适用范围也不一样,其概况见表1。
